SR.

IIT_*CO-SC(MODEL-A& APEX Date:01-04-25

Time: 3HRS GTM-14(PHASE-III) Max. Marks: 300
PHYSICS Max.Marks:100
Section – I
(SINGLE CORRECT ANSWER TYPE)
This section contains 20 multiple choice questions. Each question has 4 options (A), (B), (C) and (D) for its
answer, out of which ONLY ONE option can be correct.
Marking scheme: +4 for correct answer, 0 if not attempted and -1 if not correct.
1. A 1L glass flask contains some mercury. It is found that at different temperatures the volume of
air inside the flask remains the same. What is the volume (in cc) of mercury in this flask if
coefficient of linear expansion of glass is 9 106 / 0 C while of volume expansion of mercury is
1.8 104 / 0 C ?
A) 150 B) 120 C) 110 D) 130
2. Young's double slit experiment is made in a liquid. The 10th bright fringe in liquid lies where 6th
dark fringe lies in vacuum. The refractive index of the liquid is approximately
A) 1.6 B) 4.5 C) 1.8 D) 9.0
3. Find the friction force between the blocks in the figure. No friction between 4kg block and
ground. ( g 10 ms 2 )

A) 5 B)10 C)8 D)3

4. The volume of a liquid (V) that passes a given cross-section (area A) in a given time (t) depends
on velocity of flow (u), as V = u aAbtc. Find the correct relation
A) a = c B) a + c = 0 C) 2b + a = 1.5 D) 2b + a + 3 = 0

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5. In the arrangement shown in the figure pulley is light and smooth. The extension in the spring is
(g=10 m/s2)

A) 1.33 cm B) 1.cm C) 1.67 cm D) 2 cm

6. A particle of mass m begins to slide down on a fixed smooth sphere from the top, when it breaks
off the sphere, it’s tangential acceleration will be
5 g
A) 2g/3 B) g C) g D)
3 3
7. An artificial satellite is first taken to a height equal to half the radius of Earth. Let E1 be the
energy required. It is then given the appropriate orbital speed such that it goes in a circular orbit
E1
at that height. Let E2 be the energy required. The ratio is
E2

A) 4:1 B) 3:1 C) 1:1 D) 1:2

 dI 
8. In an LC circuit initially the capacitor has maximum charge q0.Then the value of   is
 dt  max

q0 q0 q0 q0
A) B) C) 1 D) 1
LC LC LC LC
9. A coil of inductance 0.12 H and resistance 5  are is connected to an AC – source of 13 V,
50
Hz . The power factor of this circuit is
π
12 12 5
A) B) C) 5 D)
5 13 13

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 20
10. A long solenoid with 10 turns/cm and a radius of 7 cm carries a current of mA. A charge of
π
10μC move along central axis of solenoid. The magnetic force on charge is
A) 8 N B) 11.3 N C) 11.3  10 3 N D) Zero
11. The distance between object and screen is 96 cm. The ratio of length of two images formed by a
convex lens placed between them is 4.84. The focal length f is nearly
A) 22 cm B) 20.6 cm C) 34 cm D) 24.2 cm
12. The equivalent resistance of the circuit across AB is given by

A) 4 Ω B) 13 Ω C) 4 Ω or 13 Ω D) 4 Ω or zero
13. An optical instrument uses a 25 D objective and 20 D eyepiece with a tube length of 25 cm
when eye is least strained.
A) The instrument is a telescope with angular magnification 20.
B) The instrument is a microscope with angular magnification 20.
C) The instrument is a telescope with angular magnification 24.
D) The instrument is a microscope with angular magnification 24.
14. The figure shows electronic wave function for a hydrogen atom.

