10-05-2025

4602CJA101001250002 JA

PART-A-PHYSICS

SECTION-I(i)

1)

What will be the value of this expression?

(A) 1
(B) 2
(C) 3
(D) 4

2) is a vector quantity such that = non-zero constant. Which of the following expressions is true
for ?

(A)
(B)
(C)
(D)

3) A bus is beginning to move with an acceleration of 1 m/sec2. A boy who is 48 m behind the bus
starts running at 10 m/sec. The times at which the boy can catch the bus will be-

(A) 8 sec
(B) 10 sec
(C) 12 sec
(D) 14 sec

4) The resultant of two vectors and is perpendicular to the shorter vector. If P = 2Q, the angle
between vectors is :-

(A) 150°
(B) 135°
(C) 120°
(D) 60°

5) The ratio of maximum and minimum magnitudes of the resultant of two vectors and is 3:2.
The relation between A and B is

(A) A = 5B
(B) 5A = B
(C) A = 3B
(D) A = 4B

6) Find out unit vector perpendicular to both vectors and

(A)

(B)

(C)
(D)

SECTION-I(ii)

1)

Four forces acting on a particle keep it in equilibrium, then :-

(A) the force must be coplanar.

(B) the forces cannot be coplanar.
(C) the forces may or may not be coplanar.
(D) if three of these forces are coplanar, so must be the fourth.

2)

A particle is projected vertically upwards from ground with a velocity 50 m/sec & motion is
considered till particle reaches the ground again. Find the CORRECT statement(s) :

(A) It's distance covered in 5th sec & 6th sec will be equal.
(B) For first 4 seconds distance & displacement are same
(C) Displacement in first & last second of the motion are equal.
(D) Distance in first & last second of the motion are equal.

3) If it is given that the velocity of a body is constant during its motiion, then what predictions can
be made based on the information given, here |x| represents the positive value of x.

(A) |Instantaneous Velocity vector| = Instantaneous speed

(B) |Average velocity vector| = Instantaneous speed
(C) Instantaneous Velocity vector = average velocity vector
(D) Instantaneous Speed = average speed

4) For a particle moving in straight line with constant acceleration the incorrect statement(s) :

(A) If displacement is zero, then distance covered is also zero.

(B) If distance covered is zero, then displacement is zero.
 If average velocity in an interval is zero, the instantaneous velocity must be zero at some instant
(C)
during that interval.
(D) Particle is always speeding up.

5) Given vector . The angle between and y-axis is/are

(A)

(B)

(C)

(D)

6) Angle between is 60o than:

The component of along will be

(A)

(B)
is perpendicular to resultant of

The component of along will be

(C)

(D)
The component of along will be

SECTION-III

1) A bird is flying in a straight line initially at 10 m/s. It uniformly increases its speed to 15 m/s while
covering a distance of 25 m. The time taken by the bird in seconds is.

2) If linear momentum (P) depends on time as then value of momentum (P) at time t >

0 when force (F) becomes zero is Given [ln 1 = 0]

3) A particle P starts from origin as shown and moves along a circular path of radius 1m. Time taken
by particle P to reach B is π sec. Average speed of particle P during motion is v m/s then find the
value of v. (given π2 = 10)

4) An object loses 20% of its speed after running 108 m. If maximum distance travelled by the object
before stopping is 100 x (in meter). Then value of x is.

5) A motor cyclist accelerates from rest with acceleration of 2 m/s2 for a time of 10 sec. Then he
moves with a constant velocity for 20 sec and then finally comes to rest with an deceleration of 1
m/s2. Average speed for complete journey is 2a m/s. Then find the value of a.

PART-B-CHEMISTRY

SECTION-I(i)

1) The difference between the radii of 3rd and 4th orbits of Li2+ is ΔR1. The difference between the
radii of 3rd and 4th orbits of He+ is ΔR2. Ratio ΔR1 : ΔR2 is :

(A) 8 : 3
(B) 3 : 2
(C) 3 : 8
(D) 2 : 3

2) Ejection of the photoelectron from metal in the photoelectric effect experiment can be stopped by
applying 0.5 V when the radiation of 250 nm is used. The work function of the metal is :

(A) 5 eV
(B) 4 eV
(C) 5.5 eV
(D) 4.5 eV

3) The radius of the second Bohr orbit in Li2+, in terms of the Bohr radius, :

(A)

(B)

(C)
(D)

4) The sodium salt of methyl orange has 7% sodium. What is the minimum molecular weight of the
compound?

