Chapter 2
Chapter 2
Engineering Dept.
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WASTEWATER ENGINEERING-I
(WSEE-3122)
FOR WATER SUPPLY & ENV’NTAL ENG’G
STUDENTS
YEAR III, Semister II
INSTRUCTOR: Moltot G. (MSc)
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Chapter 2
Characteristics of municipal and industrial wastewater
Outline:
Physical, chemical and biological characteristics
Flowrates and constituent loadings for process design
Solids and volatile solids & their significance
BOD progression & its formulation
Types of reactors and reactors analysis
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Fig. Thermometer
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Determination of TSS
oNon-filterable residue
oDetermined by filtering a well-mixed WW sample through a 0.2m pore size, the filter is placed in a crucible
and the residue retained on the filter is dried in an oven at 103 0C to 1050C
oAn important quality parameter for primary & secondary effluents
TSS (mg/L) =
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Determination of Total Fixed and Total volatile solids (TFS & TVS)
oThe residue from TS, TSS, or TDS tests is ignited to constant weight at 550 50 0C
oThe weight lost on ignition is total volatile solids (TVS) whereas the remaining solids represent the total
fixed solids (TFS)
Total Volatile Solids (mg/L) =
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Fig.: Imhoff cone for measuring settleable solids
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Example
A well-mixed 25-mL of raw wastewater is used for TS analyses. A well-mixed 50-mL of raw
wastewater is used for suspended solids analyses. Weights (wt.) of evaporating dish with and
without the sample either dried, evaporated, or ignited were determined to constant weight
according to Standard Methods. The laboratory results are:
Tare wt. of evaporating dish = 42.4723 g
Wt. of dish plus residue after evaporation at 105 0C = 42.4986 g
Wt. of dish plus residue after ignition at 550C = 42.4863 g
Tare wt. of filter plus Gooch crucible = 21.5308 g
Wt. of residue and filter plus crucible after drying at 105C = 21.5447 g
Wt. of residue and filter plus crucible after ignition at 550C = 21.5349 g
Compute the concentrations of total solids, volatile solids, fixed solids, total suspended solids, volatile
suspended solids and fixed suspended solids
Exercise (check your answer TS = 229mg/L; FS = 88 mg/L; VS = 132 mg/L)
A laboratory runs a solids test. The weight of the crucible=48.6212 g. A 100- mL sample is placed in the
crucible and the water is evaporated. The weight of the crucible and dry solids=48.6432 g. The crucible
is placed in a 600 ℃ furnace for 24 hr and cooled in desiccators. The weight of the cooled crucible and
residue, or unburned solids,=48.6300 g. Find the total, volatile, and fixed solids
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Measurements of Organic Matter Contents of Wastewater:Biochemical Oxygen Demand
(BOD5): is the oxygen equivalent of organic matter
oDetermined by measuring the DO used by MOs during the biochemical oxidation of organic matter in 5
days at 20 oC
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Example
Determine the 1-day BOD and ultimate BOD for a wastewater whose 5-day BOD @ 20 °C is 200 mg/L. The
reaction constant K= 0.23 d-1. What would have been the 5-day BOD if it had been conducted at 25 °C?
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Measurements of Organic Matter Contents of Wastewater: Total organic carbon (TOC):
This method measures the organic carbon existing in the WW by injecting a sample of the
WW in special device in which the carbon is oxidized to CO2 then CO2 is measured and
used to quantify the amount of organic matter in the WW.
