Sri Chaitanya IIT Academy., India.

A.P, TELANGANA, KARNATAKA, TAMILNADU, MAHARASHTRA, DELHI, RANCHI

A right Choice for the Real Aspirant

ICON Central Office – Madhapur – Hyderabad
Sec: Sr.Super-60 & All Jee-Main Date:02-05-2021
Time: 10.00Am to 01.00 GTM-22 Max.Marks:300
Key Sheet
PHYSICS
1 1 2 2 3 4 4 1 5 4
6 3 7 1 8 3 9 3 10 2
11 2 12 2 13 1 14 1 15 2
16 2 17 3 18 1 19 3 20 2
21 0009.00 22 0015.00 23 0005.00 24 0007.00 25 0011.20
26 0006.00 27 0007.20 28 0006.00 29 0006.00 30 0005.00

CHEMISTRY
31 2 32 3 33 1 34 4 35 3
36 4 37 4 38 1 39 2 40 1
41 2 42 1 43 1 44 2 45 3
46 1 47 3 48 1 49 3 50 3
51 0006.00 52 0007.00 53 0004.00 54 0003.00 55 0001.67
56 0100.00 57 0006.00 58 0003.00 59 0007.00 60 0006.00

MATHEMATICS
61 4 62 1 63 4 64 1 65 3
66 2 67 3 68 2 69 3 70 4
71 3 72 4 73 1 74 1 75 3
76 4 77 2 78 3 79 2 80 1
81 0001.00 82 0003.00 83 0005.00 84 0003.00 85 0002.00
86 0080.00 87 0003.00 88 0002.00 89 0002.00 90 0009.00
Sri Chaitanya IIT Academy 02-05-2021_Sr.Super60 & All_Jee-Main_GTM-22_Key & Sol’s

SOLUTIONS
PHYSICS
1.

pA  p  dp  A


dp  2 x dx 
p2 r2
2
 dp    x.dx
p1 r1
 r2  r2 
p2  p1  2  2 1 
 2 
 
2  p2  p1 


 r22  r12 
m x  m2 x2
2. RCM  1 1
m1  m2
R
 4m  R  m    3m  x 
2
7R
x
6
3. C 0 L, C  q  V 
q
I
t
4.
f sp
T

mg
T
2mg

FSP  T  2mg......1 T  mg........ 2 

After cutting T  0 
Fsp  2mg   2m  a A
3mg  2mg  2  m  a A
g
aA  
2
Similarly 0  mg  maB

Sec: Sr.Super-60 & All Page 2

Sri Chaitanya IIT Academy 02-05-2021_Sr.Super60 & All_Jee-Main_GTM-22_Key & Sol’s

aB   g 
u 2 sin 2  u 2 sin 2
5. H ,R 
2g g
H max is same.
1
R '  u cos T  aT 2
2
2
1 g  2u sin  
R  
2 4 g 
 RH
Q
6. r  R, E  K . .r
R3
Q
rR EK
r2
Q 2Q
 E1  K . , E2  K .
2
R R2
4QR  1 
E3  K .  let K  
 2 R 3  40 
 R
7. RS  n   ,
 2n 
1 R 
RP   
n  2n 
 Rmax  RS  RP
R 1 
 1 
2  n 2 
8.  
ig G  i  ig S ,
G 
i  i g   1
S 
9. B ||11 plane of circular loop
X
10. Tan  L  1,   450
R
 T 
t   
 360 
V
11. up  rel ,
2R
V
Low  Re l
2R

Sec: Sr.Super-60 & All Page 3

Sri Chaitanya IIT Academy 02-05-2021_Sr.Super60 & All_Jee-Main_GTM-22_Key & Sol’s

