NARMADA

NEET 4 MAY 2025

BOOKLET CODE th
45 QUESTION PAPER WITH SOLUTION KEY
Net vertical force due to surface tension = Wt of
Physics liquid risen
01. Consider a water tank shown in the figure. It has SZsin(  d )  SZ sin    g(Zydx)
one wall at x = L and can be taken to be very wide
in the z direction. When filled with a liquid of surface S[  d   ]   gydx
tension S and density ρ , the liquid surface makes
d  gy
angle 0 (0  1) with the x-axis at x = L. If y(x) is 
dx S
the height of the surface then the equation for y(x) is
: dy
As   sin   tan  
dx

d 2 y  gy
 
dx 2 S
02. A microscope has an objective of focal length 2 cm,
eyepiece of focal length 4 cm and the tube length of
40 cm. If the distance of distinct vision of eye is 25
cm, the magnification in the microscope is
(1) 100 (2) 125
(3) 150 (4) 250
dy
(take ( x )  sin ( x)  tan ( x )  , g is the
dx v  D 
(2) m  u  4 
0

acceleration due to gravity) Sol.

0  e 

d 2 y g d 2 y g
(1)  x (2)  y L
dx 2 S dx 2 S
fe
f0
d2y g dy g
(3) 2
 (4)  x
dx S dx S

f0 = 2cm
y SZ
fe = 4 cm
  d
L = 40 cm

As per NCERT
SZ y
Sol. (2)
L0  D 
   m     125 cm
dx 40 25
x m
f0  fe  2  4 

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03. An electron (mass 9 × 10 –31 kg and charge 05. The kinetic energies of two similar cars A and B are
1.6 × 10–19C) moving with speed c/100 (c = speed 100 J and 225 J respectively. On applying breaks,
 car A stops after 1000 m and car B stops after
of light) is injected into a magnetic field B of
magnitude 9 × 10–4 T perpendicular to its direction 1500 m. If FA and FB are the forces applied by the
of motion. We wish to apply an uniform electric field breaks on cars A and B, respectively, then the ratio
 FA / FB is
E together with the magnetic field so that the electron
does not deflect from its path. Then (speed of light c (1) 3/2 (2) 2/3
= 3 × 108 ms–1)
  (3) 1/3 (4) 1/2
(1) E is perpendicular to B and its magnitude is Sol. (2) stopping Distance
27 × 102 V m–1
  0 2  V02  2 as
(2) E is perpendicular to B and its magnitude is
27 × 102 V m–1 v02  2 f / m s
 
(3) E is parallel to B and its magnitude is
27 × 102 V m–1 mv02
 fs  k  fs
  2
(4) E is parallel to B and its magnitude is
27 × 104 V m–1 f A K A S B 100 1500
   
e f B K B S A 225 1000
Sol. (2) ve   3  106 m/s
100 f A 2 10 2
 
euB  eE ( velocity sector ) f B 3 = 15 3
E  vB 06. The current passing through the battery in the given
E  3  10  9  10
6 4
E  27  10 V / m
2
circuit, is :
 
EB

perpendicular to B
04. There are two inclined surfaces of equal length (L)
and same angle of inclination 45° with the horizontal.
One of them is rough and the other is perfectly
smooth. A given body takes 2 times as much time to
slide down on rough surface than on the smooth
surface. The coefficient of kinetic friction (µk)
between the object and the rough surface is close to
(1) 0.25 (2) 0.40 (1) 2.0 A (2) 0.5 A
(3) 0.5 (4) 0.75 (3) 2.5 A (4) 1.5 A
Sol. (2) balanced wheat stone bridge
1 2
Sol. (4) S  0  at 6  should be neglected
2
Req of balanced wheat stone bridge
2S S
t2  8  4 32 8
a =  
8  4 12 3
2
1 t  a
t   s   R
2
8 1
a  tR  as net Req    7
3 3
2
 ts  g sin 45 0   kg cos 45 0 30
   =  10 
 2t s  g sin 45 0 3

1 1 3 V 5
 1   k  k  1   Current i    0.5
4 4 4 Req 10
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07. A bob of heavy mass m is suspended by a light string
of length l. The bob is given a horizontal velocity v0
as shown in figure. If the string gets slack at some
point P making an angle  from the horizontal, the
Sol. (4)
ratio of the speed v of the bob at point P to its initial
speed v0 is :

Y  ( A  B )( AB )

 ( A  B )( A  B )

= A  B = A  B so NOR

1/ 2 09. The electric field in a plane electromagnetic wave is

 1  given by
(1) (sin )1/2 (2)  
 2  3sin  
1/ 2 1/ 2 E z  60 cos(5 x  1.5  109 t )V / m
 cos    sin  
(3)   (4)  
 2  3sin    2  3sin   Then expression for the corresponding magnetic field
Sol. (4) at point P is (here subscripts denote the direction of the field) :
Tension should be zero
2
(1) By  2  107 cos(5 x  1.5 109 t )T
mv
mg sin  
R
(2) Bx  2  107 cos(5 x  1.5  109 t )T
v 2  gR sin  .... (i)
From energy conservation (3) Bz  60 cos(5 x  1.5  109 t )T
1 2 1 2
mv0  mv  mgR (1  sin )
2 2 (4) By  60sin(5 x  1.5  109 t )T

v02  v 2  2 gR (1  sin )
Sol. (1) E = BC
v02  gR sin   2 gR  2 gR sin 
E 60 20
B   8  20  108
v2
sin  C 3  10 10
8

v02  2 gR  3 gR sin  .... (ii) 

v0 2  3sin 
2

= 2 × 10–7
  
1/ 2
v  sin  
  EH  n
v0  2  3sin  

08. The output (Y) of the given logic implementation is  kˆ  B  iˆ
similar to the output of an/a ______ gate.
So By  2 107 x cos(5 x  1.5  109 )

10. A ball of mass 0.5 kg is dropped from a height of

40 m. The ball hits the ground and rises to a height
of 10m. The impulse imparted to the ball during its
collision with the ground is (Take g = 9.8 m/s2)

(1) AND (2) NAND (1) 21 NS (2) 7 NS

(3) OR (4) NOR (3) 0 (4) 84 NS

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Sol. (1) Velocity just before hitting 13. In a certain camera, a combination of four similar
thin convex lenses are arranged axially in contact.
V1  2 gh1  2  9.8  40 Then the power of the combination and the total
magnification in comparison to the power (p) and
= 28 m/s magnification (m) for each lens be, respectively
Velocity just after hitting (1) 4p and 4m (2) p4 and 4m
(3) 4p and m4 (4) p4 and m4
V2  2 gh2

= 2  9.8  10  14 m/s  Sol. (3)

