13-03-2025

1201CJA1010212400116 JM

PART-1 : PHYSICS

SECTION-I

1) A microscope is focused on an object at the bottom of a bucket, if liquid with refractive index is
poured inside the bucket, then microscope have to be raised by 30cm to focus the object again. The
height of the liquid in the bucket is:

(A) 75cm
(B) 50cm
(C) 18cm
(D) 12cm

2) The ratio of wavelength of spectral lines Hα and Hβ in the Balmer series is . The value of x
is_____

(A) 27
(B) 34
(C) 45
(D) 56

3) If the electric flux entering and leaving an enclosed surface respectively is ϕ1 and ϕ2, the electric
charge inside the surface will be

(A)

(B)

(C)

(D)

4) Three bodies A, B and C of masses respectively are supplied heat at a constant

rate. The change in temperature θ versus time t graph for A, B and C are shown by I, II and III
respectively. If their specific heat capacities are SA, SB and SC respectively, then which of the
following relations is correct? (Initial temperature of the body is 0oC)

(A) SA > SB > SC

(B) SB = SC < SA
(C) SA = SB = SC
(D) SB = SC > SA

5) To construct an OR gate the number of NAND gates required is

(A) 2
(B) 3
(C) 4
(D) 1

6) Dimensional formula of mobility is

(A) ML2IT2
(B) M–1I–1T–1
(C) M–1T2I–1
(D) M–1T2I

7) The work function of a metal 12.4 eV. The wavelength of photon that can initiate photo electric
effect is

(A) 1200 Ao
(B) 990 Ao
(C) 1330 Ao
(D) 1440 Ao

8) The two light beams having intensities I and 9I interfere to produce a fringe pattern on a screen.

The phase difference between the beams is at point P and π at point Q. Then the difference
between the resultant intensities at P and Q will be:

(A) 2I
(B) 6I
(C) 5I
(D) 7I

9) A 3 volt battery with negligible internal resistance is connected in a circuit as shown in the figure.
The current I, in the circuit will be

(A) 1A
(B) 1.5A
(C) 2A

(D)

10) A double convex lens has power P and same radii of curvature R of both the surfaces. The
radius of curvature of a surface of a plano-convex lens made of the same material with 1.5P power
is:

(A) 2R

(B)

(C)

(D)

11) If the terminal speed of a sphere of gold (density = 19.5 kg/m3) is 2m/s in a viscous liquid
(density = 1.5 kg/m3), find the terminal speed of a sphere of silver (density = 10.5 kg/m3) of the same
size in the same liquid

(A) 0.4 m/s

(B) 0.133 m/s
(C) 0.1 m/s
(D) 0.2 m/s

12) If M is mass of water that rises in the capillary tube of radius r, the mass of water which will rise
in same metal glass tube but of radius 2r is

(A) 2 M
(B) M

(C)

(D) 4 M

13) The equivalent capacitance of the combination shown is

(A)

(B) 4C
(C) 2C

(D)

14) A particle moves in one dimension from rest under the influence of a force that varies with the
distance travelled by the particle as shown in the figure. The kinetic energy of the particle after it

has travelled 3m is:

(A) 4J
(B) 2.5J
(C) 6.5J
(D) 5J

15) Three rods of identical cross section area and of same material form an isosceles triangle ABC
with three rods with right angle at B. A and B ends are maintained at T and temperature
respectively. In steady state the temperature of point 'C' is TC assuming no heat loss by any other

method and flow only through conduction method then is

(A)

(B)

(C)

(D)

16) A monoatomic gas at pressure P and volume V is suddenly compressed to one eighth of
its original volume. The final pressure at constant entropy (adiabatic process) will be :

(A) P
(B) 8P
(C) 32P
(D) 64P

17) rhe temperature at which the root mean square velocity of hydrogen molecules equals
their escape velocity on earth is closest to {Boltzman constant = 1.38 x 10–23 mk units radius of earth
Re = 6.4 x 106 m g = 10ms–2}
(A) 104K
(B) 6500K
(C) 3 × 105 K
(D) 8000K

