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Overview of Electron Beam Lithography

This document discusses electron beam lithography (EBL), including its patterning techniques, types of EBL, applications, and future opportunities. It describes optical lithography and nanoimprinting as other patterning techniques. For EBL, it discusses electron beam direct write and electron projection lithography. It covers electron beam resists and their properties. Applications of EBL include nanopatterning, nanowires, gratings, and nanofluidic channels. Future opportunities include double gate FinFET devices and single electron transistors.

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100% found this document useful (1 vote)
2K views39 pages

Overview of Electron Beam Lithography

This document discusses electron beam lithography (EBL), including its patterning techniques, types of EBL, applications, and future opportunities. It describes optical lithography and nanoimprinting as other patterning techniques. For EBL, it discusses electron beam direct write and electron projection lithography. It covers electron beam resists and their properties. Applications of EBL include nanopatterning, nanowires, gratings, and nanofluidic channels. Future opportunities include double gate FinFET devices and single electron transistors.

Uploaded by

kaushik4208
Copyright
© Attribution Non-Commercial (BY-NC)
We take content rights seriously. If you suspect this is your content, claim it here.
Available Formats
Download as PPT, PDF, TXT or read online on Scribd
  • Electron Beam Lithography
  • Overview
  • Patterning Techniques
  • Electron Beam Lithography
  • Applications of EBL
  • Future Opportunities for EBL

Electron Beam Lithography

• Patterning techniques

• The electron beam lithography

• Applications of the EBL

• Future oportunities for EBL


Patterning Techniques

Criteriums about different techniques

Resolution
Speed
Easy fabrication
Cost
Patterning Techniques

[Link] LITHOGRAPHY

a) Deep Ultarviolet Lithography


b) Extreme Ultraviolet Lithography
c) X Rays

2. NANOIMPRINT
1) Optical Lithography

• Photoresistive resine

• Patterns: Masks

• Wavelenght
resolution dependant
Resolution Limits
• Contact

Advantages:


Good resolution

Drawbacks:


Masks thin and flexible

Use ->defects
Resolution Limits
• Proximity

Advantages:


Masks lifetime high

Drawbacks:


Resolution not as good
Gap ●
Diffraction
~ 20-50 μm

Fresnel diffraction
Resolution Limits
• Projection

Advantages:


Good resolution

No deterioration

Image smaller than mask

Drawbacks:


Fraunhoffer diffraction

Compromise between resolution
and depth of focus
b) Extreme Ultraviolet Lithography
• Small wavelenght
Better resolution

• No lences: mirrors

• Laser plasma
sources

• 10 nm
c) X Ray
• < 1nm for Medical purposes

• Problems of masks
• Lences, mirrors

• Difficult to produce
2) Nanoimprint
• 2 techniques:

Heat resine
Cool down

UV radiations
Patterning Techniques
EUV soon in fabrication

Nanoimprint
E beam
for 22nm

X Rays
difficult
The electron beam lithography
• Types of EBL
 Electron Beam Direct Write
 Electron Projection Lithography

Bragg-Fresnel lens for x-rays Paul Scherrer Institute


Electron Beam Direct Write
• An electron gun or
electron source that
supplies the electrons.
• An electron column that
'shapes' and focuses the
electron beam.
• A mechanical stage that
positions the wafer
under the electron
beam.
• A wafer handling system
that automatically feeds
wafers to the system
and unloads them after
processing.
• A computer system that
controls the equipment.
Electron Beam Direct Write
Types of electron guns
• Thermoionic
• Field emission

Write-field (WF)

Scanning methods
• Raster scan
• Vector scan

Raith 150 Manual (Nanostructure Physics Dept. KTH) Anders Liljeborg


Specifications, a real example
Raith150
• Beam size  ≤  2nm @
20 keV
• Beam energy 100eV -
30 keV
• Minimum line width
20 nm
• Import file format
GDSII, DXF, CIF,
ASCII, BMP
Electron Projection
Electron Beam LithographyLimited throughput
Direct Write