Impulse = P2 - (-P1)
Peq  P  P  P  P  4 P
= P1  P2
meq  m1  m2  m3  m4  m  m  m  m  m4
= mv1  mv2
14. An oxygen cylinder of volume 30 litre has 18.20
= m(v1  v2 ) moles of oxygen. After some oxygen is withdrawn
from the cylinder, its gauge pressure drops to
= 0.5  42 = 21 N-s 11 atmospheric pressure at temperature 27° C. The
11. AB is a part of an electrical circuit (see figure). The mass of the oxygen withdrawn from the cylinder is
potential difference ‘VA – VB”, at the instant when nearly equal to :
current i = 2A and is increasing at a rate of 1 amp 100
second is : [Given, R = J mol 1 K 1 , and molecular mass
12
of O2 = 32, 1 atm pressure = 1.01 × 105 N/m]
(1) 0.125 kg (2) 0.144 kg
(3) 0.116 kg (4) 0.156 kg
(1) 5 volt (2) 6 volt
niRT 18.2 RT nfRT
(3) 9 volt (4) 10 volt Sol. (3) Pi   , Pf 
V V V
Sol. (4)
18.2 RT
VA  VB Pi 18.2
 V 
Pf nfRT nf
di V
L  5  iR
dt
Pi  n f
 (1 1)  (5)  (2  2) Pf 
18.2
= 10 V As gauge press is given 11atm  Pgas = 12 atm
12. A 2 amp current is flowing through two different small
18.2 RTnf
circular copper coils having radii ratio 1 : 2. The ratio 12 1.01105 
of their respective magnetic moments will be V  18.2

(1) 1 : 4 12.2  30 103  105

 nf   14.54
(2) 1 : 2 100
 300
12
(3) 2 : 1
So no. of moles escape =
(4) 4 : 1
ni  n f  18.2  14.54  3.66
M1 2  r 2 1 So mass escape
Sol. (1)  
M 2 2  (2r ) 2
4
= n  M = 3.66 × 32 × 10–3 = 0.117 kg
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15. In some appropriate units, time (t) and position (x) Sol. (4)
relation of a moving particle is given by t = x2 + x.
As Z net = 0
The acceleration of the particle is
Angular momentum is conserved
2 2
(1)  (2) 
( x  2)3 (2 x  1)3 I i i  I f  f

2 2 2 2 2 2
(3)  (4)  MR 2  M (2 R )2
( x  1)3 2x 1 5 27 5 T

Sol. (2) t  x 2  x  T  108days.

vdV 18. A model for quantized motion of an electron in a

We know a = uniform magnetic field B states that the flux passing
dx
through the orbit of the electron is n (h/e) where n is
dt 1 1 an integer, h is Planck’s constant and e is the
So   2x  1  V  magnitude of electron’s charge. According to the
dx V 2x 1
model, the magnetic moment of an electron in its
dv 2 lowest energy state will be (m is the mass of the
Again  electron)
dx (2 x  1) 2
he
1 2 2 (1)
So a    m
(2 x  1) (2 x  1) 2
(2 x  1)3
he
(2)
2m
16. To an ac power supply of 220 V at 50 Hz, a resistor
of 20  , a capacitor of reactance 25 and an heB
inductor of reactance 45 are connected in series. (3)
m
The corresponding current in the circuit and the phase
angle between the current and the voltage is, heB
respectively - (4)
2m
(1) 7.8 A and 30° (2) 7.8 A and 45° Sol. (2)
(3) 15.6 and 30° (4) 15.6 A and 45°
Flux through the orbit,
20 25 45
h h
Br 2   Br 2 
Sol. (2) e e
XL = 25 
 mv
radius of orbit r 
eB
X L  XC 0

tan    1    45 45
R R = 20  mv  reB

220 220 L  mvr  eBr 2
i   7.8A. XC = 25
Z 20 2
eh h
 
17. The Sun rotates around its centre once in 27 days. e 
What will be the period of revolution if the Sun were

to expand to twice its present radius without any M e
external influence ? Assume the Sun to be a sphere Gyromagnetic ratio   
L 2 m
of uniform density.
(1) 100 days (2) 105 days eh
M .
2m
(3) 115 days (4) 108 days
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19. Three identical heat conducting rods are connected 20. The plates of a parallel plate capacitor are separated
in series as shown in the figure. The rods on the sides by d. Two slabs of different dielectric constant K1
have thermal conductivity 2K while that in the middle 3 d
has thermal conductivity K. The left end of the and K2 with thickness d and , respectively are
8 2
combination is maintained at temperature 3T and the
inserted in the capacitor. Due to this, the capacitance
right end at T. The rods are thermally insulated from
becomes two times larger than when there is nothing
outside. In steady state, temperature at the left
between the plates.
junction is T1 and that at the right junction is T2. The
ratio T1 / T2 is If K1 = 1.25 K2, the value of K1 is :
(1) 2.66
(2) 2.33
(3) 1.60
(4) 1.33
Sol. (1)
3 4
(1) (2)
2 3 0 A
Given C 
d
5 5
(3) (4) 20 A
3 4
Ceq  2C   Ceq 
d

Sol. (3) K1  1.25 K 2

K1 4
K2   K 2  5 K1
1.25
2T
i
2R
K1 K2 K=1
2T R
3T  T1  
2R 2
3d d d
8 2 8
T
T1  3T 
2
1 1 1 1
  
5T Ceq C1 C2 C3
T1  .......(1)
2
1 1 1 1
2T R   
T2  T   20 A K10 A K 2 0 A 0 A
2R 2 d 3 d d
d
8 2 8
T
T2  T 
2
1 3 1 1
 2  8K  2 K  8
1 2
3T
T2  .......(2)
2
1 3 5 1
 2  8K  2  4 K  8
1 1
5
T1 2 T T 5
  1  .
T2 3 T2 3 1 1 3 5 1
T   
2 2 8  8 8  K1  K1  2.66.