I) The quantum number of this state is 6

II) The wavelength of this electron is 6 r0 . (r0 is radius of ground state)
III) can go to ground state by emitting 3 different photons
IV) On de-excitation it emits at least one line in infrared region of spectrum.
A) only I correct B) I,II,III are correct C)II,III are correct D)II,III,IV are correct
15. In a particular fission process of a uranium atom at rest, fragments with mass numbers A1 and A2
are produced. A good estimate of the ratio of kinetic energies of the fragments, K1 / K 2 is:(where
K1 , K 2 are kinetic energies of fragments A1 , A 2 respectively)

d)  A1 / A2 
2
A) A 2 / A1 B) (A 2 / A1 ) 2 C) A1 / A2

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16. An insulator container contains 4 moles of an ideal diatomic gas at temperature T. Heat Q is
supplied to this gas, due to which 2 moles of the gas are dissociated into atoms but temperature
of the gas remains constant. Then
A) Q  2 RT B) Q  RT C) Q  4 RT D) Q  3RT
pV
17. The figure given below shows the plot of versus P for oxygen gas at two different
nT
temperatures. Read the following statements concerning the curves given below

A) The dotted line corresponds to the 'ideal' gas behaviour

B) T1 > T2
pV
C) The value of at the point, where the curves meet on the y-axis is the same for all gases.
nT
Which of the above statement is true ?
A) A only B) A and B only C) all of these D) B and C only
x 
18. A light beam travelling in +ve x-direction is described by E y  300sin  t  V / m. An electron
 c 

is constrained to move along y direction with a speed of 2 107 ms 1. The maximum magnetic
force (in Newton) on the electron is
A) 3.2  10 18 B) 5.1 10 16 C) 6.5 10 11 D) 7.8 10 12
19. The energy of an electron in excited hydrogen atom is -3.4 eV. Then according to Bohr’s
Theory, the angular momentum of this electron in Js is  h  6.625  10 34 Js 

A) 2.111034 B) 3.05 1034 C) 2.54 1034 D) 1.77  1034

20. A surface irradiated with light of wavelength 480 nm gives out electrons with maximum
velocity v m/s, the cut off wavelength being 600 nm. The same surface would release electrons
with maximum velocity 2v m/s if it irradiated by light of wavelength
A) 300 nm B) 360 nm C) 240 nm D) 400 nm

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 SECTION-II
(Numerical Value Answer Type)
This section contains 5 questions. The answer to each question is a Numerical value. The candidate has to answer
all questions.
Marking scheme: +4 for correct answer, 0 if not attempted and -1 in all other cases.
21. A person speaking normally produces a sound intensity of 40 dB at a distance of 1m. If
the threshold intensity for reasonable audibility is 20 dB, the maximum distance at which
person can be heard clearly is x meter. Find the value of x.
2 3
22. When a d.c. voltage of 200V is applied to a coil of self inductance H , a current of 1A

flows through it. But by replacing d.c. source with a.c Source of 200V, the current in the
coil is reduced to 0.5A. The frequency of a.c. supply in Hz is
23. An object is projected with a speed 10 m/s at an angle of 30o with the horizontal. The
object breaks down into n equal fragments during its motion. One fragment is found to
strike the ground at a distance of 3 m from the point of projection in the same azimuthal
plane, in which the object is projected. If the centre of mass of the remaining fragments
strikes the ground simultaneously at distance of 7 3 m from the point of projection, then
the value of n is (g=10 m/s2)
24. The charge in μC flown from P to Q when the switch S is closed is –

25. Three capacitors of capacities 8 F ,12  F ,16  F , are connected in series. If the potential on
12  F is 60 V, the potential difference between the ends of the combinations is

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CHEMISTRY Max.Marks:100
Section – I
(SINGLE CORRECT ANSWER TYPE)
This section contains 20 multiple choice questions. Each question has 4 options (A), (B), (C) and (D) for its
answer, out of which ONLY ONE option can be correct.
Marking scheme: +4 for correct answer, 0 if not attempted and -1 in all other cases.
26. i) XeF4  O2 F2  ii) XeF4  H 2O excess   iii) XeF2  H 2O  iv) XeF6  H 2O 

