Scribd
Upload
47 views15 pages

Dodecanoyl Chloride: CH Bend

1) Dodecanoyl chloride is a carboxylic acid derivative with a base peak of 1800 cm-1. 2) 2-Methylpropanoic acid is a carboxylic acid with characteristic O-H and C=O peaks and a base of 1710 cm-1. 3) Propanamide is an amide with symmetric and asymmetric peaks near 1690 cm-1 representing the C=O stretch.

Uploaded by

Fatima Ahmed
Copyright
© © All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
Available Formats
Download as PPTX, PDF, TXT or read online on Scribd
47 views15 pages

Dodecanoyl Chloride: CH Bend

1) Dodecanoyl chloride is a carboxylic acid derivative with a base peak of 1800 cm-1. 2) 2-Methylpropanoic acid is a carboxylic acid with characteristic O-H and C=O peaks and a base of 1710 cm-1. 3) Propanamide is an amide with symmetric and asymmetric peaks near 1690 cm-1 representing the C=O stretch.

Uploaded by

Fatima Ahmed
Copyright
© © All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
Available Formats
Download as PPTX, PDF, TXT or read online on Scribd
You are on page 1/ 15

ACID CHLORIDE

Dodecanoyl Chloride BASE = 1800

CH bend

C
C=O CH3 (CH2)10 Cl
C-H

3608
CARBOXYLIC ACID
BASE = 1710

2-Methylpropanoic Acid

O-H

C-O C
C-H C=O CH3 CH OH

CH3
AMIDE
two peaks BASE = 1690
sym / asym Propanamide

C-H O
C=O C
NH2 CH3 CH2 NH2
CH bend
ALKENES
AROMATICS

C=C STRETCHING
Typical Infrared Absorption
Regions
WAVELENGTH (mm) C=C
2.5 4 5 5.5 6.1 6.5 15.4

O-H C-H C N C=O C=N C-Cl


Very C-O
N-H C C few C=C
C-N
X=C=Y bands C-C
(C,O,N,S) N=O N=O *

4000 2500 2000 1800 1650 1550 650


FREQUENCY (cm-1)
The C=C stretching region
• C=C double bond at 1650 cm-1 is often weak or
not even seen.

• C=C benzene ring shows peak(s) near 1600 and


1400 cm-1 , one or two at each value -
CONJUGATION LOWERS THE VALUE.

• When C=C is conjugated with C=O it is


stronger and comes at a lower frequency.
ALKENE

1-Hexene

=C-H C=C C-H


bend

C-H
aliphatic
CH2 CH CH2 CH2 CH2 CH3
AROMATIC

Toluene

benzene
C-H CH3 benzene
C=C

oops
C-O STRETCHING
The C-O stretching region
• The C-O band appears in the range of
1300 to 1000 cm-1

• Look for one or more strong bands


appearing in this range!

• Ethers, alcohols, esters and carboxylic


acids have C-O bands
ETHER

Dibutyl Ether BASE = 1100

CH2 CH3
C-H bending
C-O
CH3 CH2 CH2 CH2 O CH2 CH2 CH2 CH3
N=O STRETCHING
Typical Infrared Absorption
Regions
WAVELENGTH (mm)
N-O
2.5 4 5 5.5 6.1 6.5 15.4

O-H C-H C N C=O C=N C-Cl


Very C-O
N-H C C few C=C
C-N
X=C=Y bands C-C
(C,O,N,S) N=O N=O *

4000 2500 2000 1800 1650 1550 650


FREQUENCY (cm-1)
The N=O stretching region

• N=O stretching -- 1550 and 1350 cm-1


asymmetric and symmetric stretchings

• Often the 1550 cm-1 peak is stronger than


the other one
NITROALKANE

2-Nitropropane

C-H

N=O

NO2
gem-dimethyl
CH
CH3 CH3 N=O

You might also like