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21. Two cities X and Y are connected by a regular bus N2
service with a bus leaving in either direction every T
min. A girl is driving scooty with a speed of 60 km/h Sol. (2)
600
in the direction X to Y notices that a bus goes past
her every 30 minutes in the direction of her motion, N1  mg
and every 10 minutes in the opposite direction. N1
mg
Choose the correct option for the period T of the N 2  fr
bus service and the speed (assumed constant) of the
buses. Torque about 'O' = 0 O fr

(1) 9 min, 40 km/h 5

mg  cos 30  fr  5 cos 60
2
(2) 25 min, 100 km/h

(3) 10 min, 90 km/h 5 3 1

 20  10   fr  5 
2 2 2
(4) 15 min, 120 km/h
 fr  100 3 N .
Sol. (4)
23. In an oscillating spring mass system, a spring is
30 10 connected to a box filled with sand. As the box
(Vb  Vg )  (Vb  Vg )
60 60 oscillates, sand leaks slowly out of the box vertically
so that the average frequency (t ) and average
1 1 amplitude A(t) of the system change with time t.
 (Vb  60)  (Vb  60)
2 6 Which one of the following options schematically
depicts these changes correctly ?
1
 (Vb  60)  (Vb  60)
3

 3Vb  180  Vb  60
(1)
 2Vb  240

Vb  120km/h

1
D  (120  60)  30km
2
(2)
30 1 1
T  hr   60  15min .
120 4 4
22. A uniform rod of mass 20 kg and length 5m leans
against a smooth vertical wall making an angle of
60° with it. The other end rests on a rough horizontal
floor. The friction force that the floor exerts on the
rod is (3)
(take g = 10 m/s2)
(1) 100 N

(2) 100 3N

(3) 200 N
(4)
(4) 200 3N

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Sol. (2) 25. Consider the diameter of a spherical object being
measured with the help of a Vernier callipers.
m Suppose its 10 Vernier Scale Divisions (VSD) are
T  2 equal to its 9 Main Scale Divisions (MSD). The least
K
division in the M.S. is 0.1 cm and the zero of V.S. is
at x = 0.1 cm when the jaws of Vernier callipers are
m T  closed.
decreases decreases

If the main scale reading for the diameter is M = 5

1 cm and the number of coinciding vernier division is
Here E  KA2
2 8, the measured diameter after zero error correction,
is
E  A (1) 5.18 cm (2) 5.08 cm
decreases decreases
(3) 4.98 cm (4) 5.00 cm
24. A balloon is made of a material of surface tension S
Sol. (3)
and its inflation outlet (from where gas is filled in it)
has small area A. It is filled with a gas of density  9 MSD = 10 VSD
and takes a spherical shape of radius R. When the
9
gas is allowed to flow freely out of it, its radius r  0.1  VSD
changes from R to 0 (zero) in time T. If the speed 10
v(r) of gas coming out of the balloon depends on r VSD = 0.09
as r a and T  S  A R  then LC = 1MSD – 1VSD
= 0.1 – 0.09 = 0.01 cm.
1 1 3
(1) a  ,   ,   1,   1,   Corrected reading = [MSR + VSR] – Zero error
2 2 2
= [5 + 8 × 0.01] – 0.1
1 1 1 5 = 5.08 – 0.1 = 4.98 cm.
(2) a   ,    ,   1,    ,  
2 2 2 2 26. A parallel plate capacitor made of circular plates is
being charged such that the surface charge density
1 1 1 7 on its plates is increasing at a constant rate with time.
(3) a   ,   ,   1,   ,  
2 2 2 2 The magnetic field arising due to displacement current
is :
1 1 1 1 7 (1) zero at all places
(4) a  ,   ,    ,   ,  
2 2 2 2 2
(2) constant between the plates and zero outside the
Sol. (3) plates
(3) non-zero everywhere with maximum at the
   
T S A  R imaginary cylindrical surface connecting peripheries
of the plates
[T 1 ]  [ M 1T 2 ] [ L2 ] [ M 1L3 ] [ L ] (4) zero between the plates and non-zero outside.
Sol. (3)
T 1  M T 2  L2 M  L3 L
Id
on comparison

 0

1 1
2  1    and  
2 2
Displacement current (Id) between the plate of
Only 3rd option satisfies this condition. capacitor

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d E d Sol. (4)
I d  0 A q
dt dt q
A B
r
I d
Jd  d   constant
A dt kq 2
 F ..........(i)
Hence, when we apply Ampere circulated law r2
When identical sphere (C) touched with A charges
For inside B  r
on

1 A 
q / 2
and for outside B 
r
C 
q / 2
27. An unpolarized light beam travelling in air is incident
on a medium of refractive index 1.73 at Brewster’s again when (C) touched with (B), charges on
angle. Then - C 
 3q / 4
(1) reflected light is completely polarized and the angle
of reflection is close to 60° B 
 3q / 4

(2) reflected light is partially polarized and the angle then, New force between A and B
of reflection is close to 30°
(3) both reflected and transmitted light are perfectly
polarized with angles of reflection and refraction close
to 60° and 30°, respectively.
3 kq 2 3
1
(4) transmitted light is completely polarized with angle F   F.
8 r2 8
of refraction close to 30°.
29. A container has two chambers of volumes V1 = 2
Sol. (1)
litres and V2 = 3 litres separated by a partition made
Using Brewster’s law - of a thermal insulator. The chambers contains n1 = 5
and n2 = 4 moles of ideal gas at pressures p1 = 1atm
tan i   and p2 = 2atm, respectively. When the partition is
removed, the mixture attains an equilibrium pressure
tan i  1.73 and Reflected ray completely polarized.
of :
tan i  3 (1) 1.3 atm (2) 1.6 atm
(3) 1. 4 atm (4) 1.8 atm
 i  60.
Sol. (2)
28. Two identical charged conducting spheres A and B
Initial Final
have their centres separated by a certain distance.
Charge on each sphere is q and the force of repulsion
between them is F. A third identical uncharged P1V1 P2V 2 P1(V 1 + V2)
n1 n2 (n 1 + n2 ) = n
conducting sphere is brought in contact with sphere
A first and then with B and finally removed from both.
New force of repulsion between spheres A and B n1  n2  n
(Radii of A and B are negligible compared to the
distance of separation so that for calculating force PV PV P (V1  V2 )
 1 1
 2 2 
between them they can be considered as point RT RT RT
charges) is best given as :
 PV
1 1  P2V2  P (V1  V2 )
3F 2F
(1) (2)  1 2  2  3  P (5)
5 3

F 3F 8
 P  P  1.6atm.
(3) (4) 5
2 8
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30. A particle of mass m is moving around the origin 32. A body weighs 48 N on the surface of the earth.
with a constant force F pulling it towards the origin. The gravitational force experienced by the body due
If Bohr model is used to describe its motion, the to the earth at a height equal to one-third the radius
radius r of the nth orbit and the particle’s speed v in of the earth from its surface is:
the orbit depend on n as (1) 16 N (2) 27 N
(1) r  n 1/3 1/3
,v  n (3) 32 N (4) 36 N

