CHAP2-7 Liquefaction Gaz
CHAP2-7 Liquefaction Gaz
Génie Mécanique
Earlier Lecture
• In the earlier lecture, we have seen that the
precooling of a Simple Linde – Hampson system
improved the liquid yield.
Earlier Lecture
• From the tutorial in the last lecture, we saw that
the yield of a Precooled cycle was more than that
of the Simple System.
Introduction
• The work requirement for a Precooled Linde –
Hampson System is given by
Wc
T1 s1 s2 h1 h2 r hb ,r
a,r
m
h
• The first term is the work requirement in a
Simple Linde – Hampson system.
Introduction
• The yield for a Precooled Linde – Hampson
system is as given below.
m f h h h h
y 1 2
h1 h f
m
h1 h f
• Where, the mass ratio is given by m
r
• The first term in the above expression r is the yield
for a simple Linde – Hampson system. m
• The second term is the additional yield occurring
due to the precooling of the Simple system.
Pr. Chakib SELADJI – Université 6
Université de Tlemcen
COURS DE CRYOGENIE
Génie Mécanique
Introduction
• The increment in the yield is related to the
h h
y h h
h 1 h 2
ra,r d ,r
m
m f m 1 f h1 h f r
r
Introduction
• From the above equations, it is clear that the
liquid yield and work requirement are dependent
on the parameters like refrigerant flow rate (mr),
compression pressure and precooling
temperature.
Introduction
• One such parameter which
a b
is of great importance is the
c
m r refrigerant mass ratio r.
Wc 2
4
m m
g 5
f f
m
f Pr. Chakib SELADJI – Université 9
Université de Tlemcen
COURS DE CRYOGENIE
Génie Mécanique
Introduction
• Let the heat change of the
a b
refrigerant be
c
m r represented
as Qref = r(h r, d – h r, a ).
Wc 2
Introduction
a b
1 Qref < QLHS
mr 2 Qref = QLHS
c
3 Qref > QLHS
Wc 2 • In the 1st case, the value of
T3 would not be equal to Td.
mf QR d
m 2 3
1
• The 2nd case is the
W c1
6
condition to achieve ymax.
4 • Since Qref
m m LHS in the 3
rd
g 5
>
case,
Q the liquid would enter
f f the refrigerating
m compressor.
f Pr. Chakib SELADJI – Université 11
Université de Tlemcen
COURS DE CRYOGENIE
Génie Mécanique
Introduction
• That is any excess flow of
a b
refrigerant than required,
c
m r results into an excess
Wc 2 available heat content.
Introduction
• This is better explained
a b
through a tutorial solved in
c
m r the subsequent slides.
Wc 2
4
m m
g 5
f f
m
f Pr. Chakib SELADJI – Université 13
Université de Tlemcen
COURS DE CRYOGENIE
Génie Mécanique
Tutorial
Part 1
• A Precooled Linde – Hampson System has
Nitrogen and R134a as primary and secondary
fluids respectively. Determine the Liquid yield
and FOM. The operating conditions and other
useful data are as given below.
N2 r Point 2 a b c
I 0.05 101.3 bar p (bar) 1.013 8.104 8.104
II 0.07 101.3 bar T (K) 247 314 305
III 0.05 202.6 bar h (J/g) 380 420 240
IV 0.1 202.6 bar R134a
Tutorial
Part 2
• Also, calculate the ymax for each of the pressures
mentioned and their corresponding r values. Plot
the data graphically and comment on the nature
of y, work requirement, FOM versus r.
N2 r Point 2 a b c
I 0.05 101.3 bar p (bar) 1.013 8.104 8.104
II 0.07 101.3 bar T (K) 247 314 305
III 0.05 202.6 bar h (J/g) 380 420 240
IV 0.1 202.6 bar R134a
Tutorial
Given : Part 1
Cycle : Precooled L – H Cycle with N2.
Temperature : 300 K
Refrigerant : R134a, 1 atm 8 atm
Tutorial
Given : Part 2
Cycle : Precooled L – H Cycle with N2.
Temperature : 300 K
Refrigerant : R134a, 1 atm 8 atm
Methodology
• The two pressures conditions under study are
101.3 bar and 202.6 bar.