The reaction in which oxygen gas is liberated

A) i and iv B) iii and iv C) ii and iv D) i, ii and iii
27. Read the following statements
i) Among the transition series elements the metals of 2nd and 3 rd transition series have
greater enthalpies of atomisation than 1st series
ii) The radii of the 3rd transition series (5d) are virtually the same as those of the
corresponding members of 2nd series,
iii) Ionization enthalpy of Mn  is higher than Cr 
iv) Due to the lanthanide contraction the 2nd and 3rd series exhibit similar radii
Which of the following is the correct as per the above 4- statements
A) Statements i, ii, iii are correct, iv is incorrect
B) Statement i, ii, iv are correct, iii is incorrect
C) Statement ii, iv, iii are correct , i is incorrect
D) All the four are correct statements
28. An inorganic compound “X” undergo disproportionation gives the compounds Nitric
acid, water and Nitric oxide, X is
A) Nitrous Acid B) Nitric Acid C) Hypo nitric Acid D) Per Nitric Acid
29.  Ma3b3  type of complex [a, b are monodentate ligands] can exhibit two geometrical
isomers, facial and meridional. The correct statement about the complex is
A) Both the complexes are optically active
B) Facial isomer have no plane of symmetry
C) Meridional isomer has plane of symmetry
D) Both are homoleptic complexes

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30. Zaitsev’s rule is violated in the dehydrohalogenation of
A) 2-methyl-2-chloropentane using EtOK
B) 2-methyl-2-chloropentane using MeOK
C) 2-methyl-2-chloropentane using t-BuOK
D) 2-methyl-2-chloropentane using alc.KOH
31. A peptide synthesized by the reactions of one molecule each of Glycine, Leucine,
Aspartic acid and Histidine will have ________ peptide linkages.
A) 3 B) 6 C) 9 D) 5
32. The following pairs of solution are mixed in equal volume. Which combination does not
produce a buffer solution ?
A) 0.5M HCOOH and 0.4M NaOH B) 0.1M NH 4OH and 0.1M HCl
C) 0.2M HCOONa and 0.1M HNO3 D) 0.2M HCOOH and 0.4M HCOONa
33. Among the following incorrect electron gain enthalpy order is (consider magnitude only)
A) H > Li > Na > K > Rb > Cs B) Cl > F > Br > I
C) Cl > S > Si > P D) S > Sc > Te > O > Po
34. Which one of the following statements is correct
A) Potassium permanganate can be used as primary standard in volumetric analysis
B) Permanganate at H   1 and Ce4   1 Z  58  can oxidize water but the reaction rate is
 

very slow at room temperature and hence these two can be used in volumetric analysis as
oxidant
C) Eu2 (Z = 63) has stable electronic configuration  Xe  4f 7 and hence it can not act as
reducing agent.
D) Sodium dichromate can be used as primary standard in volumetric analysis
35. Fructose reduces Tollen’s reagent due to
A) Presence of ketonic group
B) Presence of NH4OH in Tollen’s reagent
C) Rearrangement of fructose into a mixture of glucose, fructose and mannose
D) Both (B) & (C)

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36. An organic compound having the molecular formula C3H6O does not give a precipitate
with 2, 4 dinitrophenyl hydrazine and does not react with sodium metal. The compound is
expected to be
A) CH3 – CH 2 – CHO B) CH3 – CO – CH 3
C) CH2 = CH – CH2 – OH D) CH2 = CH – OCH 3
37. What will be the H+ concentration in a solution prepared by mixing 50.0 ml of 0.20 M
NaCl, 25 ml of 0.10 M NaOH and 25.0 ml of 0.30 M HCl?
A) 0.5 M B) 0.05 M C) 0.02 M D) 0.10 M
38. Calculate the energy of photon involved during a transition from n=5 state to n=2 state in
the hydrogen atom.
A) 4.58 10 18 J B) 4.58  10 19 J C) 4.58  10 20 J D) 4.58 10 17 J

39. Bond order and magnetic nature of O2 are respectively
A) 1.5, diamagnetic B) 2.5, paramagnetic C) 2.5, diamagnetic D) 1.5, paramagnetic

40. The initial concentration of N 2O5 in the following first order reaction,
1
N 2O5( g )  2 NO2( g )  O2( g ) was 1.24 10 2 molL1 at 318K . The concentration of N 2O5 after 60
2
minutes was 0.20 10 2 molL1 . Calculate the rate constant of the reaction at 318K .(given
log(62)  1.79 )

A) 0.304 min 1 B) 0.0304 min 1 C) 0.0304 sec 1 D) 0.304 sec 1

41. Frenkel defect is observed in:
A) ZnS, KCl B) AgI, ZnS C) AgBr, CsCl D) all of these
42. How many chiral carbons are present in following structure?

