PRACTICE SHEET
CHEMISTRY
REDOX REACTION
1. Find the value of oxidation state of Co in 8. The incorrect order of decreasing oxidation number
Ag[Co(CO)4]: of S in compound is:
(A) I (B) -1 (A) H2SO7> Na2S4O6> Na2S2O3> S8
(C) Zero (D) None of these (B) H2SO5 > H2SO3> SCl2 > H2S
2. Which of the following reactions involve oxidation (C) SO3 > SO2 >H2S > S8
and reduction? (D) H2SO4> SO2 > H2S > H2S2O8
(A) NaBr + HCl → NaCl + HBr
9. The reaction 3ClO − (aq)
→ ClO3− (aq) + 2Cl− (aq)
(B) HBr + AgNO3
→ AgBr + HNO3
(C) H2+ Br2 is an example of:
→ 2HBr
(D) Na2O+ H2SO4
→ Na2SO4 + H2O (A) oxidation
3. When ammonia is passed over heated copper (B) reduction
oxide, the metallic copper is obtained. The reaction (C) disproportionation
shows that ammonia is: (D) decomposition reaction
(A) a dehydrating agent 10. Oxidizing agents are species which:
(B) an oxidising agent (A) lose electrons
(C) a reducing agent (B) gain electrons
(D) a nitrating agent (C) neither lose nor gain electrons
4. Manganese achieves its maximum oxidation state (D) take part in solid-state reactions
in its compound: 11. In which of the following reactions does H2O2 act
(A) MnO2 (B) Mng04 as a reducing agent?
(C) KMnO4 (D) KMnO4 (A) 2 FeCl2 + 2HCl + H2O2
→ FeCl3 + 2H2O
5. Oxidation number of underlined elements are. (B) Cl2 + H2O2
→ 2HCl + O2
2− +
N 2O5 ,SO , NH :
3 4 (C) 2HI+ H2O2 + 2H2O +I2
(A) +5, +2, -3 (B) +6, -2, +3 (D) H2SO3 + H2O2
→ H2SO4 + H2O
(C) +6, +2, -3 (D) +5, +4, -3 12. The oxidation number of an atom in a given
6. Phosphorous has the oxidation state of +3 in: species (molecule, ion or free atom) is the:
(A) phosphorous acid (H3PO3) (A) acutal charge of the atom
(B) ortho phosphoric acid (H3PO4) (B) valency of the atom
(C) meta phosphoric acid (HPO3) (C) formal charge of the atom
(D) pyro phosphoric acid (H4P2O7) (D) actual charge of the atom if the atom exists as
7. Which statement is wrong?
monoatomic ion, or the hypothetical char
(A) Oxidation number of oxygen is +1 in peroxides
(B) Oxidation number of oxygen is +2 in oxygen assigned to the atom in the species by sim
difluoride rules.
1 13. The oxidation number of Cr is + 6 in:
(C) Oxidation number of oxygen is in
2
superoxides (A) FeCr2O4
(D) Oxidation number of oxygen is (-2) in most of (B) Fe2(CrO4)2
its compounds, (C) Cr2(SO4)O3
(D) [Cr(OH)4]-
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14. Suppose a compound contains atoms A, B and C. 22. Select the reaction which describes the existence of
The axidation number of A is +2, B is+5 and C is- I 2O5 (s) as (IO +2 ) :
2. The possible formula of the compound would
(A) I 2O5 + HF
→ HIO 2 + FIO3
be:
(B) I 2O5 + HF
→ IO 2 F + HIO3
(A) ABC2 (B) A2(BC3)2
(C) A3(BC4)2 (D) A3(B4C)2 (C) I 2O6 + HF
→ HOI + IO 4 F
15. Oxidation is a process in which: (D) I 2O6 + HF
→ IOF + HIO 4
(A) oxidation number increases 23. In FeCr2O4 the oxidation numbers of Fe and Cr are:
(B) electrons are lost (A) +2 and +3 (B) 0 and +2
(C) de-electronation takes place (C) +2 and +6 (D) +3 and +6
(D) all the above happen 24. The oxidation number of phosphorus in Mg2P2O7
16. Which of the following is not a redox reaction? is:
(A) Mg+N2
→ Mg3N2 (A) +3 (B) +2
(B) MnO 4 − + C2O 24−
→ Mn 2+ + CO 2 (C) +5 (D) -3
(C) CuSO 4 + KI
→ Cu 2 I 2 + I 2 + K 2SO 4 25. The oxidation states of sulphur in the anions SO32− ,
(D) AgCl + NH 3
→[Ag(NH 3 ) 2 ]Cl SO32− ,S2O 24− and S2O62− follow the order:
17. Oxidation states of Cu and Fe in CuFeS2 are (A) S2O62− < S2O 42− < SO32−
respectively: (B) S2O 42− < SO32− < S2O62−
(A) I and II (B) II and III
(C) SO32− < S2O 42− < S2O62−
(C) I and III (D) II and II
(D) S2O 42− < S2O62− < SO32−
18. What is the oxidation state of Sn in Ca 2Sn 2Si 6O18 ?
26. The resonating structures of cyanate ion are
(A) I (B) II
I− I− I+ 2−
(C) III (D) IV O ≡ c ≡ N ←
→ O − C ≡ N ←
→N ≡ C− N. The
19. Consider the salt K2H3(C2O4)8 2H2O. correct set of oxidiation states of O, C and N
The relationship between x, y and z is: respectively with the most stable structure out of
(A) x+y-z=0 the above is:
(B) x+y=2z (A) -2, +4,3 (B)-2, +4,-3
(C) x+y+z=0 (C) 2, +4,-3 (D) 0, +4.-5
27. Which ordering of compounds is according to the
(D) none of these
decreasing order of the oxidation state of nitrogen?