Tutorial
N2 1 2 f
a b
mr p (bar) 1.013 101.3 1.013
c
T (K) 300 300 77
Wc 2 h (J/g) 462 445 29
s (J/gK) 4.42 3.1 0.42
m f QR d
2 3 a b c
m1 p (bar) 1.013 8.104 8.104
W c1 T (K) 247 314 305
6
h (J/g) 380 420 240
4 R134a
m m
g
• hd = hc, since the
5
f f expansion is isenthalpic.
m
f Pr. Chakib SELADJI – Université 19
Université de Tlemcen
COURS DE CRYOGENIE
Génie Mécanique
Tutorial
• Ideal Work Requirement
W 1
mi T1 s1 s f h1
N2h 1 f T
f
p (bar) 1.013 1.013
T (K) 300 77
h (J/g) 462 29 f g
s (J/gK) 4.42 0.42 s
Wc
300 4.42 0.42 462 29 767 J /
m
g
Pr. Chakib SELADJI – Université 20
Université de Tlemcen
COURS DE CRYOGENIE
Génie Mécanique
Tutorial : Part – 1
• The T – s diagram for 100 1
2 1
a Precooled Linde – 3
Precooling 6
Hampson system is as Temp
shown. .
Tutorial : Part – 1
• Liquid
yield N2 r Point 2
m h1 h2
f
ha,r hd ,r I 0.05 101.3 bar
y r h h
m h h
1 f 1 f
N2 1 2 f a b c
p (bar) 1.013 101.3 1.013 1.013 8.104 8.104
T (K) 300 300 77 247 314 305
h (J/g) 462 445 29 380 420 240
s (J/gK) 4.42 3.1 0.42 R134a
Tutorial : Part – 1
• Work/unit mass of N2
compressed N2 r Point 2
Wc
T s s h h I 0.05 101.3 bar
1 1 2 1
m
2
r hb,r ha,r
N2 1 2 f a b c
p (bar) 1.013 101.3 1.013 1.013 8.104 8.104
T (K) 300 300 77 247 314 305
h (J/g) 462 445 29 380 420 240
s (J/gK) 4.42 3.1 0.42 R134a
Wc
300 4.42 3.1 462 445
Pr.Chakib SELADJI
0.05420– Université
380é
Universit 23
de Tlemcen
COURS DE CRYOGENIE
Génie Mécanique
Tutorial : Part – 1
• Work/unit mass of N2 100 1
2 1
liquefie 3 Precooling 6
d Temp.
Wc y1
m 1 381 0.055
4 h=cons
f t g
5
Wc Wc s
381 6927.2 J / g
m 1
ym
0.055
f
Tutorial : Part – 1
• Figure of Merit 100 1
2 1
(FOM) 3 Precooling 6
Wc Temp.
m 1 6927.2
Wi
f 4 h=cons
m 767 t g
f
5
s
f Wi
m 767
FOM
1 f Wc 6927.2 0.1107
Tutorial : Part – 1
• Liquid
yield N2 r Point 2
m h1 h2
f
ha,r hd ,r II 0.07 101.3 bar
y r h h
m h h
1 f 1 f
N2 1 2 f a b c
p (bar) 1.013 101.3 1.013 1.013 8.104 8.104
T (K) 300 300 77 247 314 305
h (J/g) 462 445 29 380 420 240
s (J/gK) 4.42 3.1 0.42 R134a
Tutorial : Part – 1
• Work/unit mass of N2
compressed N2 r Point 2
Wc
T s s h h II 0.07 101.3 bar
1 1 2 1
m
2
r hb,r ha,r
N2 1 2 f a b c
p (bar) 1.013 101.3 1.013 1.013 8.104 8.104
T (K) 300 300 77 247 314 305
h (J/g) 462 445 29 380 420 240
s (J/gK) 4.42 3.1 0.42 R134a
Wc
300 4.42 3.1 462 445
Pr.Chakib SELADJI
0.07 420– Université
380é de
Universit
Tlemcen
27
COURS DE CRYOGENIE
Génie Mécanique
Tutorial : Part – 1
• Work/unit mass of N2 100 1
2 1
liquefie 3 Precooling 6
d Temp.
Wc y2
m 2 381.8 0.062
4 h=cons
f t g
5
Wc Wc s
381.8 J/g
ym
m 2 6158.06
0.062
f
Tutorial : Part – 1
• Figure of Merit 100 1
2 1
(FOM) 3 Precooling 6
Wc Temp.
m 2 6158.06
Wf i
4 h=cons
m 767 t g
f
5
s
f Wi
m 767
FOM
2 f Wc 0.1245
6158.06
Tutorial : Part – 2
• Maximum Liquid yield 100 1
2 1
T3 T6 Td 247 Temp.