(2) r  n1/3 , v  n 2/3 gh R2

Sol. (2) 
g  R  4 2
(3) r  n 2/3 , v  n1/3

(4) r  n 4/3 , v  n 1/3 F R2 R2

 
F  R  R / 32  4 / 32 R 2
y
48  9
Fn 
16
= 27
Sol. (3) x
F = const 33. A wire of resistance R is cut into 8 equal pieces.
From these pieces two equivalent resistances are
made by adding four of these together in parallel.
According to Bohr’s theory : Then these two sets are added in series. The net
effective resistance of the combination is:
Using 1st postulate
R R
mv 2 (1) (2)
F 64 32
......(1)
r
R R
and using 2nd postulate (3) (4)
16 8
nh Sol. (3) V  R / 8
mvr  ......(2)
2
R
After solving equation (1) and (2) we get RP  
4 32
rn 2/3 and vn . 1/3
R
31. The radius of Martian orbit around the Sun is about Rs  2 RP 
16
4 time the radius of the orbit of Mercury. The Martian
year is 687 Earth days. Then which of the following 34. De-Broglie wavelength of an electron orbiting in the
is the length of 1 year on Mercury? n = 2 state of hydrogen atom is close to (Given Bohr
radius = 0.052 nm)
(1) 88 earth days (2) 225 earth days
(1) 0.067 nm (2) 0.67 nm
(3) 172 earth days (4) 124 earth days
Sol. (1) T 2  R 3 (3) 1.67 nm (4) 2.67 nm
4
2
Tmercury 3
Rmercury Sol. (2) MVR2  n
 3 2
2
Tmercury Rmercury
4
P  R2  2
T 2 3 2
   1
mercury
   64
 687 
2
 4 R  4 4
r
 R0  4  

687 687
Tmercury   r  4R0
64 8
88 earth days r  0.67 nm

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35. An electric dipole with dipole moment 5 × 10–6 Cm 37. A photon and an electron (mass m) have the same
energy E. The ratio   photn / electron  of their de
is aligned with the direction of a uniform electric field
of magnitude 4 × 105 N/C. The dipole is then rotated
through an angle of 60o with respect to the electric Broglie wavelengths is:
field. The change in the potential energy of the dipole ( c is the speed of light)
is:
(1) 0.8 J (2) 1.0 J (1) E (2) c 2mE
2m
(3) 1.2 J (4) 1.5 J
2m 1 E
Sol. (2) P P  cos  (3) c (4) 2m
E c
1
 5 106  4  105   photon electron 2me E
2 Sol. (3)  
 electron photon E
 10 6 106 c
 
=1J
2me E 2me
36. A constant voltage of 50 V is maintained between c c
the points A and B of the circuit shown in the figure. E E
The current through the branch CD of the circuit is: 38. Which of the following options represent the variation
of photoelectric current with property of light shown
on the x-axis?

(1) 1.5 A (2) 2.0 A

(3) 2.5 A (4) 3.0 A

25
Sol. (2)  = Req
12

25
R eq Now v = IReq
12

 I  24 A
V = 50
I = 24
Current Division
Current in

3
(1 )  24 ×  18
4

 3    6A
4
(2 )  24   16 A
6

 4   8A (1) A only (2) A and C

 2A (3) A and D (4) B and D

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1  7
Sol. (1) Current  MR 2 8  
5  8

57
 MR 2
5

2M 2 M 2
I2 = R  R
5 5 8
Intensity

Current is directly proportional to Intensity. 7

= M /8 R 2
5
39. A sphere of radius R is cut from a larger solid sphere
of radius 2R as shown in the figure. The ratio of the
moment of inertia of the smaller sphere to that of the 7M 2
I2 R 7
rest part of the sphere about the Y-axis is: 5 8 
I1 57 M 2 57
R
5 8

40. A full wave rectifier circuit with diodes (D1) and (D2)
is shown in the figure. If input supply voltage
Vin  220sin(100t ) volt, then at t = 15 msec

7 7
(1) (2)
8 40
7 7
(3) (4)
57 64

y
Sol. (3)
Initial

(1) D1 is forward biased, D2 is reverse biased

(2) D1 is reverse biased, D2 is forward biased

(3) D1 and D2 both are forward biased

y’ (4) D1 and D2 both are reverse biased

15
y Sol. (2) VIn  220  sin  
With cut 1000

 3 
 220  sin  
x x’  2 

= – Ve (Value)

y’  D2 will be F  B

2 7M 2 D1 will be R  B
M  2R  
2
I R
5 5 8

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41. Two gases A and B are filled at the same pressure in 42. A physical quantity P is related to four observations
separate cylinders with movable pistons of radius rA a, b, c and d as follows:
and rB, respectively. On supplying an equal amount
P  a 3b 2 /c d
of heat to both the systems reversibly under constant
pressure, the pistons of gas A and B are displaced The percentage errors of measurement in a, b, c and
by 16 cm and 9 cm, respectively. If the change in d are 1%, 3%, 2%, and 4% respectively. The
percentage error in the quantity P is
rA
their internal energy is the same, then the ratio rB (1) 10% (2) 2%
is equal to (3) 13% (4) 15%
a 3b 2
4 Sol. (3) P 
(1) c d
3
 p   a   b   c  1 d 
3  p 100    3 a    2 b    c   2 d 100
(2)         
4
1 
2   3  1   2  3  2    4 
(3) 2 
3
=3+6+2+2
3 = 13%
(4)
2 43. The intensity of transmitted light when a polaroid
sheet, placed between two crossed polaroids at 22.5o
Sol. (2) rA rB from the polarization axis of one of the polaroid, is
(I0 is the intensity of polarise light after passing
 
through the first polaroid):
I0 I0
(1) (2)
2 4
I0 I0
(3) (4)
8 16
PA  P  PB  P
Sol. (3) I0
QA  Q  QB  Q
I1
X A  16cm & X B  9cm 22.50

UA  U & UB  U I2

rA
?  Q  U  W
rB

Q  same, U = same
I1  I 0 cos 2 
 WA  WB I 2  I1 sin 2 
PA VA  PB VB  AA X A  AB X B I 2  I 0 cos 2  sin 2 

rA2 (16)  rB2 (9) I0

I2 
4
 cos 2  sin 2   4
2
 rA  9
 r   16 
I0
sin 2 2 
I0
 sin 2  2  22.5 
 B 4 4

rA 3 I0 2 I0 1 I
  sin  45o     0
rB 4 4 4 2 8
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44. Two identical point masses P and Q, suspended from
Sol. (2)
two separate massless springs of spring constants
k1 and k2, respectively, oscillate vertically. If their
maximum speeds are the same, the ratio (AQ/AP) of
L1 = L
the amplitude AQ of mass Q to the amplitude AP of
mass P is:

k2
(1) k
1
Open end

k1
(2) k
2
Closed end
L2 = L/2

k2
(3) k1

k1
(4) pipe open at both end
k2
V V
n f 
Sol. (4) M P  M Q 2 L1  2L

 Vmax  P  Vmax  Q V
 V 2f  n  4L
L 2

wkt, Vmax = Vmean = A

V V 2f
n2   n 
2L 2
4  
AP P  AQ Q L
2
AQ P n=f

AP Q

k
wkt, w    k
m

AQ KP AQ k1
  A  k
AP KQ P 2

45. A pipe open at both ends had a fundamental

frequency f in air. The pipe is now dipped vertically
in a water drum to half of its length. The fundamental
frequency of the air column is now equal to:

f
(1)
2

(2) f

3f
(3)
2

(4) 2 f
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Chemistry 48. Match List I with List II