20. The average oxidation state of sulphur in sodium (A) HNO3, NO, NH4Cl, N2
tetrathionate (Na2S4O6) is: (B) HNO3, NO, N2, NH4Cl
(C) HNO3, NH4Cl, NO,N2
(A) 0 (B) 5
(D) NO, HNO3, NH4Cl, N2
(C) 2.5 (D) 3.0
21. The difference in the oxidation numbers of the two 28. In the reaction 2Ag + 2H2SO4 →
Ag2SO4+2H2O + SO2, sulphuric acid acts as:
types of sulphur atoms in Na2S4O4 is: (A) an oxidizing agent
(A) 5 (B) 4 (B) a reducing agent
(C) 3 (D) 2 (C) a catalyst
(D) an acid as well as an oxidant
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29. Among the following, the species in which 36. Which of the following is a redox reaction?
oxidation state of an element is +6, is: (A) NaCl + KNO3
→ NaNO3+KCl
(B) Cr ( CN )6
3−
(A) MnO −4 (B) CaC2O4 + 2HCl
→ CaCl2 + H2C2O4
(C) NiF62− (D) CrO 2Cl2 (C) Mg(OH)2+2NH4Cl
→ MgCl2+2NH4OH
30. Oxidation number of iron in Na2[Fe(CN)3(NO*)] (D) Zn + 2AgCN
→ 2Ag +Zn(CN)2
is: 37. A substance which participates readily in both
(A) +2 (B) +3 acid-base and oxidation-reduction reactions is:
8 (A) Na2CO3 (B) KOH
(C) + (D) none of these
3 (C) KMnO4 (D) H2C2O4
31. 1 mole of N2H4 loses ten moles of electrons to 38. Which of the following may act both as an
form a new compound Y. Assuming that all the oxidizing OHS and reducing agent?
nitrogen appears in the new compound, what is the (A) H2O2 (B) MnO2
oxidation state of nitrogen in Y? (There is no (C) SO2 (D) All of these
change in the oxidation state of hydrogen). 39. In compound HN3 (hydrazoic acid), oxidation state
(A) -1 (B)-3 of N atoms are:
(C) +3 (D) +5 (A) 0, 0, 3 (B) 0,-2,+1
32. The oxidation number of sulphur in S8, S2F2 and (C) 1, 1,-3 (D) -3,-3,-3
H2S respectively are: 40. In the reaction Ca + H2 → CaH2 select the
(A) 0,+1 and -2 incorrect statement.
(A) Calcium undergoes oxidation
(B) +2, +1 and -2
(B) Hydrogen undergoes reduction
(C) 0, +1 and +2 (C) Calcium acts as oxidising agent
(D)-2, +1 and -2 (D) Hydrogen acts as oxidising agent
41. Which of the following is not a redox reaction?
33. Amongst the following, the pair having both the
(A) CO+NO2 → CO2+ NO
metals in their highest oxidation state is:
(B) 3SnCl2+6 HCl +2 NO
→ 3SnCl4 +2NH2OH
(A) [Fe(CN6)]3- and [Co(CN)6]3-
(C) PCl3 + Cl2
→ PCl5
−
(B) CrO2Cl2 and MnO 4 (D) SiO2 + 4 HF → SiF4+2H2O
(C) TIO2 and MnO2 42. The oxidation states of the most electronegative
element in the products of the reaction of BaO2
(D) [MnCl4]2- and [NiF6]2-
with dilute H2SO4 is:
34. Which of the following chemical reactions depic (A) 0 and -1 (B) -1 and -2
the oxidizing behaviour of H2SO4? (C) -2 and 0 (D) -2 and +1
43. Which equation represents an oxidation-reduction
(A) 2HI + H 2SO 4
→ I 2 + SO 2 + 2H 2O reaction?
(B) Ca ( OH )2 + H 2SO 4
→ CaSO 4 + 2H 2O (A) H2SO4 +2NH3 → (NH4)2SO4
(B) H2SO4+ Na2CO3
→ Na2SO4 +H2O+CO2
(C) NaCl + H 2SO 4
→ NaHSO 4 + HCl
(C) 2K2CrO4 + H2SO4
→ K2Cr2O7+ K2SO4 +
(D) 2PCl5 + H 2SO 4
→ 2POCl3 + 2HCl + SO 2Cl2 H2O
35. The oxidation state of Cr in [Cr(NH3)4Cl2]+ is: (D) 2H2SO4 + Cu
→ CuSO4 + 2H2O+ SO2
(A) +3 (B) +2
(C) +1 (D) 0
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44. For which substance is the oxidation number a 53. Which substance can act only as a reducing agent?
vanadium the same as that in the VO3− ion? (A) I2 (B) BrCl
(A) VN (B) VCl3 (C) NaBr (D) HIO4
(C) VOSO4 (D) VF5 54. Which species can act as an oxidizing agent but no
45. Which substance participates readily in both acid- as a reducing agent?
base and oxidation-reduction reactions? (A) Cl2 (B) Cl-
(A) Na2CO3 (B) KOH (C) ClO −2 (D) ClO −4
(C) KMnO4 (D) H2C2O4 55. What is the oxidation number of Ti in the
46. P4(s) + 3OH-(aq) + 3H2O(l)
→ PH3(g) +3H2PO2 compound Na 2Ti3O 2 ?
-
(aq). For this reaction, the oxidizing and reducing (A) -2 (B) +4
agents are, respectively: (C) +6 (D) +12
- -
(A) P4 and OH (B) OH and P4 56. Which range includes the average oxidation state
(C) P4 and H2O (D) P4 and P4 of S in Na2S4O6?
47. What is the average oxidation number of tungsten (A) Less than 0 (B) 0 to +2)
2−
in the ion, W6O6Cl12 ? (C) +2 to +4 (D) Greater than +4
(A) 2.7 (B) 3.3 57. Which change represents an oxidation?
(C) 3.7 (D) 4.3 (A) NO −2
→ N 2 (B) VO 2+
→ VO3−
48. In which case does chromium undergo reduction? (C) ClO −
→ Cl− (D) CrO 24−
→ Cr2O7
→ CrOF3 (B) Cr 3+
(A) Cr CrO3 → Cr(OH) −4 58. What is the oxidation number of Mo in MoO2Cl2?
(C) 2CrO 24−
→ Cr2O72− (D) Cr 3+
→ CrO 24− (A) 0 (B) +3
49. In which species does the underlined element have (C) +5 (D) +6
an oxidation number of +2? 59. All of the reactions below represent oxidation
reduction processes except the
(B) Fe ( CN )6
4−
(A) SO 2Cl2
(A) combustion of tin in chlorine gas.
(C) HNO 2 (D) Ni ( CO )4 (B) decomposition of potassium chlorate.