(A) 420
(B) 375
(C) 329
(D) 295

5) Which of the following contains greatest number of oxygen atoms :

(A) 1 g of O
(B) 1 g of O2
(C) 1 g of O3
(D) all have the same number of atoms

6) A 15 mL sample of 0.20 M MgC12 is added to 45 mL of 0.40 M A1C13, What is the molarity

of Cl–ions in the final solution :

(A) 1.0 M
(B) 0.60 M
(C) 0.35 M
(D) 0.30 M

SECTION-I(ii)

1) Which of the following option(s) is/are correct. (Molar mass Ca(40), Br(80), Cl(35.5))
[Take H2O be solvent in every case & solute is completely soluble]

(A) If mass fraction of CaBr2 and H2O are same then molality of CaBr2 is 5 m.
(B) If equal moles of NaC1 and H2O are taken then molality of NaC1 is 55.55 m.
(C) If in place of NaC1 we use NaBr as solute in option (B) then molality of NaBr changes.
(D) If mole fraction of NaC1 is same as that of H2O then molality of NaC1 will be 55.55 m.

2) The number of protons in 180 ml of H2O with density 1 gm/ml are:

(A) 6.022 × 1023

(B) 6.022 × 1024
(C) 6.022 × 1025
(D) 6.022 × 1022

3) The correct statement(s) regarding 2M MgCl2 aqueous solution is/are

(dsolution = 1.09 gm/ml) (Molar mass Mg(24), Cl(35.5))
(A) Molality of Cl– is 4.44m
(B) Mole fraction of MgCl2 is more than 0.030
(C) The concentration Of MgCl2 is 19% w/v
4
(D) The concentration Of MgCl2 is 19×10 ppm

4) Choose the INCORRECT relation on the basis of Bohr’s Atomic model ?

(A)
Velocity of an electron ∝
Frequency of revolutions ∝
(B)

(C) Radius of orbit ∝ n–2

(D) Force on an electron ∝

5) Bohr theory is/are not applicable for

(A) He+
(B) Li+
(C) Be+
(D) H

6) The kinetic energy of photoelectron emitted on irradiating a metal surface with frequency ν is
related by
KE = hν – ϕ. The plots of KE vs. incident frequency ν shows :

(A) A straight line with slope equal to Planck's constant.

A straight line with intercept on x-axis equal to the product of threshold frequency and Planck's
(B)
constant.
(C) A straight line with extrapolated intercept on y-axis equal to negative work function.
(D) A straight line with intercept on x-axis equal to threshold frequency.

SECTION-III

1) How many minimum number of H-atoms are required to get maximum number of 10 spectrum
lines when electrons are de excited from 5th energy levels

2) Electrons in the H-atoms jump from some higher level upto 3rd energy level. If six spectral lines
are possible for the transition, find the initial position of electron.

3) A 60 gm sample of organic compound having empirical formula CxHyO on complete combustion

gives 88 gm of CO2 & 36 gm of H2O. The value of (x + y) is.
4) Calculate the number of Na+ ion present in 710 mg of Na2SO4 in aqueous solution.
"(NA = 6 × 1023)" (Molar mass Na(23), S(32))
If your answer is x × 10y then fill ‘x’ in OMR. Where ‘x’ is single digit number.

5)

The mass of ‘O’ in 1 mole KClO3 is x gm. (Molar mass K(39))

Then is :

PART-C-MATHEMATICS

SECTION-I(i)

1) Sum of the roots of the equation is equal to

(A) 2
(B) 4
(C) 6
(D) 8

2) If log2(x2 + 1) + log13(x2 + 1) = log2(x2 + 1) log13(x2 + 1), (x 0), then log7(x2 + 24) is equal to

(A) 1
(B) 2
(C) 3
(D) 4

3) If , then find the remainder when p(x) is divided by (x+1).

(A) 12
(B) -12
(C) 24
(D) -24

4) If x2 + x – 1 = 0 then value of is

(A) 49
(B) 47
(C) 9
(D) 7
5) The numerical value of is (a, b, c are distinct real numbers)

(A) 1
(B) 8
(C) 0
(D) None

6) ______.