A) 1 B) 2 C) 3 D) 4
43. What is the index of hydrogen deficiency in the molecule C12H17NO?
A) 4 B) 5 C) 6 D) 7

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44. The amount of U-235 required per day to run a power house of capacity 15 MW
(efficiency of nuclear reactor 75%. Assume energy liberated by fission of 1 U-235 atom
is 200 MeV) is
A) 15.8 g B) 28.1 g C) 21.1 g D) None of these
45. The activity of a radioactive sample reduced from 20 Ci to 1.25 Ci in 2000 years. The
half life of the sample and its decay constant are respectively
A) 4000 years and 1.1 × 10–3 y–1 B) 500 years and 1.1 × 10–2 y–1
C) 500 years and 1.386 × 10–3 y–1 D) 1000 years and 1.386 × 10–3 y–1

SECTION-II
(Numerical Value Answer Type)
This section contains 5 questions. The answer to each question is a Numerical value. The candidate has to answer
all questions.
Marking scheme: +4 for correct answer, 0 if not attempted and -1 in all other cases.
46. In the following reaction sequence, the amount of D (in g) formed from 10 moles of
acetophenone is
(Atomic weights in g mol-1; H = 1, C=12, N=14, O=16, Br =80. The yield (%)
corresponding to the product in each step is given in the parenthesis)
O CH3

i) NaOBr NH3 Br2/KOH Br2(3eq )

A (60%) B (50%) C (50%) D (100%)
+
ii) H3O  AcOH

47. The total number of negative charges in the tetrapeptide, Gly-Glu-Asp-Tyr, at pH 12.5
will be __________. (Integer answer)
48. For the disproportionation reaction 2Cu   aq   Cu  s   Cu 2  aq  at 298 K, In K (where K is

0 RT
the equilibrium constant) is …….. 10 1 Given ( ECu 2
/ Cu 
0
 0.16V , ECu 
/ Cu
 0.52V ,  0.025)
F
49. 1.22 g of benzoic acid is dissolved in 100 g of benzene shows a depression in freezing
point equal to 0.375 K. Molal depression constant for benzene is 5 Kg mol1 . What is the
percentage association of acid if it forms dimer in solution?

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50. An acidic solution of dichromate is electrolysed for 8 minutes using 2A current. As per
the following equation
Cr2O72   14 H   6e   2Cr 3  7 H 2O

The amount of Cr3+obtained was 0.104 g. The efficiency of the process (in %) is (Take:
F=96000 C, At. Mass of chromium = 52)……..

MATHEMATICS Max.Marks:100
Section – I
(SINGLE CORRECT ANSWER TYPE)
This section contains 20 multiple choice questions. Each question has 4 options (A), (B), (C) and (D) for its
answer, out of which ONLY ONE option can be correct.
Marking scheme: +4 for correct answer, 0 if not attempted and -1 in all other cases.
51. Let distinct lines L1 , L2 belong to family of lines  x  2 y  3    x  3 y  2   0 and B1 is

angle bisector of L1 and L2 which passes through point A(2,3), then equation of other
bisector of L1 and L2 is (  is a parameter)
A) x  4 y  3  0 B) 4 x  y  3  0 C) x  y  5 D) 2 x  y  1
dy y
52. The solution of the differential equation  2 is
dx  y  x 

A) y3  xy  c B) y3  3xy  c C) y3  3xy  c D) y3  xy  c

53. If sin 2 x  sin x cos x  6 cos 2 x  0 and   x  0 , then the value of cos 2x , is
2
3 3 4 4
A)  B) C)  D)
5 5 5 5

54. Let  ,  be the roots of the quadratic equation ax 2  bx  c  0 . If a, b, c are in A.P. and
    15 , then  equals

A) -21 B) -29 C) -31 D) -39

1 2017 2
55. If A-1= 1 2017 4 , then 2 A  2 A1 is equal to
1 2018 8

A) 3 B) -3 C) 12 D) -12
4
log x 2
56. 2 log x2  log  36  12 x  x2 dx is equal to
A) 2 B) 4 C) 1 D) 6
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 x2 y 3 z 4 x 1 y  2 z  6
57. The lines   and   are coplanar if
1 2 2k k 3 1

