Sri Chaitanya IIT Academy.,India.

 A.P  T.S  KARNATAKA  TAMILNADU  MAHARASTRA  DELHI  RANCHI

A right Choice for the Real Aspirant
ICON Central Office - Madhapur - Hyderabad
SEC: Sr.Super60_STERLING BT JEE-MAIN Date: 19-07-2025
Time: 09:00AM to 12:00PM WTM-38 Max. Marks: 300
IMPORTANT INSTRUCTION:
1. Immediately fill in the Admission number on this page of the Test Booklet with Blue/Black Ball Point
Pen only.
2. The candidates should not write their Admission Number anywhere (except in the specified space) on
the Test Booklet/ Answer Sheet.
3. The test is of 3 hours duration.^
4. The Test Booklet consists of 75 Questions. The maximum marks are 300.
5. There are three parts in the question paper 1,2,3 consisting of Mathematics, Physics and Chemistry
having 25 Questions in each subject and subject having two sections.
(I) Section –I contains 20 Multiple Choice Questions with only one correct option.
Marking scheme: +4 for correct answer, 0 if not attempt and -1 in all other cases.
(II) Section-II contains 05 Numerical Value Type Questions.
∎ The Answer should be within 0 to 9999. If the Answer is in Decimal then round off to the Nearest
Integer value (Example i,e. If answer is above 10 and less than 10.5 round off is 10 and If answer is
from 10.5 and less than 11 round off is 11).
To cancel any attempted question bubble on the question number box.
For example: To cancel attempted Question 21. Bubble on 21 as shown below

.
Question Answered for Marking Question Cancelled for Marking
Marking scheme: +4 for correct answer, 0 if not attempt and -1 in all other cases.
6. Use Blue / Black Point Pen only for writing particulars / marking responses on the Answer Sheet. Use
of pencil is strictly prohibited.
7. No candidate is allowed to carry any textual material, printed or written, bits of papers, mobile phone
any electron device etc, except the Identity Card inside the examination hall.
8. Rough work is to be done on the space provided for this purpose in the Test Booklet only.
9. On completion of the test, the candidate must hand over the Answer Sheet to the invigilator on duty in
the Hall. However, the candidate are allowed to take away this Test Booklet with them.
10. Do not fold of make any stray marks on the Answer Sheet
Name of the Candidate (in Capital): ________________________________________________

Admission Number:

Candidate’s Signature:________________ Invigilator’s Signature: ________________

 Sri Chaitanya IIT Academy, India 19-07-25_Sr.Super60_STERLING BT_Jee-Main_WTM-38_Q.P
19-07-25_Sr.Super60_STERLING BT_Jee-Main_WTM-38_Test Syllabus

MATHEMATICS : Probability: Classical definition of probability, types of events,

Addition theorem and problems based on it, Problems
based on P &C.
PHYSICS : PHOTO ELECTRIC EFFECT: Electron emission, Photoelectric effect: A
historical account of its discovery, Experimental study of
photoelectric effect, Laws of photoelectric emission, Photoelectric
effect and wave theory of light, Einstein's photoelectric equation,
Experimental verification of Einstein's photoelectric equation,
Radiation Force and Radiation Pressure, ATOMS & X - RAYS DUAL
NATURE OF RADIATION AND MATTER: Particle nature of light: the
photon, Wave nature of matter, The de Broglie waves or matter
waves, Wave length of an electron, Variation of mass With
Velocity, Mass-Energy Equivalence, Davisson-Germer experiment,
Experimental verification of de Broglie wave equation (Deleted
pertaining to JEE MAINS but still in JEE ADV Syllabus), Matter waves
and Heisenberg's uncertainity principle
CHEMISTRY : CARBOXYLIC ACIDS: Preparation of benzoic acid from
alkylbenzenes; Reactions: reduction, halogenation, formation of
esters, acid chlorides and amides., Derivatives of Carboxylic acids:
preparation, properties & Reactions,test for carboxylic acids,
AMINES : Preparation, properties & Reactions of Aliphatic
amines,Preparation from nitro compounds, nitriles and amides,
Hoffmann bromamide degradation, Gabriel phthalimide
synthesis,Reaction with nitrous acid, Carbylamine reaction, Hinsberg
test, Alkylation and acylation reactions,Electrophilic substitution
reactions of aniline, Hofmann exhaustive methylation,Aromatic
Amines, Preparation of aniline & Derivatives,Azo coupling reaction
of diazonium salts of aromatic amines; Sandmeyer and related
reactions of diazonium salts;