46. Tthe ratio of the wavelengths of the light absorbed List-I List-II
by a Hydrogen atom when it undergoes n = 2  n = (Ion) (Group Number in
3 and n = 4  n = 6 transitions, respectively, is Cation Analysis)
A. Co2+ I. Group-I
1 1 B. Mg2+ II. Group-III
(1) (2)
36 16 C. Pb2+ III. Group-IV
D. Al3+ IV. Group-VI
1 1
(3) (4)
9 4
Choose the correct answer from the options given
Sol. (4) below :
n 02 ×n i2 (1) A-III, B-IV, C-II, D-I
λ n 0 n 
i R H z 2 (n 02  n i2 ) (2) A-III, B-IV, C-I, D-II
To find (3) A-III, B-II, C-IV, D-I
λ2  3 (4) A-III, B-II, C-II, D-IV
?
λ4  6
Sol. (2)
λ2  3 4  9 20 1
   The correct match are A-III, B-IV, C-I, D-II
λ4  6 5 16  36 4
Co2+  Group-IV Mg2+  Group-VI
47. Which of the following statements are true ?
Pb2+  Group-I Al3+  Group-III
A. Unlike Ga that has a very high melting point, Cs
has a very low melting point. 49. Predict the major product ‘P’ in the following
B. On Pauling scale, the electronegativity values of sequence of reactions -
N and Cl are not the same.
(i) HBr, benzoyl peroxide
CH 3 (ii) KCN
C. Ar, K+, Cl–, Ca2+, and S2– are all isoelectronic
P
species. (iii) Na(Hg)/C2H 5OH (Major)

D. The correct order of the first ionization enthalpies

of Na, Mg, Al, and Si is Si > Al > Mg > Na. CH 3 CH 3
(1) (2) CH2NH 2
E. The atomic radius of Cs is greater than that of Li CH 2NH 2
and Rb.
Choose the correct answer from the options given CH 3
NC
below : (3) (4) CH3

(1) A, B and E only (2) C and E only NC

(3) C and D only (4) A, C and E only Sol. (1)

Sol. (2)
CH 3 (i) HBr CH3
The correct statement are only C and E.
benzoylperoxide
Ga and Cs both have low m.p. Br

Both have (N and Cl) same EN around 3.0 KCN

Ar, K , Cl , Ca , S all have 18 e s.
+ – 2+ 2– –
CH 3 CH 3
Na, Hg
The correct order ois Si > Mg > Al > Na
C 2H5OH
Atomic radius are Cs > Rb > Li CH 2 NH 2 C N

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50. Energy and radius of first Bohr orbit of He+ and Li2+ 51. Which of the following are paramagnetic ?
are A. [NiCl4]2– B. Ni(CO)4
[Given RH = 2.18 × 10–18 J, a0 = 52.9 pm] C. [Ni(CN)4]2– D. [Ni(H2O)6]2+
(1) En(Li2+) = – 19.62 × 10–18 J; E. Ni(PPh3)4

rn(Li2+) = 17.6 pm Choose the correct answer from the options given
below:
En(He+) = – 8.72 × 10–18 J;
(1) A and C only (2) B and E only
rn(He ) = 26.4 pm
+
(3) A and D only (4) A, D and E only
(2) En(Li2+) = – 8.72 × 10–18 J; Sol. (3)
rn(Li2+) = 26.4 pm [NiCl4]2– and [Ni(H2O)6]2+ shows paramagnetism
En(He+) = – 19.62 × 10–18 J; due to presence of unpaired electrons.
52. Given below are two statements :
rn(He+) = 17.6 pm
Statement - I : Like nitrogen that can form
(3) En(Li2+) = – 19.62 × 10–16 J; ammonia, arsenic can form arsine.
rn(Li2+) = 17.6 pm Statement - II : Antimonay cannot form antimony
pentoxide.
En(He+) = – 8.72 × 10–16 J;
In the light of the above statements, choose the most
rn(He+) = 26.4 pm appropriate answer from the options given below :
(4) En(Li2+) = – 8.72 × 10–16 J; (1) Both Statement I and Statement II are correct
(2) Both Statement I and Statement II are incorrect
rn(Li2+) = 17.6 pm (3) Statement I is correct but Statement II is incorrect
En(He+) = – 19.62 × 10–16 J; (4) Statement I is incorrect but Statement II is correct
rn(He+) = 17.6 pm Sol. (3)
Sol. (1) Nitrogen forms NH3 while As form AsH3 (statement
I is correct). Antimony conform Sb2O5.
z2
En = – 2.18 × 10 –18
× 2J (Statement II is incorrect)
n
53. Which among the following electronic configurations
9 belong to main group elements ?
(E1 ) Li2+  2.18  10 18 
1 A. [Ne]3s1 B. [Ar]3d3 4s2
= – 19.62 × 10–18 J C. [Kr]4d105s25p5 D. [Ar]3d104s1
4 E. [Rn]5f06d27s2
(E1 ) He+  2.18  10 18 
1 Choose the correct answer from the option given
= – 8.72 × 10 –18
J below :
(1) B and E only (2) A and C only
a 0 n 2 52.9 n 2
rn   pm (3) D and E only (4) A, C and D only
z z
Sol. (2)
52.9 12
(r1 )Li2+  = 17.63 pm (A) [Ne]3s1  Na  s-block
3
(B) [Ar]3d3 4s2  Tii  d-block
52.9  1 2
(C) [Kr]4d105s25p5  I  p-block
(r1 ) He+ 
2
(D) [Ar]3d 4s10 1
 Cu  d-block
= 26.45 pm (E) [Rn]5f06d27s2  Th  d-block