50. Which transformation is an oxidation? (C) neutralization of sodium hydroxide.
(A) VO3−
→ VO +2 (B) CrO 2−
→ CrO 42− (D) reaction of magnesium with hydrochloric acid.
(C) SO 24−
→ SO 24− (D) NO3−
→ NO 2 60. Which pair of substances do the nitrogen atoms
51. Which represents an oxidation? have the same oxidation state?
(A) BrO −
→ Br2 (B) NO 2
→ N 2O 4 (A) HNO3 and N2O5 (B) NO and HNO2
(C) Cr 3+
→ CrO 24− (D) VO3−
→ VO +2 (B) N2 and N2O (D) HNO2 and HNO3
52. For the balanced equation: 61. In the equation below, which species acts as the
8H ( aq ) + 5Fe
+ 2+
( aq ) + MnO ( aq )
−
4 oxidizing agent?
→ 5Fe 3+
( aq ) + Mn 2+ ( aq ) + 4H 2O8 ) Pb(s)+ PbO2(s)+2 H+(aq) + 2 HSO −4 (aq)
Which statement is correct?
(A) Fe2+(aq) undergoes oxidation → 2 PbSO 4 (s) + 2H 2O ( l )
(B) Fe2+(aq) is the oxidizing agent (A) Pb(s) (B) PbO2(s)
(C) H+ (aq) undergoes oxidation
(D) H+(aq) is the oxidizing agent (C) H+(aq) (D) HSO 4− ( aq )
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62. In which species does sulphur have the lowest 70. What is the oxidation number of As in the
oxidation state? compound K(NH4)2AsO4 6H2O?
(A) SCl2 (B) OSF2
(A)-3 (B) +1
(C) H2SO3 (D) SF6
(C) +3 (D) +5
63. What is the average oxidation state of copper in the
superconductor YBa2 Cu3O7? 71. aMnO −4 + bI − + cH +
→ dMn 2+ + eI 2 + fH 2O
(A) +2 (B) +2.33 In above balanced reaction, value of will be:
(C) +2.67 (D) +3 (A) 1.3 (B) 1.2
64. Which species has an atom with an oxidation (C) 8 (D) 5
number of +3? 72. In the reaction,
(A) ClO −2 (B) PO34− xFeCl3 + yH 2S
→ FeCl2 + S + HCl
(C) S2O 22− (D) NO +2 (A) x=2,y=1 (C) x3,y=2
(C) x=4,y=3 (D) x2,y=2
65. What is the oxidation number of rhenium in
73. For the redox reaction
Ca(ReO 4 ) 2 ?
xP4 + yHNO3
→ H 3PO 4 + NO 2 + H 2O
(A) +1 (B) +3
(C) +6 (D) +7 (A) x=1,y=5 (B) x=2,y=10
(C) x=1, y=3 (D) x1,y=15
66. When the half-reaction NO3−
→ NO is balanced
74. In the reaction xHI + yHNO3
→ NO + I 2 + H 2O
for one NO3− in acid solution,…… electron(s) is
(A) x=3,y=2 6,y=2 (B) x 2,y=3
(are)
(C) x=6, y=2 (D) x 6, y=1
(A) 3 gained (B) 1 gained
75. For the redox reaction
(C) 1 lost (D) 3 lost
MnO 4− + C2O52− + H +
→ Mn 2+ + CO 2 + H 2O
67. In the reaction
the correct stoichiometric coefficients of
ClO3− ( aq ) + 5C1− ( aq ) + 6H + ( aq )
→
MnO 4− .C2O 24− and H are respectively:
3C12 ( g ) + 3H 2O(l) the oxidizing and reducing
(A) 2, 5, 16 (B) 16, 5, 2
agents are, respectively:
(C) 5, 16, 2 (D) 2, 16, 5
- −
(A) Cl (aq) and ClO (aq) 2 76. In the half reaction:
− -
(B) ClO (aq) and Cl (aq)
3 2 ClO3−
→ Cl2
(C) ClO3− (aq) and H+(aq) (A) 5 electrons are gained
- +
(D) Cl (aq) and H (aq) (B) 5 electrons are liberated
68. What is the oxidation number of C in (C) 10 electrons are gained
formaldehyde, CH2O? (D) 10 electrons are liberated
(A) -2 (B) 0 77. In the reaction Axe
(C) +2 (D) +4 (A) n1 + n 2
69. Which one of the following cannot act as an (B) n 2 − n1
oxidizing agent?
(C) n1 − n 2
(A) S2- (B) 0
(D) n1 × n 2
(C) SO 24− (D) S2O62
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78. Cu reacts with HNO3 according to the equation 84. The following equations are balanced stom wise
Cu+ HNO3
→ Cu(NO3)2+ NO+ NO2 + H2O If (p) Cr2O72− + 8H + + 3H 2O 2 → 2Cr 3+ + 7H1O + SO 2
NO and NO2 are formed in a 2:3 ratio, what is the (q) Cr2O72− + 8H + + 5H 2O 2 → 2Cr 3+ + 9H 2O + 4O 2
coefficient for Cu when the equation is balanced
(r) Cr2O72− + 8H + + 7H 2O 2 → 2Cr 3+ + 11H 2O + 5O 2
with the simplest whole numbers?
The precise equation/equations representing the
(A) 2 (B) 3
oxidation of H2O2 is/are:
(C) 6 (D) 9
(A) (P) only (B) (Q) only
79. Consider the following reaction:
(C) (R) only (D) all the three
3Br2 + 6CO32− + 3H 2O
→ 5Br + + BrO3− + 6HCO3−
85. During the disproportionation of iodide to and
Which of the following statements is true regarding
iodate ions, the ratio of iodate and iodide formed in
this reaction?
alkaline medium is:
(A) Bromine is oxidized and the carbonate radical
(A) 1:5 (B) 5:1
is reduced.
(C) 3:1 (D) 1:3
(B) Bromine is reduced and the carbonate radical is
86. Which of the following equations is correct
oxidized.
balanced?
(C) Bromine is neither reduced nor oxidized.
(A) 5BiO3− + 22H + + Mn 2+
(D) Bromine is both reduced and oxidized.