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 Sri Chaitanya IIT Academy, India 19-07-25_Sr.Super60_STERLING BT_Jee-Main_WTM-38_Q.P
MATHEMATICS Max Marks: 100
SECTION-I (SINGLE CORRECT ANSWER TYPE)
This section contains 20 Multiple Choice Questions. Each question has 4 options (1), (2), (3) and (4) for its
answer, out of which ONLY ONE option can be correct.
Marking scheme: +4 for correct answer, 0 if not attempted and –1 in all other cases.
1. Given that the sum of two non- negative quantities is 200, the probability that their
3
product is not less than times their greatest product value is _______
4
1 103 105 101
1) 2) 3) 4)
2 200 200 200
2. A committee of the five is to be chosen from a group of 9 people. The probability that a
certain married couple will either serve together or not at all is _____
2 4 1 5
1) 2) 3) 4)
3 9 2 9
3. Three persons A,B and C are to speak at a function along with five others. If they all
speak in random order, the probability that A speaks before B and B speaks before C
is________
1 3 3 5
1) 2) 3) 4)
6 5 8 6
3x  1 1 x
4. Events A,B,C are mutually exclusive events such that P  A   , P B  and
3 4
1  2x
P C   .The set of all possible values of x are in the interval.
2
1 2   1 2   1 1 
1)  ,  2)  ,  3)  ,  4)  0,1
3 3   3 3  3 2
5. A and B are two events such that odds against A are 2:1 odds in favour of A  B are 3:1.
If x  P  B   y ,then the ordered pair  x, y  is

 5 3 2 3 1 3  3 2
1)  ,  2)  ,  3)  ,  4)  , 
 12 4  3 4 3 4  10 5 
6. Let  be a complex cube root of unity with   1.A fair die is thrown three times. If r1 , r2
and r3 are the numbers obtained on the die, then the probability that  r1   r2   r3  0 is
1 1 2 1
1) 2) 3) 4)
36 9 9 18
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 Sri Chaitanya IIT Academy, India 19-07-25_Sr.Super60_STERLING BT_Jee-Main_WTM-38_Q.P
7. Fifteen persons, among whom are A and B, sit down at random at a round table. The
probability that there are 4 persons between A and B is
9! 10! 1
1) 2) 3) 4) None of these
14! 14! 7
8. There are four machines and it is known that exactly two of them are faulty. They are
tested one by one, in a random order till both the faulty machines are identified. Then the
probability that only two tests are needed is
1 1 1 1
1) 2) 3) 4)
3 6 2 4
9. A five digit number is formed by writing the digits 1,2,3,4,5 in a random order without
repetitions. Then the probability that the number is divisible by 4 is
3 2 1 4
1) 2) 3) 4)
5 5 5 5
10. If x  3n , where n is a positive integral value, then what is the probability that x will
have 3 at unit’s place?
1 1 1 1
1) 2) 3) 4)
4 2 3 5
11. Two integers x and y are chosen with replacement out of the set 0,1,2,3.....,10. Then
the probability that x  y  5 , is
81 30 25 20
1) 2) 3) 4)
121 121 121 121
12. Three numbers are chosen from 1 to 30. The probability that they are not consecutive is
1 144 143 142
1) 2) 3) 4)
145 145 145 145
13. A sum of money is rounded off to the nearest rupee. The probability that round off error
is at least ten paisa is
19 19 81 81
1) 2) 3) 4)
101 100 101 100
14. The probability that when 12 balls are distributed among three boxes, the first will
contain three balls is,
12c3 29 12c3  29 12c3  212
1) 2) 12 3) 4)
123 3 312 312