18) Two identical metal wires of thermal conductivities K1 and K2 respectively are connected in
series. The effective thermal conductivity of the combination is:

(A)

(B)

(C)

(D)

19) The ratio of de-Broglie wavelength of an α- particle and a proton accelerated from rest by

the same potential is , the value of rn is

(A) 4
(B) 16
(C) 8
(D) 2

20) The diode when it is forward biased the voltages are changing from corresponding currents are
2 mA & 1 mA respectively. The dynamic resistance of the diode is in ohms is

(A) 500
(B) 1000
(C) 1500
(D) 5000

SECTION-II

1) In an electrical circuit, a battery is connected to pass 20C of charge through it in a certain given
time. The potential difference between two plates of the battery is maintained at 15 V. The work
done by the battery is_____J.

2) When current in a coil changes from 5A to 2A in 0.1s, average voltage of 50 V is produced. The
self-inductance (in H) of the coil is: (Round-off to the nearest integer)
3) From an excited state of hydrogen atom six spectral lines are emitted then the excited state n =
_____

4) The least count of main scale of a screwguage is 1 mm. The minimum number of divisions on its
circular scale required to measure 5 μm diameter of a wire is_____

5) The position of a particle related to time is given by x = (5t2 – 4t + 5)m the magnitude of velocity
in ms–1 at t = 2s is

PART-2 : CHEMISTRY

SECTION-I

1) [Ma6]+2, [Mb6]+2, [Mc6]+2 and [Md6]+2 octahedral complex absorbs wavelengths in the region of red,
green, blue and yellow respectively. What is the strongest ligand among a, b, c and d (given ligand
are neutral nature).

(A) a
(B) b
(C) c
(D) d

2) Wave length of electron waves in two Bohr's orbits is in ratio 3:5. The ratio of kinetic energy of
electron is

(A) 2.78
(B) 0.36
(C) 1.66
(D) 0.6

3) Assertion (A): Chlorobenzene is more reactive than benzene towards fridel craft alkylation.
Reason (R): Positive mesomeric effect of chlorine governs the orientation effect of elctrophilic
aromatic substitution (EAS) reactions on benzene.
Find the true relation from the following.

(A) A and R are true and R is correct explanation of A.

(B) A and R are true but R is not the correct explanation of A.
(C) A is true but R is wrong.
(D) A is wrong but R is true.

4) Which of the following reaction is the correct match of given energy profile diagram
(A) It is a single step reaction
(B) It is a multi step reaction
(C) Reaction involves one intermediate
(D) Reaction involve two transition states

5) During change of O2 to O2– ion, the electron adds on which one of the following orbitals ?

(A) σ* orbital
(B) σ orbital
(C) π* orbital
(D) π orbital

6) A Positive Carbylamine test given by

(A) N, N - dimethyl aniline

(B) N-methyl ethanamine
(C) N - methyl - 2 - methyl aniline
(D) p - methyl benzylamine

7)
If [R] is the concentration of reactant, which of the following is the correct match of graph.

(A) first order

(B) zero-order
(C) second order
(D) third order

8) A → Product [A] = 2M. After 10 minutes reaction is 10% completed if then T50% is
approximately.
(A) 0.693 min
(B) 69.3 min
(C) 66.0 min
(D) 0.0693 min

9) Which of the following element do not have vacant "d-orbitals" ?

(A) P
(B) As
(C) N
(D) Sb

10) Which of the following has maximum negative electron gain enthalpy

(A) F
(B) Cl
(C) Br
(D) I

11)
If a, b, c, d, e are the successive members of a group in the increasing order of their atomic number
and EN is the electro negativity of the corresponding elements in pauling scale. Find the correct
group which matches given graph

(A) Group-13
(B) Group-14
(C) Group-15
(D) Group-16

12) What is the spin only magnetic moment of Zn+2 ion in BM

(A) 1.73
(B) 2.84
(C) 0
(D) 3.87

13) Which of the following species do not show disproportionation reaction ?