I
12. T  2
M ' gd
L
M    mL
2
M ' m M, d   
m  M 
ML2
I  mL2
3
13. m1.1. 50  30   m2.1. 80  50 
m1 3

m2 2
3 2
m1   40  , m2   40 
5 5
14. Conceptual
100
15. For each Bulb i  A
220
if n Bulbs in parallel
n i  I fuse
16. 60  ic
sin 600  sin ic
3 L
 ,  L  1.5  0.866
2 g
 1.299
1.3
 N 
17. No’ of turns in thickness dx is    dx
ba
b
  .Nidx
 dB   2 0b  a  x
a
b
 .N i  dx 
B 0
2b  a   x 
 
a
1 TAB
18. n AB  ……. (1)
2 
2 TCD
nCD  …….. (2)
2 
1   2  solve, TAB  4 TCD
For Rot. equilibrium
TAB  x   TCD  L  x 
Sec: Sr.Super-60 & All Page 4
Sri Chaitanya IIT Academy 02-05-2021_Sr.Super60 & All_Jee-Main_GTM-22_Key & Sol’s
L
Solve x 
5
19. L cos      L    cos 
 L cos    
  cos 1  
 L 
20. Conservation of energy
1 2 GMm GMm
m  Kve   
2 R Rh
Put Ve  2 gR,
GM  gR 2 solve
R
hR
1 K 2
12 12 0
21. B  C e  
5 6 1
m  12.014  12 
Energy released  13.041 mev
 Energy converted to
K .E of electron
 13.041  4.041
 9 meV
 i
22. Bn  0 n
2rn
i f
Bn n  n
rn rn
v / r 
Bn n n
rn
 z / n z3
Bn  
2
n5
 n2 / z 
23.
   1 t D  5D ,
d d
5
t  50,000 A0
 1
 5  106 m
 5m
24. f0  fc  2
 1 1  v
v   2, 8
 2 L 4 L  L

Sec: Sr.Super-60 & All Page 5

Sri Chaitanya IIT Academy 02-05-2021_Sr.Super60 & All_Jee-Main_GTM-22_Key & Sol’s
v v 7v
f 01  fc1   
L 8L 8L
Am
25. m , Am  0.8  14  11.2V
Ac
P 1 2
26. I   0 E 2C  E   2  103 v / m
A 2 A 0 C
27.   MB sin 
 0.018
MB  
sin  1 / 2
 
 0.036 J , w  MB cos 00  cos1800  7.2  10 12 Joule .
28.
F
A
300

fs C

mg

About C
 F  mg
a
Fa cos300  mg  
2
mg
F
3
mg
If no translation F 
3
But f s  mg
mg 1
 mg  
3 3
29. C  n1/3 , C
Big small
30.  z  12   CONSTANT
 9  12    z  12  4  .

Sec: Sr.Super-60 & All Page 6

Sri Chaitanya IIT Academy 02-05-2021_Sr.Super60 & All_Jee-Main_GTM-22_Key & Sol’s
CHEMISTRY
31. K .E  frequency of incident radiation order of v  x  uv  visible
32. Based on H-bond
33. Based on E.N. difference between atoms, ionic nature  difference in E.N.
34. 10 volume H 2O2  3% H 2O2
35.  f H 0 for graphite  0, Diamond  1.90 KJ / mol fullerene  38.1 KJ / mol
W
36. pv  nRT  RT
M
wRT
mol.wt M   256 g
pv
 256 g of ' S '  S8
37. 2 MnO4  5C2O42  16 H  
 2 Mn 2  10CO2  8 H 2O
n5 n2
N 4 2
KMnO4 5M 510 , N  2M  210
C2O 2
4
From Law of equivalents
No. of eq of MnO4  C2O42
2
2  10  0.5
 vol of MnO4   20 L
5  104
38. N 2O4 2 NO2
g g
1 ___
1-0.5 2  0.5
0.5 1
xN 2O4  , x NO2 
1.5 1.5
p 0.5 1
N 2O4  1 atm, p NO2  1 atm
1.5 1.5
2
Kp 
 PNO  2
 1.33 atm
PN 2O4
G 0  2.303 RT log K p  763 KJ
39. AgCl in H 2O
K sp  s  s  s 2

s  K sp  1.8  1010

 1.3  105 mol / lit

AgCl in 0.01M CaCl2
 Ag    s , Cl    2  0.01  S
  2   2

Sec: Sr.Super-60 & All Page 7

Sri Chaitanya IIT Academy 02-05-2021_Sr.Super60 & All_Jee-Main_GTM-22_Key & Sol’s

