Cathodic Protection
Cathodic Protection
PG&E Office San Francisco January 18, 2007 Craig K. Meier Corrosion Control Incorporated
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Corrosion process for tanks and piping Principles of cathodic protection Effects of coatings Cathodic protection design requirements Selecting the proper system Construction implementation issues Compliance testing Continued monitoring and maintenance
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Energy
Ore
Mill Steel
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Conventional Current Flow Fe++ Iron ion eCathode Anode Electron flow H2O + 1/2O2 + 2e- 2OHFe Fe++ + 2e-
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Rate of Corrosion
Soil Corrosivity
Resistivity pH Salts
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Sand
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Corrosion Current
Corrosion
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Copper ground
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Concrete or asphalt
API recommends against the use of asphalt and concrete tank pads.
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Corrosion Losses
Will occur in all plants Rate of loss dependent on soil and materials used Coatings alone do not stop soil corrosion Care during construction can significantly reduce losses
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Corrosion Control
Material selection Bedding Coatings Cathodic Protection
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Coating
Coating flaw
Steel
Cathodic Protection
Pipe Ground
Cathodic Protection
Galvanic Impressed Current
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Galvanic Anode
Exothermic weld Pipe -500mV Magnesium anode
-1700mV
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Bare steel tank bottom Protects only outer floor Galvanic anode
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Impressed Current
AC Power Rectifier
(+)
(-)
Structure
Anode
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Impressed Current
Anode
Unit 1
Unit 2
Unit 3 Rectifier
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Impressed Current
Tank
Rectifier
20
Impressed Current
Anodes produce high amounts of current, 1000 to 5000 milliamperes per anode. High current output allows protection of bare steel structures. Structures do not necessarily need to be electrically isolated.
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Design Options
Design documents issued in construction plans Contract responsible for cathodic design
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Design Submittal
Qualifications of person responsible for design, supervision during installation and testing
Can not mail order
Detailed calculations for each tank and pipeline showing current required, number of anodes, circuit resistance and life Material list providing descriptions, models and quantities Product data sheets Detailed installation plans not diagrams
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Implementation
The cathodic design submittals must be approved before construction of structures A site meeting must be held to discuss how the cathodic protection system will be installed, and special concerns during construction Mechanical and electrical foremen should be involved in cathodic discussions
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Grounded Pipeline
Pipe
Ground wire
Anode
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Instrument
Dielectric gasket
Conduit
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Test station
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Weld Coating Pipe wall Standard Weld Clip Post Hydro Weld
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Rectifier
Tank bottom
12 sand
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-.892
6 PES
Set to DC millivolts
Shunt
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(-)
(+) PES
Meter
Cell
Potential of steel
Impressed anode
Voltage gradient
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Emeasured = Ptank + I R If the current is momentarily interrupted, I=O, then; Emeasured = Ptank + (O) (R) Instant Off potential
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Impressed current
-850mV or more negative instant-off -or 100mV polarization shift
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Compliance Report
Tabulated Data Narrative analysis of the data Compliance statement Calculated anode life Test procedures and instrumentation As-built drawings O&M Manual
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O&M Manual
Test Procedures Instrument requirements Qualification requirements Frequency Criteria Trouble shooting Spare parts Wiring diagrams
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Conclusions
Cathodic protection is viable and necessary to preserve power plant structures Proper planning and coordination are essential through out the design and construction phases, to ensure cathodic protection systems work properly Properly implemented and monitored cathodic protection will extend the service life of storage tanks and yard piping more than 30 years
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