Sri Chaitanya IIT Academy, India 28-06-25_Sr.
Super60_STERLING# BT_Jee-Main_WTM-36_Key & Sol’s
Sri Chaitanya IIT Academy.,India.
A.P T.S KARNATAKA TAMILNADU MAHARASTRA DELHI RANCHI
A right Choice for the Real Aspirant
ICON Central Office - Madhapur - Hyderabad
SEC: Sr.Super60_STERLING BT JEE-MAIN Date: 28-06-2025
Time: 09:00AM to 12:00PM WTM-36 Max. Marks: 300
KEY SHEET
MATHEMATICS
1 3 2 4 3 1 4 2 5 2
6 3 7 2 8 2 9 4 10 4
11 3 12 2 13 2 14 3 15 3
16 1 17 3 18 4 19 3 20 1
21 7 22 53 23 1686 24 144 25 4607
PHYSICS
26 1 27 2 28 3 29 2 30 2
31 4 32 4 33 3 34 2 35 1
36 2 37 3 38 2 39 3 40 3
41 2 42 2 43 3 44 3 45 1
46 2 47 4 48 2 49 3 50 4
CHEMISTRY
51 4 52 4 53 1 54 1 55 2
56 2 57 1 58 4 59 1 60 3
61 1 62 2 63 3 64 1 65 4
66 4 67 3 68 3 69 1 70 3
71 4 72 5 73 14 74 10 75 4
SEC: Sr.Super60_STERLING BT Page 1
Sri Chaitanya IIT Academy, India 28-06-25_Sr.Super60_STERLING# BT_Jee-Main_WTM-36_Key & Sol’s
SOLUTION
MATHEMATICS
1. A) the no.of 3 digit no’s greater than 500 are 2 4 P2 24
the number of 4 digit no’s less than 4000 are 2 4 P3 48
n 24 48 72
B) The no.of 3 digited even no’s greater than 200 are
0 3 3 9
2 or 4 2 3 2 12
The no.of 4 digited even no’s less than 3000 are
1 0 or 2 or 4 3 3 P2 1 8
2 0 or 4 2 3 P2 1 2
n 9 12 18 12 51
C) Required no.of words. 630 (180 180 60) 330
D) (2r 1)! 11!
8! 9 P2
2. Statement- I : The required number of ways of arranging false
2!2! 2!
Statement –II is true
6! 6
3. The total no. of ways (7 r ) 2700
2!2! r 2
4. Since repetition is allowed first four places can be filled in 94 ways. and the last place
can be filled in 3 ways according to the sum obtained by the first four places
5 3
5. Values of x at which as max or min are , , ,
6 2 6 2
points of max are 2 and minima are 2
2 2! 2! 8
6. In between the two brothers exactly 3 or 4 or 5 or 6 or 7 or 8 persons can sit in
2 18! ways and exactly 9 person can sit is 18!ways 6 2 18! 18!
2010
7. 402 402 5!
5
6!
8. The required no 7 P5 5! 6 P5
2!
SEC: Sr.Super60_STERLING BT Page 2
Sri Chaitanya IIT Academy, India 28-06-25_Sr.Super60_STERLING# BT_Jee-Main_WTM-36_Key & Sol’s
9.
B ,B ,H ,J ,O
B 4! 24
4!
H 12
2!
JB 3! 6
JH B 2 ! 2
44
J H O B B - 4 5 th
10. 30 volumes
-2 volumes (not together)
--------------
28 volumes
--------------
26 + 1 unit of 2 volumes ( together) = 27 volumes
So. required no.of arrangements = 27! 2! 28P2
11. i) placing boys in circular table (ii) but of 6 places between boys placing 2 particular
girls to any 4 places which is not adjacent to a particular boy (iii) remaining 4 girls to
remaining 4 places 5!4.3.4! 2.6!4!
12. Least digit used = 4
we can use 4,5,6,7,8,9
64 54 ( no 4 at all ) = at least one 4
13.
5ways 6ways 6way 6way 2way
s s s
2160
14. If the number is 100a 10b c where 1 a 9
bc ac ac
0 b, c 9 then a or b or b where a, b, c are distinct
2 2 2
171 4n 2 20n
15. xn 0
4n !
4n 2 20n 171 0
Which is true for n 1, 2,3,4
16. for r 6, r ! is divisible by 240
remainder 1! 2! 3! 4! 5! 153
17. Number of sequences that can be formed 45
Number of sequences that include BAD 3 42 48
Required number 45 48 976
SEC: Sr.Super60_STERLING BT Page 3
Sri Chaitanya IIT Academy, India 28-06-25_Sr.Super60_STERLING# BT_Jee-Main_WTM-36_Key & Sol’s
18. Sum of the digits in odd places and sum of the digits in even places are equal or differ by
multiple of 11
19. a11 a12 a13 0 , remaining ‘6’ elements can be filled in 76
( 3,0,3),( 2,0, 2),(1,0,1)
3! 5 30
( 3,1,2),(3, 1, 2
3!
ways ( 2,1,1)(2, 1, 1) 2 6
2!