→ 5Bi3+ + 7H 2O + MnO 4
80. In which of the following reactions is there a
change in the oxidation number of nitrogen atom? (B) 5BiO3− + 14H + + 2Mn 2+
(A) 2NO 2
→ N 2O 4 → 5Bi3+ + 7H 2O + 2MnO 4−
(B) NH3+ H2O
→ NH4++OH- (C) 2BiO3− + 4H + + Mn 2+
(C) N2O5+ H2O
→ 2 HNO3 → 2Bi3+ + 2H 2O + MnO 4−
(D) None of these (D) 6BiO3− + 12H + + 3Mn 2+
81. Which reaction does not represent auto redox or
disproportionation? → 6Bi3+ + 6H 2O + 3MnO 4−
(A) Cl2 + OH − → Cl− + ClO3− + H 2O 87. The values of x, y and z in the reaction in
(B) 2H 2O 2
→ H 2O + O 2 respectively:
(C) 2Cu +
→ Cu 2+ + Cu 4KO 2 + xH 2O + yCO 2
→ 4KHCO3 + zO 2
(D) ( NH 4 )2 Cr2O7
→ N 2 + Cr2O3 + 4H 2O
(A) 3, 6, 6
− − +
82. In the reaction X + XO + H
3 → X 2 + H 2O , the (B) 2,4,3
molar ratio in which X- and XO3− react is: (C) 3, 2, 5
(D) 4,3,6
(A) 1:5 (B) 5:1
88. For the balanced redox reaction:
(C) 2:3 (D) 3:2
aNO3− + bCu 2O + cH +
→ NO + eCu 2+ + H 2O
83. CN- is oxidized by NO3− in presence of acid:
c where a, b, c, d and e are stoichiometric coefficient
→ ( a + b ) NO + aCO 2 + H 2O
aCN − + bNO3− + cH +
2 if 'e' is 14, then the value of 'e' is:
What are the values of a, b, c in that order: (A) 2 (B) 3
(A) 3,7,7 (B) 3, 10, 7
(C) 3, 10, 10 (D) 3, 7, 10 (C) 6 (D) 7
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89. Consider the balanced chemical reaction: 95. _ Sn 2+ ( aq ) + _ NO3− ( aq ) + H + ( aq )
aI 2O5 + bBrF3
→ cIF5 + dO 2 + eBr2
→ _ Sn 4+ ( aq ) + _ NO ( g ) + _ H 2O
Calculate the value of (b+c+e)(a).
What is the coefficient for H+(aq) when the
(A) 10 (B) 7
equation above is balanced correctly with the
(C) 6 (D) 3
smallest integer coefficients?
90. What are the value of p, q, r and a for the following
(A) 2 (B) 4
reaction?
(C) 6 (D) 8
pO3 + qHI
→ rI 2 + sH 2O 96. What is the coefficient for OH after the equation
(A) 1, 6, 3, 1 (B) 1,6,3,3 _ Br2 + −OH −
→ _ Br − + _ BrO3− + _ H 2O is
(C) 1, 6, 6, 3 (D) 1,6,3,6
balanced with the smallest integer coefficients?
91. The unbalanced equation for the reaction of P4S3
(A) 3 (B) 6
with nitrate in aqueous acidic medium is given
(C) 12 (D) 18
below:
97. _ Sn 2+ ( aq ) + _ MnO 4− ( aq ) + _ H + ( aq )
− 3−
P4S3 + NO
→ H 3PO 4 + SO + NO
3 4
→ _ Sn 4+ ( aq ) + _ Mn 2+ ( aq ) + _ H 2O(l)
The number of moles of water required per mole of
When this equation for the reaction of Sn2+(aq) and
P4S3
MnO4-, (aq) is balanced correctly, what is the ratio,
8
(A) 18 (B) Sn 2+ / MnO 4− ?
3
(C) 8 (D) 28 1 1
(A) (B)
1 2
92. _ ClO −2 + _ I − + H +
→ _ Cl− + _ I 2 + _ H 2O
2 5
When this equation is balanced with whole number (C) (D)
1 2
coefficients, what is the H+/I2 coefficient ratio?
98. What is the coefficient for H when the half
2 3
(A) (B) equation is balanced with the smallest whole
1 1
number coefficients?
6
(B) (D) Some other ratio _ S2+ + _ H 2O
→ −SO 2 + _ H + + _ e −
1
93. MnO −4 + NO −2 + H + → Mn2+ + NO3− + H 2O (A) 2 (B) 4
(C) 6 (D) 8
When this equation is balanced correctly with the 99. When the reaction: Cl− + ClO3−
→ Cl2 + H 2O is
smallest integer coefficients, what is the coefficient balanced in acid solution what is the ratio of Cl- to
for H+?
(A) 1 (B) 6 ClO −2 ?
(C) 8 (D) 16 1 2
− (A) (B)
94. Cl2 + OH → Cl + ClO3−
−
1 1
What is the coefficient for OH when this equation 3 5
(C) (D)
is balanced with the smallest integer coefficients? 1 1
(A) 2 (B) 3
(C) 4 (D) 6
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100. What is the coefficient for O2 when the equation 105. When the equation below is balanced correctly
NH 3 + O 2
→ NO + H 2O is balanced with using the simplest whole number coefficients, what
smallest whole number coefficients? is the coefficient for CO2(g)?
(A) 2 (B) 3 _ Cr2O72− ( aq ) + _H 2C 2O 4 ( aq ) + _ H ( aq )
(C) 4 (D) 5 → _ Cr 3+ ( aq ) + _ CO 2 (g ) + _ H 2O(l)
101. When the equation Sn 2+ ( aq ) + lO3− ( aq ) + H + ( aq ) (A) 4 (B) 6
→ Sn 4+ ( aq ) + I 2 (aq ) + H 2O(l) is balanced, what
(C) 8 (D) 12
106. How many H+ ions are required when the equation
is the Sn 2+ ( aq ) / II3− ( aq ) mole ratio?
below is balanced with the smallest whole number
1 2
(A) (B) coefficients?