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 Sri Chaitanya IIT Academy, India 19-07-25_Sr.Super60_STERLING BT_Jee-Main_WTM-38_Q.P
15. A fair die is rolled once.
1
Statement- I: The probability of getting a composite number is .
3
Statement- II: There are three possibilities for the obtained number (i) the number is a
prime number (ii) The number id a composite number (iii) The number is 1, and hence
1
probability of each possibility is .
3
1) Only statement-I is true
2) Only statement-II is true
3) Both statement-I and statement-II are false
4) Both statement-I and statement-II are true
16. Match the items of Column-I with Column-II
Column- I Column –II
A) The probability that a non- leap year Will have only 52 P) 3
Fridays is 7
B) The probability that a leap year will have 53 Sundays is Q) 1
14
C) The probability that a leap year will have 53 Sundays (or) R) 6
53 Mondays is 7
D) The chance that a leap year selected at random Will contain S) 2
53 Sundays is 7
T) 1
7
1) A  R, B  S , C  T , D  P 2) A  P, B  R, C  S , D  Q
3) A  R, B  S , C  P, D  Q 4) A  P, B  S , C  R, D  T
17. A point is selected at random inside a circle of radius ‘a’ then the probability that it is
nearer to the centre than the circumference is
1 1 1 2
1) 2) 3) 4)
2 4 3 3
18. A coin is tossed 2 times the probability of getting one head and one tail is
1 1 1 1
1) 2) 3) 4)
4 5 3 2

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 Sri Chaitanya IIT Academy, India 19-07-25_Sr.Super60_STERLING BT_Jee-Main_WTM-38_Q.P
19. From  2n  1 consecutive positive integers 3 are selected at random. The probability that
they are in A.P is
n 2n 3n 4n
1) 2) 3) 4)
4n  1
2
4n 2  1 4n2  1 4n 2  1
20. A is a set containing ' n ' elements. A subset P of A is chosen at random. The set A is
reconstructed by replacing the elements of the subset of P, a subset Q of A is again
chosen at random. The probability that P  Q  A and P  Q   is
n n n n
3 1 1 1
1)   2)   3)   4)  
4  4 2  3
SECTION-II (NUMERICAL VALUE TYPE)
This section contains 5 Numerical Value Type Questions. The Answer should be within 0 to 9999. If the Answer is
in Decimal then round off to the Nearest Integer value (Example i,e. If answer is above 10 and less than 10.5
round off is 10 and If answer is from 10.5 and less than 11 round off is 11).
Marking scheme: +4 for correct answer, 0 if not attempt and -1 in all other cases.
21. If 6 Letters are put at random in the ‘6’ addressed envelopes then the probability that
exactly one letter will be placed in wrong envelope is
22. There are 2 Black, 2 Pink , 2 yellow and a certain positive number of Brown balls in a
bag. If two balls are taken at random from the bag without replacement, the probability
1
that they are of same colour is , then the number of Brown balls is
5
23. If the probability of a six-digit number ‘M’ whose six digits are 3,4,1,2,6,5 written as
3
1
random order is divisible by 6 is K then the value of   
K
24. Two different numbers are taken from the set 0,1,2,3,4,5,6,7,8,9,10 The probability
x
that their sum and positive difference are both multiple of 4 is, then x=
55
25. Two cards are drawn from a well shuffled pack of 52 cards. The probability that one is
heart card and the other is a king is  , then 104   
2