(A)
(B)
(C)
(D)

14) Which of the following is extensive property

(A) Enthalpy
(B) Specific heat capacity
(C) Molarity
(D) Molality

15) Calculate the pH of 0.08 M solution of hypochlorous acid (HOCl). The ionization constant of the
acid is 2.5 × 10–5. (Consider 0.08 x = 0.08 and log (1.41) = 0.15)

(A) 2.80
(B) 2.85
(C) 11.15
(D) 6.5

16) Ionic product of water is 10–12 at [Link] many of the following samples are acidic at 90° C.
(a) pH = 6.2 (b) pH = 6.4
(c) pH = 7 (d) pH = 6.0
(e) pH = 5.2 (f) pH = 6.9
(g) pH = 7.1

(A) 3
(B) 5
(C) 7
(D) 1

17) Correct match of the following is

Column-II
Column - I
(hybridization of
(species)
central atom)

I) SF4 a) sp3

II) SO2 b) sp3d2

III) [Zn(CN)4]–2 c) dsp2

IV) [Ni(CO)4] d) sp2

V) [PtCl4]–2 e) sp3d

(A) I-a, II-d, IV-c,V-c

(B) II-d, III-a, IV-c,V-a
(C) I-e, III-a, IV-c,V-a
(D) I-e, II-d, III-a,V-c

18) 1 mole of KMnO4 can oxidize x mole of iodide in acidic medium. What is the value of 'x'.

(A)

(B) 5
(C) 6

(D)

19) CH3CONH2 + Br2 + x NaOH → CH3NH2 + Byproducts.

What is the value of x.

(A) 3
(B) 8
(C) 4
(D) 1

20) The process with negative entropy change is

(A) dissociation of in to a CaO(s) and CO2(g)

(B) synthesis of NH3 from N2 and H2 gases
(C) Dissociation of CaSO4(s) in to CaO(S) and SO3(g)
(D) Sublimation of dry ice

SECTION-II

1) Find out total number of aromatic compounds from the following list
a) Benzene
b) Naphthalene
c) Anthracene

d)

e)

2) Among the following the number of reaction (s) that produce (s) benzaldehyde is

I)
II)

III)

IV)

3) In a 7.0 litre evacuated chamber 0.50 mole H2 and 0.50 mole I2 react at 427ºC.

At the given temperature KC = 49 for the reaction. If the total pressure at equilibrium is P atm in the
chamber, then report your answer P atm × 100.
(Given R = 0.0821 atm LK–1 mole–1)

4) How many of the first series transition elements are heavier (more density) than Fe

5) The electronic configuration of Gd is 4f x 5d1 6s2. Find the value of sum of atomic number of Gd
and x.

PART-3 : MATHEMATICS

SECTION-I

1) Let W denote the set of words in the English dictionary. Define the relation R by
R = {(x,y} ∈ w × w: the words x and y have atleast one letter in common}. Then R is

(A) reflexive, symmetric and not transitive

(B) reflexive, symmetric and transitive
(C) reflexive, not symmetric and transitive
(D) not reflexive, symmetric and transitive

2)
is equal to

(A) log|secx(secx – tanx)| + C

(B) log|secx(secx + tanx)| + C
(C) log cosecx(secx + tanx) + C
(D) log (sec x + tan x) + C
3) If α, β are the roots of equation x2 + px – r = 0 and are the roots of the equation x2 + qx –
r = 0 then r equals

(A)

(B)

(C)

(D)

4) If then

(A)

(B)

(C)

(D)

5) If y(t) is a solution of and y(0) = –1, then y(1) is equal to

(A)

(B)

(C)

(D)

6) Points (t – 1, 2t + 2) and (2t + 1, t + 1) are images of each other with respect of line 'L'. If 'L'
passes through (–1, 0) then value of 't' is

(A)
(B)

(C)

(D)

7) The difference between the radii of the largest and the smallest circles, which have their centres
on the circumference of the circle x2 + 2x + y2 + 4y = 4 and pass through the point (3, 4) is equal to

