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Aieee Paper 2005

The document contains a series of chemistry questions from the AIEEE Paper-2005, covering various topics such as quantum mechanics, chemical bonding, thermodynamics, and reaction kinetics. Each question presents multiple-choice answers, testing knowledge on concepts like isoelectronic species, bond types, and the effects of temperature on gas behavior. The questions are designed for students preparing for competitive exams in chemistry.

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0% found this document useful (0 votes)
10 views32 pages

Aieee Paper 2005

The document contains a series of chemistry questions from the AIEEE Paper-2005, covering various topics such as quantum mechanics, chemical bonding, thermodynamics, and reaction kinetics. Each question presents multiple-choice answers, testing knowledge on concepts like isoelectronic species, bond types, and the effects of temperature on gas behavior. The questions are designed for students preparing for competitive exams in chemistry.

Uploaded by

adityadubey10n
Copyright
© © All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
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AIEEE PAPER-2005

CHEMISTRY Q.11 Of the following sets which one does not contain
Q.1 In a multi-electron atom, which of the following orbitals isoelectronic species?
described by the three quantum members will have the (A) PO34 , SO 24 , CIO4 (B) CN – , N 2 , C22 
same energy in the absence of magnetic and electric fields
(a) n = 1,  = 0, m = 0 (b) n = 2,  = 0, m = 0 (C) SO32  , CO32 , NO3 (D) BO33 , CO32 , NO3
(c) n = 2,  = 1, m = 1 (d) n = 3,  = 2, m = 1 Q.12 The number and type of bond between two carbon atom in
(e) n = 3,  = 2, m = 0 calcium carbide are:
(A) (b) and (c) (B) (a) and (b) (A) One sigma, one pi bond (B) One sigma, two pi bond
(C) (d) and (e) (D) (c) and (d) (C) Two sigma, one pi bond (D) Two sigma, two pi bond
Q.2 Of the following sets which one does NOT contain Q.13 Which one of the following statements is not true about
isoelectronic species ? the effect of an increase in temperature on the distribution
(A) CN–, N2, C22– (B) PO43–, SO42–, ClO4– of molecular speeds in a gas ?
3–
(C) BO3 , CO3 , NO32– – (D) SO32–, CO32–, NO3– (A) The fraction of the molecules with the most probable
Q.3 In which of the following arrangements the order is NOT speed increases
according to the property indicated against it ? (B) The most probable speed increases
(A) Al3+ < Mg2+ < Na < F– – increasing ionic size (C) The area under the distribution curve remains the same
(B) B < C < N < O – increasing first ionization enthalpy as under the lower temperature
(C) I < Br < F < Cl – increasing electron gain enthalpy (with (D) The distribution becomes broader
negative sign) Q.14 Due to the presence of an unpaired electron, free radicals
(D) Li < Na < K < Rb – increasing metallic radius are:
Q.4 Which of the following oxides is amphoteric in character ? (A) Chemically reactive (B) Chemically inactive
(A) SnO2 (B) SiO2 (C) Anions (D) Cations
(C) CO2 (D) CaO Q.15 Consider the reaction : N2 + 3 H2 2 NH3 carried out at
Q.5 Hydrogen bomb is based on the principle of – constant temperature and pressure. If H and U are the
(A) Nuclear fission (B) Natural radioactivity enthalpy and internal energy changes for the reaction,
(C) Nuclear fusion (D) Artificial radioactivity which of the following expressions is true ?
Q.6 The lanthanide contraction is responsible for the fact that (A) H = U (B) H = 0
(A) Zr and Y have about the same radius (C) H > U (D)H < U
(B) Zr and Nb have similar oxidation state Q.16 If the bond dissociation energies of XY, X2 and Y2 (all
(C) Zr and Hf have about the same radius diatomic molecules) are in the ratio of 1 : 1 : 0.5 and fH for
(D) Zr and Zn have the same oxidation state the formation of XY is –200 kJ mol–1. The bond dissociation
Q.7 Which of the following factors may be regarded as the energy of X2 will be -
main cause the lanthanide contraction ? (A) 200 kJ mol–1 (B) 100 kJ mol–1
(A) Poor shielding of one of 4f electron by another in the (C) 800 kJ mol–1 (D) 300 kJ mol–1
subshell Q.17 For the reaction : 2 NO2(g) 2 NO(g) + O2(g),
(B) Effective shielding of one of 4f electrons by another in (Kc = 1.8 × 10–6 at 184ºC) (R = 0.0831 kJ/(mol.K))
the subshell When Kp and Kc are compared at 184ºC it is found that
(C) Poorer shielding of 5d electrons by 4f electrons (A) Kp is less than Kc (B) Kp is greater than Kc
(D) greater shielding of 5d electrons by 4f electrons (C) Whether Kp is greater than, less than or equal to Kc
Q.8 Which one of the following species is diamagnetic in depends upon the total gas pressure (D) Kp = Kc
nature? Q.18 The exothermic formaton of ClF3 is represented by the
(A) He2+ (B) H2 equation -
(C) H2+ (D) H2– Cl2(g) + 3F2(g) 2 ClF3(g) ; rH = –329 kJ
Q.9 Lattice energy of an ionic compound depends upon: Which of the following will increase the quantity of ClF3 in
(A) charge on the ion only (B) size of the ion only an equilibrium mixture of Cl2, F2 and ClF3 ?
(C) packing of the ion only (D) charge and size of the ion (A) Removing Cl2
Q.10 The molecular shapes of SF4, CF4 and XeF4 are: (B) Increasing the temperature (C) Adding F2
(A) the same with 2, 0 and 1 lone pair ofelectrons on the (D) Increasing the volume of the container
central atom, respectively Q.19 A schematic plot of ln Keq versus inverse of temperature
(B) the same with 1, 1 and 1 lone pair of electrons on the for a reaction is shown below
central atoms, respectively
(C) different with 0, 1 and 2 lone pair of electrons on the 6.0
central atoms, respectively
ln K eq