1 1
Cu(s) + NO3− ( aq ) + H + ( aq )
→
1 5
(C) (D)
2 2 Cu 2+ ( aq ) + NO ( g ) + H 2O(l)
102. Ethanol reacts with dichromate ions in acid.
(A) 2 (B) 4
solution according to the equation:
(C) 6 (D) 8
C2 H 5OH(l) + Cr2O 2−
7 ( aq ) + H ( aq )
+
107. When this equation is balanced using the smallest
→ CO 2 ( g ) + Cr 3+ ( aq ) + H 2O ( l )
possible integers, what is the sum of the
What is the coefficient for H+(aq) when this coefficients?
equation is balanced with the smallest whole. _(NH)4PO4 (aq) +_CaCl2(aq)
number coefficients? → −Ca 2 ( PO 4 ) ( s ) + _ NH 4Cl ( aq )
2
(A) 10 (B) 12 (A) 8 (B) 9
(C) 14 (D) 16 (C) 11 (D) 12
103. What is the coefficient for Zn when the equation 108. Boron carbide, B4C3 is made by the high
below is balanced with the smallest whole number temperature reaction of boron oxide with graphite,
coefficients? yielding carbon monoxide as a by-product.
Zn + H ( aq ) + NO ( aq )
+ −
3 _ B2 O 3 + _ C
→ _ B4C + CO
→ Zn 2+ ( aq ) + N 2O ( g ) + H 2O(l)
What is the total of the smallest coefficients for the
(A) 2 (B) 4 reactants and products in the balanced equation?
(C) 6 (D) 8 (A) 9 (B) 10
104. What is the coefficient for O, when the following (C) 15 (D) 16
reaction 109. When the equation:
_ As 2S3 + _ O 2
→ As 2O3 + _ SO 2 _ MnO −4 + _ SO32− + _ H +
→ _ Mn 2+ + _ SO 24− + _ H 2O
is correctly balanced with the smallest integer is balanced correctly with the smallest whole
coefficients? number coefficients, what is the coefficient for
(A) 5 (B) 6 H2O?
(C) 8 (D) 9 (A) 3 (B) 5
(C) 8 (D) 10
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110. What is the coefficient of I2 (s) when the reaction 116. In the following reaction hydrazine is oxidized
below is balanced with smallest whole number N2
coefficients?
_ Cr2O72− ( aq ) + _ I − ( aq ) + _ H + ( aq ) N2H4+OH-
→ N2+H2O+e
→ _ I 2 ( s ) + _ Cr 2+ + ( aq ) + _ H 2O ( l )
The equivalent weight of N2H4 (hydrazine) is:
(A) 2 (B) 3 (A) 8 (B) 16
(C) 4 (D) 6 (C) 32 (D) 64
111. The following redox reaction occurs in basic 117. The molecular weight of the compounds
medium: NO + Zn ( s )
−
3
2+
→ Zn + NH , when the +
4 (I) Na2SO4 (II) Na3PO4.12H2O and
above reaction is balanced such that the (III) Ca2(PO4)2
stoichiometric coefficients are in smallest whole.
respectively are X, Y and Z the correct set of the
number ratio, then the difference of stoichiometr
coefficient of Zn(s) and OH- ion will be: equivalent weights will be:
(A) 4 (B) 10 X Y Z
(A) (I) (II) (III)
(C) 6 (D) none of these 2 3 6
112. Ratio of stoichiometric coefficient of N2H4 to Cl- Y Z
(B) (I)X(II) (III)
the following reaction: 3 3
ClO3− + N 2 H 4
→ NO −4 + Cl− X Z
(C) (I) (II)Y(III)
8
2 3
(A) (B) 15
15 (D) (I)X(II)Y(III)Z
(C)
2
(D)
6 118. When one mole NO3− is converted into 1 mole
3 14
NO20.5 mole Na and 0.5 mole N2O respectively.
113. What is the atomic mass of a metal whose specheat
Itaccepts x, y and z mole of electrons, y, z
1
capacity is cal/gm2C and whose percentage by arerespectively
9
(A) 1.5.4 21.3 (B) 1,2,3
mass in its superoxide is 36%?
(C) 2,1,3 (D) 2, 3, 4
(A) 57.6 (B) 54
119. to the equation,
(C) 36 (D) 64
114. Equivalent weight of Br2 in the following reactions SnCl2 + 2HgCl2
→ HgCl2 + SnCl4
is: The equivalent weight of stannous chloride
Br2+HgO+H2O → HgBr2.HgO+HBrO molecular weight= 190) will be:
(Given: Br=80)
(A) 190 (B) 95
160
(A) (B) 80 (C) 47.5 (D) 154.5
3
(C) 160 (D) 160 × 3 120. In the following change,
115. In the reaction, 3Fe+ 4H2O
→ Fe3O4+ 4H2
2 CuSO4 +4 Kl
→ Cu2I2+I2+2 KSO4 If the atomic weight of iron is 56, then its
the equivalent weightof Cu will be: equivalent weight will be:
(A) 31.75 (B) 63.5 (A) 42 (B) 21
(C) 127 (D) 15.88 (C) 63 (D) 84
(Atomic weight of Cu= 63.5).
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121. Which statement is correct for equivalent weight of 126. When KMnO4 acts as an oxidizing agent and
KMnO4? ultimately forms MnO 24− ,MnO 2 , Mn 2O3 and
1 Mn2+, then the number of electrons transferred in
(A) Equivalent weight is of molecular mass in
3
eachcase is:
neutral and weak basic medium
(A) 4, 3, 1,5 (B) 1,5,3,7
1 (C) 1,3,4,5 (D) 3,5,7,1
(B) Equivalent weight is of molecular mass in
5
127. Equivalent weight of chlorine molecule in
Basic medium
theequation is:
(C) Equivalent weight is equal to molecular mass
in acidic medium 3C12+ 6NaOH
→ 5NaCl + NaClO3+3H2O
1 (A) 42.6 (B) 35.5
(D) Equivalent weight is of molecular mass in
3 (C) 59.1 (D) 71
acidic medium
128. In the reaction:
122. Equivalent weight of NH3 in the change
Na2S2O2 +4 Cl2+5 H2O
N 2
→ NH 3 is:
→ Na2SO4+ H2SO4+8HCl
17
(A) (B) 17 the equivalent weight of Na2S2S2 will be: (M-
6
molecular weight of Na2S2S2)
17 17
(C) (D)
2 3 M M
(A) (B)
123. If M represents molecular mass of Mn3O4 thenwhat 4 8
will be its equivalent mass if it undergoes M M
(C) (D)
disproportionation reaction as shown: 1 2
→ MnO −4 + Mn 2+
Mn 3O 4 129. X gm of metal gave Y gm of its oxide, so
M M equivalentmass of metal is:
(A) (B)
13 2 X Y−X
(A) ×8 (B) ×8
15M 26M Y−X X
(C) (D)
26 15
Y+X X
2− (C) ×8 (D) ×8
124. What is the equivalent mass of S2O 3 ion as per X Y
the following disproportionation reaction, 130. In the following conversion of sulphide of
2− 2− 2−
S2O
3→ S4O + S 6 2 phosphorous
where the charge above species represents charge P4S3
→ P2O5 + SO 2
on the ion and not oxidation state?
