Here E is basically free charge density (Volume) and D is the electric
displacement Note Since E = -∇V, ∇. ε(-∇V) = ρ the above equation for a homogeneous medium can be written as ∇2V = -ρ/ε Poisson’s and Laplace’s Equation
This equation is called as Poisson’s equation. For a free charge region,
i.e., where ρ = 0, the Poisson’s equation takes the form ∇2V = 0.
This equation is Laplace’s Equation. This equation is much useful in
solving electrostatic problems where a set of conductors are maintained at different potentials; for example, capacitors and Vacuum tube diodes. Poisson’s and Laplace’s Equation
Using the expressions for Laplace’s operator ∇2 in cartesian, cylindrical
and spherical coordinate system, we can write Laplace’s Eq. in these coordinate, respectively, as