PET-2022 CHEMISTRY-XII CHAPTER-05 (1)

++
1. The coordination number of Pt in [(Pt(NH3)4Cl2] ion is:
A.2 B. 4 C.8 D.6
2. According to Lewis theory the ligands are:
[Link] in nature B. Basic in nature
[Link] acidic nor basic [Link] are acidic and other are basic
3. Which of the following ligands is expected to be bidentate?
[Link] B. C2𝐎𝟐−
𝟒 C.CH3NH2 D.CH3𝐂 ≡ 𝐍
4–
4. [EDTA] is a:
[Link] ligand B. Bidentate ligand [Link] ligand [Link] ligand
5. Which of the following are is called malachite?
A.Cu2S B. [Link](OH)2 C.Cu2O D.CuCO3
6. Indicate the mineral form which copper is manufactured:
[Link] B. Cuprite [Link] [Link]
7. The chromite ore is:
A.FeCr2O4 B. CoCr2O3 C.CrFe2O4 D.FeCr2O3
8. Roasting is generally done in case of the following:
[Link] ores B. Silicate ores [Link] ores [Link] ores
9. Heating of ore in presence of air to remove sulphur impurities is called:
[Link] B. Calcination [Link] [Link]
10. Matte contains mainly:
A.Cu2S and FeS B. CuS and Fe2S3 [Link] D.Cu2S
11. The substance which is mixed with the ore for removal of impurities is termed as:
[Link] B. Gangue [Link] [Link]
12. Transitional elements exhibit variable valencies because they release electrons from the following orbits:
A. ns orbit B. ns and np orbits C.(n-1)d and ns orbits D.(n-1)d orbit
13. Variable valency is shown by:
[Link] B. Cu [Link] [Link]
14. The coinage metals are:
[Link], Cobalt, Nickel B. Copper and Zinc [Link], Silver and gold [Link] and Platinum
15. Which ion has maximum magnetic moment?
A.𝐕 +𝟑 B. 𝐌𝐧+𝟑 C.𝐅𝐞+𝟑 D.𝐂𝐮+𝟐
16. The number of unpaired electrons in ferric ion is:
A.5 B. 4 C.2 D.3
17. Maximum oxidation state is shown by:
[Link] B. Mn [Link] [Link]
18. Zinc and mercury do not show variable valency like d-block elements because:
[Link] are soft B. Their d-shells are complete
[Link] have only two electrons in the outermost subshell [Link] d-shells are incomplete
19. The number of unpaired electrons in cobalt atom is (atomic number of Co = 27)
A.2 B. 3 C.4 D.1
20. Zn is related to which group:
[Link] B. IIA [Link] [Link]
21. Which of the following element does not show variable valency?
[Link] B. Zn [Link] [Link]
22. The incorrect statement for d – block elements is:
[Link] shows magnetic properties B. It has variable valency
[Link] has tendency for formation of coloured ions [Link] has complete d – orbitals
SINDH PU BL IC S CHO OL & COLLE GE UMERK OT COMPOSED BY: M. HANIF MAHAR
PET-2022 CHEMISTRY-XII CHAPTER-05 (2)
23. Which of the following is not a characteristic of transition elements?
[Link] oxidation states B. Formation of coloured compounds
[Link] of interstitial compound [Link] radioactivity
24. Which of the following elements is alloyed with copper to form brass?
[Link] B. Silver [Link] [Link]
25. The transition metals mostly are:
[Link] B. Paramagnetic
[Link] diamagnetic nor paramagnetic [Link] diamagnetic and paramagnetic
3+
26. The number of unpaired electrons in Cr ion is:
A.3 B. 4 C.5 D.1
27. Ce – 58 is a member of:
A.s – block B. p – block C.d – block D.f – block
28. Transition metals show paramagnetism:
[Link] to characteristic configuration B. High lattice energy
[Link] to variable oxidation states [Link] to unpaired electrons
29. The colour of light absorbed by an aqueous solution of CuSO4 is:
[Link] – red B. Blue – green [Link] [Link]
30. Potassium permanganate acts as an oxidant in neutral, alkaline as well as acidic media. The final
products obtained from it in the three conditions are, respectively:
A.MnO2,MnO2,Mn2+ B.𝐌𝐧𝐎𝟐− 3+
𝟒 , Mn , Mn
2+
C.MnO2,𝐌𝐧𝐎𝟐− 𝟒 , Mn
3+
[Link],MnO4,Mn+2
31. In acidic medium one mole of 𝐌𝐧𝐎− 𝟒 accepts how many moles of electrons in a redox process:
A.1 B. 3 C.5 D.6
32. On heating potassium permanganate, one of the following compound is not obtained:
A.MnO2 B. O2 C.K2MnO4 [Link]
33. Blue vitriol is:
A.CuSO4 B. CuSO4.5H2O C.Cu2SO4 D.CuSO4.H2O
34. V2O5 is useful as catalyst in:
[Link] of H2SO4 B. Manufacture of HNO3
[Link] of Na2CO3 [Link] is not a catalyst
35. KMnO4 in basic medium is reduced to:
A.K2MnO4 B. MnO2 [Link](OH)2 D.Mn2+
36. Amalgams are:
[Link] coloured alloys B. Always solid
[Link] which contain mercury as one of the contents
[Link] which have great resistance to abrasion
37. Silvering of mirror is done by:
A.AgNO3 B. Ag2O3 C.Fe2O3 D.Al2O3
38. The colour of K2Cr2O7 changes from red orange to lemon yellow on treatment with aqueous KOH
because of:
[Link] reduction of CrVI to CrIII B. The formation of chromium hydroxide
[Link] conversion of dichromate to chromate
D. The oxidation of potassium hydroxide to potassium peroxide
39. Kl and CuSO4 solution when mixed, give:
A.Cul2 + K2SO4 B. Cu2l2 + K2SO4 C.K2SO4 + Cu2l2 + I2 D. K2SO4 + Cul2 + I2
40. Silica is added to roasted copper are during smelting in order to remove:
[Link] sulphide B. Cuprous oxide [Link] oxide [Link] sulphide
SINDH PU BL IC S CHO OL & COLLE GE UMERK OT COMPOSED BY: M. HANIF MAHAR
PET-2022 CHEMISTRY-XII CHAPTER-05 (3)
41. The co – ordination number of cobalt in the complex [Co(en)2Br2]Cl2 is:
A.2 B. 6 C.5 D.4
42. Which of the following ligands forms a chelate?
[Link] B. Oxalate [Link] [Link]
43. [Pt(NH3)6]Cl4 complex gives:
A.4 ions B. 3 ions C.2 ions D.5 ions
44. Which of the following fact is not shown by transition metals?
A. Formation of coloured salt B. Variable oxidation state
C. Inert pair effect D. Catalytic activity
45. A transition element containing only one electron in 4s orbital is:
A. 21Sc B. 25Mn C. 26Fe D. 29Cu
46. Catalyst used in the Haber process for the manufacture of ammonia is:
A. Pt B. Pd C. Ni D. Fe
47. Tollen’s reagent is:
A. Magnesium complex B. Cobalt complex
C. Iron complex D. Chromium complex E. Silver complex
48. The number of ions produced by the complex [CO(NH3)4Cl2]Cl is:
A. 2 B. 3 C. 4 D. 6
49. Which of the following does not represent the correct sequence of indicated property?
(I) Mn+2<Ni+2<Co+2<Fe+2 magnetic moment (II) FeO>CoO>NiO basic character
(III) Sc<Ti<Cr<Mn number of oxidation state
A. I only B. II only C. III only D. II and II E. I, II and III
50. The highest oxidation state of chromium is:
A. +4 B. +5 C. +6 D. +7
51. The reduction 𝐂𝐫𝟐 𝐎𝟐−
𝟕 in strongly acidic medium produce:
A. 𝐂𝐫𝐎𝟐−
𝟒 B. CrO2 C. Cr2O5 D. Cr+3
−
52. Reduction of 𝐌𝐧𝐎𝟒 in strongly basic solution produces:
A. Mn+2 B. 𝐌𝐧𝐎𝟐− 𝟒 C. MnO2 D. Mn2O7
53. The oxidation state Mn in K2MnO4 and KMnO4 respectively are:
A. +6, +7 B. +6, +6 C. +7, +7 D. +7, +6
54. Which one of the following transition elements displays the highest oxidation state?
A. Cr B. Mn C. Fe D. V
+3
55. The number of unpaired electrons in V Ion is:
