Chapter 11 Introduction To Organic Chemistry: Alkanes
Chapter 11 Introduction To Organic Chemistry: Alkanes
General, Organic, and Biological Chemistry Copyright © 2010 Pearson Education, Inc. 1
Organic Compounds
An organic compound
is a compound made from carbon atoms
has one or more C atoms
has many H atoms
may also contain O, S, N, P, and halogens
General, Organic, and Biological Chemistry Copyright © 2010 Pearson Education, Inc. 2
Properties of Organic Compounds
Typical organic compounds
contain carbon
have covalent bonds
have low melting points
have low boiling points
are flammable
are soluble in nonpolar
solvents
are not soluble in water Oil (organic) and
water (inorganic)
General, Organic, and Biological Chemistry Copyright © 2010 Pearson Education, Inc. 6
Solution
General, Organic, and Biological Chemistry Copyright © 2010 Pearson Education, Inc. 7
Writing Formulas for Carbon
Compounds
In carbon compounds,
carbon has 4 valence electrons, and hydrogen has 1
•
•C• H•
•
to achieve an octet, C forms four bonds
H H
HCH H C H
H H CH4 (methane)
General, Organic, and Biological Chemistry Copyright © 2010 Pearson Education, Inc. 8
Tetrahedral Structure of Carbon
VSEPR theory predicts
that a carbon atom with
four single, covalent
bonds is tetrahedral as
shown in a
(a) tetrahedron
(b) ball-and-stick model
(c) space-filling model
(d) expanded structural
formula
HCCH H C C H
•• ••
H H H H CH3─CH3 (methane)
General, Organic, and Biological Chemistry Copyright © 2010 Pearson Education, Inc. 10
Tetrahedral Structure of Ethane
In VESPR, two carbon
atoms in ethane each has
a tetrahedral shape as
shown in a
(a) tetrahedron
(b) ball-and-stick model
(c) space-filling model
(d) expanded structural
formula