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54. Dalton’s Atomic theory could not explain which of 56. If the half-life (t1/2) for a first order reaction is 1 minute,
the following ? then the time required for 99.9% completion of the
reaction is closest to :
(1) Law of conservation of mass
(1) 2 minutes
(2) Law of constant proportion
(2) 4 minutes
(3) Law of multiple proportion (3) 5 minutes
(4) Law of gaseous volume (4) 10 minutes
Sol. (4)
Sol. (4)
T99.9% = 10T50%
Dalton’s atomic could not explain law of gaseous
T99.9% = 10 × 1 min
volume.
T99.9% = 10 min
55. Consider the following compounds :
57. The correct order of the wavelength of light absorbed
KO 2 , H 2 O 2 and H 2 SO 4 . by the following complexes is,
A. [Co(NH3)6]3+ B. [Co(CN)6]3–
The oxidation state of the underlined elements in them
are, respectively, C. [Cu(H2O)4]2+ D. [Ti(H2O)6]3+
(1) +1, –1, and +6 Choose the correct answer from the options given
below :
(2) +2, –2, and +6
(1) B < D < A < C
(3) +1, –2, and +4
(2) B < A < D < C
(4) +4, –4, and +6
(3) C < D < A < B
Sol. (1) (4) C < A < D < B
KO2 Sol. (2)
Weak field ligand absorption is more
 1 
x +    2  0 58. Which one of the following compounds can exist as
 2 
cis-trans isomers ?
x–1=0 (1) Pent-1-ene
x = +1 (2) 2-Methylhex-2-ene

H2 O2 (3) 1,1-Dimethylcyclopropane
(4) 1,2-Dimethylcyclohexane
+1 × 2 + x × 2 = 0
Sol. (4)
2 + 2x = 0
2x = –2 CH 3

x = –1 CH 3

H 2 SO 4 Trans
Cis
CH 3 CH 3
+1 × 2 + x + (–2 ×4) = 0
2+x–8=0 CH 3 CH3
(or)
CH 3
x–6=0

x = +6 CH 3

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59. Phosphoric acid ionizes in three steps with their 61. If the molar conductivity ( m ) of a 0.050 mol L–1
ionization constant values solution of a monobasic weak acid is 90 S cm2 mol–
K a , K a and K a , respectively,,
1
, its extent (degree) of dissociation will be
1 2 3
while K is the overall ionization constant. [Assume  o  349.6 S cm2 mol–1 and
Which of the following statements are true?
 o  50.4 S cm2 mol–1.]
A. log K = log K a1  log K a 2 +log K a3
(1) 0.115 (2) 0.125
B. H3PO4 is a stronger acid than H2PO4– and HPO42–
(3) 0.225 (4) 0.215
C. K a1  K a 2 > K a3
Sol. (3)
Ka  Ka
D. K a  3 2 C = 0.05 M
1 2
Choose the correct answer from the options given m  90S cm2 mol1
below :
(1) A and B only (2) A and C only  m  349.6  50.4
(3) B, C and D only (4) A, B and C only
 400Scm 2 mol1
Sol. (4)
H3PO4  H+ + H2PO4– ; K a1 m 80
 
  0.225
 m 400
H2PO4–  H+ + HPO4–2; Ka2
62. Given below are two statements:
HPO4–2  H+ + PO4–3 ; K a3
H3PO4  3H+ + PO4–3 Koverall Statement I : A hypothetical diatomic molecule
with bond order zero is quite stable.
Koverall = K a1 × K a2 × K a3
Statement II : As bond order increases, the bond
 log k = log K a1 + log K a2 + log Ka3 length increases.
 K a1 > K a2 > K a3 . In the light of the above statements, choose the most
appropriate answer from the options given below:
60. Which one of the following reactions does NOT give
benzene as the product ? (1) Both Statement I and Statement II are true
O (2) Both Statement I and Statement II are false
sodalime
(1) C O Na (3) Statement I is true but Statement II is false


Mo 2O 3 (4) Statement I is false but Statement II is true

(2) 773K, 10-20 atm
n-hexane
Sol. (2)
red hot Iron Tube
(3) H C C H
at 873 K If bond order is zero, molecule is unstable if bond
order increases, bond length decreases both
H2O
(4) N N
warm statements  incorrect.
Cl
Sol. (4) 63. Out of the following complex compounds, which of
H2O the compound will be having the minimum
N2Cl OH
warm conductance in solution ?
O
Soda
+ Na2CO 3
(1) [Co(NH3)3Cl3] (2) [Co(NH3)4Cl2]
(1) C ONa
Lime
 (3) [Co(NH3)6]Cl3 (4) [Co(NH3)5Cl]Cl
Mo 2O3
(2) Sol. (4)
n-hexane 773K

red hot
More number of ions, more conductivity. Lesser
(3) H C C H
Iron number of ions, lesser conductivity.
3 mole

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64. Match List-I with List-II 65. C(s) + 2H2(g)  CH4(g); H  74.8 kJ mol–1
Which of the following diagrams given an accurate
List - I List - II representation of the above reaction?
[R  reactants; P  products]
A. XeO3 I. sp3d; linear

B. XeF2 II. sp3; pyramidal

C. XeOF4 III. sp3d3; distorted (1)

octahedral

D. XeF6 IV. sp3d2; square

pyramidal (2)

Choose the correct answer from the options given

below:

(1) A-II, B-I, C-IV, D-III

(3)
(2) A-II, B-I, C-III, D-IV

(3) A-IV, B-II, C-III, D-I

(4) A-IV, B-II, C-I, D-III

Sol. (1) (4)

bp  3 
lp  1  Sol. (1)
 XeO3 pyramidal
ep  4 (sp 3 )  H r  H p  H r


H r  74.8 for 1st option.
Hp < Hr.
bp  2  66. Match List - I with List - II
lp  3 
 XeF2  linear List - I List - II
ep  5(sp3d) 
 (Example) (Type of Solution)

A. Humidity I. Solid in solid
B. Alloys II. Liquid in gas
bp  5  C. Amalgams III. Solid in gas
 lp  1  D. Smoke IV. Liquid in solid
 XeOF4 square pyramidal
ep  6 (sp3d 2 )  Choose the correct answer from the options given
 below:

(1) A-II, B-IV, C-I, D-III
(2) A-II, B-I, C-IV, D-III
bp  6  (3) A-III, B-I, C-IV, D-II
lp  1 
 XeF6  Distorted octahedral (4) A-III, B-II, C-I, D-IV
ep  7 (sp3d 3 )  Sol. (2)

 A-II, B-I, C-IV, D-III

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67. The correct order of decreasing basic strength of 69. Match List I with List II.
the given amines is :
List - I List - II
(1) N-methylaniline > benzenamine >
ethanamine > N-ethylethanamine (Name of Vitamin) (Deficiency disease)
(2) N-ethylethanamine > ethanamine >
A. Vitamin B12 I. Cheilosis
benzenamine > N-methylaniline
(3) N-ethylethanamine > ethanamine > B. Vitamin D II. Convulsions

N-methylaniline > benzenamine C. Vitamin B2 III. Rickets

(4) benzenamine > ethanamine > D. Vitamin B6 IV. Pernicious anaemia
N-methylaniline > N-ethylethanamine
Choose the correct answer from the options given
Sol. (3) below:
CH3  CH 2  NH  CH 2  CH  CH 3  CH 2  NH 2
2o 3 1o (1) A-I, B-III, C-II, D-IV