Electron Projection Huge penetration


Lithography depth of electrons

• SCALPEL (Bell
Laboratories and
New solutions Lucent technologies)
1995
• PREVAIL (IBM) 1999
Electron Projection
Lithography
• SCALPEL
– High contrast
– Image reduction

• PREVAIL
– Larger effective field
Electron beam resists
1. Important parameters
2. Types of resist
3. Resist limitations
EBL resists

Important parameters
 Resolution (nm)
 Sensitivity (C/cm^2)

Types of resist
• Positive resist
Polymethyl methacrylate
(PMMA)
• Negative resist

Recent progress in electron-beam resists for advanced mask-making by [Link], [Link],


[Link], [Link], [Link], [Link], [Link], [Link], [Link], and [Link]
Resist limitations
• Tendency of the resist to swell in
the developer solution.

• Electron scattering within the


resist.
– Broadens the diameter of the incident
electron beam.
– Gives the resist unintended extra
doses of electron exposure .
Applications of Electron Beam Lithography

• Research
- Nanopatterning on Nanoparticles
- Nanowires
- Nanopillars
- Gratings
- Micro Ring Resonators
- Nanofluidic Channels

• Industrial / Commercial
- Exposure Masks for Optical Lithography
- Writing features
Nanopatterning on
• Significance nanoparticles
- Photonic Crystals
- Quantum Dots
- Waveguides

• Electron Beam Lithography


- Fine writing at moderate electron energies
- 37nm thick lines with 90nm periodicity
- 50nm diameter dots with 140nm periodicity

(2003), Patterning of porous Silicon by Electron Beam Lithography, S. Borini, A. M. Rossi, L. Boarino, G. Amato
Nanowires
• Applications
- High-Density Electronics (Sensors, Gates in FETs)
- Molecular Electronics & Medical/Biological Applications

• EBL with Electrochemical size reduction


- High-Resolution Controlled Fabrication
- Widths approaching 10nm regime

• Patterning of Films of Gold Nanoclusters with Electron


Beam Direct Write Lithography
- Sub 50nm wide Nanowires
- Controlled thickness at single particle level

Controlled Fabrication of Silicon Nanowires by Electron beam lithography and Electro- chemical size
reduction (2005), Robert Juhasz, Niklas Elfstrom and Jan Linnros
Nanometer Scale Petterinng of Langmuir-Blodgett Films of Gold Nanoparticles by Electron Beam
Lithography (2001), Martinus H.V Werts, Mathieu Lambert, Jean-Philippe Bourgoin and Mathias Brush
Nanopillars
• Significance
- Quantum Confinement Effects
- Photoconductive response in Nanopillar arrays

• EBL and Reactive Ion Etching


- Etched Pillars with 20nm diameter

Nanotechnology using Electron Beam Lithography, Center for Quantum Devices


Gratings
• Applications
- Distributed Feedback Lasers
- Vertical Cavity Surface Emitting Lasers

• Continuous Path Control Writing using EBL


- Avoids stitching errors

Nanotechnology using Electron Beam Lithography, Center for Quantum Devices



Micro Ring Resonators
Applciations
- Optical Telecommunication and Networks

• EBL and Dry Etching


- 105 devices/cm2 density

Nanotechnology using Electron Beam Lithography, Center for Quantum Devices



Nanofluidic Channels
Significance
- Laboratory on a chip
- Single Molecule Detection

• Electron Beam Lithography


- Single step planar process
- Tubes with inner dimension of 80nm

(2005) A single-step process for making nanofluidic channels using electron beam lithography, J. L. Pearson
and D. R. S. Cumming
Industrial Applications

• Exposure Masks for Optical Lithography using EBL

• Writing Features
Some Applications of E-Beam
Lithography
• Cryo-electric devices
• Optoelectronic devices
• Quantum structures
• Multi-gate Devices
• Transport mechanism for semi and superconductor
interfaces
• Optical devices
• Magnetism
• Biological Applications
– Nano-MEMS
– Nanofluidics
Future opportunities for electron beam
lithography