(D) different with 1, 0 and 2 lone pair of electrons on the


central atoms, respectively
2.0
–1
1.5 × 10 1/T (K ) 2.0 × 10-3
-3

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The reaction must be is
(A) endothermic (B) exothermic (A) (d), (c) , (b) , (a) (B) (a), (b), (c) , (d)
(C) highly spontaneous at ordinary temperature (C) (c) , (b) , (a) , (d) (D) (b), (c) , (a) , (d)
(D) one with negligible enthalpy change O O
Q.20 An amount of solid NH4HS is placed in a flask already Q.29 The reaction R – C Nu R–C +X is fastest
containing ammonia gas at a certain temperature and 0.50 X Nu
atm pressure. Ammonium hydrogen sulphide decomposes when X is –
to yield NH3 and H2 S gases in the flask. When the (A) NH2 (B) Cl
decomposition reaction reaches equilibrium, the total (C) OCOR (D) OC2H5
pressure in the flask rises to 0.84 atm ? The equilibrium Q.30 Amongst the following the most basic compound is–
constant for NH4HS decomposition at this temperature (A) aniline (B) benzylamine
is– (C) p–nitroaniline (D) acetanilide
(A) 0.18 (B) 0.30 Q.31 Which types of isomerism is shown by 2,3–dichlorobutane
(C) 0.11 (D) 0.17 (A) Optical (B) Diastereo
Q.21 The solubility product of a salt having general formula (C) Structural (D) Geometric
MX2, in water is 4 × 10–12. The concentration of M2+ ions Q.32 Reaction of one molecule of HBr with one molecule of
in the aqueous solution of the salt is – 1,3–butadiene at 40ºC given predominantly
(A) 1.0 × 10–4 M (B) 2.0 × 10–6 M (A)1–bromo–2–butene under thermodynamically
–10
(C) 4.0 × 10 M (D) 1.6 × 10–4 M controlled conditions
Q.22 The oxidation state of Cr in [Cr(NH3)4Cl2]+ is – (B) 3–bromobutene under kinetically controlled conditions
(A) +2 (B) +3 (C) 1–bromo–2–butene under kinetically controlled
(C) 0 (D) +1 conditions
Q.23 The oxidation state of chromium in the final product formed (D) 3–bromobutene under thermodynamically controlled
by the reaction between Kl and acidified potassium conditions
dichromate solution is – Q.33 Acid catalyzed hydration of alkenes except ethene leads
(A) +6 (B) +4 to the formation of –
(C) +3 (D) +2 (A) secondary or tertiary alcohol
Q.24 The structure of diborane contains (B) primary alcohol
(A) Four 2c-2e bonds and four 3c-2e bonds (C) mixture of secondary and tertiary alcohols
(B) Two 2c-2e bonds and two 3c-2e bonds (D) mixture of primary and secondary alcohols
(C) Two 2c-2e bonds and four 3c-2e bonds Q.34 An ionic compound has a unit cell consisting of A ions at
(D) Four 2c-2e bonds and two 3c-2e bonds the corners of a cube and B ions on the centres of the faces
Q.25 Heating an queous solution of aluminium chloride to of the cube. The empirical formula for this compound would
dryness will give :- be –
(A) AlCl3 (B) Al2Cl6 (A) A2B (C) AB
(C) Al2O3 (D) Al(OH)Cl2 (C) A3B (D) AB3
Q.26 In silicon dioxide : Q.35 If  is the degree of dissociation of Na2SO4, the vant Hoff's
(A) Each silicon atom in surrounded by four oxygen atoms factor (i) used for calculating the molecular mass is –
and each oxygen atom is bonded to two silicon atoms (A) 1 –  (B) 1 + 
(B) Each silicon atom is surrounded by two oxygen atoms (C) 1 – 2 (D) 1 + 2
and each oxygen atoms is bonded to two silicon atoms Q.36 Benzene and toluene form nearly ideal solutions. At 20ºC,
(C) Silicon atom is bonded to two oxygen atoms the vapour pressure of benzene is 75 torr and that of toluene
(D) There are double bonds between silicon and oxygen is 22 torr. The partial vapour pressure of benzene at 20ºC
