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Author(s): Sati Manrich; Amélia S. F. Santos
ISBN(s): 9781614705901, 1614705909
Edition: 1
File Details: PDF, 2.67 MB
Year: 2008
Language: english
Copyright © 2008. Nova Science Publishers, Incorporated. All rights reserved.
Plastic Recycling, edited by Sati Manrich, and Amélia S. F. Santos, Nova Science Publishers, Incorporated, 2008. ProQuest
Copyright © 2008. Nova Science Publishers, Incorporated. All rights reserved.
Plastic Recycling, edited by Sati Manrich, and Amélia S. F. Santos, Nova Science Publishers, Incorporated, 2008. ProQuest
PLASTIC RECYCLING
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Plastic Recycling, edited by Sati Manrich, and Amélia S. F. Santos, Nova Science Publishers, Incorporated, 2008. ProQuest
PLASTIC RECYCLING
SATI MANRICH
AND
Copyright © 2008. Nova Science Publishers, Incorporated. All rights reserved.
AMÉLIA S. F. SANTOS
Plastic Recycling, edited by Sati Manrich, and Amélia S. F. Santos, Nova Science Publishers, Incorporated, 2008. ProQuest
Copyright © 2009 by Nova Science Publishers, Inc.
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Copyright © 2008. Nova Science Publishers, Incorporated. All rights reserved.
New York
Published by Nova Science Publishers, Inc.
Plastic Recycling, edited by Sati Manrich, and Amélia S. F. Santos, Nova Science Publishers, Incorporated, 2008. ProQuest
CONTENTS
Preface vii
Chapter 1 Introduction 1
Chapter 2 Waste Management of Plastics Residues 3
Chapter 3 First Steps of Plastic Material Recovery Process:
Sorting and Cleaning 7
Chapter 4 Mechanical Recycling 21
Chapter 5 Chemical Recycling 59
Copyright © 2008. Nova Science Publishers, Incorporated. All rights reserved.
Plastic Recycling, edited by Sati Manrich, and Amélia S. F. Santos, Nova Science Publishers, Incorporated, 2008. ProQuest
Copyright © 2008. Nova Science Publishers, Incorporated. All rights reserved.
Plastic Recycling, edited by Sati Manrich, and Amélia S. F. Santos, Nova Science Publishers, Incorporated, 2008. ProQuest
PREFACE
systems impacts directly on the amount of recycled plastics and on their cleanness
and quality, therefore, enlarging their market potential. The development of new
recycling technologies is diversified and can be classified into mechanical,
chemical and energetic recycling. In mechanical recycling, successful
technologies are achieved through the improvement of existing processes using
additives, blends with other plastics and alternative processing routes in order to
maintain the original properties of the virgin resin and even allowing them to
return to the same application as originally intended. Chemical recycling
processes to obtain intermediary products for new polymers become feasible due
to the cost reduction of the raw materials involved. Lastly, despite the under use
of the gross energy potential of the raw materials employed, energetic recycling
plants are gaining a proportion of residues whose technological solutions for
separation and/or reprocessing are deficient, but which, on the other hand, are
voluminous, consequently solving the problem of both residue accumulation in
densely populated regions and their respective insufficient energy supplies. In this
chapter, the authors proposed to present an overview of the current state of this
whole plastic recycling sector including their recent advances, and highlighting
Plastic Recycling, edited by Sati Manrich, and Amélia S. F. Santos, Nova Science Publishers, Incorporated, 2008. ProQuest
viii Sati Manrich and Amélia S. F. Santos
new markets and recent trends on recycling technologies around the world.
However, mechanical recycling has been emphasized owing to the experimental
and published work of Manrich’s workgroup at the 3R Residues Recycling
Center, which has concentrated on studying all the steps in the process of
mechanical recycling.
Copyright © 2008. Nova Science Publishers, Incorporated. All rights reserved.
Plastic Recycling, edited by Sati Manrich, and Amélia S. F. Santos, Nova Science Publishers, Incorporated, 2008. ProQuest
Chapter 1
INTRODUCTION
would remain for some decades. Since from the stand-point of thermodynamics
and engineering practice, it is impossible to end such emissions altogether, efforts
have to be made to reduce the risks to the environment, whenever the opportunity
arises [1-3].