K sp   Ag   Cl  
  
1.8  1010  S 2  0.02  S2 
S2  9  109 mol / lit
AgCl in 0.01 M NaCl
 Ag    S . Cl    0.01  S
  3  3

1.8  1010  S3  0.01  S3 

S3  1.8  10 8 mol / lit
 1.8  108
40.  i  ,  ii  ,  iii  and  iv 
41. In XeOF4 molecule:
Xe

sp3d 2 hybridised with 1 1p

O
F F
Xe
F F

Square – pyramidal shape.

42. Ionic radii decrease across lanthanide series due to lanthanide contraction. As all ions
are in 3 O.S ., ionic radii will follow the trend of atomic radii.
 La3  Ce3  Pm3  Yb3
 Z  57   Z  58  Z  61  Z  70 
43. TTTT
dil .H 2 SO4
 C O 2  2 H  
 2 4  No vapour or gas is evolved
44. a:
 
 NO3 : No reaction wiht dil. H 2 SO4
 
 NO3 : No reaction with dil H 2 SO4
b:
dil . H 2 SO4
 NO2  H  
  HNO2

Dispropotionation

Atm.air
NO2   HNO3  NO 
Light brown

Hence, distinction is possible.

C: Both Cl  and Br  have no reaction with dil. H 2 SO4 .
D: Both HCO3 and CO32 produce CO2  which evolves with effervescences.
1
45. C  s   O2 g  
 CO g  ; S increases.
2
Sec: Sr.Super-60 & All Page 8
Sri Chaitanya IIT Academy 02-05-2021_Sr.Super60 & All_Jee-Main_GTM-22_Key & Sol’s

Hence, as the temperature increases, T S increases and hence G  H  T S 

decreases. In other words, the slope of the curve for formation of CO decreases.
However, for all other oxides, it increases.
46. Given K  3  102
cm  12  102
K  1000 3  102  1000
 0m    3  103
c 0.01
cm 12  102
   0.4
0m 3  103
i  1   n  1   1  1  0.4  1.4
T f  i K f m  1.4  1.86  0.1  0.2604
 E1a

47. With catalyst K1  A.e  R400 

 Ea

Without catalyst K 2  A.e  R500 

Given rate of run is same then
K1  K 2
 E1a  Ea
 
R  400 R  500
Ea Ea'
 [Given Ea  Ea'  20 ]
R  500 R  400
Ea Ea  20

500 400
 Ea  100 Kj / mol
48. A  r , B  s, C  q, D  p
49. Let x, mole fraction of Benzene in solution then 1  x1  be mole fraction of Toluene.
Applying raoults law
PTot  x1PB0  1  x1  PT0
760  x1 1375   1  x1  558 
x1  0.247
Mole fraction of benzene in vapour phase is
x P 0 0.217  1375
yB  1 B   0.447
PTot 760
50. a  b  c,       900
51. a, b, c, d , e, f are correct.

Sec: Sr.Super-60 & All Page 9

Sri Chaitanya IIT Academy 02-05-2021_Sr.Super60 & All_Jee-Main_GTM-22_Key & Sol’s
CH 2 CH 2 CH 2 CH 2 CH 2

   
NO2 Cl
for ' g ' correct order is OMe CH 3

52. All are correct

53. a, d , f , i are non – aromatic
b, g , h are aromatic
c, e, are Anti – Aromatic
54. b, c, e are essential Amino acids
Remain are Non – essential Amino acids.
M
55. PDI  w
Mn
i i
 Ni M i2  M i Ni
M w  n 1 , M n  n 1
i i
 Ni M i  Ni
n 1 n 1
56. Aspartame is 100 times sweater than cane sugar.
57. a , c, d , e, g , h will give positive test with Tollen’s reagent
58. a, b, d will give Haloform test
59. a, b, c, d , e, f , g will give CH 4 on run with CH 3MgBr . Acidic ‘H’ contain group will
produce methane . ‘H’ attached to S , O, N & C SP  are acidic hydrogen
60. Correct options are b,c,d,e,f,h