Done instrumentally (5-10 min) to determine TOC in WW sample (mg C/L)
Measures all C as CO2
Only used for small concentration of organic matter
Inorganic C (CO2, HCO3) present in WW must be removed by acidification and aeration of
sample prior to analysis
Typical BOD/TOC of untreated domestic WW 1.2-2 mg O2/mg C
Theoretical Oxygen Demand (ThOD):
If the chemical formula of the OM in the WW is known the ThOD may be computed as the
amount of oxygen required to completely oxidize the organic carbon to CO2 and other end
products (e.g., H2O, PO4-3, SO4-2 and NO3-)
The amount of oxygen required to oxidize a substance to carbon dioxide and water may be
calculated by stoichiometry if the chemical composition of the substance is know
Example: What is the theoretical oxygen demand in mg/L for a 1.67×10-3 molar solution of
glucose, C6H12O6, to decompose completely? 22
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Chemical characteristics: Alkalinity
o A measure of the wastewater’s capability to neutralize acids
o Domestic wastewater is normally alkaline receiving its alkalinity from the water
supply, the groundwater, the materials added during domestic use
o Alkalinity in wastewater results from the presence of the hydroxide ions, carbonate
and bicarbonates of elements such as Ca, Mg, Na, K and NH3
o Essential to buffer (hold the neutral pH) of the wastewater during the biological
treatment processes
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Chemical characteristics: Metals
Discharged from residential dwellings, groundwater infiltration, commercial and
industrial discharge
Nickels, Mn, Lead, chromium, cadmium, zinc, copper, iron ,mercury
Toxic metals : Copper, lead, silver, chromium, arsenic, boron
Chemical characteristics: Nutrients (nitrogen, phosphorus)
Total nitrogen: the sum of ammonia, nitrate, nitrite and organic nitrogen (organic &
inorganic N)
The organic nitrogen concentration is determined by a total kjeldahl nitrogen
(TKN) analysis, which measures the sum of organic and ammonia nitrogen
Organic nitrogen is then calculated by subtracting ammonia nitrogen from the
TKN measurement
Total phosphorus:
Organic phosphorus and inorganic phosphorus
An essential nutrient in biological wastewater treatment
Both nitrogen and phosphorus in wastewater serve as essential elements for biological
growth and reproduction during wastewater treatment processes and in the natural24
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Chemical Constituents of Wastewater and their sources
Carbohydrates Domestic, commercial, and industrial wastes
Organics Fats, oils and grease Domestic, commercial and industrial wastes
Pesticides Agricultural wastes
Phenols Industrial wastes
Proteins Domestic, commercial, and industrial wastes
Priority pollutants Domestic, commercial, and industrial wastes
Surfactants Domestic, commercial, and industrial wastes
VOCs Domestic, commercial, and industrial wastes
Other Natural decay of organic materials
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Mathematical Model for the BOD Curve
The rate of oxygen utilization, at a given
incubation time decreases as
concentration of organic matter
remaining un-oxidized becomes
gradually smaller.
The rate of de-oxygenation depends on
temperature and amount and nature of
organic matter
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Mathematical Model for the BOD Curve
☺Integrating the above equation (2.2), we get
………(2.3)
Where, C is a constant of integration,
When t = zero (0), i.e. at start Lt = L. Substituting in the
equation (2.3), we have
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……..(2.4)
Using 0.434k = kD is the De-oxygenation constant or the
BOD rate constant,
……..(2.5)
……..(2.6)
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……(2.8)
Hence, the ultimate first state (Yu) of a given sewage is
equa1 to the initial oxygen equivalent of the organic
matter present in this sewage (L)
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Mathematical Model for the BOD Curve
KD value
The value of KD determines the
speed of the BOD reaction,
without influencing the ultimate
BOD
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This bioreactor may also help a city upgrade an older treatment plant that cannot
use outdated equipment.
The MBR may work in conjunction with the activated sludge process to treat waste.
The bioreactor reduces the liquid component in the waste mixture that then
provides an opportunity to treat the remaining with an activated sludge process.
The filtration unit with the MBR is usually either an internal or submerged system
or the external sidestream system.
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The operating costs for this treatment are much lower, and the process
uses less room than a standard septic tank.
This method accelerates the treatment of sewage.
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Sewage sprayed over the rock covers the surface and purifies the liquid as it
trickles through the filter.
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The biocarrier is efficient and protects the surface area along with supporting
the growth of bacteria necessary to break down waste.
These bacteria are responsible for the high-rate biodegradation process in the
system.
The MBBR is much smaller and expandable than other systems.
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Water Supply and Environmental Engineering
water is life! 49