Meissner Effect - Wikipedia
Meissner Effect - Wikipedia
The Meissner effect (or Meißner–Ochsenfeld effect) is the expulsion of a magnetic field from a
superconductor during its transition to the superconducting state when it is cooled below the
critical temperature. This expulsion will repel a nearby magnet.
The German physicists Walther Meißner (anglicized Meissner) and Robert Ochsenfeld[1]
discovered this phenomenon in 1933 by measuring the magnetic field distribution outside
superconducting tin and lead samples.[2] The samples, in the presence of an applied magnetic
field, were cooled below their superconducting transition temperature, whereupon the samples
cancelled nearly all interior magnetic fields. They detected this effect only indirectly because the
magnetic flux is conserved by a superconductor: when the interior field decreases, the exterior
field increases. The experiment demonstrated for the first time that superconductors were more
than just perfect conductors and provided a uniquely defining property of the superconductor
state. The ability for the expulsion effect is determined by the nature of equilibrium formed by
the neutralization within the unit cell of a superconductor.
A superconductor with little or no magnetic field within it is said to be in the Meissner state. The
Meissner state breaks down when the applied magnetic field is too strong. Superconductors can
be divided into two classes according to how this breakdown occurs.
In type-II superconductors, raising the applied field past a critical value Hc1 leads to a mixed
state (also known as the vortex state) in which an increasing amount of magnetic flux
penetrates the material, but there remains no resistance to the electric current as long as the
current is not too large. Some type-II superconductors exhibit a small but finite resistance in the
mixed state due to motion of the flux vortices induced by the Lorentz forces from the current. As
the cores of the vortices are normal electrons, their motion will have dissipation. At a second
critical field strength Hc2, superconductivity is destroyed. The mixed state is caused by vortices
in the electronic superfluid, sometimes called fluxons because the flux carried by these vortices
is quantized.
Most pure elemental superconductors, except niobium and carbon nanotubes, are type I, while
almost all impure and compound superconductors are type II.
Explanation
The Meissner effect was given a phenomenological explanation by the brothers Fritz and Heinz
London, who showed that the electromagnetic free energy in a superconductor is minimized
provided
This equation, known as the London equation, predicts that the magnetic field in a
superconductor decays exponentially from whatever value it possesses at the surface. This
exclusion of magnetic field is a manifestation of the superdiamagnetism emerged during the
phase transition from conductor to superconductor, for example by reducing the temperature
below critical temperature.
In a weak applied field (less than the critical field that breaks down the superconducting phase),
a superconductor expels nearly all magnetic flux by setting up electric currents near its surface,
as the magnetic field H induces magnetization M within the London penetration depth from the
surface. These surface currents shield the internal bulk of the superconductor from the external
applied field. As the field expulsion, or cancellation, does not change with time, the currents
producing this effect (called persistent currents or screening currents) do not decay with time.
Near the surface, within the London penetration depth, the magnetic field is not completely
canceled. Each superconducting material has its own characteristic penetration depth.
Any perfect conductor will prevent any change to magnetic flux passing through its surface due
to ordinary electromagnetic induction at zero resistance. However, the Meissner effect is distinct
from this: when an ordinary conductor is cooled so that it makes the transition to a
superconducting state in the presence of a constant applied magnetic field, the magnetic flux is
expelled during the transition. This effect cannot be explained by infinite conductivity, but only by
the London equation. The placement and subsequent levitation of a magnet above an already
superconducting material does not demonstrate the Meissner effect, while an initially stationary
magnet later being repelled by a superconductor as it is cooled below its critical temperature
does.
The persisting currents that exist in the superconductor to expel the magnetic field is commonly
misconceived as a result of Lenz's Law or Faraday's Law. A reason this is not the case is that no
change in flux was made to induce the current. Another explanation is that since the
superconductor experiences zero resistance, there cannot be an induced emf in the
superconductor. The persisting current therefore is not a result of Faraday's Law.
Perfect diamagnetism
Superconductors in the Meissner state exhibit perfect diamagnetism, or superdiamagnetism,
meaning that the total magnetic field is very close to zero deep inside them (many penetration
depths from the surface). This means that their volume magnetic susceptibility is = −1.
Diamagnetics are defined by the generation of a spontaneous magnetization of a material which
directly opposes the direction of an applied field. However, the fundamental origins of
diamagnetism in superconductors and normal materials are very different. In normal materials
diamagnetism arises as a direct result of the orbital spin of electrons about the nuclei of an
atom induced electromagnetically by the application of an applied field. In superconductors the
illusion of perfect diamagnetism arises from persistent screening currents which flow to oppose
the applied field (the Meissner effect); not solely the orbital spin.
Consequences
The discovery of the Meissner effect led to the phenomenological theory of superconductivity by
Fritz and Heinz London in 1935. This theory explained resistanceless transport and the Meissner
effect, and allowed the first theoretical predictions for superconductivity to be made. However,
this theory only explained experimental observations—it did not allow the microscopic origins of
the superconducting properties to be identified. This was done successfully by the BCS theory in
1957, from which the penetration depth and the Meissner effect result.[5]
A tin cylinder— T = 4.2 K, B =
in a Dewar 8 mT (80 G).
flask filled with Tin is in the
liquid helium— normally
has been conducting
placed state. The
between the compass
poles of an needles
electromagnet. indicate that
The magnetic magnetic flux
field is about 8 permeates the
millitesla (80 cylinder.
G).
The cylinder
has been
cooled from
4.2 K to 1.6 K.
The current in
the
electromagnet
has been kept
constant, but
the tin became
superconducti
ng at about
3 K. Magnetic
flux has been
expelled from
the cylinder
(the Meissner
effect).
See also
References
Further reading
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