5  15 5  15
A) k  0, k  2 B) k  ,k  3 C) k  D) k  3, k  5
2 2
58. If PQ is the focal chord of parabola y 2   x and P is (-4, 2), then the slope of tangent at Q
is
A) 2 B) 3 C) 4 D)5
 ^ ^ ^ ^ ^  ^ ^ ^ ^ ^
59. If the lines r  2 i  j  k    i  2 j  and r  i  j  3k    j  2 k  intersect each other, then
   

     is equal to-
A) 2 B) -1 C)0 D) 1
dy
60. General solution of x  y  y 2 x 3 cos x, is
dx
1 1
A)  x sin x  cos x  c B)  x sin x  cos x  c
xy xy
1 1
C)  x cos x  sin x  c D)  x sin x  cos x  c
xy xy

61. The value of m for which one of the roots of x2-3x+2m = 0 is double of one of the roots
of x2-x+m = 0 is
A) 2 B) 1 C) -2 D)-1
   2 
62. The value of tan cos1     is
  7  2
2 2 1 4
A) B) C) D)
3 5 3 5 5
x  x 1
 1  x  x  e
1
63. dx is equal to
1 1 1 1
A) x.e x  x  c B)  x . e x  x  c C)  x  1 . e x  x  c D)  x  1 . e x  x  c
1 1
64. Let A and B be two independent events such that P (A) = and P(B) = . Then, which of
3 6
the following is TRUE?
2 1 1 1
A) P (A/B) = B) P (A/(A  B))= C) P(A/Bc) = D) P(Ac/Bc) =
3 4 3 3

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  1, x  0

65. Let g  x   1  x   x  and f  x    0, x  0 . Then for all x, f  g  x   is equal to (where .
 1, x  0


represents the greatest integer function)

A) x B) 1 C) f  x  D) g  x 

66. If pqr  0 and the system of equations  p  a  x  by  cz  0 , ax   q  b  y  cz  0 ,

a b c
ax  by   r  c  z  0 has a non-trivial solution, then value of   is
p q r

A) 1 B) 0 C) 1 D) 2
67. If a  i  4 j  2k , b  3i  2 j  7k and c  2i  j  4k then the vector d which is perpendicular
to both a and b (given c.d  15 ) is,
1 1 1 1
A)
3

160 i  5 j  70k  B)
3

60 i  5 j  70k  C)
3

60 i  5 j  70k  D)
3

60 i  5 j  70k 
dy
68. The solution of  x 3 y 3  xy is
dx
2
A) y 2  1  ce y  1  2

  2
B) x 2  1  ce x y 2  1 C) 1  x 2  ce x y 2  1   2
D) x  1  ce y x 2  1 
x  2 y 1 z
69. Perpendiculars are drawn from points on the line   to the plane x  y  z  3 .
2 1 3
The feet of perpendiculars lie on the line
x y 1 z  2 x y 1 z  2 x y 1 z  2 x y 1 z  2
A)   B)   C)   D)  
5 8 13 2 3 5 4 3 7 2 7 5
70. If the first and nth term of a G.P are a and b respectively, and if P is the product of first n
terms of such G.P., then p 2  _______
n n 1
A)  ab  B) a n b C) ab n D)  ab 

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 SECTION-II
(Numerical Value Answer Type)
This section contains 5 questions. The answer to each question is a Numerical value. The candidate has to answer
all questions.
Marking scheme: +4 for correct answer, 0 if not attempted and -1 in all other cases.

71. If the coefficient of rth term and (r + 1)th term in the expansion of (1 + x)20 are in the
ratio 1 : 2, then r is equal to
72. If x  2  3i , then value of 2x4 + 5x3 + 7x2 – x + 41 is
73. The number of integral values of k if x coordinate of the point of intersection of the lines
5x + 7y = 12 and y = kx + 2 is also an integer is
74. If the circles x2 + y2 + 2b 1y + 1 = 0 and x2 + y2 + 2b2y + 1 = 0 cuts orthogonally then the
value of b1b 2 is.
k dx
75. Let  x 6 sin  5 x 7  dx  cos  5 x 7   C1 , x  0, and   m log | 7 x  14 |  C2 then k + m
5 7 x  14
equals
\

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