K
ymax h6 h3
h6 h f
4 h=cons
N2 3 6 f t
f g
p (bar) 101.3 1.013 1.013 5
T (K) 247 247 77 s
h (J/g) 380 408 29
N2 Point 2
101.3 bar
y 408 @ ymax
max 3
408 29 28379 0.074
380 Pr. Chakib SELADJI – Université 30
Université de Tlemcen
COURS DE CRYOGENIE
Génie Mécanique
Tutorial : Part – 2
• r corresponding to ymax
N2 Point 2
m h1 h2 ha,r hd ,r @ ymax
y f
r 101.3 bar
m h h h h
1 f 1 f
N2 1 2 f a b c
p (bar) 1.013 101.3 1.013 1.013 8.104 8.104
T (K) 300 300 77 247 314 305
h (J/g) 462 445 29 380 420 240
s (J/gK) 4.42 3.1 0.42 R134a
462 445 r
380 240
0.074
r 0.11
462 29 462 29
Tutorial : Part – 2
• Work/unit mass of N2
compressed @ ymax Point 2
Wc
T s s h h r=0.11 101.3 bar
1 1 2 1
m
2
r hb,r ha,r
N2 1 2 f a b c
p (bar) 1.013 101.3 1.013 1.013 8.104 8.104
T (K) 300 300 77 247 314 305
h (J/g) 462 445 29 380 420 240
s (J/gK) 4.42 3.1 0.42 R134a
Wc
300 4.42 3.1 462 445
Pr.Chakib SELADJI
0.11420– Université
380éde Tlemcen
Universit 32
COURS DE CRYOGENIE
Génie Mécanique
Tutorial : Part – 2
• Work/unit mass of N2 100 1
2 1
liquefie 3 Precooling 6
d Temp.
Wc ymax 3 0.074
m 3 384
4 h=cons
f t g
5
Wc Wc s
384 5189.2 J / g
m 3
ym
0.074
f
Tutorial : Part – 2
• Figure of Merit 100 1
2 1
(FOM) 3 Precooling 6
Wc Temp.
m 3 5189.2
Wi
f 4 h=cons
m 767 t g
f
5
s
f Wi
m 767
FOM
3 f Wc 5189.2 0.1478
Tutorial : Part – 2
• From the above
a b
m calculations, the value of r
c
r corresponding to ymax
Wc 2 0.11 at the compression
is
pressure of 101.3 bar.
m f QR d
2 3
m1 • For r= 0.12, the enthalpy of
W c1 the refrigerant at the state
6 a is calculated by applying
the energy balance across
4
m m the 3 – fluid heat
g 5 exchanger.
f f
m
f Pr. Chakib SELADJI – Université 35
Université de Tlemcen
COURS DE CRYOGENIE
Génie Mécanique
Tutorial : Part – 2
• Consider a control volume
a b
m enclosing the 3 fluid heat
c
r exchanger.
Wc 2 IN OUT
mr @ d mr @ a
mf QR d
m 2 3 m@2 m@3
1 m – mf @ 6 m – mf @ 1
W c1
6 • Applying the heat balance,
we have
4
m m
m r hd m h m m
g 5 2
f f ,r
m m r m 3 h3 m
f h a,r
f h 6
Pr. Chakib SELADJI – Université 36
Université de Tlemcen
COURS DE CRYOGENIE
Génie Mécanique
Tutorial : Part – 2
• Rearranging the terms,
a b
m
r c m r ha , r hd , r m h3 h2 h1
Wc 2
h6
m f QR d
2 3 • Denoting
m1 m f hthe ratios
1 h6
W c1 m y
6
r m f m
4
m m r
g 5 r ha ,m
r hd , r h3 h2 h1 h6
f
f
m
f
y Pr. h6 SELADJI – Université
h1Chakib 37
Université de Tlemcen
COURS DE CRYOGENIE
Génie Mécanique
Tutorial : Part – 2
r ha , r hd , r h3 h2 h1 h6 y h1 h6
Tutorial : Part – 2
• Substituting the values, we have
N2 1 2 f 6 a c
p (bar) 1.013 101.3 1.013 1.013 1.013 8.104
T (K) 300 300 77 247 247 305
h (J/g) 462 445 29 408 ha,r 240
R134a
ha ,r h d ,r h3 h 2 h1 h6
y 54 y 0.12h a, r 39.8
r h1 h6 h1 h6
Tutorial : Part – 2
• Solving the simultaneous equations we have
values as
y 4 0.074 h a,r
• It is important
364.9to note that the value of y is
same as ymax = 0.074.