1
0,0,0
37
20. m = 240, n = 660
8 7
7! P4 P
21. 6! 4
2! 4! 4!
41 52 63 71
a 1, b 2, c 3, d 1
22.
E , F , M ,O , R , R
5!
E 4! 36
2!
4!
F E 3! 6
2!
4!
F M 3! 6
2!
3!
FO E 2! 1
2!
3!
FO M 2! 1
2!
FORE 2! 2
FORM ER 1
53
23.
1 54
2 54
3 1 53
3 2 53
3 3 53
3 51 52
3 5 2 52
3 5 31 5
3 53 2 5
35331 1
1686
SEC: Sr.Super60_STERLING BT Page 4
Sri Chaitanya IIT Academy, India 28-06-25_Sr.Super60_STERLING# BT_Jee-Main_WTM-36_Key & Sol’s
24. 1) Arrangement of 2 units of 3 girls and 4boys 2 ! ways
2) 3 girls can be stand together in 3! ways
3) 4 boys can be stand together and B1 and B2 not adjacent to each other is
2! 3 P2 2!3!
required ways 2!3! 2! 3! 144
25.
3
5 0 or 1 or 2 or 3 4 8 2048
6 0 or 1 or 2 3 83 1536
7 0 or 1 2 83 1024
4608
Since 5000 not included so 4608 -1 = 4607
SEC: Sr.Super60_STERLING BT Page 5
Sri Chaitanya IIT Academy, India 28-06-25_Sr.Super60_STERLING# BT_Jee-Main_WTM-36_Key & Sol’s
PHYSICS
26. Conceptual
A 5A
27. 2i A i
4 4
3 1
28. 1 sin r r 60
2 2
1.5t
29. NA
t
NB
4
3t
1.6
NC 4
N A N B NC
30.
4
9 12
3
d 10
31. d app real 7.5cm
4
3
For plane mirror u 10 7.5
v u
d h
32. apparent depth of P = x1
d h
apparent depth of image of P x2
apparent distance between P and its image x2 x1
33. glass slab doesnot change angle of incidence on prism
A
at minimum deviation r1 r2 30
2
sin i 3 sin 30 i 60
D 2i A
34. Conceptual
3
35. A) Velocity of fish in air 8 6
4
Velocity of fish w.r.t. bird 6 6 12
3
(B) Velocity of image of fish after reflection from mirror in air 8 6 w.r.t. bird
4
6 6 0
SEC: Sr.Super60_STERLING BT Page 6
Sri Chaitanya IIT Academy, India 28-06-25_Sr.Super60_STERLING# BT_Jee-Main_WTM-36_Key & Sol’s
4
(C) Velocity of bird as seen from water 6 8
3
Velocity of bird in water after reflection from mirror 8
w.r.t. fish 8 8 0
10
36. f 5cm
2
u 4cm
1 1 1
v 20cm
f u v
30 1
apparent hight ha hr 1 = 20 cm
2 1.5
R
37. f 20cm
2
1 1 1
v1 20cm
f u v
d 5 20 25cm
After refraction final image is at d ' d 2 18.75cm
1
38. 1 sin 2 sin r ....(1)
1 sin 90 2 sin 90 r 2 cos r ....(2)
1 sin r
sin
2 cos r
22
sin 1
12
1 B
39. sin , A is less for large
40. Conceptual
x
41. 14 ...(1)
24 14 4
4
3
a
42. For the first medium, sin
a b2
2
c
And for the second medium, sin 2
c2 d 2
1a 2a
By Snell’s law, we have 1 sin 1 2 sin 2
a2 b2 c2 d 2
Hence, the correct answer is (2).
SEC: Sr.Super60_STERLING BT Page 7
Sri Chaitanya IIT Academy, India 28-06-25_Sr.Super60_STERLING# BT_Jee-Main_WTM-36_Key & Sol’s
3 6
43. sin C sin 0
2 5
4
sin C C 53 = 90 C = 90 C = 37 = 53
5
1 R
44. sin C
R2 H 2
45. Conceptual
46. sin i sin C
R 1
Rr
d d
47. d 1 2
1 2
dy dy
48. dy '
1 y
H
H dy
H ' H n 2
0 y
1
H
49. 1sin 60 sin r ....(1)
sin r 1 sin ....(2)
60
sin 60
2r (180 ) 180 r 30 =
sin 30
2
50. sin C
3 3
2
At common surface
2
sin 60
3
3 2
2 3
3 3
4
SEC: Sr.Super60_STERLING BT Page 8
Sri Chaitanya IIT Academy, India 28-06-25_Sr.Super60_STERLING# BT_Jee-Main_WTM-36_Key & Sol’s
CHEMISTRY
51.