The reuse and various types of recycling of waste residues can lead to
reductions in the use of non-renewable material and energy resources, with the
energy savings generally ranked as follows: reuse > material recovery > energy
recovery (energy from waste). Conversely, burying the residues in landfills,
entailing as it does the total loss of material and energy, makes no such
contribution [2, 4]. In the case of plastics, whose main current source of raw
material is the petroleum, all recycling methods are technically viable and are
briefly described next [5,6].
Mechanical recycling consists of the reprocessing of plastic residues into new
products, different from or similar to the original products. The waste plastic used
may come from the manufacturing process or from post-consumer products. This
is the simplest way of recycling plastic waste, demanding the lowest initial
investments.
Plastic Recycling, edited by Sati Manrich, and Amélia S. F. Santos, Nova Science Publishers, Incorporated, 2008. ProQuest
2 Sati Manrich and Amélia S. F. Santos
present an overview of the current state of the whole plastics recycling sector, if
somewhat sketchily in some areas, including a brief review of the recent research
and development in the fields of mechanical, chemical / thermochemical and
energy recycling of plastic waste. However, there is an emphasis on mechanical
recycling, owing to the experimental and published work of Manrich’s workgroup
at the 3R Residues Recycling Center, which has concentrated on studying all the
steps in the process of mechanical recycling.
Plastic Recycling, edited by Sati Manrich, and Amélia S. F. Santos, Nova Science Publishers, Incorporated, 2008. ProQuest
Chapter 2
WASTE MANAGEMENT
OF PLASTICS RESIDUES
Since the emergence of plastics in the 1940s, which was impelled by their
notable cost-benefit advantages over the traditional materials they replaced, the
concepts of security, comfort and hygiene have been improved. In addition, their
intrinsic characteristics of lightness, low processing temperatures, durability, low
thermal and electric conductivity, transparency and flexibility, among others, had
an immediate and growing impact on the correlated manufacturing sectors,
reducing consumption of both energy and natural resources. Furthermore, the
Copyright © 2008. Nova Science Publishers, Incorporated. All rights reserved.
Plastic Recycling, edited by Sati Manrich, and Amélia S. F. Santos, Nova Science Publishers, Incorporated, 2008. ProQuest
4 Sati Manrich and Amélia S. F. Santos
responsibility for the management of plastic residues in MSW [15]. The difficulty
in recycling plastics arises largely from the big fraction of plastic products
considered unsuitable for recycling from the outset and from the high operational
cost of plastic´s collection systems.
Several mechanisms have been employed to increase the viability of the
reversed logistics of returning the end-product packing material to the recycler:
taxation of the manufacturing sector about government regulations [16] the
establishment of taxes on non-recyclable packaging [17] the mandatory use of
recycled materials in some sectors [9] incentives on the use of articles made
entirely of such materials, with the removal of all licensing requirements on those
who wish to produce them [18] the opening of new markets for recycled plastic,
implementation of policies of exchanging post-used packages etc. for toys,
spendable vouchers, or sports material in needy communities [19, 20] and lastly
programs to inform, raise public awareness and provide opportunities for
consumers to play their part [21].
In parallel, initiatives used to improve the recyclability of packaging by
manufacturing plastics parts with fewer different resins and with easier separation
of components that contain distinct resins, and reduce the use of multilayered
material [13] adhesives, additives and labels on packs also play an important role
[9].
Thus, in various parts of the world regulations have been adopted in order to
achieve short and medium-term recycling targets [13]. In the European
Copyright © 2008. Nova Science Publishers, Incorporated. All rights reserved.
Community (EC), which became the European Union (EU) in 1992, the goals for
rates of recovery and recycling in the packaging sector were set by the Directive
94/62/EC [22] to member countries, establishing June 2001 as the deadline by
which these goals had to be reached: recycling of at least 25% and at most 40% by
weight of all waste packaging and recovery of at least 50% and at most 65%. In
addition, for each specific type of material, the fraction recycled should be at least
15%.
The available data confirm that these projected rates have been achieved in
paper recycling in the EU [23]. Considering the plastic packaging sector, in
Germany, the country that recycles the highest fraction of its waste in Europe,
these targets have also been accomplished, or at least approximated, except in the
case of composites. New EU targets for individual types of plastic waste have
already been outlined for 2006, in which at least 20% of each type should be
recycled [23]. These targets are currently being revised by the EU, but national
governments, such as the UK, are also reconsidering their own packaging
recycling and recovery targets for 2008 [21].