atoms for a solution containing 78 g of benzene and 46 g of toluene
Q.27 The highest electrical conductivity of the following in torr is –
aqueous solutions is of (A) 25 (B) 50
(A) 0.1 M acetic acid (B) 0.1 M chloroacetic acid (C) 53.5 (D) 37.5
(C) 0.1 M fluoroacetic acid (D) 0.1 M difluoroacetic acid Q.37 Two solutions of a substance (non electrolyte) are mixed
Q.28 The decreasing order of nucleophilicity among the in the following manner. 480 ml of 1.5 M first solution + 520
nucleophiles mL of 1.2M second solution. What is the molarity of the
final mixture ?
(a) CH3C  O (b) CH3O–
(A) 1.50 M (B) 1.20 M (C) 2.70 M (D)1.344 M
||
O Q.38 Equimolal solutions in the same solvent have
O (A) Same freezing point but different boiling point
(B) Same boling point but different freezing point
(c) CN– (d) H3C S – O– (C) Different boiling and different freezing point
O (D) Same boiling and same freezing points
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Q.39 Aluminium oxide may be electrolysed at 1000ºC to furnish (A) Eb < Ef (B) Eb > Ef
aluminium metal (At. Mass = 27 amu ; 1 Faraday = 96,500 (C) Eb = Ef
Coulombs). The cathode reaction is Al3+ + 3e–  Alº (4) There is no definite relation between Eb and Ef
To prepare 5.12 kg of aluminium metal by this method would Q.49 The value of the 'spin only' magnetic moment for one of
require - the following configurations is 2.84 BM . The correct one
(A) 1.83 × 107 C of electricity(B) 5.49 × 107 C of electricity is –
(C) 5.49 × 101 C of electricity (D) 5.49 × 104 C of electricity (A) d4 (in strong ligand field)
Electrolyt e KCl KNO 3 HCl NaOAc NaCl
(B) d4 (in weak ligand field)
Q.40  (S cm 2 mol 1 ): 149 .9 145 .0 426 .2 91 .0 126 .5 (C) d3 (in weak as well as in strong field)
(D) d5 (in strong ligand field)
Calculate  HOAc using appropriate molar conductance of
Q.50 Tertiary alkyl halides are practically inert to substitution
by SN2 mechanism because of –
the electrolytes listed above at infinite dilution in H2O at
(A) instability (B) insolubility
25ºC
(C) steric hindrance (D) inductive effect
(A) 552.7 (B) 517.2
Q.51 Alkyl halides react with dialkyl copper reagents to give
(C) 217.5 (D) 390.7
(A) alkyl copper halides (B) alkenes
Q.41 A reaction involing two different reactants can never be –
(C) alkenyl halides (D) alkanes
(A) first order reaction (B) unimolecular reaction
Q.52 Elimination of bromine from 2–bromobutane results in the
(C) bimolecular reaction (D) second order reaction
formation of –
Q.42 t1/4 can be taken as the time taken for the concentration of
(A) predominantly 2–butene
a reactant to drop to 3/4 of its initial value. If the rate constant
(B) equimolar mixture of 1 and 2–butene
for a first order reaction is K, t1/4 can be written as –
(C) predominantly 2–butyne
(A) 0.29/K (B) 0.10/K
(D) predominantly 1–butene
(C) 0.75/K (D) 0.69/K
Q.53 p–cresol reacts with chloroform in alkaline medium to give
Q.43 The volume of a colloidal particle, VC as compared to the
the compound A which adds hydrogen cyanide to form,
volume of a solute particle in a true solution VS, could be –
the compound. B The latter on acidic hydrolysis gives
VC 23 VC chiral carboxylic acid. The structure of the carboxylic acid
(A) V  10 (B) V  1 is -
S S
CH3 CH3
VC 3 VC 3
(C) V  10 (D) V  10 CH(OH)COOH
S S (A) (B)
Q.44 The dispersed phase in colloidal iron (III) hydroxide and CH(OH)COOH
colloidal gold is positively and negatively charged, OH OH
respectively. Which of the following statements is NOT
correct ? CH3 CH3
