Air Pollution Dispersion
Air Pollution Dispersion
Dispersion Modeling
Stability
Dry adiabatic lapse rate temperature
decreases due to lower pressure (ideal gas law)
dT
Example
Z(m)
2
318
T(C)
-3.05
-6.21
T T2 T1 6.21 3.05
0.0100 C/m
z z 2 z1
318 2
1.00 C/100 m
Since lapse rate = , atmosphere is neutral
Example
Z(m)
10
202
T(C)
5.11
1.09
T T2 T1 1.09 5.11
0.0209 C/m
z z 2 z1
202 10
2.09 C/100 m
Since lapse rate is more negative than ,
(-1.00 C/100 m), atmosphere is unstable
In unstable air, the plume will whip up and down as the atmosphere mixes
around (whenever an air parcel goes up, there must be air going down
someplace else to maintain continuity, and the plume follows these air currents).
This gives the plume the appearance that it is looping around.
Vertical dispersion is very high.
Less wind speed: Strong & Moderate radiation, day time Mechanical Turbulence
is enhanced.
High probability of high concentrations sporadically at ground level close to
stack.
Example
Z(m)
18
286
T(C)
14.03
12.56
T T2 T1 12.56 14.03
0.0055 C/m
z z 2 z1
286 18
0.55 C/100 m
High wind speed: Night time, High horizontal dispersion, Vertical dispersion is
suppresses by stable atmosphere.
In the vertical, dispersion is suppressed by the stability of the atmosphere, so
pollution does not spread toward the ground. This results in very low pollution
concentrations at the ground
Temperature Inversions
Extreme case of stability when lapse rate
is actually positive, i.e. temperature
increases with altitude
Resulting temperature inversion prevents
nearly all upward mixing
Fanning Plume:
Usually occurs at night, or 1200m-1800m above ground. There is high ground
concentration if stack is short or if plume moves through rugged terrain. Occurs
in stable inversion atmospheric conditions.
Fumigation:
most dangerous plume: contaminants are all coming
down to ground level. They are created when
atmospheric conditions are inversion stable above the
plume and unstable below. This happens most often
after the daylight sun has warmed the atmosphere,
which turns a night time fanning plume into fumigation
for about a half an hour.
x, y,0, H
E
exp
s y s z u
1 y
2 s y
1
H
exp
s
2
vs
H
u
1.5
Ts Ta
d
2.68 10 P
T
a
A Extremely Unstable
D Neutral
B Moderately Unstable
E Slightly Stable
C Slightly Unstable
F Moderately Stable
z2
u2 u1
z1
Example
A stack in an urban area is emitting 80 g/s
of NO. It has an effective stack height of
100 m. The wind speed is 4 m/s at 10 m.
It is a clear summer day with the sun
nearly overhead. Estimate the ground
level concentration at a) 2 km downwind
on the centerline and b) 2 km downwind,
0.1 km off the centerline.
Example
1. Determine stability class
Assume wind speed is 4 km at ground
surface. Description suggests strong
solar radiation.
Stability class B
Example
2. Estimate the wind speed at the effective stack
height
Note: effective stack height given no need to
calculate using Hollands formula
z2
u2 u1
z1
100
4
10
0.15
5.65 m/s
Example
3. Determine y and z
y = 290
z = 220
220
290
Example
4. Determine concentration using Eq
a. x = 2000, y = 0
80
1 0
1 100
C (2000,0)
exp
exp
(290)(220)(5.6)
2 290
2 220
Example
b. x = 2000, y = 0.1 km = 100 m
80
1
C (2000,100)
exp
(290)(220)(5.6)
2
100
1 100
exp
290
2 220