5.

1 Werner's Theory of (a) 3 (b) 6 (c) 4 (d) 5

Coordination Compounds (2020) R
MCO
10. Assertion (A) : [Pt(en),Cl,j complex is less stable
than [Pt(NH),C1, complex.
1 Assertion:(Co(NH),SOJCI gives a white precipitate Reason (R) : (Pt(en),CI,] complex shows chelate
with silver nitrate solution.
effect.
Reason :The complex dissociates to give CI and (a) Both Assertion (A) and Reason (R) are correct
SO? ions. statements, and Reason (R) is the correct
(a) Both Assertion (A) and Reason (R)are true and explanation of the Assertion (A).
Reason (R) is the correct explanation of the (b) Both Assertion (A) and Reason (R) are correct
Assertion (A). statements, but Reason (R) is not the correct
(b) Both Assertion (A)and Reason (R) are true, but explanation of the Assertion (A).
Reason (R)is not the correct explanation of the (c) Assertion (A) is correct, but Reason (R) is
Assertion (A). incorrect statement.
(c) Assertion (A) is true, but Reason (R) is false.
(d) Assertion (A) is incorrect, but Reason (R) is
(d) Assertion (A) is false,but Reason (R) is true. correct statement. (2020)
(2023)
11. The oxidation state of Niin [Ni(CO)] is
2 One mole of CrCI-6H,0 compound reacts with (b) 2
(a) 0
excess AgNO, solution to yield two moles of AgClr (d) 4 (2020) An
The structural formula of the compound is (c) 3
(a) [Cr(H,0),CI) CI, H,0 (b) [Cr(H,0),CI,)-3H,0 VSA (1 mark)
(c) [Cr(H,0),C,JCI-2H,o (d) (Cr(H,0),cll (2020) 12. Amongst [Fe(C,0)] and (Fe(NH) which is
VSA (1 mark) more stable and why? (2019C)
13. Write the coordination number and oxidation state
3 When a coordination compound CrClz óH,0 is (2018)
mixed with AgNO, 2 moles of AgCl are precipitated of platinum in the complex [Pt(ern),Ci,l.
per mole of the compound. Write structural formula 14. Which of the following is more stable complex and
of the complex. (AI 2019, 1/2, Delhi 2016) why?
4 What is the difference between a complex and a [Co(NH,) and [Co(en) ]* (Delhi2014)
double salt? (AI 2019)R 5.3 Nomenclature of Coordination
5. When a coordination compound CoCl,-6NH, is Compounds
mixed with AgNO 3moles of AgClare precipitated
MCQ
per mole of the compound. Write structural formula
of the complex. (1/2, Al 2016) 15, The formula of the coordination compound
tetraamminechloridonitrito-N-cobalt(ll) chloride is:
5.2 Definitionof Some Important Terms (a) [Co(NH)4C(ONO)]CI,
Pertaining to (b) [Co(NH),CI,(NO,))CI
CoordinationCompounds () [Co(NH),CI(NO,)]cI
(d) [Co(NH),(NO,)]CI, (2021C)
MCQ
VSA (1 mark)
6 The oxidation number of Coin [Coen),),(S0), is 16. Write the formula of the following coordination
(a) +2 (b) +3 (c) +4 (d) +6
compound:
(2021C) Ap (1/3, 2018)
Iron(ll) hexacyanidoferrate(l1)
7. Which of the following ligands form a 'chelate'
17. Write the IUPAC name of the following complex :
complex withmetal ion? (1/3, Delhi 2017)
(a) H,0 (b) CN (c) C,0 (d) Cr (Cr(NH),CI
(2021C) 18. Write the lUPAC name of the following complex:
(1/3, Delhi 2017)
8.
The coordination number of Cr in (CrCl,(ox),] is [Co(NH),(co)]CL.
(a) 6 (b) 5 (c) 4 (d) 3 19. When a coordination compound CrCl,-6H,0 is
(2021C) mixed with AgNO 2moles of AgClare precipitated
9. The coordination number of C¡' in the complex per mole of the compound. Write IUPAC name of the
[Colen),]3* is complex. (1/2, Delhi 2016) An
 SAI (2 marks) 13
20. Give the formulae of the following compounds:
(0) (i) (Cr(CO)]
(a) Potassium tetrahydroxidozincate(1)
(b) Hexaammineplatinum(IV) chloride (2020) (Ap (ii) [PtCI,(C,H)I
(At. nos. Cr = 25, Co = 27, Pt =78) (AI2014C) Cr
21. Using IUPAC norms write the formulae for the
following: 5.4 Isomerism inCoordination
() Pentaamminenitrito-O-cobalt(||) chloride
(i) Potassium tetracyanidonickelate(l) Compounds
(NCERT, Delhi 2019)
Structural Isomerism
22. Using IUPAC norms write the formulae for the
following: MCQ
(a) Sodium dicyanidoaurate() 32. The compounds (Co(SO,)(NH,),JBr and
(b) Tetraamminechloridonitrito-N-platinum(V)
sulphate (AI2017) [Co(Br)(NH),]SO, represent
(a) optical isomerism
23. Using IUPAC norms write the formulae for the (b) linkage isomerism
following : (c) ionisation isomerism
(a) Tris(ethane-1,2,diamine)chromium(|) chloride (d) coordination isomerism. (2023)
(b) Potassium tetrahydroxozincate(l) (AI 2017)
24. Using IUPAC norms write the formulae for the 33. The pair [Co(NH,),CI,JBr, and [Co(NH),Br,]Cl, will
show
following: (a)
linkage isomerism
(a) Potassium trioxalatoaluminate(ll) (b)hydrate isomerism
(b) Dichloridobis(ethane-1,2-diamine)cobalt(l) (c)
ionization isomerism
(AI2017) Ap (d)
coordinate isomerism (2020) U
25. (0) Write down the IUPAC name of the following 34. Assertion (A) : Linkage isomerism arises in
complex : coordination compounds because of ambidentate
[Cr(NH),CI,(en)]Cl (en =ethylenediamine) ligand.
(i) Write the formulafor the following complex: Reason (R) : Ambidentate ligand like NO, has two
Pentaamminenitrito-O-cobalt (|l). (Delhi 2015) different donor atoms i.e., N and O.
26. Using IUPAC norms write the formulae for the (a) Both Assertion (A) and Reason (R) are correct
following coordination compounds: statements, and Reason (R) is the correct
() Hexaamminecobalt(|||) chloride explanation of the Assertion (A).
(ii) Potassium tetrachloridonickelate(l||) (Al 2015) (b) Both Assertion (A) and Reason (R) are correct
27. (i) Write down the IUPAC name of the following statements, but Reason (R) is not the correct
complex: (Cr(en) ]Cl,
(ii) Write the formula for the following complex:
explanation of the Assertion (A).
(c) Assertion (A) is correct, but Reason (R) is
Potassium trioxalatochromate(||I). incorrect statement.
(Foreign 2015) (d) Assertion (A) is incorrect, but Reason (R) is
SA | (3 marks) correct statement. (2020)
28. () Write the IUPAC name of the following complex: VSA (1 mark)
[Co(NH)4(H,0)CIjCI, 35. What type of isomerism is shown by the complex
(iü) What is the difference between an Ambidentate [Co(NH,),NO,]CI,? (2020)
ligand and aBidentate ligand?
36. What type of isomerism is exhibited by the complex
(ii) Out of [Fe(NH,)J and [Fe(C,O),], which (Co(NHJ),CIjso,? (1/3, 2018)
complex ismore stable and why?
(Term Il, 2021-22)(U OR