A. 1 B. 2 C. 3 D. 5
56. The oxidation state of Nickel in [Ni(CO)4] is:
A. Zero B. +1 C. +2 D. −1
57. Fusion of MnO2 with KOH in air produces:
A. Purple coloured KMnO4 B. Green coloured K2MnO4
C. Reddish Brown coloured M2O7 D. Brown coloured Mn2O3
58. When excess of NH4OH is added to the aqueous solution of CuSO4 the compound formed is:
A. Cu(OH)2 B. [Cu(NH3)2] (OH)2 C. [Cu(NH3)4]SO4 D. [Cu(NH3)2]SO4
𝟐−
59. The IUPAC name of 𝐍𝐢 𝐂𝐍 𝟒 is:
A. Tetra cyno Nickel (II) ion B. Tetra cyno Nickel (O) ion
C. Tetra cyno Nickelate (II) ion D. Tetra cyno Nickelate (O) ion
60. Which of the following is tri dentate ion?
A. 𝐍𝐎−𝟐 B. Oxilate ion C. dien D. en
SINDH PU BL IC S CHO OL & COLLE GE UMERK OT COMPOSED BY: M. HANIF MAHAR
PET-2022 CHEMISTRY-XII CHAPTER-05 (4)
61. The IUPAC name [COCl2(en)2]Cl is:
A. bis(ethylene diamine) dichloro cobalt (III) chloride B. Di chloro bis(ethylene diamine) cobalt (III) chloride
C. Trichloro bis(ethylene diamine) cobalt (I) chloride D. Trichloro bis (ethylene diamine) cobalt (O)
62. Di methyl glyoxime is co-ordinate to Ni+2 through:
A. Two oxygen atoms B. Two nitrogen atoms
C. Two oxygen and one Nitrogen atoms D. Two oxygen and two nitrogen atoms
63. The complex CuSO4. 5H2O is represented as:
A. [Cu(H2O)5]SO4 B. [Cu(H2O)4]SO4(H2O) C. [Cu(H2O)4]SO4]H2O D. [Cu(H2O)2SO4].3H2O
64. Among the following ion which one has the highest para magnetism?
A. [Cr(H2O)6]+3 B. [Fe(H2O)6]2+ C. [Cu(H2O)6]2+ D. [Zn(H2O)6]2+
65. Which of the following electronic configuration would be associated with highest magnetic moment?
A. d2 B. d4 C. d5 D. d7
66. Which of the following electronic configuration would be associated with lowest magnetic moment?
A. d2 B. d3 C. d4 D. d9
67. Which of the ion is expected to be para magnetic?
A. 29Cu+ B. 30Zn+2 C. 26Fe+2 D. 21Sc+3
68. If a transition metal compound absorbs red radiation from visible region its colour would be:
A. Yellow green B. Orange C. Blue D. White E. Yellow
69. Transition metal compounds are usually coloured this is due to the electronic transition:
A. From p ortibal to s-orbtial B. From d-orbital to s-orbital
C. From d-orbital to p-orbital D. Within the d orbital
70. For the redox reaction 𝐌𝐧𝐎− 𝟐− +
𝟒 + 𝐂𝟐 𝐎𝟒 + 𝐇 ⟶ 𝐌𝐧
+𝟐
+ 𝐂𝐎𝟐 + 𝐇𝟐 𝐎
The correct co-efficient
𝐌𝐧𝐎−
𝟒 𝐂𝟐 𝐎𝟐−
𝟒 𝐇+
A. 2 5 16
B. 5 16 2
C. 16 5 2
D. 2 16 5
71. The compound having lowest oxidation state of iron is:
A. K4[Fe(CN)6] B. K2FeO4 C. Fe2O D. Fe(CO)5
72. Which is redox reaction?
A. Cr2O3 +6HCl 2CrCl3+3H2O B. CrO3 + 2NaOH  Na2CrO4 + H2O
C. 𝟐𝐂𝐫𝐎𝟐− + 𝟐−
𝟒 + 𝟐𝐇 ⇌Cr2𝐎𝟕 + H2O D. 𝐂𝐫𝟐 𝐎𝟐− − + +
𝟕 + 𝟔𝐈 + 𝟏𝟒𝐇 ⟶ 𝟐𝐂𝐫 + 𝟑𝐈𝟐 + 𝟕𝐇𝟐 𝐎
73. The correct order compounds with increasing oxidation number of Ni is:
A. Ni(CO)4<K2[NiF6]<K2[Ni(CN)4] B. Ni(CO)4<K2[Ni(CN)4]<K2[NiF6]
C. K2[Ni(CN)4]<K2[NiF6]<NiCO4 D. K2[Ni(CN)4]<Ni[(CO)4]<K2[NiF6]
74. Which is not oxidized by ozone?
A. KI B. KMnO4 C. K2MnO4 D. FeSO4
75. Which of the following statement is correct?
A. The chemical composition of azurite is [Link](OH)2
B. Copper is most extracted from the ore copper pyrite whose composition is CuS
C. Copper is extracted by carbon reduction method
D. The composition of chromite ore is Fe2O3.Cr2O3
76. Which of the following ore contains both iron and copper?
A. Malachite B. Azurite C. Dolomite D. Chalcopyrite

