BOILING &
CONDENSATION
Boiling
Boiling - transformation of
liquid to vapor when the
liquid is brought into contact
with a solid surface
maintained at a temperature
(Ts) greater than the
saturation temperature (Tsat)
of the liquid
Convection heat transfer from
solid surface to the liquid
Involves formation of bubbles
at the surface
FS 2015-2016
ChE 134/Dr. J.A. Bedano
Contrast this to evaporation
Which occurs at the liquidvapor interface when the
liquid temperature reaches
saturation, or when the vapor
pressure is less than the
saturation pressure of the
liquid at the given
temperature
Evaporation occurs under
equilibrium conditions and is
not characterized by bubble
formation
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ChE 134/Dr. J.A. Bedano
FS 2015-2016
ChE 134/Dr. J.A. Bedano
Heat transfer
FS 2015-2016
ChE 134/Dr. J.A. Bedano
Boiling classification
FS 2015-2016
ChE 134/Dr. J.A. Bedano
Boiling regimes
Transition
boiling
Natural
convection
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Film
boiling
Nucleate
boiling
ChE 134/Dr. J.A. Bedano
Pool boiling curve
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ChE 134/Dr. J.A. Bedano
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ChE 134/Dr. J.A. Bedano
From the start until pt. A pure
convection with liquid rising to the
surface and evaporates
A-B: nucleate boiling with isolated
bubble formation in few preferential
sites; bubbles condense in the liquid
since higher bubble T cause heat
transfer from bubble to liquid
causing the vapor to condense and
the bubble to collapse
FS 2015-2016
ChE 134/Dr. J.A. Bedano
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B-C: nucleate boiling with
rapid bubble formation
rising to the surface in
columns; liquid is now
hotter than the bubble,
and heat transfer from
liquid to bubble causes
the bubble to grow and
rise due to bouyancy
Agitation by rising
bubbles further increases
heat flux (q/A)
Pt. C: peak heat flux
FS 2015-2016
ChE 134/Dr. J.A. Bedano
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C-D: transition phase, partial
nucleate boiling and unstable film
boiling; surface becomes blanketed
with vapor pockets that decrease the
q/A
Pt D Leidenfrost point lowest het
flux
Beyond pt D surface covered by a
vapor blanket and heat transfer is by
convection and radiation, thereby
increasing q/A
FS 2015-2016
ChE 134/Dr. J.A. Bedano
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Further lecture/discussion on:
Film coefficients and heat transfer
equations for nucleate boiling & film
boiling for different plate/pipe
configurations
Maximum heat flux at pt C, and
minimum heat flux at the Leidenfrost
point
Sample problems
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ChE 134/Dr. J.A. Bedano
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CONDENSATION
Condensation occurs when the
temperature of the vapor is reduced
below its saturation temperature
Classification
Film condensation
Dropwise condensation
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ChE 134/Dr. J.A. Bedano
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Film condensation
Dropwise
condensation
Forms on outside surface
Small drops form, coalesce
of vertical pipes or plates
and liquid flows from surface
Large h (110000 W/m2-K)
Small h
Used for design
purposes
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2015-2016
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Water-tube boiler
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ChE 134/Dr. J.A. Bedano
Superheated
steam
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Assignments:
Geankoplis: Nos. 4.8-1 to 4.8-5
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ChE 134/Dr. J.A. Bedano
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