29, Write the IUPACname of the following: What type of isomerism is exhibited by the following
(0 (Co(NH),]Cl, (ii) (NiCI, complex:(Co(NH),SO,]CI (Foreign 2014)
(i) K[Fe(CN),) (AI2015C) Ap 37. What type of isomerism is shown by the complex
30. Write down the lUPAC name for each of the (Co(NH),][Cr(CN)J?
following complexes:
(1/3, Delhi2017, Foreign 2014)
() (Co(NH),CijCI, (i) K,[Fe(CN),] 38. What type of isomerism is shown by the complex
(ii) [NiCI,? (Delhi 2014C) U (Co(NH,),(SCN)*? (1/3, Al 2017)
31. Write the IUPAC name and draw the structure of 39. What type of isomerism is exhibited by the complex
each of the followingcomplex entities: (Co(NH,),NO,? (Foreign 2014)
 SAI (2 marks)
40. (a) Which of the following species cannot act as a
ligand? Give reason.
OH,NH, CH,NH, H,0
(b) The complex [Co(NH),(NO,))CI, is red in colour.
Give IUPAC name of its linkage isomer.
(2023)

tereolsaomerism
VSA (1 mark)
41. What type of isomerism is shown by the complex
[Colen),CI,]? Name the structure of an isomer of
this complex which is optically active. (1/2, 2020) An
42. What type of isomerism is shown by the complex
(Colen),]CI,? (NCERT Intext, 1/3, Delhi 2017)
OR
What type of isomerism is exhibited by the complex
[Colen)3*? (en =ethane-1,2-diamine) (1/3, Al 2014)
43. Draw one of the geometrical isomers of the complex
[Pt(en),Cl,]* which is optically active.
(1/3, Delhi 2016)
44. Draw one of the geometrical isomers of the complex
[Pt(en),CI,]* which is optically inactive. (AI2016)
45. Draw the geometrical isomers of complex
[Pt(NH),CI,). (1/3, Delhi2015)
46. Write down the |UPAC name of the complex
[Pt(en),Cl,]'*. What type of isomerism is shown by
this complex? (AI 2015)
47. Draw the geometrical isomers of complex
[Pt(en),Ci,), (1/3, Foreign 2015)(Cr
SAI (2 marks)
48. Write IUPAC name of the complex [Pt(en),Cl,].
Draw structures of geometrical isomers for this
complex. (2019)
49. Write IUPAC name of the complex [Cr(NH),CI,T".
Draw structures of geometrical isomers for this
complex. (Delhi 2019)
SAII (3 marks)
50. Indicate the types of isomerism exhibited by
the
following complexes:
() (Co(NH),(NO,)
(i) (Colen)]Cl, (en =ethylene diamine)
(ii) (Pt(NH,),CI,) (Delhi 2015C) U
51. Write the IUPAC name of the complex
[Cr(NH,),CI,]". What type of isomerism does it
exhibit?
52. Draw the structures of (Delhi2014)
optical isomers of each of the
following complex ions:
|Cr(C,0). [PrCI,len),*, |Cr(NH),C,(en)l'
(Delhi 2014C)