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1.0 VPS (Z&C+) Structure of Atom (Quantum Numbers) (14!6!18)

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25 views4 pages

1.0 VPS (Z&C+) Structure of Atom (Quantum Numbers) (14!6!18)

Uploaded by

chemistrypacket
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© © All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
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CHEMISTRY

Course: VelocIITy 1.0 VPS Date: 14 – 06


– 2018
JR. Z & C+
STRUCTURE OF ATOM (QUANTUM MECHANICAL MODEL OF AN ATOM)

Single Correction Answer Type:

1. The correct time independent Schrödinger’s wave equation for an electron with E as
total energy and V as potential energy is

A) B)

C) D)

2. Radial part of wave function depend on Quantum numbers


A) B) C) n & l D)

3. Which orbital is non-directional


A) s B) p C) d D) f

4. The number of nodal planes in a px orbital is


A) one B) two C) three D) zero

5. 3py orbital has.......... plane as nodal plane


A) XY B) YZ C) ZX D) All of these

6. A 3p-orbital has
A) Two non-spherical nodes
B) Two spherical nodes
C) One spherical and one non spherical nodes
D) One spherical and two non spherical nodes

7. The radial distribution curve of 2s sublevel consists of x nodes, x is


A) 1 B) 3 C) 2 D) 0

8. In case of orbital
A) Probability of finding the electron along x-axis is zero
B) Probability of finding the electron along y-axis is zero
C) Probability of finding the electron is maximum along x and y-axis
D) Probability of finding the electron is zero in xy plane

9. The maximum radial probability in 1s-orbital occurs at a distance when


[ r0 = Bohr radius ]

A) B) C) D)
2

10. For a 3s-orbital

Where
What is the maximum radial distance of node from nucleus?

A) B) C) D)

11. The principal quantum number of an atom is related to the


A) size of the orbital B) spin angular momentum
C) orbital angular momentum D) orientation of the orbital in space.

12. 2p – orbitals have


A) n = 1, l = 2 B) n = 1, l = 0 C) n = 2, l = 1 D) n = 2, l = 0

13. The possible set of quantum numbers for the unpaired electron of chlorine is :
n m n m
A) 2 1 0 B) 2 1 1
C) 3 1 1 D) 3 0 0

14. Which of the following represents the correct set of quantum numbers of a 4d electron?

A) 4, 3, 2, + B) 4, 2, 1, 0 C) 4, 3, -2, + D) 4, 2, 1, -

15. From the given sets of quantum numbers, the one that is inconsistent with the theory is
A) n = 3; = 2; m = -3; s = +1/2 B) n = 4; = 3; m = 3; s = +1/2
C) n = 2; = 1; m = 0; s = -1/2 D) n = 4; = 3; m = 2 ; s = +1/2

16. If electron has spin quantum number of + ½ and a magnetic quantum number – 1, it
cannot be present in
A) d-orbital B) f-orbital C) p-orbital D) s-orbital

17. Given is the electronic configuration of element X


K L M N
2 8 11 2
The number of electrons present with = 2 in an atom of element X is
A) 3 B) 6 C) 5 D) 4

18. For azimuthal quantum number l = 3, the maximum number of electrons will be
A) 2 B) 6 C) 0 D) 14

19. How many electrons can have the values n = 2, = 1 and s = + ½ in the configuration

A) 1 B) 3 C) 5 D) 7

20. A p-orbital can accommodate


A) 4 electrons B) 6 electrons
C) 2 electrons with parallel spins D)2 electrons with opposite spins.
3

21. Consider the ground state of Cr atom (Z = 24). The number of electrons with the
azimuthal quantum number values, = 1 and 2 are, respectively

A) 16 and 5 B) 12 and 5 C) 16 and 4 D) 12 and 4

22. The Quantum number not obtained from the Schrodinger’s equation is
B) C) l D)
A) n

Multiple Correct Option Type:

23. Which of the following properties can be described by wave function  ?


A) Type of orbital occupied by electron
B) energy of the electron in the orbital
C) shape of the orbital
D) probability of finding the electron in any particular region within the orbital

24. The probability of finding an electron in the orbital is


(A) zero at nucleus (B) same on all the sides around nucleus
(C) zero on the z-axis
(D) maximum on two opposite sides of the nucleus along the x-axis

25. Angular node in 4S orbital is equal to radial node in


A) 3d B) 2p C) 3p D) 4f

Matrix Matching Type :

26. Match the orbitals given in column - I with appropriate information given column - II.
(Here - radial probability distribution is probability function and is the
distance from the nucleus of atom)

Orbital Graph/information

A) 3s (P)

B) 2s (Q)

C) 1s (R)
4

D) 2p (S)

(T) Zero angular node


Integer Type :

27. The maximum number of electrons that can have principle quantum number n = 3 and

spin quantum number is

28. The number of radial node in 2p orbital is

Key :

1. C 2. C 3. A 4. A 5. C 6. C 7. A

8. C 9. A 10. C 11. A 12. C 13. C 14. D

15. A 16. D 17. A 18. D 19. B 20. D 21. B

22. A 23. ABCD 24. ACD 25. ABD

26. A  r, t; B  q, t ;C  p, s, t; D  s 27. 9 28. 0

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