Measurement in Chemistry
Measurement in Chemistry
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Measurement
The Metric System of Units
• Other units are related to the base unit by a power of 10.
• The prefix of the unit name indicates if the unit is larger
or smaller than the base unit.
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Measurement
Measuring Length
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Measurement
Measuring Mass
Mass is a measure of the amount of matter in an
object.
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Measurement
Measuring Volume
1 mL = 1 cm3 = 1 cc
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Uncertainties in Measurements
–Every measurement carries
uncertainty
–All measurements must include
estimates of uncertainty with them
–There is an uncertainty of at least
one unit in the last digit
Three volume measurements
with their uncertainties:
• Large graduated cylinder, 8 ± 1 mL
• Small graduate cylinder, 8.0 ± 0.1 mL
• Pipet or buret, 8.00 ± 0.01 mL
–Uncertainty of ± in the last
digit is assumed but not
stated
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Significant Figures
Tell us…
• How much information we
know about a
measurement…
• How good a measurement
is…
Significant Figures
Exact and Inexact Numbers
An exact number results from counting objects or is
part of a definition.
•10 fingers
•10 toes
•1 meter = 100 centimeters
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Significant Figures
Determining Significant Figures
65.2 g 255.345 g
3 sig. figures 6 sig. figures
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Significant Figures
Rules to Determine When a Zero
is a Significant Figure
29.05 g 1.0087 mL
4 sig. figures 5 sig. figures
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Significant Figures
Rules to Determine When a Zero
is a Significant Figure
2570 m 1245500 m
3 sig. figures 5 sig. figures
Example:
Using different balances, 3 different students
weigh the same object. They report the
following masses:
a.1.611 g
b.1.60 g
c.0.001611 kg
How many significant figures does each
value have?
A. Determine the number of
significant figures.
1) 23000 g
2) 0.0045 kg
3) 2009 mL
4) 26.09 km
5) 7653 m
B. Determine the number of
significant figures.
1) 193000 mL
2) 0.0028000 kg
3) 2011 cm
4) 10.09 km
5) 7653000 mg
Significant Figures
Rules for Multiplication and Division
The answer has the same number of significant figures
as the original number with the fewest significant
figures.
4 sig. figures
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Significant Figures
Rules for Rounding Off Numbers
to be retained to be dropped
y x 10x Exponent:
Any positive
or negative
Coefficient: whole number.
A number between
1 and 10.
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Scientific Notation
HOW TO Convert a Standard Number to Scientific Notation
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Seatwork: Express into scientific notation
1) 123.05 mL
2) 975,200,000 g
3) 0.0000025 km
4) 0.1258 oC
5) 0.0025003 m
Seatwork: Express into standard number
1) 6.852x105
2) 5.85x1015
3) 3.6x10-5
4) 2.68452x10-1
5) 8.2x10-7
Problem Solving Using the Factor-Label
Method
Conversion Factors
Conversion factor: A term that converts a quantity in
one unit to a quantity in another unit.
original desired
x conversion factor = quantity
quantity
2.21 lb
1 kg
130 lb x or Answer
2 sig. figures
1 kg
2.21 lb = 59 kg
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Using the Factor-Label Method
HOW TO Solve a Problem Using Conversion Factors
325 mg x 1g = 0.325 g
1000 mg
3 sig. figures 3 sig. figures
Unwanted unit
cancels.
1.0 pt x 1 qt x 1 L = 0.47 L
2 pt 1.06 qt
2 sig. figures 2 sig. figures
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Convert!
a) 3.9 mL to L
b) 112.2 lbs to kg
c) 2.814 cm2 to m2
d) 50.9 km/hr to m/s
e) 28.3 g/cm3 to kg/m3
Temperature
Temperature is a measure of how hot or cold an object is.
Three temperature scales are used:
•degrees Fahrenheit (oF)
•degrees Celsius (oC)
•Kelvin (K)
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Density
Density
Density: A physical property that relates the mass of
a substance to its volume.
mass (g)
density =
volume (mL or cc)
5.0 g x 1 mL = 4.8 mL
1.05 g
2 sig. figures 2 sig. figures
Unwanted unit
cancels.