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 Sri Chaitanya IIT Academy, India 19-07-25_Sr.Super60_STERLING BT_Jee-Main_WTM-38_Q.P
PHYSICS Max Marks: 100
SECTION-I (SINGLE CORRECT ANSWER TYPE)
This section contains 20 Multiple Choice Questions. Each question has 4 options (1), (2), (3) and (4) for its
answer, out of which ONLY ONE option can be correct.
Marking scheme: +4 for correct answer, 0 if not attempted and –1 in all other cases.
26. All electrons ejected from a surface by incident light of wavelength 200nm can be
stopped before travelling 1m in the direction of uniform electric field of 4 N/C. The work
function of the surface is
1) 4eV 2) 6.2eV 3) 2eV 4) 2.2eV
27. An electron of mass ‘m’ when accelerated through a potential V has de- Broglie
wavelength  .The de Broglie wavelength associated with a proton of mass M accelerated
through the same potential difference will be
M m M  m
1)  2)  3)    4)   
m M m M 
28. Matter waves are
1) electro magnetic waves 2) Transverse chemical waves
3) Long individual mechanical waves 4) neither longitudinal nor mechanical waves
4 1
29. The wavelength of K x-rays of two metals ‘A’ and ‘B’ are and
1875R 675R
respectively, where ‘R’ is Rydberg’s constant. The number of elements lying between
‘A’ and ‘B’ according to their atomic numbers is
1) 3 2) 6 3) 5 4) 4
30. If the short wavelength limit of the continuous spectrum coming out of a coolidge tube is
10Ao , then the debroglie wavelength of the electrons reaching the target metal in the
coolidge tube is approximately:
1) 0.3 Ao 2) 3 Ao 3) 30 Ao 4)10 Ao
31. In a photoelectric experiment, with light of wavelength  , the fastest electron has
3
speed v. If the exciting wavelength is changed to , the speed of the fastest emitted
4
electron will become
3 4 3 4
1) v 2) v 3) less than v 4) greater than v
4 3 4 3

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 Sri Chaitanya IIT Academy, India 19-07-25_Sr.Super60_STERLING BT_Jee-Main_WTM-38_Q.P
32. 1.5 mw of 400 nm light is directed at a photoelectric cell. If 0.10% of the incident
photons produce photoelectrons, the current in the cell is
1) 0.36μA 2) 0.48μA 3) 0.42mA 4) 0.32mA
33. The element which has a K x- rays line of wavelength 1.8 Ao is:

 R  1.110 , b  1and
7
5 / 33  0.39 
1) Co, Z  27 2) Iron,Z=26 3) Mn,z=25 4) Ni,z=28
34. When an electron accelerated by potential difference U is bombarded on a specific metal,
the emitted X- ray spectrum obtained is shown in adjoining graph. If the potential
difference is reduced to U/3 , the correct spectrum is

1) 2)

3) 4)
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 Sri Chaitanya IIT Academy, India 19-07-25_Sr.Super60_STERLING BT_Jee-Main_WTM-38_Q.P
35. Statement–1: Though light of a single frequency (monochromatic light) is incident on a
metal, the energies of emitted photoelectrons are different.
Statement-2: The energy of electrons just after they absorb photons incident on metal
surface may be lost in collision with other atoms in the metal before the electron is
ejected out of the metal.
1) Statemtnt-1 is True, Stement-2 is True; Statemt-2 is a correct explanation for
Statement- 1
2) Statemtnt-1 is True, Statement- 2 is Tru; Statement-2 is a not a correct explanation for
Statemnt-1
3) Statement-1 isTrue, Statement-2 is False
4) Statement-1 is False, Statement-2 is True
36. Statement-1: The de-Broglie wavelength of a molecule(in a sample of ideal gas) varies
inversely as the square root of absolute temperature.
Statement-2: The rms velocity of a molecule (in a sample of ideal gas)depends on
temperature
1) Statement-1 is true, Statement-2 is True; Statement-2 is a correct explanation for
Staement-1
2) Statement-1 is true, Statement-2 is true,Statement-2 is not a correct explanation for
Statement-1
3)Statement-1 is True, Statement-2 is False
4) Statement-1 is False, Statement-2 is True
37. The radiation force experienced by a body exposed to radiation of intensity I assuming
surface of body to be perfectly absorbing is

 R2 I 2 R 2 I 4 R 2 I
1) 2) 3) 4) None of these
c c c
38. An electron, accelerated by a potential difference V , has de Broglie wavelength  . If the
electron is accelerated by a potential difference 4V , its de Broglie wavelength will be
 