1. Double gate FinFET devices


2. Single electron transistors
3. Photonic crystals
Double gate FinFET devices - Concept
• Principle
Full control over a very
thin body region by two gates

• Fabrication thanks to e-beam


- Beam diameter smaller than 2nm
- Low energy (5 keV)
- High resolution organic resist
- Overlay accuracy thanks to scanning of registration marks
- Silicon etching

20 nm electron beam lithography and reactive ion etching for the fabrication of double gate FinFET
devices (2003), J. Kretz , L. Dreeskornfeld, J. Hartwich, W. Rosner
Nanoscale FinFETs for low power applications (2004), W. Rösner, E. Landgraf, J. Kretz, L. Dreeskornfeld, H.
Schäfer, M. Städele,T. Schulz, F. Hofmann, R.J. Luyken, M. Specht, J. Hartwich, W. Pamler, L. Risch
Double gate FinFET devices –
Characteristics & Applications

• High performance devices


Transfer characteristic similar to
those obtained with bulk transistors
Appl: SRAM because high density
+ capability of driving a large bitline load

• Low power applications


High on-current, very low off-current

Nanoscale FinFETs for low power applications (2004), W. Rösner, E. Landgraf, J. Kretz, L. Dreeskornfeld, H.
Schäfer, M. Städele,T. Schulz, F. Hofmann, R.J. Luyken, M. Specht, J. Hartwich, W. Pamler, L. Risch
Single electron transistor - Concept
• Physic principle
Weak external force to bring an additional
electron to a small conductor “island”
=> Repulsing electric field

• SET concept
- Down-scaling
- Low power consumption

• Difficulties
- Need of very small “islands” because
the addition energy must overload the
temperature effects

- Polarization in case of impurities


=> randomness background charge
Single-Electron Devices and Their Applications (1999), Konstantin K. Likharev
Single electron transistor -
• Classic technique
Fabrication
Smallest “island” needed
=> Use of high resolution lithography technique
=> E-beam lithography

• With silicon nanowires


Lithography with e-beam, with specific beam current density and dose

Results: single electron charging effect


Polysilicon grain = “islands”
Grain boundaries = mini tunnel barriers

Fabrication of silicon nanowire structures based on proximity effects of electron-beam lithography


(2003), S.F. Hua, W.C. Wengb, Y.M. Wanb
Single electron transistor -

Applications
Supersensitive electrometry
Very small change of gate voltage
=> measurable variation of I
Very useful for physical experiments

• Single electron spectroscopy NO !!!


• Replacing MosFET?

• Random access memory


- Bit stored in large conductive
island (floating gate)
- Need of a sense amplifier
=> association with FET amplifier
- Very impressive density: 1011 bit/cm
Single-Electron Devices and Their Applications (1999), Konstantin K. Likharev
Photonic crystals - Concept
• Aim: propagation of light in a controllable
manner

• => Optical “chips” with waveguides,


cavities, mirrors, filters…
Example of very compact quantum
optical integrated circuit:

• Need of a dielectric or metallic lattice, with


adjustable parameters: geometry, dielectric
constant…
Three-dimensional photonic crystals operating at optical wavelength region (2000), Susumu Noda
2D photonic crystals
• Creation of the desired lattice
- With e-beam lithography at low beam energy (5keV)
- Negative resist. Ex: SU8-2000, with high refractive index (1,69) and
good mechanical stability

• Results
A few mode are allowed to propagate, depending of the photonic crystal
parameters

Two-dimensional photonic crystal waveguide obtained by e-beam direct writing of SU8-2000


photoresist (2004), M. De Vittorio, M.T. Todaro, T. Stomeo, R. Cingolani, D. Cojoc, E. Di Fabrizio
3D photonic crystals
• Several methods to create the lattice
- Wafer-fusion and alignment
technique
Ex: Layers of III-V semiconductors (AlGaAs…)