Tutorial : Part – 2
• Work/unit mass of N2
compressed above ymax Point 2
Wc
T s s h h r=0.12 101.3 bar
1 1 2 1
m
2
r h b,r ha,r
N2 1 2 f a b c
p (bar) 1.013 101.3 1.013 1.013 8.104 8.104
T (K) 300 300 77 247 314 305
h (J/g) 462 445 29 364.9 420 240
s (J/gK) 4.42 3.1 0.42 R134a
Wc
300 4.42 3.1 462 445Pr.Chakib 420 – Université
0.12SELADJI 364.8é de Tlemcen
Universit 41
COURS DE CRYOGENIE
Génie Mécanique
Tutorial : Part – 2
• Work/unit mass of N2 100 1
2 1
liquefie 3 Precooling 6
d Temp.
Wc y4
m 4 385.6 0.074
4 h=cons
f t g
5
Wc Wc s
385.6 J/g
ym
m 4 5239.13
0.074
f
Tutorial : Part – 2
• Figure of Merit 100 1
2 1
(FOM) 3 Precooling 6
Wc Temp.
m 4 5239.13
Wf i
4 h=cons
m 767 t g
f
5
s
f Wi
m 767
FOM
4 f Wc 0.1464
5239.13
Tutorial : Part – 1
• Tabulating the results for 101.3 bar pressure
condition, we have the following comparison for
the various values of
W W
r y FOM
m f m
I 0.05 0.055 381.0 6927.2 0.111
II 0.07 0.062 381.8 6158.1 0.125
III (ymax) 0.11 0.074 384.0 5189.2 0.148
IV 0.12 0.074 385.6 5239.1 0.146
Tutorial : Part – 1
• Similarly, calculating the results for 202.6 bar
pressure condition, we have the following
comparison for the various values of
W W
r y FOM
m f m
I 0.05 0.085 476.0 5600.0 0.137
II 0.1 0.102 478.0 4704.7 0.163
III (ymax) 0.17 0.127 479.0 3783.5 0.203
IV 0.18 0.127 483.5 3819.6 0.201
Tutorial : Part – 2
• Liquid yield v/s. r
101.3 r y
I 0.05 0.055
II 0.07 0.062
III (ymax) 0.11 0.074
y IV 0.12 0.074
202.6 r y
Precooled L – H System I 0.05 0.085
with N2 and R134a
II 0.1 0.102
III (ymax) 0.17 0.127
IV 0.18 0.127
r
Pr. Chakib SELADJI – Université 46
Université de Tlemcen
COURS DE CRYOGENIE
Génie Mécanique
Tutorial : Part – 2
• Liquid yield v/s. r
• It is clear that the yield
of the system increases
with the increase in the
refrigerant flow rate for a
y given compression
pressure.
Precooled L – H System
with N2 and R134a
• As the compression
pressure increases, the
yield increases for a
given amount of the
r refrigerant flow rate.
Pr. Chakib SELADJI – Université 47
Université de Tlemcen
COURS DE CRYOGENIE
Génie Mécanique
Tutorial : Part – 2
• Liquid yield v/s. r
• For each compression
pressure, the yield
reaches to a maximum
values and thereafter, it
y remains constant.
Precooled L – H System
with N2 and R134a • This value of r is the
limiting value.
r
Pr. Chakib SELADJI – Université 48
Université de Tlemcen
COURS DE CRYOGENIE
Génie Mécanique
Tutorial : Part – 2
• Liquid yield v/s. r
• Any additional increase in
r leads to the liquid flow
into the refrigerant
compressor, which is not
y a desirable condition.
Precooled L – H System
with N2 and R134a • Also, the limiting value
increases with the
increase in the
compression pressure.
r
Pr. Chakib SELADJI – Université 49
Université de Tlemcen
COURS DE CRYOGENIE
Génie Mécanique
Tutorial : Part – 2
• Work/unit mass compressed v/s. r
W
101.3 r
202.6 bar m
I 0.05 381.0
II 0.07 381.8
III (ymax) 0.11 384.0
W
m Precooled L – H System
with N 2and R134a
IV 0.12 385.6
W
202.6 r
m
101.3 bar I 0.05 476.0
II 0.1 478.0
III (ymax) 0.17 479.0
r
IV 0.18 483.5
Pr. Chakib SELADJI – Université 50
Université de Tlemcen
COURS DE CRYOGENIE
Génie Mécanique
Tutorial : Part – 2
• Work/unit mass compressed v/s. r
• We see that the
202.6 bar work/unit mass of gas
compressed increases
with the increase in the
refrigerant flow rate for a
W
m Precooled L – H System given compression
with N and R134a
2
pressure.
• As the compression
101.3 bar
pressure increases, work
requirement also
r increases.