(A) Sodium sulphate solution causes coagulation in both CH2COOH
sols (C) (D)
(B) Magnesium chloride solution coagulates, the gold sol CH2 COOH
more readily than the iron (III) hydroxide sol. OH OH
(C) the processes of electrophoresis provied charge on Q.54 The best reagent to convert pent–3–en–2–ol into pent–3–
both the sols in–2–one is -
(D) Colloidal iron is coagulated by Mg+2 and colloidal gold (A) Acidic dichromate
is coagulated by Cl– (B) Acidic permanganate
Q.45 During the process of electrolytic refining of copper, some (C) Pyridinium chloro–chromate
metals present as impurity settle as 'anode mud'. These are (D) Chromic anhydride in glacial acetic acid
(A) Pb and Zn (B) Sn and Ag Q.55 Which one of the following methods is neither meant for
(C) Fe and Ni (D) Ag and Au the synthesis nor for separation of amines ?
Q.46 Heating mixture of Cu2O and Cu2S will give (A) Hofmann method (B) Hinsberg method
(A) Cu + SO3 (B) Cu + SO2 (C) Curtius reaction (D) Wurtz reaction
(C) Cu2SO3 (D)CuO + CuS Q.56 Reaction of cyclohexanone with dimethylamine in the
Q.47 The number of hydrogen atoms (s) attached to phosphorus presence of catalytic amount of an acid forms a compound
atom in hypophosphorous acid is – if water during the reaction is continuously removed. The
(A) two (B) zero compound formed is generally known as –
(C) three (D) one (A) an enamine (B) a Schiff's base
Q.48 Consider an endothermic reaction, X Y with the activa- (C) an amine (D)an imine
tion energies Eb and Ef for the backward and forward reac-
tions, respectively. In general
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Q.57 In both DNA and RNA, heterocylic base and phosphate Q.70 2 methylbutane on reacting with bromine in the presence
ester linkages are at – of sunlight gives mainly –
(A) C2' and C5' respectively of the sugar molecule (A) 1-bromo-2- methylbutane (B) 2-bromo-2-methylbutane
(B) C5' and C2' respectively of the sugar molecule (C) 2-bromo-3-methylbutane (D) 1-bromo-3-methylbutane
(C) C5' and C1' respectively of the sugar molecule Q.71 The photon of hard gamma radiation knocks a proton out
(D) C1' and C5' respectively of the sugar molecule 24
of 12 Mg nucleus to form–
Q.58 Which one of the following types of drugs reduces fever-
(A) Antipyretic (B) Analgesic (A) the isotope of parent nucleus
(C) Tranquiliser (D) Antibiotic (B) the isobar of parent nucleus
Q.59 Which of the following is a polyamide ? 23
(C) the nuclide 11 Na 23
(D) the isobar of 11 Na
(A) Nylon-66 (B) Teflon
(C) Bakelite (D) Terylene Q.72 Among the following acids which has the lowest pKa
Q.60 Which of the following is fully fluorinated polymer- value?
(A) Teflon (B) Neoprene (A) CH3COOH (B) HCOOH
(C) PVC (D) Thiokol (3) (CH3)2COOH (D) CH3CH2COOH
Q.61 Hydrogen ion concentration in mol / L in a solution of Q.73 Of the five isomeric hexanes, the isomer which can give
pH = 5.4 will be two monochlorinated compounds is
(A) 3.98 × 108 (B) 3.88 ×106 (A) n-hexane (B) 2, 3-dimethylbutane
(3) 3.68 × 10–6 (4) 3.98 ×10–6 (C) 2,2-dimethylbutane (D) 2-methylpentane
Q.62 If we consider that 1/6, in place of 1/12; mass of carbon Q.74 Which of the following statements in relation to the
atom is taken to be the relative atomic mass unit, the mass hydrogen atom is correct?
of one mole of a substance will – (A) 3s orbital is lower in energy than 3p orbital
(1) Decrease twice (B) 3p orbital is lower in energy than 3d orbital
(2) Increase two fold (C) 3s and 3p orbitals are of lower energy than 3d orbital