- XRay and e-beam lithography

• Introduction of defect states, light emitting elements…)


By wafer-fusion, two-resist process…

Three-dimensional photonic crystals operating at optical wavelength region (2000), Susumu Noda
XRay and e-beam lithography of three dimensional array structures for photonics (2004), F. Romanato,
E. Di Fabrizio,M. Galli

Common questions

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Future opportunities for electron beam lithography (EBL) center on its potential to drive advancements in fabrication technology for cutting-edge semiconductor and photonic devices, including double gate FinFETs, single electron transistors, and photonic crystals . EBL offers the ability to pattern features smaller than 2 nm with high resolution, which is crucial for pushing the boundaries of device miniaturization and improving performance . It can contribute significantly to low-power electronics, ultra-dense data storage, and advanced optical components . However, to fully exploit these opportunities, several challenges must be addressed: the technique's low throughput limits its scalability for high-volume manufacturing, and the high costs associated with EBL systems can be prohibitive . Additionally, overcoming electron scattering and resist sensitivity limitations is critical for enhancing pattern accuracy and resolution . Addressing these challenges requires ongoing research into faster e-beam writing strategies, more efficient resists, and hybrid lithography processes to complement EBL's strengths .

Finer resolutions provided by electron beam lithography (EBL) can significantly benefit various industrial applications, particularly those requiring nanoscale precision and complexity. In semiconductor manufacturing, EBL is crucial for next-generation device fabrication such as quantum dots, FinFETs, and single electron transistors, where scaling down the feature size enhances performance and energy efficiency . In photonics, it enables the creation of photonic crystals and advanced optical devices with precise control over light propagation, which is essential for developing compact and efficient optical communication networks. Furthermore, in the realm of biotechnology, EBL can be applied to produce nanofluidic channels and nano-MEMS devices for single-molecule detection and lab-on-a-chip applications, promising advancements in diagnostic and analytical tools . However, the low throughput of EBL remains a limiting factor for its widespread industrial adoption and requires innovative optimization for production scaling .

The key advantages of using electron beam lithography (EBL) in creating photonic crystals include its ability to offer high precision and control over the patterning of complex geometries at the nanoscale, which is essential for the fabrication of photonic crystals that require precise periodic structures to manipulate light effectively . The flexibility in design that EBL provides helps in achieving desired optical properties by accurately adjusting the lattice parameters, such as geometry and dielectric constant . However, challenges include the time-intensive nature and low throughput of the EBL process, which makes it less suitable for large-scale production . Additionally, electron scattering can affect the quality of the patterned features, necessitating careful optimization of process parameters like beam energy and resist thickness to maintain the required resolution and pattern fidelity . These challenges must be managed to fully exploit EBL's potential in producing functional and efficient photonic crystal structures.

Electron scattering within the resist is a significant limitation in electron beam lithography as it affects the precision and quality of the final pattern. As electrons penetrate the resist, they scatter both elastically and inelastically, broadening the addressed area beyond the intended focus. This broadening results in unintended exposure of the resist, effectively widening the diameter of the incident electron beam. Consequently, this broadening leads to a decrease in resolution and can cause overlaps and unintended pattern features, thus affecting the fidelity of the lithographic process . Additionally, electron scattering contributes to an uneven dose distribution, increasing the complexity of achieving accurate pattern profiles . Mitigating these effects requires precise control of electron dose, resist sensitivity adjustments, and sometimes the use of thinner resists to limit scattering .

The use of a negative resist such as SU8-2000 in electron beam lithography for photonic crystal applications is important due to its excellent mechanical properties and high refractive index. SU8-2000 provides good stability and adherence to substrates, which are essential for maintaining the integrity of the finely structured photonic crystals throughout the fabrication process . Its high refractive index (around 1.69) is particularly beneficial for photonic applications because it enhances the contrast between the patterned features and the surrounding material, a crucial factor for effective light propagation and confinement. Furthermore, SU8-2000's ability to create high aspect ratio structures with excellent feature fidelity is vital for ensuring the precise geometrical configuration needed to achieve specific photonic bandgap properties . Although it can pose challenges in terms of resolution, careful optimization of the exposure and development process helps harness its advantages in nanofabrication applications .