Equivalent weight of P4S3 (molecular weight =
(A) 132 (B) 22
M)is:
(C) 130.6 (D) 113.15
125. The equivalent mass of MnSO4 is half its
M M
(A) (B)
molecular mass when it is converted to: 14 18
(A) Mn2O3 (B) MnO2 M M
(C) (D)
(C) MnO −4 (D) MnO 24− 32 38
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131. [Co(H 2 N – CH 2 − CH 2 – NH 2 )]2S3 137. 2.00 g of a mixture of NaHCO3 and KClO3
requires 100 mL of 0.1 N HCl for complete
oxidation
→ Co +4 + CO3−2 + NO3− + SO 4−2
neutralization. The weight of KClO3 present in the
What is the equivalent weight of the reactant in
mixture is:
theabove reaction?
(A) 0.84 g (B) 1.84 g
3M M (D) 0.16 g (C) 1.16 g
(A) (B)
182 182
138. A 25 mL HCl solution containing 3.65 g HCI/L is
11M 7M neutralized by 50 mL of NaOH solution. Again, 25
(C) (D)
182 182
mL of the same NaOH solution neutralized by 50
132. 3.65 gm equimolar mixture of NaOH and Na2CO3
mL of an H2SO4 solution of unknown strength. The
is titrated against 0.1 M HCI using phenolphthalein
normality of the H2SO4 solution is:
as an indicator, V1 mL of acid was required to
(A) 0.25 N (B) 0.025 N
reach end point. In another experiment 3.65 gm of
(C) 0.05 N (D) 0.50 N
same mixture is titrated against 0.2 M HCl using
139. 10 mL of 0.5 N HCl, 30 mL of 0.1 N HNO3 and 75
methyl orange as an indicator, V2 mL of acid was
mL of 0.1 M H2SO4 are mixed together. The
required to reach end point. V1 + V2 is:
normality of the resulting solution will be:
(A) 875 mL (B) 750 mL
(A) 0.2 N (B) 0.1 N
(C) 500 mL (D) 1000 mL
(C) 0.4 N (D) 0.5 N
133. How many milliliters of a 9 N H2SO4 solution will
140. The amount of KMnO4 required to prepare 100 mL
be required to neutralize completely 20 mL of a 3.6
of a 0.1 N solution in an acidic medium is:
N NaOH solution?
(A) 3.16 g (B) 1.58 g
(A) 18.0 mL (B) 8.0 mL
(C) 0.316 g (D) 31.6 g
(C) 16.0 mL (D) 80.0 mL
141. 0.185 g of an iron wire containing 99.8% Iron
134. What is the normality of the H2SO4 solution, 18.6
dissolved in an acid to form ferrous ions. The
mL of which neutralizes 30.0 mL of a 1.55 N KOH
solution requires 33 mL of K2Cr2O7 solution for
solution?
complete reaction. The normality of the
(A) 5.0 N (B) 1.25 N
K2Cr2O7solution is:
(C) 2.5 N (D) 3.5 N
(A) 0.05 (B) 0.02
135. 50 ml of 5.6% KOH (w/v) is added to 50 mL of a
(C) 0.20 (D) 0.10
5.6% HCl (w/v) solution. The resulting solution
142. 8.7 gm of pyrolusite (impure MnO2) were heated
will be:
with concentrated HCl. The Cl2 gas evolved was
(A) neutral (B) alkaline
passed through excess of KI solution. The
(C) strongly alkaline (D) acidic
N
136. Calculate the normality of an NaOH solution, 21.5 iodinegas evolved required 80 ml of hypo
10
mL of which is required to convert 0.240 g of
solution.
NaH2PO4 in a solution to monohydrogen
The percentage of MnO2 in pyrolusite will be:
phosphate. [Mn=55)
(A) 1.093 N (B) 0.093 N (A) 4% (B) 40%
(C) 8% (D) 80%
(C) 0.048 N (D) 0.93 N
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143. Volume of 0.1 M ferrous oxalate solution required 148. The CO in a 20.3 L sample of gas was converted to
to react completely with 60 ml of 0.1 N CO2 by passing the gas over iodine pentoxide
acidifiedKMnO4 solution. heated to 150°C
(A) 30 mL (B) 20 mL I 2 I5 (s) + 5CO ( g )
→ 5 CO 2 ( g ) + I 2 (g)
(C) 150 mL (D) 10 mL
The iodine distilled at this temperature and was
144. An equimolar mixture of Na2C2O4 and KHC2O4
collected in an absorber containing 8.25 mL of
3H2C2O4 required V1litre of 0.1 M KMnO4 in acid
0.01101 M Na2SO3. The excess hypo was back-
medium for complete oxidation. The same amount
titrated with 2.16 mL of 0.00947 M I2 solution. The
of mixture required V2litre of 0.2 M NaOH for
milligrams of CO in 1 L of the original gassample
complete neutralization. What is the ratio of V1:V2
was therefore:
(A) 4:7 (B) 10:7
(A) 0.172 mg (B) 0.283 mg
(C) 8:7 (D) 2:7
(C) 0.349 mg (D) 0.506 mg
145. What volume of O2(g) measured at 1 atm and 273
149. Bleaching powder and bleach solution are
K will be formed by action of 200 mL of 0.4 M
produced products. The effectiveness of bleach
KMnO4 of hydrogen peroxide in acidic solution?
solution is on a large scale and used in several
(A) 4.48 litre (B) 2.24 litre
household often measured by iodometry.