MATHEMATICS
4
61. 
Coefficient of x 20 in 1  x  x 2  ........  x10 
62. For ranked 1 and 2 players to be winners and runners up res., they should not be paired
30 14 6 2 16
with each other in any round. Therefore, the required probability     
31 15 7 3 31
63. Favourable cases for bijections is 100C .9! possible cases; If n  B   1, no. of
9

functions=1 if n  B   2, no. of functions  29

|
|
|
9
If n  B   101, number of continuous  101
9
n  S   1  100C1.29  100C2 .39  ......  100C100 101
101
  100Cr 1.r 9
r 1
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Sri Chaitanya IIT Academy 02-05-2021_Sr.Super60 & All_Jee-Main_GTM-22_Key & Sol’s

n E 
pE 
n S 
n  n  1
64. Period of  x    2 x   .......   nx   x is 1
2
 Period of x   x  is 1.
1 2r 1 1 1 
65. tr    
2 2 2  r 2  r  1 r 2  r  1 
 
r2 1  r2
n
1 1  1
LT
n 
 tr  n
Lt 1 
2 1  n  n  1

2
r 1  
1 1 1 1
66.   
z1 z2 z3 z1
z2  z1 z1  z3

z1z2 z1z3
z z   z 
Arg  2 1  Arg   2 
 z3  z1   z3 
z 
    Arg  2 
 z3 
z 
    Arg  3 
 z2 
     
P, Q, R, S areconcyclic.
2 106  13 4 5
67. x  111111  1  10  10  10  10  10 
9
2
 106  1   106  1 
f 111111  90    20   1
 9   9 
   
2



10 106  1  

20 106  1  1
9 9
10 12 1013  1

9

10  1  1 
9

 1111111111111
Sum of digits = 13
404 303 202
68. Required value is coefficient of x 4 in 1  x  .4C0  1  x  .4C1  1  x  .4C2
101 101
 1  x  .4C3  4C4  1 where y  1  x 
 4C0. y 4  4C1. y 3  4C2 y 2  4C3 y  4C4  1
Sec: Sr.Super-60 & All Page 11
Sri Chaitanya IIT Academy 02-05-2021_Sr.Super60 & All_Jee-Main_GTM-22_Key & Sol’s
4

 y  14  1  1  x 101  1  1
4

 101C1x  101C2 x 2  _____  1
4 4
Coefficient of x 4  101C1   101
1
69.  sin x  3  t
1
2 1 2
1 t t
 dt   dt
4 2
1 t  1 2
t    2
 t
 
 1
t 
1 1 
 Tan  t   C
2  2 
 
1
70.   x sin x  dx
1
1
 2  x sin x  dx  f is even
0
 2 0  0
0  .x  1 0  sin x  1
0  x sin x  1  x sin x   0
71.  
If y  e x C1  C2 x  C3 x 2 then D.E. is

d3y d2y dy
 3  3 2
 y0
3 2 dx
dx dx
72. Chord having P  x1, y1  as midpoint is S1  S11
p a
xx1  yy1   x  x1    y  y 1 
2 2
2 2
 x1  y1  px1  qy1
 p  x1, y1  lies on x  axes
 y1  0
p q
xx1   x  x1   y  x12  2  px1
2 2
Passes through  p, q 
p q
px1   p  x1   .q  x12  px1
2 2

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Sri Chaitanya IIT Academy 02-05-2021_Sr.Super60 & All_Jee-Main_GTM-22_Key & Sol’s