1) 2 2) 4 3) 4)
2 4
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39. In an electron microscope if the potential is increased from 20 KV to 80 KV, the
resolving power R of the microscope will become
R
1) R 2) 2R 3) 4R 4)
2
40. A small metal plate (work- function W0 ) is kept at a distance d from a singly ionised
fixed ion. A monochromatic light beam is incident on the metal plate and photoelectrons
are emitted. The maximum wavelength of light so that the photo- electrons may go round
the ion along a circle is
 hc 
2  e2 
8 0W0 d  e 2
8 hc 0d  W0  8 0 d
1) 2) 3) 4)
8 hc 0 d 8 0W0 d  e 2
n hceW0
41. A perfectively reflecting body sphere in shape of radius R is placed on a path of parallel
light beam of intensity I shown in figure. One end of a spring is attached to centre of
sphere and the other end to a rigid wall as shown in figure. Assuming the sphere to be in
equilibrium the spring constant of spring to be K, then compression in spring is

2I I I R 2
1) R 2
2) R 2
3) 4)None of these
KC KC C
42. A radiation of energy E falls normally on a perfectly reflecting plane surface. The change
in momentum of radiation is
E 2E E
1) 2) 3) 4) Zero
C C 2C
43. Light of intensity I is incident normally on a perfectly reflecting plate of area A kept in a
gravity free space. If the photons strike the plate symmetrically and initially the springs
are in their natural lengths, then the maximum compression in the springs is

IA 2IA 3IA 4 IA
1) 2) 3) 4)
KC 3KC KC 3KC
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 Sri Chaitanya IIT Academy, India 19-07-25_Sr.Super60_STERLING BT_Jee-Main_WTM-38_Q.P
44. Statement- 1: The de Broglie wavelength of an electron accelerated through
941 volt is 0.4A
Statement- 2: Higher the accelerating potential, smaller is the de- Broglie wavelength.
1) Statement-1 is true, Statement-2 is true; Statement-2 is a correct explanation for
Staement-1
2) Statement-1 is true, Statement-2 is true, Statement-2 is not a correct explanation for
Statement-1
3) Statement-1 is True, Statement-2 is False
4) Statement-1 is False, Statement-2 is true
45. Statement – 1 :Work function of copper is greater than that of sodium. But both will have
same value of the threshold frequency and threshold wavelength.
Statement –2 :The frequency is inversely proportional to wavelength
1) Statement-1 is true, Statement-2 is true; Statement-2 is a correct explanation for
Staement-1
2) Statement-1 is true, Statement-2 is true, Statement-2 is not a correct explanation for
Statement-1
3) Statement-1 is True, Statement-2 is False
4) Statement-1 is False, Statement-2 is true
SECTION-II (NUMERICAL VALUE TYPE)
This section contains 5 Numerical Value Type Questions. The Answer should be within 0 to 9999. If the Answer is
in Decimal then round off to the Nearest Integer value (Example i,e. If answer is above 10 and less than 10.5
round off is 10 and If answer is from 10.5 and less than 11 round off is 11).
Marking scheme: +4 for correct answer, 0 if not attempt and -1 in all other cases
46. Find the ratio of de- Broglie wavelength of an electron in metal at 27 oC and the mean
separation between two electrons in a metal which is given to be about 2 × 10–10m
47. Light of wavelength 180nm ejects photoelectrons from a plate of metal whose work-
function is 2eV .If a uniform magnetic field of 5  105 T be applied parallel to the plate,
what would be radius of the path, in mm, followed by electrons ejected normally from the
plate with maximum energy
48. A metallic sphere of radius 21 cm is kept in the path of a parallel beam of light of
1
intensity Wm2 . The force exerted by beam on the sphere is x  1013 N . Find x .
110
49. The wavelength of light incident on a metal surface is reduced from 300 nm to 200 nm
(both are less than threshold wavelength). Find the change in the stopping potential, in
volt, for photoelectrons emitted from the surface. Take h  6.6  10 34 JS
50. A proton and an   particle are fired through the same magnetic fields which is
perpendicular to their velocity vectors. Both move such that radius of curvature of their

path is the same.Find the ratio of the de-Broglie wavelength of proton and  -particle.