(C) 8.96 litre (D) 1.12 litre
25 mL of household bleach solution was mixed
146. 10 moles of KMnO4 were consumed in each
with 30 mL of 0.50 M KI and 10 mL of 4 N acetic
separate titration with oxalic acid, one in presence
acid. In the titration of the liberated iodine, 48 mL
of H2SO4 and other in presence of HCl. Identify the
of 0.25 N Na2SO3 was used to reach the end point.
correct option.
The molarity of the household bleach solution is:
(A) 25 moles of oxalic acid will be consumed in
(A) 0.48 M
bothcases.
(B) 0.96 M
(B) 25 moles of oxalic acid will be consumed
(C) 0.24 M
with H2SO, and with HCl more than 25
(D) 0.024 M
moles of oxalic acid will be consumed.
150. The number of moles of ferrous oxalate oxidized
(C) No oxalic acid will be consumed in case of
by one mole of KMnO4 in acidic medium is:
HC and less than 25 moles will be consumed
5 2
in case of H2SO4 (A) (B)
2 5
(D) 25 moles of oxalic acid will be consumed
3 5
with H2SO4 and less than 25 moles of oxalic (C) (D)
5 3
acid will be consumed with HCI.
151. How many moles of KMnO4 are needed to
147. 100 mL each of 1NH2O2 and 11.2 VH2O2 solution
oxidisea mixture of 1 mole of each FeSO4 and
are mixed, then the final solution is equivalent to:
FeC2O4 in acidic medium?
Assume 1 mole of an ideal gas occupies 22.4 L at
4 5
STP) (A) (B)
5 4
(A) 3M H2O2 solution
(B) 0.5 NH2O2 solution 3 5
(C) (D)
(C) 34 g/L H2O2 solution 4 3
(D) 2.55 g/L H2O2solution
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152. An aqueous solution containing 0.1 g KIO3 159. 125 mL of 63% (w/v) H2C2O4.2H2O solution is
(formula weight=214) and an excess of KI was made to react with 125 mL of a 40% (w/v) NaOH
acidified with HCl. The liberated I2 consumed 45
solution. The resulting solution is: (ignoring
mL of thiosulphate. The molarity of sodium
thiosulphate solution is: The reaction involved is: hydrolysis of ions)
IO3− + I − + H +
→ I 2 + H 2O (A) neutral (B) acidic
(A) 0.0623 M (B) 0.0313 M (C) strongly acidic (D) alkaline
(C) 0.126 M (D) 0.252 M
160. A certain weight of pure CaCO3 is made to react
153. When N2 is converted into NH3, the
completely with 200 mL of a HCl solution to give
equivalentweight of nitrogen will be:
227 mL of CO2 gas at STP. The normality of the
(A) 1.67 (B) 2.67
HCl solution is:
(C) 3.67 (D) 4.67
(A) 0.05 N (B) 0.1 N
154. In the conversion NH2OH
→ NO. the (C) 1.0N (D) 0.2 N
equivalent weight of NH4OH will be: 161. Volume V1 mL of 0.1 M K2Cr2O7 is needed for
M M complete oxidation of 0.678 g N2H4 in acidic
(A) (B)
4 2 medium. The volume of 0.3 M KMnO4 needed for
M M same oxidation in acidic medium will be:
(C) (B)
5 1 2
(A) V1
(M-molecular weight of NH2OH) 5
155. Which of the following relations is incorrect for 5
(B) V1
solutions? 2
(A) 3 N Al2(SO4)3=0.5 M Al2(SO4)3 (C) 113 V1
(B) 3 M H2SO4= 6 N H2SO4 (D)can not be determined
(C) 1 MH3PO4=1/3 N H3PO4 162. Which of the following solutions will exactly
(D) 1 M Al2(SO4)3=6N Al2(SO4)3 oxidize 25 mL of an acid solution of 0.1 M iron (II)
156. How many millilitres of 0.1 N H2SO4 solution will oxalate:
be required for complete reaction with a solution (A) 25 mL of 0.1 M KMnO4
containing 0.125 g of pure Na2CO2: (B) 25 mL of 0.2 M KMnO4
(A) 23.6 mL (B) 25.6 mL (C) 25 mL of 0.6 M KMnO4
(C) 26.3 mL (D) 32.6 mL (D) 15 mL of 0.1 M KMnO4
157. If 25 mL of a H2SO4 solution reacts completely 163. An element A in a compound ABD has oxidation
with 1.06 g of pure Na2CO3 what is the normality number-n. It is oxidized by Cr2O72− in acid
of thisacid solution:
medium. In the experiment, 1.68 × 10-3 moles of
(A) 1N (B) 0.5 N
K2Cr2O7 were used for 3.36 × 10-3 moles of ABD.
(C) 1.8 N (D) 0.8 N
The new oxidation number A after oxidation is:
158. The mass of oxalic acid crystals (H2C2O4.2H2O)
(A) 3
required to prepare 50 mL of a 0.2 N solution is:
(B) 3-n
(A) 4.5 g (B) 6.3 g
(C) n-3
(C) 0.63 g (D) 0.45 g
(D) + n
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–14–
164. A mixture of 0.02 mole of KBrO3 and 0.01 mole of 171. HNO3oxidises NH + ions to nitrogen and itself g
4
KBr was treated with excess of KI and acidified.
reduced to NO2. The moles of HNO3 required by
The volume of 0.01 M Na2S2O3 solution required
1mole of (NH4)2SO4 is:
to consume the liberated iodine will be:
(A) 4 (B) 5
(A) 1000 mL (B) 1200 mL
(C) 6 (D) 2
(C) 1500 mL (D) 800 mL
172. 25 mL of a 0.1 M solution of a stable cation d
165. Hg5(IO6)2 oxidizes KI to I2 in acid medium and the
Macidified KMnO4 solution. Which of the
other product containing iodine is K2HgI4. If the I2
liberated in the reaction requires 0.004 mole of following transition metal Z reacts exactly with 25
Na2S2O3, the number of moles of Hg5(IO6)2 that mL ofis most likely to represent the change in
have reacted is: oxidation state of Z correctly?