(A) 0
(B) 1
(C) 2
(D) 3

SECTION-I(ii)

1) If where x, y > 0

then which of the following is/are correct.

(A) x + y = 12
(B) x – y = 3
(C) x2 + y2 = 74
(D) x2 – y2 = 24

2) If x = a and x = b are the two roots of the equation 9x – 4 × 3x+1 + 27 = 0 then

(A) a + b = 3
(B) (a – b)2 = 1

(C)

(D) a + b = 4

3) The equation has

(A) one irrational solution

(B) no prime solution
(C) two real solutions
(D) one integral solution
4) The equation has

(A) exactly three real solution

(B) Atmost two real solution
(C) exactly two irrational solution
(D) at least one real solution

5)

If S is the set of all real x such that is positive, then S contains

(A)

(B)

(C)

(D)

6) Which of the following statements are true

(A) log2 3 < log12 10

(B) log6 5 < log7 8
(C) log326 < log29
(D) log1615 > log1011 > log76

SECTION-III

1) Suppose a and b are constants such that

(x3 + bx2 – 7x + 9)(x2 + ax + 5)= x5 + 13x4 + 38x3 – 22x2 + 37x + 45 ∀ x ∈ R. Find the value of b.

2) Let x1, x2, x3 are the solutions of the equation

, then is

3) Let , then a1a2a3 is

4) The units digit of the least positive integer which when divided by 6, 7, 8, 9 and 12 leaves the
remainder 1 is
5) The value of is
 ANSWER KEYS

PART-A-PHYSICS

SECTION-I(i)

Q. 1 2 3 4 5 6
A. C C B C A B

SECTION-I(ii)

Q. 7 8 9 10 11 12
A. C,D A,B,D A,B,C,D A,D C,D A,B

SECTION-III

Q. 13 14 15 16 17
A. 2 2 1 3 7

PART-B-CHEMISTRY

SECTION-I(i)

Q. 18 19 20 21 22 23
A. D D D C D A

SECTION-I(ii)

Q. 24 25 26 27 28 29
A. A,B,D C A,B,C C B,C A,C,D

SECTION-III

Q. 30 31 32 33 34
A. 6 6 3 6 6

PART-C-MATHEMATICS

SECTION-I(i)

Q. 35 36 37 38 39 40
A. A B C B A B

SECTION-I(ii)

Q. 41 42 43 44 45 46
A. A,C,D A,B,C A,B,C,D A,D A,D B,C
 SECTION-III

Q. 47 48 49 50 51
A. 5 1 2 1 1
 SOLUTIONS

PART-A-PHYSICS

1)

2(sin15°+sin75°)2
⇒ 2(sin15°+cos15°)2 (Q sinθ = cos(π/2–θ))
⇒ 2[sin215° + cos215° + 2sin15°cos15°]
⇒ 2[1 + sin30°] (∵ 2sinqcosθ = sin2θ)
⇒ 3

2)

3) Let police jeep catches the thief in time t then 1000 = 20t ⇒ t = 50sec

⇒1000 =15(t + Δt) ⇒1000 = 15(50 + Δt) ⇒1000 = 750 +15Δt ⇒250 =15 Δt ⇒Δt = =16.67
sec

6) Vector perpendicular to both vector is

unit vector is

7)

Conceptual

8)
(A) distance travelled in 5th second and 6th second are 5 m both.
(B) in first 4 second direction of velocity does not change so distance = displacement
(C & D) displacement is a vector quantity. Distance in first and last second are equal but
displacement not.

11)

13) v 2 = u2 + 2as

m/ sec2
Now v = x + at

15 = 10 + ×t t = 2sec

15)

Average speed v = =1

16)

For stopping V = 0
O2 = + 2a S
 S=
100 x = 300
x=3

17)

Vav = = 14 m/s

PART-B-CHEMISTRY

18) for Li+2 ⇒ r4 – r3

= 0.529 × × [42 – 32] = ΔR1 ...(1)

for He+ ⇒ r4 – r3

= 0.529 × × [42 – 32] = ΔR2

19) KE = q × Δv = e × Δv = 0.5 ev
λ = 250 nm

20)

(n = 2, z = 3)

21)

M=

22) Theory based.