Plastic Recycling, edited by Sati Manrich, and Amélia S. F. Santos, Nova Science Publishers, Incorporated, 2008. ProQuest
Plastic Recycling 5
The particular concern over post-consumer plastic from the packaging sector
can be explained by its short useful life, which reflects in its fraction 75% of all
plastic waste [24]. In the EU, the recovery of plastic packaging residues was
boosted mainly by improvements in mechanical recycling that resulted from better
solid residue management practice [25]. The system of selective waste collection
used in Germany, organized by Dual System Deutschland (DSD), is a worldwide
reference [26].
In the EU countries in the decade from 1993 to 2003, generally speaking, the
mechanically recycled fraction of all discarded plastic rose from 5.6% to 14.9%.
Over the same period, largely because of the contribution made by energy
recycling indexes, the fraction of plastic in landfill fell from 75.7% to 61% [14,
25, 27]. In Japan, the equivalent fraction for solid residues in sanitary tips is
around 40% and much of this waste goes for energy recovery. The use of energy
recycling in those countries is justified by the reduced combustion of fuels to
produce energy, by the release of oil for the manufacture of virgin plastics and by
the provision of an alternative source of energy that reduces the problem of
energy shortage.
Similarly, in 2000, about 11% of all plastic produced in the USA was
recycled. This represents a great advance, since a mere 1% of plastic residues
were recycled in 1987 [9]. Nevertheless, this advance in recycling indexes has
been achieved by formal recycling regulations [28]. Relating to Poly(ethylene
terephthalate) (PET) recycling indexes, the USA is currently going through a
Copyright © 2008. Nova Science Publishers, Incorporated. All rights reserved.
period of stagnation in the recycling of this resin, according to the annual reports
published by the American Plastics Council (APC), in spite of the very high
recycling levels of PET achieved in 1995. At most, the amount of recycled PET is
increasing in proportion to the growth in production of the resin [17, 29]. In 2001,
the fraction recycled did not actually fall, but only because the slack in the home
demand was absorbed by the export market [17, 30]. In 2004, the fraction of
recycled PET was of the order of 21.6%, according to the National Association
for PET Container Resources (NAPCOR) [31].
Turning to Brazil, in a national survey carried out by Plastivida, the plastics
division of the Association of the Brazilian Chemical Industry (ABIQUIM), the
proportion of plastic residues transformed by mechanical recycling is around
16.5%, higher than that in Europe [32]. Furthermore, Brazil is the third biggest
market in the world for bottle-grade PET [18, 32] and the amount of this resin sent
for recycling is of the order of 35% [20, 34, 35].
Given the precarious state of waste collection system in Brazil, such high
rates of recycling are achieved only with the spontaneous involvement of low-
income families whose earnings come largely from collecting plastic residues [20,
Plastic Recycling, edited by Sati Manrich, and Amélia S. F. Santos, Nova Science Publishers, Incorporated, 2008. ProQuest
6 Sati Manrich and Amélia S. F. Santos
35]. This segment of the population currently represents about 500,000 informal
workers [32].
Finally, another type of residue demands our attention: the great volume of
rubber tires discarded annually in Brazil and accumulated annually around the
world [36, 37]. Since the beginning of the nineties, many Federal and State
Government ministries have been developing their own legal responsibility for
this residue. In Brazil, resolution 258, passed by CONAMA (National Council for
the Environment), obliges tire manufacturers and rebuilders (of retreads, remolds)
to provide an environmentally correct destination for an amount of used tires
proportional to their volume of production since 2002 and 2004, respectively [38].
Copyright © 2008. Nova Science Publishers, Incorporated. All rights reserved.
Plastic Recycling, edited by Sati Manrich, and Amélia S. F. Santos, Nova Science Publishers, Incorporated, 2008. ProQuest
Chapter 3
SORTING
One of the stages of plastic recycling that most threaten its feasibility as a
productive operation is the sorting of plastic material from mixed waste and,
especially, separation of the different types of plastic, which is hindered by the
Copyright © 2008. Nova Science Publishers, Incorporated. All rights reserved.
fact that quite different plastics may be used for the same end. In other words, a
given product can be fabricated with very similar characteristics from distinct
plastics and these act, in mixed residues, as impurities of each other after
separation. This reduces the viability of the process and, in serious cases, can
cause a whole production line to be shut down [39, 40].