Pr. Chakib SELADJI – Université 51
Université de Tlemcen
COURS DE CRYOGENIE
Génie Mécanique
Tutorial : Part – 2
• Work/unit mass compressed v/s. r
W
101.3 r
202.6 bar m
IV 0.12 385.6
W
202.6 r
W m
m Precooled L – H System
with N 2and R134a IV 0.18 483.5
• It is clear that the work
requirement is increased
101.3 bar
when the r value is
increased beyond the
limiting value.
r
Pr. Chakib SELADJI – Université 52
Université de Tlemcen
COURS DE CRYOGENIE
Génie Mécanique
Tutorial : Part – 2
• Work/unit mass compressed v/s. r
• For each compression
202.6 bar pressure, the increase in
the work requirement is
very small.
W
m Precooled L – H System
with N 2and R134a • Hence, the work
requirement for the
precooling compressor is
negligible as compared to
101.3 bar
that of liquefaction
compressor.
r
Pr. Chakib SELADJI – Université 53
Université de Tlemcen
COURS DE CRYOGENIE
Génie Mécanique
Tutorial : Part – 2
• Work/unit mass Liquified v/s. r
101.3 r W
Precooled L – H
System with
N2 and R134a f m
I 0.05 6927.2
II 0.07 6158.1
W
III (ymax) 0.11 5189.2
mf IV 0.12 5239.1
202.6 r W
f m
I 0.05 5600.0
II 0.1 4704.4
III (ymax) 0.17 3783.5
r
IV 0.18 3819.0
Pr. Chakib SELADJI – Université 54
Université de Tlemcen
COURS DE CRYOGENIE
Génie Mécanique
Tutorial : Part – 2
• Work/unit mass Liquified v/s. r
Precooled L – H
• For each compression
System with
N and R134a
2
pressure, the work
requirement decreases
with the increase in the
W
refrigerant flow rate.
m • As the compression
f pressure increases, the
work requirement
decreases for a given
amount of the refrigerant
r flow rate r.
Pr. Chakib SELADJI – Université 55
Université de Tlemcen
COURS DE CRYOGENIE
Génie Mécanique
Tutorial : Part – 2
• Work/unit mass Liquified v/s. r
Precooled L – H
• The limiting values of r
System with
N and R134a
2
are as shown.
IV 0.12 5239.1
202.6 r W
r f m
IV 0.18 3819.0 56
Pr. Chakib SELADJI – Université
Université de Tlemcen
COURS DE CRYOGENIE
Génie Mécanique
Tutorial : Part – 2
• Work/unit mass Liquified v/s. r
Precooled L – H
• Any further increase in
System with
N and R134a
2
the r, increases the work
input. But under such
conditions, the liquid
W
refrigerant would enter
the precooling
mf
compressor.
r
Pr. Chakib SELADJI – Université 57
Université de Tlemcen
COURS DE CRYOGENIE
Génie Mécanique
Tutorial : Part – 2
• FOM v/s. r
101.3 r FOM
Precooled L – H
System with
I 0.05 0.111
N2 and R134a II 0.07 0.125
III (ymax) 0.11 0.148
IV 0.12 0.146
202.6 r FOM
I 0.05 0.137
II 0.1 0.163
III (ymax) 0.17 0.203
IV 0.18 0.201
r
Pr. Engineering,
Chakib SELADJIIIT
– Université
Universit 58
é de Tlemcen
Prof. M D Atrey, Department of Mechanical Bombay
COURS DE CRYOGENIE
Génie Mécanique
Tutorial : Part – 2
• FOM v/s. r
Precooled L – H
• For each compression
System with
N2 and R134a
pressure, the FOM
increases with the
increase in the
refrigerant flow rate.
• As the compression
pressure increases, the
FOM increase for a given
amount of the refrigerant
flow rate r.
r
Pr. Chakib SELADJI – Université 59
Université de Tlemcen
COURS DE CRYOGENIE
Génie Mécanique
Tutorial : Part – 2
• FOM v/s. r
Precooled L – H
• The limiting values of r
System with
N2 and R134a
are as shown.
101.3 r FOM
IV 0.12 0.146
202.6 r FOM
IV 0.18 0.201
• Any further increase in
the r, decreases the
FOM. But, the liquid
refrigerant would enter
r the precooling
compressor.
Pr. Chakib SELADJI – Université 60
Université de Tlemcen
COURS DE CRYOGENIE
Génie Mécanique
Summary
• For a Precooled Linde – Hampson system, the
liquid yield and work requirement are dependent
on the parameters like refrigerant flow rate (mr),
compression pressure and precooling
temperature.
Summary
• The yield of the system increases with the
increase in the refrigerant flow rate and the
compression pressure.
Summary
• The work requirement for the precooling
compressor is negligible as compared to that of
liquefaction compressor.
Summary
• Figure of Merit (FOM) increases with the increase
in the refrigerant flow rate and the compression
pressure.