23) Concl. of C1– ion =

24) (A)

m=

(B)

(C)
(D) As mole fraction of NaC1 and H2O are same which means both have same moles hence m
will be 55.5.

25) Mass of H2O = 180 × 1 = 180 g

Mole of H2O = = 10
1 mole H2O = 6.022 × 1023 H2O molecules.
Number of protons in 1 molecule of H2O = 10
Total proton in 10 mole of H2O molecules = 6.022 × 1023 × 10 × 10 = 6.022 × 1025

26) (A)

molal MgCl2 solution

⊝
Molality of Cl = 2 × molality of MgCl2
= 2 × 2.22
= 4.44 m

(B) Xsolute =

= (Mass of solvent = 900)

(C)
= 19%
(D) The concentration of Mg Cl2 is ppm
27)

(A) Velocity of e– = 2.186 ×106 × m/s

Velocity of e– ∝ (B) Frequency of revolution =

Frequency of revolution ∝

(C) Radius of orbit = 0.529 ×

Radius ∝

(D) Force of an electron =

Force =

∴ r = 0.529 ×

Force ∝
So the correct options are (A) (B) (D) and the incorrect option is (C)

28) Bohr’s model is only applicable to uni-electronic species (H, He+, Li2+, Be3+…..)

29)

30) conceptual
 31)

Number of spectral lines =

6= ⇒ 12 =

∴ n22 – 5n2 – 6 = 0.

∴ n2 = 6 or – 1.

Since n2 = –1 is not possible. Hence n2 = 6.

32) CH2O
1+2=3

33)
no of Na+ ions = 2 × 5 × 10–3 × 6 × 1023
= 6 × 1021

34)

1 mole KClO3 = 3 mole O

= 3 × 16 = 48 gm O = 0

PART-C-MATHEMATICS

35) Sum of the root of equation

∵ By property
(log2x)2 + (log2x)2 – (log2x) – 1 = 0
Let log2x = t
∴ 2t2 – t – 1 = 0
2t(t – 1) + (t – 1) = 0

log2x = 1
⇒x=2

36) Let log2(x2 + 1) = a and log13(x2 + 1) = b

a + b = ab
∴ x2 = 25
log7(x2 + 24) = log749 = log772 = 2

39) = xº = 1

40)

=1

41)

x=
x2 - 7x = 0 x=7
y=
y2 - y - 20 = 0
(y -5) (y +4) = 0
y = 5, -4
x = 7, y =5

42) 3x = t
t2 - 12t + 27 = 0
t = 9, 3
3x = 9, 3
x = 2, 1

43)

⇒
but log2x = t

∴
⇒ 3t2 – 5t – 2 = 0
⇒ (3t + 1) (t – 2) =

⇒
⇒ x = 2–1/3

⇒=
t=2
log2x = 2
x=4

44)

⇒
Let log3x = t

⇒
⇒ 2t3 – 9t2 + 10t – 3 = 0
t = 1 satisfies it
2t3 – 9t2 + 10t – 3
= 2t2(t – 1) – 7t(t – 1) + 3(t – 1)
= (t – 1) (2t2 – 7t + 3)
= (t – 1) (2t – 1) (t – 3) = 0

⇒ t = 1, t = , t = 3

⇒ log3x = 1, log3x = , log3x = 3

⇒ x = 3, x = 31/2, x = 27
all real roots are called complex

45)

⇒ ⇒

⇒ x ∈ (–∞, –1) ∪

46) log23 > 1, log1210 < 1 ⇒ log23 > log12 10

log65 < 1, log78 > 1 ⇒ log65 < log78
log326 < 3, log29 > 3 ⇒ log326 < log29
log1615 < 1, log1011 > 1 ⇒ log1615 < log1011

47)

a = 8 and b = 5

on comparing coefficients
a + b = 13
ab – 2 = 38
5b – 7a + 9 = –22
9a – 35 = 37 ⇒ a = 8
Solving above equation a = 8, b = 5.

48) RHS = x

x = 1 or (log2x)2 + 5log2x) + 4 = 0

x1 = 1, &

⇒ x1 + x2 + x3

49)
a1= log35, a2 = log57, a3 = log79
a1a2a3 = log39 = 2

50) Through L.C.M. of 6, 7, 8, 9, 12 is 504 and if it leaves remainder 1 than number is 505 but
least positive integer is still 1

51)

Hence