Related problems that must also be taken into account are those of
multicomponent items, good examples being car parts and plastic electric and
electronic devices with embedded metal inserts, and multilayered products such as
laminated, co-extruded or metalized flexible packaging [39-41].
The ideal practical solution to this problem would be to make suitable
alterations in the plastic residues at source; that is, to redesign the original plastic
product. At the design stage, then, priority should be given to reducing the
number and variety of components in one product and the variety of materials
employed as consumer goods with identical functions. Such ideas are exactly the
opposite of current design trends, particularly in the packaging and disposable
goods sectors. In most cases, the existence of multicomponent and multilayer
residues is justified primarily on technical grounds, while the reasons for
Plastic Recycling, edited by Sati Manrich, and Amélia S. F. Santos, Nova Science Publishers, Incorporated, 2008. ProQuest
8 Sati Manrich and Amélia S. F. Santos
fabricating essentially the same product from diverse materials are based on
economics and marketing [41]. It is thus hard to imagine the above-mentioned
reversal in product design trends becoming a manufacturing priority on the
grounds of purely environmental gains.
Nevertheless, on the positive side, all over the world we see a lot of effort
being put into the research and development of appropriate technology that will
minimize the problems caused by mixed plastic waste and varying materials.
These studies concentrate on two fronts: the efficient separation of different
plastics and other components, and optimization of the composition of compatible
blends, or plastic composites of different materials, that combine, profitably, the
distinct properties of the component polymers [39-46]. The first of these research
areas will be discussed here and blends and composites in later sections.
The techniques used to separate mixed plastic residues can be classified in
several ways, but here they will be grouped as manual or automatic and each will
be approached in a specific way.
Manual Separation
Plastic Recycling, edited by Sati Manrich, and Amélia S. F. Santos, Nova Science Publishers, Incorporated, 2008. ProQuest
Plastic Recycling 9
HDPE, LDPE and LLDPE are high density, low-density and linear low
density polyethylene, respectively, PVC is poly(vinyl chloride), PP is
polypropylene, and PS is polystyrene. However, the residue from a
product, part or component does not always display a code, which may be
molded in relief or printed on the surface. If the code is missing or
identified as 7, the procedure has to move on to the following steps.
− Step 2: Consult a table of data, such as table 1, which helps the user to
identify the most likely material in a given product. It is found that,
contrary to what would be environmentally correct, the number of most
probable materials rises through the years, albeit rather slowly. Hence,
from time to time, these tables need revising.
Plastic Recycling, edited by Sati Manrich, and Amélia S. F. Santos, Nova Science Publishers, Incorporated, 2008. ProQuest
10 Sati Manrich and Amélia S. F. Santos
− Step 3: Given the list of most likely plastics, determine some specific
distinguishing properties that are simple to compare; these are indicated
below, for the case of post-consumer plastic packaging. Here we will
omit the techniques of differential scanning calorimetry and infrared
spectroscopy. Depending on the plastics in question, identification may
be achieved by testing only one of these properties, or a sequence of tests
may be required. This sequence varies from case to case and an example
will be given later, for the case of plastic bottles.
− Transparency: transparent ⇒ PET, PP, PVC, PS; translucent or
opaque ⇒ HDPE, PP, high-impact polystyrene (HIPS),
LDPE/LLDPE, PET.
− Whitening: exhibit whitening when folded ⇒ PP, HIPS, PS, PVC.
− Hinge: PP is the only plastic that withstands the repeated force used
to open and close the pack with a one-part device, the hinge.
− Density: the polyolefins, (HDPE, LDPE, LLDPE, PP) and expanded
polystyrene (EPS) float on water, being less dense (ρ < 1.0 g.cm-3).
− Combustion: the flames and smoke given off by burning plastic are
characteristic of each type. Table 2 describes these features of several
plastics.
− Solubility: ability to dissolve in various liquids or solvents is specific
to each plastic. Table 3 shows some examples.
Copyright © 2008. Nova Science Publishers, Incorporated. All rights reserved.
Plastic Recycling, edited by Sati Manrich, and Amélia S. F. Santos, Nova Science Publishers, Incorporated, 2008. ProQuest
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PACIFIC COAST, 9 FOOT SINGLE AND
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PACIFIC COAST, 10 FOOT BAND MILL
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California Agents
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Plant of
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