(A) 4
(B) 6
(C) 8
(D) 10

8) The function is decreasing in the interval

(A)

(B)

(C)

(D)

9) The value of

(A) π
(B) aπ

(C)

(D) 2π

10) Let P(x, y) be a variable point on the curve

4x2 + 9y2 – 8x – 36y + 15 then
min(x2 – 2x + y2 – 4y + 5) + max(x2 – 2x + y2 – 4y + 5) is equal to

(A)

(B)
(C)

(D)

11) The remainder when 2740 is divided by 12 is

(A) 3
(B) 7
(C) 9
(D) 11

12) If then

equals

(A) 1
(B) π
(C) 3π
(D) 4

13) The mean of 21 observations (all DIFFERENT) IS 40. If each observations greater than the
median are increases by 21 then mean of observations will become

(A) 50
(B) 50.5
(C) 30
(D) 45

14) If and

(where b ≠ 0) then is

(A)

(B)

(C)
(D)

15) are there vectors with magnitude and such

that is perpendicular to is perpendicular to and is perpendicular

to It follows that is equal to

(A) 9
(B) 6
(C) 5
(D) 4

16) Product of all the solution of equation

is

(A)

(B) 1
(C) 10
(D) 100

17) If d, e, f are in G.P and two quadratic equations ax2 + 2bx + c = 0 and dx2 + 2ex + f = 0 have a

common root then are in

(A) H.P
(B) G.P
(C) A.P
(D) A.G.P

18) From the focus of the parabola y2 = 8x as centre, a circle is described so that a common chord of
the curves is equidistant from the vertex and focus of the parabola. The equation of the circle is

(A) (x – 2)2+ y2 = 3
(B) (x – 2)2+ y2 = 9
(C) (x + 2)2+ y2 = 9
(D) (x + 2)2+ y2 = 7

19) A circle has the same centre as an ellipse and passes through the foci F1 and F2 of the ellipse
such that the two curves intersect in 4 points. Let 'P' be any one of their point of intersection. If the
major axis of the ellipse is 17 and the area of the triangle PF1F2 is 30, then the distance between the
foci is

(A) 11
(B) 12
(C) 13
(D) 14

20) The area of the region bounded by the curve y = x|x|, x-axis and the ordinates x = 1, x = –1 is
given by

(A) zero

(B)

(C)

(D) 1

SECTION-II

1) If α and β are the roots of the quadratic equation

then find the value of (α2 + β2)

2) Let α and β are roots of x2 – 6(t2 – 2t + 2)x – 2 = 0 with α > β. If an = αn – βn for n > 1, then find the

minimum value of (where t R)

3) If and the angle between be 120o, then is equal to _____

4) If the line 2x – 1 = 0 is the directrix of the parabola y2 – kx + 6 = 0 then the positive value of k is
_____

5) and

If then determine λ2
 ANSWER KEYS

PART-1 : PHYSICS

SECTION-I

Q. 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20
A. A A A C B D B B B D C A C C C C A A C B

SECTION-II

Q. 21 22 23 24 25
A. 300 2 4 200 16

PART-2 : CHEMISTRY

SECTION-I

Q. 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45
A. C A D A C D B C C B B C D A B D D B C B

SECTION-II

Q. 46 47 48 49 50
A. 4 4 821 3 71

PART-3 : MATHEMATICS

SECTION-I

Q. 51 52 53 54 55 56 57 58 59 60 61 62 63 64 65 66 67 68 69 70
A. A B C B A D B D C D C D A C B C A B C C

SECTION-II

Q. 71 72 73 74 75
A. 29 6 12 4 25
 SOLUTIONS

PART-1 : PHYSICS

PART-2 : CHEMISTRY

30)
As π* molecular orbitals are half filled so, one extra electron can be added to π* molecular
orbital

48) As Δng = 0, so total mole will remain same throughout the reaction.
So total number of moles = 0.5 + 0.5 = 1

PART-3 : MATHEMATICS