(A) 10-3 (B) 10-4
(C) 2.5 × 10-4 (D) 2.5 × 10-2 (A) Z+
→ Z 2+ (B) Z2+
→ Z3+
166. The normality of 0.3 M phosphorus acid (H3PO3)
(C) Z3+
→ Z 4+ (D) Z2+
→ Z 4+
is:
(A) 0.1 (B) 0.9 173. How many litres of Cl2 at STP will be liberated by
(C) 0.3 (D) 0.6 the oxidation of NaCl with 10g KMnO4 in add
167. An aqueous solution of 6.3 g of oxalic acid medium? (Atomic weight: Mn 55 and K=39)
dihydrate is made upto 250 mL. The volume of 0.1 (A) 3.59 (B) 7.08
N NaOH required to completely neutralize 10 mL (C) 1.77 (D) None of these
of thissolution is: 174. One gram of Na3AsO4 is boiled with excess of d KI
(A) 40 mL (B) 20 mL in presence of strong HCl. The iodine evolved
(C) 10 mL (D) 4 mL absorbed in KI solution and titrated against 023
168. In basic medium, I- is oxidized by MnO 4− . In this hypo solution. Assuming the reaction to be:
process, I- changes to: AsO34− + 2H + + 2I −
→ AsO33− + H 2O + I 2
(A) IO3− (B) I 2
calculate the volume of hypo consumed.
− −
(C) IO 4 (D) IO [Atomweight of As=75]
169. The amount of wet NaOH containing 15% (A) 48.1 mL (B) 38.4 mL
waterrequired to prepare 70 litres of 0.5 N solution (C) 24.7 mL (D) 30.3 mL
is: 175. What will happen if the solution of potassium
(A) 1.65 kg (B) 1.4 kg chromate reacts with excess amount of nitric
(C) 16.5 kg (D) 140 kg
170. In an experiment, 50 mL of 0.1 M solution of s acid(A) Cr reduces in the oxidation state + 3 from
reacted with 25 mL of 0.1 M solution of w CrO62−
sulphite. The half equation for the
oxidationsulphite ion is: (B) Cr oxidisesin the oxidationstate + 7 from
SO33− ( aq ) + H 2O
→ SO 42− ( aq ) + 2H + + 2e − CrO 24−
If the oxidation number of metal in the salt was,
(C) Cr and Cr2O 72− will be formed
what would be the new oxidation number of
(D) Cr2O 72− and H2O will be formed
(A) 0 (B) 1
(C) 2 (D) 4
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176. The oxidation state of chromium in the final 180. Statement-1: In the redox reaction 8H+ (aq) + 4N
product formed by the reaction between Kl and O3− + 6C1− + Sn ( s )
→ SnCl62− + 4NO 2 + 4H 2O
acidified potassium dichromate solution is: , the reducing agent is Sn(s).
(A) + 4 (B) +6 Statement-2: In balancing half reaction,
(C) +2 (D) +3 S2O32−
→ S(s) , the number of electrons added
on the left is 4.
Each question has 5 choices (A), (B), (C), (D) and
181. Statement-1: In the reaction,
(E) out ofwhich ONLY ONE is correct.
MnO −4 + 5Fe 2+ + 4H 2O, MnO −4 ,acts as oxidizing
(A) Statement-1 is True, Statement-2 is True;
Statement-2is a correct explanation for agent.
Statement-1. Statement-2: In the above reaction,
(B) Statement-1 is True, Statement-2 is True, Fe2+ is converted to Fe3+
Statement-2 is NOT a correct explanation for 182. Statement-1: If 200 mL of 0.1 N NaOH is added to
Statement-1. 200 mL of 0.1 N H2SO4 solution, then the resulting
(C) Statement-1 is True, Statement-2 is False. solution is acidic.
(D) Statement-1 is False, Statement-2 is True. Statement-2: If milliequivalents of acid is greater
(E) Statement-1 and Statement-2 both are False. than milliequivalents of base, then upon mixing the
Reactions solution is acidic.
177. Statement-1: Moles of KMnO4 required for 183. Statement-1: Equivalent weight of FeC2O4 in the
oxidation of Fe2in acidic and basic medium will be reaction,
different. FeC2O4 + Oxidisingagent
→ Fe3++ CO2
Statement-2: Final oxidation state to which Mn+7 is M/3, where M is molar mass of FeC2O4
will be reduced will be different in case of acidic Statement-2: In the above reaction total two moles
and basic medium. of electrons are given up by 1 mole of FeC2O4 to
178. Statement-1: Both CrO 24− and Cr2O 72− ions when the oxidizing agent.
184. Statement-1: In the titration of Na2CO3 with HCl
treated with acidified H2O2 solution gives blue
using methyl orange indicator, the volume of the
solution which turns green on standing.
acid required at the equivalence point is twice that
Statement-2: Blue solution of CrO5 is stabilized in
of the acid required using phenolphthalein as
the presence of organic solvent, eg., ether,
indicator.
pyridine, etc.
Statement-2: Two moles of HCl are required for
179. Statement-1: The oxidation state of oxygen in
the complete neutralization of one mole of
superoxide ion in KO2, CsO2, and RbO2 is-1/2.
Na2CO3.
Statement-2: Since the oxidation state of an alkali
metal in any compound is always + 1, the oxidation
state of oxygen is -1/2 in the O −2 ion.
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PRACTICE SHEET
CHEMISTRY
REDOX REACTION
ANSWER KEY
1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20
B C C C D A A D C B B D B C D D A D B C
21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40
A B A C B B B D D A C A B A A D D D B C
41 42 43 44 45 46 47 48 49 50 51 52 53 54 55 56 57 58 59 60
D B D D D D C A B B C A C D B C B D C A
61 62 63 64 65 66 67 68 69 70 71 72 73 74 75 76 77 78 79 80
B A B A D A B B A D C A C C A C C D D D
81 82 83 84 85 86 87 88 89 90 91 92 93 94 95 96 97 98 99 100
D B D A A B B C B B B A B D D B D B D D
101 102 103 104 105 106 107 108 109 110 111 112 113 114 115 116 117 118 119 120
D D B D B D D D A B C D A C B A A A B B
121 122 123 124 125 126 127 128 129 130 131 132 133 134 135 136 137 138 139 140
A D C C B C A B A C B A B C D B C B A C
141 142 143 144 145 146 147 148 149 150 151 152 153 154 155 156 157 158 159 160
D A B A A D C A C D A A D B C A D C A B
161 162 163 164 165 166 167 168 169 170 171 172 173 174 175 176 177 178 179 180
A D B B C D A A A C C D A A D D A B A B
181 182 183 184
A D C B
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