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 Sri Chaitanya IIT Academy, India 19-07-25_Sr.Super60_STERLING BT_Jee-Main_WTM-38_Q.P
CHEMISTRY Max Marks: 100
SECTION-I (SINGLE CORRECT ANSWER TYPE)
This section contains 20 Multiple Choice Questions. Each question has 4 options (1), (2), (3) and (4) for its
answer, out of which ONLY ONE option can be correct.
Marking scheme: +4 for correct answer, 0 if not attempted and –1 in all other cases.
51. Assertion (A) 1o  Amides react with Br2 in presence of NaOH to form 1o  amine
having one carbon atom less than amide.
Reason (R) It is degradative reduction involving acylnitrene intermediate
1) Both (A) and (R ) are correct 2) Both (A) and (R) are incorrect
3) (A) True but (R) is false 4) (A) is false but (R) is true
52. A) Carbylamine reaction involves chemical reaction between 10 amine and chloroform in
basic medium,
R) In carbylamine reaction,  NH 2 group changes into  NC group.
1) Both (A) and (R ) are correct and (R ) is the correct explanation of (A)
2) Both (A) and (R) are correct but (R ) is not the correct explanation of (A)
3) (A) True but (R) is false
4) (A) is false but (R) is true
53. Statement – 1: Formation of aromatic diazonium salt take place with all aromatic amine
when they reacts with NaNO2 / HCl .

Statement- 2: N  O is electrophile during the formation of Diazonium salt
1) Statement-1 is true, Statement-2 is true; Statement-2 is a correct explanation for
Staement-1
2) Statement-1 is true, Statement-2 is true, Statement-2 is not a correct explanation for
Statement-1
3) Statement-1 is True, Statement-2 is False
4) Statement-1 is False, Statement-2 is true
54. Match the following columns:
Column- I (Reaction) Column-II
(Characteristics of product)
a) Hundsdicker reaction p) Product contain less carbon than reactant)
b) Decarboxylation of   Ketoacid q) Product contain more number
of carbon than reactant
c) Schmidt reaction of Carboxylic acid r) Product contains halogen atom
d) Wurtz reaction s) Product gives isocyanide test
1)  a  pr  b  p  c  ps  d  q  2)  a  pr  b  p  c  ps  d  s 
3)  a  qr  b  p  c  ps  d  p  4)  a  qr  b  r  c  ps  d  p 

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 Sri Chaitanya IIT Academy, India 19-07-25_Sr.Super60_STERLING BT_Jee-Main_WTM-38_Q.P
CH 3  C  ND2
55. Statement-1: || on reaction with Br2 / KOH gives CH 3  NH 2 as a major
O
product.
Statement-2: This is an example of Curtius degradation.
1) Statement-1 is true, Statement-2 is true; Statement-2 is a correct explanation for
Staement-1
2) Statement-1 is true, Statement-2 is true, Statement-2 is not a correct explanation for
Statement-1
3) Statement-1 is True, Statement-2 is False
4) Statement-1 is False, Statement-2 is true
O

 i  PhMgCl 1eq 
Et  C  OEt  Product.
56.
 ii  H 2 O
True about product of above reaction :
1) One of the product will give positive iodoform test
2) Product will give CO2 heating
3) Product will give only one ketoxime with NH 2OH
4) Product will give chiral alcohol with EtMgBr followed by hydrolysis
57. What will be correct sequence of following conversion?
CH3  CH 2  C  NH 2   CH 3  CH 2  NH 2
?
CH 3  CH 2  Cl  ?
 ?