(3) Remain unchanged (D) 3s, 3p and 3d orbitals all have the same energy
(4) Be a function of the molecular mass of the substance Q.75 An organic compound having molecular mass 60 is found
Q.63 Based on lattice energy and other considerations which to contain C = 20%, H = 6.67% and N = 46.67% while rest is
one of the following alkali metal chlorides is expected to oxygen. On heating it gives NH3 alongwith a solid residue.
have the highest melting point – The solid residue give violet colour with alkaline copper
(A) LiCl (B) NaCl sulphate solution. The compound is
(C) KCl (D) RbCl (A) CH3NCO (B) CH3CONH2
Q.64 What is the conjugate base of OH– ? (C) (NH2)2CO (D) CH3CH2CONH2
(A) O2 (B) H2O
(C) O– (D) O–2 PHYSICS
Q.65 The correct order of the thermal stability of hydrogen Q.1 Out of the following pair, which one does NOT have iden-
halides (H – X) is tical dimensions is
(A) HI > HBr > HCl > HF (B) HF > HCl > HBr > HI (A) angular momentum and Planck’s constant
(C) HCl < HF > HBr < HI (D) HI > HCl < HF < HBr (B) impulse and momentum
Q.66 Calomel (Hg2Cl2) on reaction with ammonium hydroxide (C) moment of inertia and moment of a force
gives – (D) work and torque
(A) HgNH2Cl (B) NH2 – Hg – Hg – Cl Q.2 The relation between time t and distance x is t=ax2 + bx
(C) Hg2O (4) HgO where a and b are constants. The acceleration is
Q.67 The IUPAC name of the coordination compound (A) – 2 av3 (B) 2av2
K3[Fe(CN)6] is (C) – 2 av 2 (D) 2bv3
(A) Potassium hexacyanoferrate (II) Q.3 A car, starting from rest, accelerates at the rate f through a
(B) Potassium hexacyanoferrate (III) distance S, then continues at constant speed for time t and
(C) Potassium hexacyanoiron (II) then decelerates at the rate f/2 to come to rest. If the total
(D) tripotassium hexcyanoiron (II) distance traversed is 15 S, then
Q.68 Which of the following compounds shows optical
isomerism? 1 2 1 2
(A) S = ft (B) S = ft
(A) [Cu(NH3)4]+2 (B) [ZnCl4]–2 72 4
(C) [Cr (C2O4)3] –3 (D) [Co(CN)6]–3 1 2
Q.69 Which one of the following cyano complexes would exhibit (C) S = ft (D) S = ft
6
the lowest value of paramagnetic behaviour?
(A) [Cr(CN)6]–3 (B) [Mn(CN)6]–3
(C) [Fe(CN)6] –3 (D) [Co(CN)6]–3
(At. No. Cr = 24, Mn = 25, Fe = 26, Co = 27)
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Q.4 A particle is moving eastwards with a velocity of 5m/s. In Q.11 A spherical ball of mass 20 kg is stationary at the top of a
10s the velocity changes to 5m/s northwards. The average hill of height 100 m. It rolls down a smooth surface to the
acceleration in this time is ground, then climbs up another hill of height 30 m and
(A) zero finally rolls down to a horizontal base at a height of 20 m
above the ground. The velocity attained by the ball is
(B) 1/ 2 ms–2 towards north-west
(A) 40 m/s (B) 20 m/s
(C) 1/ 2 ms–2 towards north-east (C) 10 m/s (D) 1030 m/s
(D) 1/2 ms–2 towards north Q.12 The block of mass M moving on the frictionless horizontal
Q.5 A parachutist after bailing out falls 50 m without friction. surface collides with the spring of spring constant K and
When parachute opens, it decelerates at 2 m/s2. He reaches compresses it by length L. The maximum momentum of the
the ground with a speed of 3 m/s. At what height, did he block after collision is
bail out ?
(A) 91 m (B) 182 m
(C) 293 m (D) 111 m
Q.6 A block is kept on a frictionless inclined surface with angle
of inclination ''. The incline is given an acceleration 'a' to
keep the block stationary. Then 'a' is equal to