SINDH PU BL IC S CHO OL & COLLE GE UMERK OT COMPOSED BY: M. HANIF MAHAR

PET-2022 CHEMISTRY-XII CHAPTER-05 (5)
77. When AgNO3 is heated strongly the gas evolved is/are:
A. NO2 only B. NO2 + O2 C. O2 only D. NO + NO2
78. Chromyl chloride test is shown when the following compound is heated along K2Cr2O7 and
concentrated H2SO4:
A. KCl B. KNO3 C. Na2SO4 D. CuO
79. Which of the following represents Blue vitriol?
A. CuSO4.5H2O B. FeSO4.5H2O C. FeSO4.7H2O D. ZnSO4.7H2O
80. The dissolution of AgBr in 𝐒𝟐 𝐎𝟐−
𝟑 produce:
3 3
A. Ag(S2O3)  B. Ag(S2O3) 2 C. Ag(S2O3) 53  D. Ag(S2O3) 4
81. In the metallurgy of copper, the material obtained from the bottom of blast furnace is:
A. Slag B. Copper C. Matte D. Cuprous oxide
82. Which of the following compound of vanadium is not possible?
A. V2O5 B. K2VCl4 C. K2VO4 D. K2VF6
83. Copper is mainly extracted by:
A. Carbon reduction method B. Self reduction method
C. The method of electrolysis D. Leaching with aqueous solution of NaCN followed by reduction
84. Ethylene diamine tetra acetate has charge:
A. 2 B. 4 C. 6 D. Zero
85. In chromite ore, the oxidation number of Iron and chromium are respectively:
A. +3, +2 B. +3, +6 C. +2, +6 D. +2, +3
86. When ferrous sulphate is treated with acidified K2Cr2O7 solution, the oxidation state of Fe is changed form:
A. 0 to +2 B. +3 to +2 C. 0 to +3 D. +2 to +4 E. +2 to +3
87. How many moles of Iodine are liberated when 1mole of potassium dichromate reacts with potassium iodide?
A. 1 B. 2 C. 3 D. 4

88. In acidic solution, MnO : 4
2
A. Is oxidized to MnO 4 B. Is reduced to MnO2
2+
C. Is reduced to Mn D. Is oxidized to Mn+2

89. MnO 4 reacts with 𝐈  in alkaline medium to give:
2 2
A. IO 3 , MnO2 B. I2, MnO 4 C. I2, MnO2 D. I  , MnO 4
90. A solution of H2O2 will be oxidized to O2 by KMnO4 solution in an acidic medium. KMnO4 is reduced to
Mn2+. How many moles of H2O2 will be oxidized by one mole of KMnO4?
A. 5 B. 3 C. 2.5 D. 1
91. The aqueous solution of the salt will be colored in the case of:
A. Zn (NO3)2 B. LiNO3 C. Co(NO3)2 D. NaNO3 E. Except B, D
92. Which element do you expect to have the smallest radius?
A. Sc B. Zn C. La D. Hg
93. Which one of the following is a bi dentate ligand?

A. NO 2 B. Oxalate ion C. EDTA D. Di ethylene tri amine
94. The correct IUPAC name of [Pt(NH3)2 Cl2] is:
A. Di amine di chloro platinium (II) B. Di amine di chloro Platinium (IV)
C. Di amine di chloro Platinium (O) D. Di chloro di amine platinium (IV)
95. A chelating agent has two or more than two donor atoms to bind to a single metal Ion which of the
following is not a chelating agent:
A. Ethan -1,2 di amine B. EDTA
C. Di ethylene tri amine D. Ammonia
SINDH PU BL IC S CHO OL & COLLE GE UMERK OT COMPOSED BY: M. HANIF MAHAR
PET-2022 CHEMISTRY-XII CHAPTER-05 (6)
96. Which of the following species is not expected to be a ligand?