Constant of p  x1,0  is
3p p2  q 2
x2  x 0
2 2
 There are two chords
 b 2  4ac  0
p 2  8q 2
73. Focus  h  1, k  and  0,0  lie on opposite side of the line x  y  1  0 and same side of
the line x  y  3  0
 h  k  1  0  0  h  k
 h  k  2  3  0  h  k  2
74. r 2  r  6  0 and r 2  6r  5  0
75. Director circles are x 2  y 2  a 2  b2 and x 2  y 2  a 2  b 2
2 2 2 2 2 2 25r 2
a  b  4r ; a  b  r  a 
2
3r 2 2 b2 b2
b2  ; ea  1  , eb2  1 
2 a2 a2
76. a  b mod m  ' m ' devides ' a  b '
77. R1  R1  R2 ; R3  R3  R1
k 4 1
78. 4 k 2 0
2 2 1
79. PR  PQ  PS
PR1 PQ1 PS1
 
3 1 2
 Q1, R1, S1 are collinear
1 1 1
  
1  2 3
80. Put n  2 and verify
81. If x is irrational cos 2m  n!x   0 As m  
 f  x  1
  
82. 0  cos x  1; x    , 
 2 2
3  3  2cos x  5
 f  x  is discontinuous
 3  2cos x is an integer

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Sri Chaitanya IIT Academy 02-05-2021_Sr.Super60 & All_Jee-Main_GTM-22_Key & Sol’s
1 
If 3  2cos x  4 . Then cos x  x
2 3
If 3  2cos x  5 then cos x  1  x  0
83. sin 1 x  is discontinuous when sin 1 x  1,0,1
 
x   sin1,0,sin1
 a3
 2 
g  x   , x  0 is decreasing function
2
1  x 
2
  0,2
2
1 x
2
 g  x  is discontinuous when  1,2  x  1,0
2
1 x
b2 ab5
84. Let f  x   ax 4  bx3  cx 2  dx
f  0   0  f  3 ; By Rolle’s theorem c   0,3
f '  c   0;   0,   3
85. If x, y  R and x 2  y 2  xy  1 . Then the maximum value of x3 y  xy 3 is 2
x  r cos , y  r sin 

 
r 2 cos 2   sin 2   r 2 sin  cos   1
2 2 
r2    ,2
2  sin 2  3 

 
xy3  x3 y  xy x 2  y 2  r 4 sin  cos 
2
1  1   2
2
 r 1 r  2
    r 2     2, 
4  2  9
max  2
86. 7 cos 2   1  4cos 
2
 7 cos 2   1   16cos 2 
1  cos2
Put cos 2  
2
2
49cos 2  38cos 2  7  0
p  49, q  38, r  7
p  q  r  80
87. y  cos 1  cos x   2  x if  2  x  
 x if    x  0
x if 0  x  
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Sri Chaitanya IIT Academy 02-05-2021_Sr.Super60 & All_Jee-Main_GTM-22_Key & Sol’s
 2  x if   x  2
y  ,   ,    2  x if 2  x  3

y  2  x y  x

 O
2  2 3

 x, y    2,0  ,  0,0  2,0 

No. of solutions = 3
88.
A
60 0 T

a
h

P
R R
2
B C

a
 2R
sin A
a
R

2sin
3
a
R
3
AT  BT  R 2  h 2
AB 2  AT 2  BT 2  2 AT .BT cos ATB


a 2  2 R 2  h2  2 R 2  h 2 cos
3
  
2 a 2  3h 2
89. Image of A  3,2  is A '  3,2 
B   2,5
3
Equation of A ' B is y  5    x  2
1
3 x  y  11 P  0, k  is intersection point of y  axis
And 3 x  y  11
k 1
 k  11 2
5
90. A   t  3,3t  1,6  t 
B   7t ' 5,2  6t ',4t ' 3 
By comparing A & B we get t  1, t '  1
B   2, 4,7   R Reflection of R  2, 4,7  in xy  plane is  2, 4, 7    , ,  
   247 9

Sec: Sr.Super-60 & All Page 15