KL2 ML2
(A) MK L (B) (C) zero (D)
2M K
Q.13 A mass 'm' moves with a velocity 'v' and collides
inelastically with another identical mass. After collision
a
( the Ist mass moves with velocity v / 3 in a direction
(A) g / tan  (B) g cosec  perpendicular to the initial direction of motion. Find the
(C) g (D) g tan  speed of the 2nd mass after collision.
Q.7 A particle of mass 0.3 kg is subjected to a force F = – kx
with k = 15 N/m. What will be its initial acceleration if it is v/ 3
released from a point 20 cm away from the origin ? after
collision
(A) 3 m/s2 (B) 15 m/s2
(C) 5 m/s 2 (D) 10 m/s2
before m
Q.8 A smooth block is released at rest on a 45º incline and then
slides a distance 'd'. The time taken to slide is 'n' times as collision
much to slide on rough incline than on a smooth incline. (A) v (B) 3 v
The coefficient of friction is
2
(C) v (D) v / 3
1 1 3
(A) µK = 1 – (B) µk= 1  2
n2 n Q.14 An annular ring with inner and outer radii R1 and R2 is
rolling without slipping with a uniform angular speed. The
1 1 ratio of the forces experienced by the two particles situated
(C) µS = 1  (D) µS = 1  2
n on the inner and outer parts of the ring, F1/F2 is –
n2
Q.9 The upper half of an inclined plane with inclination  is 2
R2  R1  R1
perfectly smooth while the lower half is rough. A body (A) R (B)  (C) 1 (D) R
starting from rest at the top will again come to rest at the 1  R 2  2
bottom if the coefficient of friction for the lower half is Q.15 The moment of inertia of uniform semicircular disc of mass
given by M and radius r about a line perpendicular to the plane of
(A) 2 sin  (B) 2 cos  the disc through the centre is
(C) 2 tan  (D) tan 
1 2 1
Q.10 A body of mass m is accelerated uniformly from rest to a (A) Mr 2 (B) Mr 2 (C) Mr2 (D) Mr
2
speed v in a time T. The instantaneous power delivered to 4 5 2
the body as a function of time is given by Q.16 A 'T' shaped object with dimensions shown in the figure, is