O
1) KMnO4 , NH 3 , KOBr 2) AgCN , HOH , NaOBr
3) KCN , Partial hydrolysis, KOBr 4) Aq, KOH , NH 3 , NaOBr
58. Predict the major product P in following reaction:

1) 2) 3) 4)
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59. Which of the following is secondary amine?
1) t-butyl amine 2) aniline 3) sec.butylamine 4) N-methyl methanamine
60. In the following reaction ,
O

CH 3
C6 H 5  C  N 
LiAlH 4
  A ,
CH 3
, The product (A) will be :
1) C6 H 5CH 2OH 2) C6 H 5COOH 3) C6 H 5CONH 2 4) C6 H 5CH 2 N  CH 3 2
61. What will be reactivity order for isocyanide test for following amines?
NH 2
NH NH 2
2

 R
NH 2
P Q 
H 3C CH 3
OCH 3 CH 3 CH 3
S 
1) P  R  Q  S 2) P  S  Q  R 3) P  Q  R  S 4) Q  R  S  P
62. What could be the product for the following reaction?

1) 2) 3) 4)

63.
1) H 2 / Pd BaSO4 2) LiAlH 4 3) NaBH 4 4) CH 3 MgBr
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64. Correct order of relative rates of esterification of the following acids
with MeOH is
P) Me  COOH Q) n Pr  COOH R) Me3C  COOH S) Et3C  COOH
1) P  Q  R  S 2) Q  R  S  P 3) S  P  Q  R 4) S  R  Q  P

 i SOCl
CH 3CO2 H 
 ii 3 methylaniline 
2

65.
 iii  LiAlH 4 ,then H 3O 
NH 2 NH 2
H 3C H 3C

CH 3 CH 3

1) O 2) OH

H 3C
NH CH 3
N
H 3C H
3) 4)
66. An organic compound (A)  C4 H11 N  , shows optical activity and gives N 2 gas on
treatment with HNO2 and with PhSO2Cl producing a compound (B) which is soluble in
KOH .The compound ‘B’ is :
O
O H
S
S N
O
O NH 2
1) 2)

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O O
NH 2 CH 3
S S

3) O 4) O
67. Statement- I- Adrenaline contains secondary amine group
Statement- II- Benadryl a antihistamine contains tertiary amine group
1) Statement-I is false but Statement-II is true
2) Statement-I is true but Statement-II is false
3) Both Statement-I and Statement-II are true
4) Both Statement-I and Statement-II are false

68.
CH 3

H 3C
N
NH  OH
1) COOH 2)
CH 3

CH 3 N OH
NH
CHO OH
3) 4)

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69.
CN

CN
  A ;Product  A  of thereaction is:

H 3O / 

CN
CN
O O

O O

1) O 2) O
O

CO2 H
O

CO2 H O
3) 4)
70. Among the given compounds, the most susceptible to nucleophilic attack at the
carbonyl group
1) MeCOCl 2) MeCHO 3) MeCOOMe 4) MeCOOCOMe
SECTION-II (NUMERICAL VALUE TYPE)
This section contains 5 Numerical Value Type Questions. The Answer should be within 0 to 9999. If the Answer is
in Decimal then round off to the Nearest Integer value (Example i,e. If answer is above 10 and less than 10.5
round off is 10 and If answer is from 10.5 and less than 11 round off is 11).
Marking scheme: +4 for correct answer, 0 if not attempt and -1 in all other cases
71. If molecular weight of the final major product ( C) is W , then, calculate W .For the
product C in neutral form

Ph  N2 Cl 
 
conc.HNO3 Sn / HCl
   A   B    C
conc.H 2 SO4 0  50 C  
yellow dye
72. How many 10 amine of the formula C5 H13 N can be used to resolve racemic
2- methylbutanoic acid?

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O O

C2 H 5 O Na 
CH 3  C  OC2 H 5  CH 3CH 2  C  OC2 H 5 

73.
How many different condensation products (excluding stereo) would be formed by above
reaction?
74. Consider the reaction sequence:
CH 3

KMnO4

 Q 
P4O10

R
CH 3
P
The molecular weight of “R” is
75. How many of following will form some coloured compound on reaction with phenyl
diazonium chloride under suitable conditions

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