NH–CH3 NH2 (2) A-IV, B-III, C-I, D-II

> >
(3) A-II, B-III, C-I, D-IV

Aliphatic amins are more basic than aromatic amines (4) A-IV, B-III, C-II, D-I
and in aliphatic amines 2o amines are greater than 1o
- amines. Sol. (2)

68. Among the following, choose the ones with equal A-IV, B-III, C-I, D-II
number of atoms.
(Name of Vitamin) (Deficiency disease)
A. 212 g of Na2CO3(s) [molar mass =106 g]
B. 248 g of Na2O (s) [molar mass = 62 g] A. Vitamin B12 IV. Pernicious anaemia
C. 240 g of NaOH (s) [molar mass = 40 g] B. Vitamin D III. Rickets
D. 12 g of H2 (g) [molar mass = 2 g]
C. Vitamin B2 I. Cheilosis
E. 220 g of CO2(g) [molar mass = 44 g]
Choose the correct answer from the options given D. Vitamin B6 II. Convulsions
below:
70. The correct order of decreasing acidity of the
(1) A, B and C only (2) A, B, and D only following aliphatic acids is:
(3) B, C, and D only (4) B, D and E only
(1) (CH3)3CCOOH > (CH3)2CHCOOH >
Sol. (2)
CH3COOH > HCOOH
No. of atoms = Atomicity × n × NA
(2) CH3COOH > (CH3)2CHCOOH >
212
(A) N atoms   6 N A  12 N A
106 (CH3)3CCOOH > HCOOH

248 (3) HCOOH > CH3COOH >

(B) N atoms   3 N A  12 N A
62
(CH3)2CHCOOH > (CH3)3CCOOH
240
(C) N atoms   3 N A  18 N A (4) HCOOH > (CH3)3CCOOH >
40
(CH3)2CHCOOH > CH3COOH
12
(D) N atoms   2 N A  12 N A Sol. (3)
2

220 1
(E) N atoms   3 N A  15 N A Acidic strength 
44  I  effect
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71. Given below are two statements: 73. For the reaction A(g)  2B(g), the backward
Statement - I : Ferromagnetism is considered as reaction rate constant is higher than the
an extreme form of paramagnetism. forward reaction rate constant by a factor of 2500,
at 1000 K.
Statement - II : The number of unpaired electrons
in a Cr2+ ion (Z = 24) is the same as that of a Nd3+ [Given : R = 0.0831 L atm mol–1 K–1]
ion (Z = 60). KP for the reaction at 1000 K is
In the light of the above statements, choose the (1) 83.1 (2) 2.077 × 105
correct answer from the options given below: (3) 0.033 (4) 0.0211
(1) Both Statement I and Statement II are true Sol. (3)
(2) Both Statement I and Statement II are false
Kf
(3) Statement I is true but Statement II is false KC 
Kb
(4) Statement I is false but Statement II is true
Sol. (3) 1
KC 
 Statement I is True 2500
 Statement II is False  ng
K p  K c (RT) (  ng  1)
Cr = [Ar]3d (n = 4)
2+ 4
1
Nd3+ = [Xe] 4f3 (n = 3). Kp  (0.0821 1000)
2500
72. Match List I with List II
82.1
Kp   0.033.
List - I List - II 2500
(Mixture) (Method of Separation) 74. Given below are two statements:
A. CHCl3 + C6H5NH2 I. Distillation under Statement - I : Benzenediazonium salt is prepared
reduced pressure by the reaction of aniline with nitrous acid at
273 - 278 K. It decomposes easily in the dry state.
B. Crude oil in II. Steam distillation
petroleum industry Statement - II : Insertion of iodine into the benzene
ring is difficult and hence iodobenzene is prepared
C. Glycerol from III. Fractional distillation
through the reaction of benzenediazonium salt with
spent-lye KI.
D. Aniline - water IV. Simple distillation In the light of the above statements, choose the most
Choose the correct answer from the options given appropriate answer from the options given below:
below: (1) Both Statement I and Statement II are correct
(1) A-IV, B-III, C-I, D-II (2) Both Statement I and Statement II are incorrect
(2) A-IV, B-III, C-II, D-I (3) Statement I is correct but Statement II is incorrect
(3) A-III, B-IV, C-I, D-II (4) Statement I is incorrect but Statement II is correct
(4) A-III, B-IV, C-II, D-I Sol. (1)
Sol. (1) Statement-I: Benzene diazonium salt is prepared by
A-IV, B-III, C-I, D-II the reaction of aniline with nitrous acid at 273-278
K. It decomposes easily in dry state.
(Mixture) (Method of Separation)
Cl
A. CHCl3 + C6H5NH2 IV. Simple distillation NH2 HNO2 + HCl N NH2

B. Crude oil in III. Fractional distillation 273-278K

spent-lye Benzene diazonium chloride

(stored in water at cold condn)
C. Glycerol from I. Distillation under
Statement-II:
reduced pressure
D. Aniline - water II. Steam distillation Cl
NH2 HNO + HCl N N KI
2 I
petroleum industry Cold

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75. How many products (including stereoisomers) are Sol. (1)
expected from monochlorination of the following
compound ? Br 2
No reaction
H 2O

OH OH
Br2 Br Br
water

(1) 2 (2) 3 Br
OH
(3) 5 (4) 6 CH = CH 2 Br
Br2
Sol. (4) water

CH3 NH2 NH2

Cl2 Cl
CH3–CH–CH2–CH3 Cl * + Br Br
hv Br2
water
+
* + Br
Cl
Cl 78. The major product of the following reaction is :
O
 Total isomers  (6). (i) CH3MgBr
CN (excess)
76. Among the given compounds I-III, the correct order
of bond dissociation enerty of C–H bond marked (ii) H3O +
with * is : H 3C OH OH
H 3C
CH3
H H (1) CN (2)
* O
* C C
* H
H H 3C OH O
III OH CH3
I II
(3) (4)
H 3C CH3 O
(1) II > I > III (2) I > II > III
(3) III > II > I (4) II > III > I Sol. (2)

Sol. (1) O H3C OH

CH3
(i) CH3 MgBr(excess)
1 C N
We know, Bond energy  (ii) H 3O +
O
bond distance of C  H bond
H 112 pm
109 pm 79. Which of the following aqueous solution will exhibit
C C-H
H highest boiling point ?
 109 pm
H
(I) (II)
(III)
(1) 0.01 M Urea (2) 0.01 M KNO3