(A)
NH2 OH
NaNO2+HCl
H2O, warm
(B)
OH O
Na Cr O
2
2 7
H 2SO4
O
(C)
OH
OH
CHO
(i) CHCl3 +aqNaOH
(ii) H+
(D)
OH
OH
NO2
NO2
Conc.HNO3
NO2
52. Statement-1: Picric acid is 2, 4, 6- tri nitro phenol
Statement-2: Phenol -2, 4 disulphonic acid is treated with conc. HNO3 to get picric
acid
SEC: Sr.Super60_STERLING BT Page 9
Sri Chaitanya IIT Academy, India 28-06-25_Sr.Super60_STERLING# BT_Jee-Main_WTM-36_Key & Sol’s
OCH3 OH
OH
OCH3
3H I 3 C H 3 -I
OCH3 OH
53.
1
54. Acidity
pKa
Order of pKa value E<B<D<A<C
55.
K C2H5Br
Ph-CH2-CH-CH3 Ph-CH2-CH-CH3 Ph-CH2-CH-CH3
+
OH OK OC2H5
56. Both statement 1 and statement 2 are correct
57. Assertions and Reason both are correct and reason is correct explanation for assertion
58. SN 2 Reaction would occur more easily with primary alkyl halide (chloro ethane) rather
than with secondary. Alkyl halide (2-chloro propane)
59.
OH O Na O
NaOH Br
CH3 CH3
O2/ H3O+
Ph-CH CH3 Ph-C- CH3
O
O
H
HO CH3+Ph-C-
CH3
60.
61. C2 H5O Will abstract proton from phenol to form phenaxide lon C6 H 5O . Since
C2 H5O is better nucleophile than C6 H 5O
, there fore, it will preferentially attack
C2 H 5 I to form C2 H 5 O C2 H 5
SEC: Sr.Super60_STERLING BT Page 10
Sri Chaitanya IIT Academy, India 28-06-25_Sr.Super60_STERLING# BT_Jee-Main_WTM-36_Key & Sol’s
62.
CH3 CH3
OH
OH OH2
H 2S O 4
OH OH CH3
CH3 CH3
OH
CH3
H
O
63.
C H 2O H C H 2I CH 2
C H O H 3 H I Wa rm C H I C H I 2
C H 2O H C H 2I C H 2I
G ly c e ro l 1 ,2 ,3 - tr iio d o p r o p a n e A lly lio d id e
( u n s ta b le )
HI
CH3 CH 3 CH3
HI
CHI C H I C H I
2
CH3 CH 2 C H 2I
2 - io d o p r o p a n e P r o p e n e (u n s ta b le )
64.
CH2-O Br2/Fe
CH2-O Br
Conc.HBr
CH2-Br+HO Br
65. In acidic medium, phenol exists in following resonating structures.
SEC: Sr.Super60_STERLING BT Page 11
Sri Chaitanya IIT Academy, India 28-06-25_Sr.Super60_STERLING# BT_Jee-Main_WTM-36_Key & Sol’s
Since, o / p positions are electron rich sites, so electrophile will attack on these site,
i.e., hydrogen of these sites get exchanged by D (deuterium). Hence, the final product
of the
66.
18
O 18
CH3 +
OH OH
H /H 2 O
+
CH3
CH3 CH3
18
O
67. P-cresol (4-methyl phenol) has a methyl group at the para Position, which blocks the
reaction with pthalic anhydride, resulting in no colour change
68.
O
OR OH
OH
O-C-CH3
(i) NaOH COOH
HI (ii) CO2 COOH
-RI (i) (CH3CO)O
(iii) H3O+ (ii) H+
P Q
R
S
69.
MgBr OH
O
Mg
Et2O
(A)
SEC: Sr.Super60_STERLING BT Page 12
Sri Chaitanya IIT Academy, India 28-06-25_Sr.Super60_STERLING# BT_Jee-Main_WTM-36_Key & Sol’s
70. Phenol give characteristic colour reaction with neutral FeCl3 soluiton
71. (i), (ii), (iii), (iv) produce tribromo derivative with Br2 / H 2O
Mass of product-massof reactant
72. Number of hydroxyl groups ( n)
n
390 180
n 5
42
A 5, B 9
73.
A B 14
1 2 2 1
3 1 1
74.
75. i, ii, v, vi ethers can be synthesized by Williamson synthesis
SEC: Sr.Super60_STERLING BT Page 13