Double gate FinFET devices fabricated by electron beam lithography are significant for low-power applications due to their superior electrical characteristics compared to traditional bulk transistors. The double gate structure allows for better control over the channel, reducing leakage currents and providing high on-current and very low off-current, which is ideal for energy-efficient operation in electronics . This makes them particularly useful in static random-access memory (SRAM) applications, where high density and the capability of driving large bitline loads are beneficial . The precision of electron beam lithography enables the fabrication of these devices with nanoscale thickness and high resolution, essential for achieving the desired electrical performance . Moreover, EBL's ability to create small feature sizes allows the continued down-scaling of these devices, which is critical for enhancing device performance and maintaining Moore's Law .

Electron beam lithography (EBL) offers significantly higher resolution compared to traditional optical lithography, which is limited by the diffraction limit of light. EBL can achieve resolutions as small as a few nanometers due to the much shorter wavelengths of electrons . This allows it to be used in applications requiring extremely fine patterning, such as the fabrication of photonic crystals, quantum dots, and other nanostructures . However, optical lithography, including techniques such as deep ultraviolet and extreme ultraviolet lithography, is still favored for mass production due to its higher speed and lower cost per unit area, although it provides less resolution compared to EBL . EBL's low throughput makes it more suitable for research settings and small-scale production where precision is critical .

Electron beam lithography (EBL) plays a significant role in the production of nanofluidic channels, which are vital for biomedical applications such as single-molecule detection and lab-on-a-chip devices. EBL's ability to offer high precision and control in patterning enables the creation of extremely small channel structures, such as tubes with inner dimensions as small as 80 nm, allowing for the manipulation and analysis of single molecules . This precision is critical for facilitating targeted biomedical diagnostics and analytical procedures at the nanoscale, which is increasingly important for personalized medicine and molecular biology . The versatility of EBL also allows for the integration of these nanofluidic channels into complex devices, enhancing their capability and functional diversity. However, the high costs and low throughput of EBL pose challenges for large-scale industrial application . Nonetheless, its contribution to advancing microfluidic technology continues to open new avenues for research and clinical applications .

Electron Beam Direct Write (EBDW) and Electron Projection Lithography (EPL) are both methods used in electron beam lithography, but they differ significantly in their approach and performance. EBDW uses a highly focused electron beam to draw patterns directly onto a resist-coated substrate, allowing for high precision and resolution in nanofabrication. This method is advantageous for its flexibility and ability to pattern a variety of complex geometries . However, it suffers from low throughput due to the serial nature of patterning, which limits its use in mass production . On the other hand, EPL employs the projection of a patterned electron beam through a mask onto the substrate. This allows for higher throughput compared to EBDW as it can transfer the pattern in parallel over a larger area, similar to photolithography. EPL is thus more suited for high-volume production . Despite its higher throughput, EPL's resolution is generally lower than that achievable with EBDW due to electron-optical inaccuracies and limitations .

Electron beam lithography (EBL) facilitates the development of nanoscale FinFETs by enabling the precise patterning of extremely small and complex geometries required for these devices. The ability to produce features smaller than 20 nm with high accuracy aids in achieving excellent gate control, which is crucial for minimizing leakage currents and improving transistor performance . This precision is essential for FinFETs, as the control of current flow in these devices involves multiple gates covering the conductive fin, requiring accurate alignment and dimension control . The implications for future semiconductor technologies are profound, as EBL's role in fabricating FinFETs supports continued device scaling, aligning with Moore's Law, and facilitating the development of low-power, high-performance integrated circuits . This technology is set to bolster advancements in high-density memory storage and computing applications, where space and power-saving features are paramount .

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