 Correct order of decreasing bond dissociation (3) 0.01 M Na2SO4 (4) 0.015 M C6H12O6
energy
Sol. (3)
II > I > III
(1) 0.01 M Urea (2) 0.01 M KNO3
77. Which one of the following compounds does not
decolourize bromine water ? ic = 1 × 0.01 ic = 2 × 0.01
= 0.01 = 0.02
(1) (2) OH
(3) 0.01 M Na2SO4 (4) 0.15 M C6H12O6
ic = 3 × 0.01 ic = 1 × 0.15
(3) CH = CH2 (4) NH2
= 0.03 = 0.15
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80. Match List – I with List – II 82. Sugar ‘X’
A] is found in honey.
List - I List - II
B] is a keto sugar.
A) Haber process I) Fe catalyst C] exists  and  - anomeric forms.
B) Wacker oxidation II) PdCl2 D] is laevorotatory.
‘X’ is
C) Wilkinson catalyst III) [PPh3)3RhCl]
(1) D-Glucose
D) Ziegler catalyst IV) TiCl4 with (2) D-Fructose
Al(CH3)3 (3) M altose
(4) Sucrose
Choose the correct answer from the options given
Sol. (2)
below :
Sugar X is D-Fructose
(1) A–I, B–II, C–IV, D–III  D-Fructose is ketohexose
(2) A–II, B–III, C–I, D–IV  D-Fructose is found in honey

(3) A–I, B–II, C–III, D–IV  D-Fructose exist in  &  anometic forms
 D-Fructose is laevorotatory
(4) A–I, B–IV, C–III, D–II 83. Identify the suitable reagent for the following
Sol. (3) conversion.
O
CHO
 Haber process - Fe Catalyst OCH3

 Wacker oxidation PdCl2

(1) (i) LiAlH4, (ii) H+/H2O
 Wilkinson Catalyst [Rh(PPh3)3Cl] (2) (i) AlH(iBu)2, (ii) H2O
 Ziegler Catalyst TiCl4 with Al(CH3)3 (3) (i) NaBH4, (ii) H+/H2O
(4) H2/Pd-BaSO4
81. 5 moles of liquid X and 10 moles of liquid Y make a
Sol. (2) O
solution having a vapour pressure of 70 torr. The O
vapour pressures of pure X and Y are 63 torr and C -H
(i) AlH(iBu)2
OCH3
78 torr respectively. Which of the following is true (ii) H2O

regarding the described solution ?

Methyl Benzoate Benzaldehyde
(1) The solution shows positive deviation.  DIBAL-H Reduces Ester to Aldehyde
84. Given below are two statements : one is labelled as
(2) The solution shows negative deviation.
Assertion (A) and the other is labelled as Reason
(3) The solution is ideal. (R).

(4) The solution has volume greater than the sum of Assertion (A) : I undergoes S N2
individual volumes. reaction faster than Cl

Sol. (2) Reason (R) : Iodine is a better leaving group

because of its size.
PT  PA0  A  PB0  B In the light of the above statments, choose the correct
answer from the options given below :
5 10 (1) Both A and R are true and R is the correct
PT  63   78   73 explanation of A
15 15
(2) Both A and R are true but R is not the correct
Pobs = 70 explanation of A
Pobs < Pcal (3) A is true but R is false
(4) A is false but R is true
So Negative Deviation

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Sol. (1) 88. Higher yield of NO in
Assertion (A) I
N2(g) + O2(g)  2NO(g) can be obtained at
Ag and L.g.  I [Rate  L.gr. Ability] [  H of the reaction = + 180.7 kJ mol–1 ]
L.gr. Tendency  I– > Br– > Cl– > F– A] higher temperature
85. The standard heat of formation, in kcal/mol of Ba2+ B] lower temperature
is : C] higher concentration of N2
[Given : standard heat of formation of SO42– ion (aq) D] higher concentration of O2
= –216 kcal/mol, standard heat of crystallisation of Choose the correct answer from the options given
BaSO4(s) = – 4.5 kcal/mol, standard heat of below :
formation of BaSO4(s) = – 349 kcal/mol] (1) A, D only (2) B, C only
(1) –128.5 (2) –133.0 (3) B, C, D only (4) A, C, D only
(3) +133.0 (4) +220.5 Sol. (4)
Sol. (1) Reaction is endothermic, so
-2 -344.5 K.cal  high temp is fav. condition.
Ba+2 + SO 4
-4.5 K.cal/mole
BaSO 4 BaSO 4
(aq) (aq) (aq) (s)
 Adding reactant favours forward reaction.
H = – 349 K.cal/mole
89. If the rate constant of a reaction is 0.03 s–1, how
much time does it take for 7.2 mol L–1 concentration
 H = –344.5 =  H Ba   H SO 2
4
2
of the reactant to get reduced to 0.9 mol L–1 ?
– 344.5 = H Ba 2 + (-216) (Given : log 2 = 0.301)
(1) 69.3 s (2) 23.1 s
H Ba 2 = –128.5 K.cal/mole
(3) 210 s (4) 21.0 s
86. Total number of possible isomers (both structural as Sol. (1)
well as stereoisomers) of cyclic ethers of moelcular K = 0.03 S–1 (First order reaction)
formula C4H8O is :
Ri = 7.2
(1) 6 (2) 8 Rf = 0.9
(3) 10 (4) 11
 8 
Sol. (3) 2.303 7.2 
T log 
C4H 8O 0.03  0.9 
O
 
O O O
O O 2.303
* * T 3 log 2
(1) *
(2) (1) (1) (2) 3  102
(2)
*
3  0.693
87. Identify the correct orders against the property T  69.3sec
3  102
mentioned
90. Which one of the following reactions does NOT
(A) H2O > NH3 > CHCl3 – dipole moment
belong to “Lassaigne’s test” ?
(B) XeF4 > XeO3 > XeF2 – number of lone pairs on
(1) Na + C + N  
 NaCN
central atom
(2) 2Na + S  
 Na2S
(C) O-H > C-H > N-O – bond length
(3) Na + X   + NaX
(D) N2 > O2 > H2 – bond enthalpy 

Choose the correct answer from the options given (4) 2CuO + C 
 2Cu + CO2
below : Sol. (4)
(1) A, D only (2) B, D only Option 4 is used to detect of C
(3) A, C only (4) B, C only C + 2CuO  
 2Cu + CO2
Sol. (1) “Lassaigne test”
A)  dipole moment depends on electronegativity Na + C + N  
 NaCN
B)  2Na + S  
 Na2S
C)  Correct order C – H > N – O > O – H Na + X  
 NaX
D)  N  N > O = O > H – H (X = Cl , Br or I)

EMPOWERING NATION THROUGH EDUCATION ! 24 THINK NEET- JEE THINK IIB