A. Cl  B. NH 4 C. NH2-CH2-CH2-NH2 D. CO 32 
97. Identify the correct statement for the behavior of ethan-1, 2-diamine as a ligand:
A. It is a neutral ligand B. It is bi dentate ligand
C. It is a chelating agent D. It is uni dentate ligand E. All are correct except “d”
98. The oxidation state of Fe is the complex [Fe(H2O)5 Cl]SO4 is:
A. +1 B. +2 C. +3 D. +4
99. Oxidation number and co-ordination number of silver in Tollen’s regent respectively:
A. 1, 1 B. 2,1 C. 2, 2 D. 1, 2
100. Zn(OH)2 is insoluble in water but it dissolve in excess of NaOH. This due to formation of the complex:
A. Na2 [Zn (OH)2] B. Na[Zn(OH)4] C. Na2[Zn(OH)3] D. Na2 [Zn(OH)4]
101. Heating pyrites to remove sulphur is called:
A. Smelting B. Calcinations C. Liquation D. Roasting
102. Copper matte contains:
A. Sulphide of Copper (II) and Iron (II) B. Sulphide of copper (III) and Iron (III)
C. Sulphide of copper (I) and Iron (II) D. Sulphide of copper (I) and Iron (III)
103. In the extraction of copper from its sulphide ore, the metal is formed by reduction of Cu2O with:
A. FeS B. CO C. Cu2S D. SO2
104. The ore having two different metals is:
A. Hematite B. Magnetite C. Copper pyrite D. Chalcocite E. All of these
105. The chemical formula of copper pyrite is:
A. CuFeS2 B. Cu2S C. Cu2O D. CuCO3 Cu(OH)2
106. The chemical composition of the slag formed during smelting process:
A. CuSiO3 B. FeSiO3 C. CaSiO3 D. Cu2SiO2
107. Iron is removed from chalcopyrite as:
A. FeO B. FeS C. Fe2O3 D. FeSiO3
108. Partial roasting of chalcopyrite produces:
A. Cu2S and FeO B. Cu2O and FeO C. Cu2S and Fe2O3 D. Cu2O and Fe2O3
109. Which of the following is not a transition element?
A. Zn B. Ru C. Ag D. Pb
110. Permanent magnets are generally made of alloy:
A. Fe B. Co C. Ni D. Any one of these
111. Chromite ore has the formula:
A. Cr2O3 B. Cr2O5 C. Fe2O3 Cr2O3 D. FeO. Cr2O3
112. KMnO4 on heating gives:
A. K2MnO4 +MnO2+O2 B. K2MnO3+MnO2+O2
C. K2O+MnO2+O2 D. None of these
113. Electronic configuration of a transition element X is +3 oxidation state in [Ar] 3d5.
What is its atomic number?
A. 25 B. 26 C. 27 D. 24
114. Which of the following outer transition show oxidation state up to +7?
A. Mn B. Fe C. Cr D. Ni

SINDH PU BL IC S CHO OL & COLLE GE UMERK OT COMPOSED BY: M. HANIF MAHAR

PET-2022 CHEMISTRY-XII CHAPTER-05 (7)
CHEMISTRY CHAPTER-05
[Link] OPTION [Link] OPTION [Link] OPTION
1 D 51 D 101 D
2 B 52 C 102 C
3 B 53 A 103 C
4 D 54 B 104 C
5 B 55 B 105 A
6 D 56 A 106 B
7 A 57 B 107 D
8 C 58 C 108 A
9 A 59 C 109 D
10 A 60 C 110 D
11 A 61 B 111 D
12 C 62 B 112 A
13 B 63 B 113 B
14 C 64 B 114 A
15 C 65 C 115 =======
16 A 66 D 116 =======
17 B 67 C 117 =======
18 B 68 C 118 =======
19 B 69 D 119 =======
20 A 70 A 120 =======
21 B 71 D 121 =======
22 D 72 D 122 =======
23 D 73 B 123 =======
24 C 74 B 124 =======
25 B 75 A 125 =======
26 A 76 D 126 =======
27 D 77 B 127 =======
28 D 78 A 128 =======
29 A 79 A 129 =======
30 A 80 B 130 =======
31 C 81 C 131 =======
32 D 82 C 132 =======
33 B 83 B 133 =======
34 A 84 B 134 =======
35 B 85 D 135 =======
36 C 86 E 136 =======
37 A 87 C 137 =======
38 C 88 C 138 =======
39 C 89 A 139 =======
40 C 90 C 140 =======
41 D 91 C 141 =======
42 B 92 B 142 =======
43 D 93 B 143 =======
44 C 94 A 144 =======
45 D 95 D 145 =======
46 D 96 B 146 =======
47 E 97 E 147 =======
48 A 98 C 148 =======
49 C 99 D 149 =======
50 C 100 D 150 =======

SINDH PU BL IC S CHO OL & COLLE GE UMERK OT COMPOSED BY: M. HANIF MAHAR