lying on a smooth floor. A force ' F ' is applied at the point
mv 2 mv 2 1 mv2 1 mv2 2
(A) .t (B) . t 2 (C) .t (D) .t P parallel to AB, such that the object has only the
T2 T2 2 T2 2 T2 translational motion without rotation. Find the location of

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P with respect to C. Q.23 If 'S' is stress and 'Y' is Young's modulus of material of a
wire, the energy stored in the wire per unit volume is
 (A) 2S2Y (B) S2/2Y
A (C) 2Y/S 2 (D) S/2Y
B
Q.24 A 20 cm long capillary tube is dipped in water. The water
P rises upto 8 cm. If the entire arrangement is put in a freely
2 falling elevator the length of water column in the capillary
F tube will be
(A) 8 cm (B) 10 cm
(C) 4 cm (D) 20 cm
C Q.25 The figure shows a system of two concentric spheres of
radii r 1 and r 2 and kept at temperatures T 1 and T 2
2 3 4 respectively. The radial rate of flow of heat in a substance
(A)  (B)  (C)  (D) 
3 2 3 between the two concentric spheres is proportional to
Q.17 Average density of the earth
(A) does not depend on g
(B) is a complex function of g
(C) is directly proportional to g
r1 T1
(D) is inversely proportional to g
Q.18 The change in the value of 'g' at a height 'h' above the
surface of the earth is the same as at a depth 'd' below the r2 T2
surface of earth. When both 'd' and 'h' are much smaller
than the radius of earth, then which one of the following is
(A) (r2 – r1)/(r1r2) (B) ln (r2/r1)
correct ?
(A) d = h/2 (B) d = 3h/2 r1r2
(C) d = 2h (D) d = h (C) (r  r ) (D) (r2 – r1)
2 1
Q.19 A particle of mass 10 g is kept on the surface of a uniform
Q.26 A gaseous mixture consists of 16 g of helium and 16 g of
sphere of mass 100 kg and radius 10 cm. Find the work to
oxygen. The ratio Cp/Cv of the mixture is –
be done against the gravitational force between them to
(A) 1.59 (B) 1.62
take the particle far away from the sphere
(C) 1.4 (D) 1.54
(Take G = 6.67 × 10–11 Nm2 / kg2)
Q.27 Which of the following is incorrect regarding the first law
(A) 13.34 × 10–10 J (B) 3.33 × 10–10 J
–9 of thermodynamics?
(C) 6.67 × 10 J (D) 6.67 × 10–10 J
2 (A) It is not applicable to any cyclic process
Q.20 The function sin (t) represents
(B) It is a restatement of the principle of conservation of
(A) a periodic, but not simple harmonic motion with a period
energy
2/
(C) It introduces the concept of the internal energy
(B) a periodic, but not simple harmonic motion with a period
(D) It introduces the concept of the entropy
/
Q.28 The temperature-entropy diagram of a reversible engine
(C) a simple harmonic motion with a period 2/
cycle is given in the figure. Its efficiency is
(D) a simple harmonic motion with a period /
T
Q.21 If a simple harmonic motion is represented by

d2 x
 x = 0, its time period is 2T0
dt 2

2 2 T0
(A) (B)
 
(C) 2 (D) 2
Q.22 The bob of a simple pendulum is a spherical hollow ball S
S0 2S0
filled with water. A plugged hole near the bottom of the (A) 1/2 (B) 1/4
oscillating bob gets suddenly unplugged. During (C) 1/3 (D) 2/3
observation, till water is coming out, the time period of Q.29 A system goes from A to B via two processes I and II as
oscillation would shown in the figure. If U1 and U2 are the changes in
(A) first increases and then decrease to the original value internal energies in the processes I and II respectively, the
(B) first decrease and then increase to the original value
(C) remain unchanged
(D) increase towards a saturation value
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capacitance is –
P (A) (n – 1)C (B) (n + 1)C
II
(C) C (D) nC
B Q.35 A moving coil galvanometer has 150 equal divisions. Its
A current sensitivity is 10 divisions per milliampere and
I voltage sensitivity is 2 divisions per millivolt. In order that
V each division reads 1 volt, the resistance in ohms needed
to be connected in series with the coil will be
(A) U1 = U2 (A) 103 (B) 105
(B) relation between U1 and U2 can not be determined (C) 99995 (D) 9995
(C) U2 > U1 (D) U2 < U1 Q.36 In the circuit, the galvanometer G shows zero deflection. If
Q.30 A charged ball B hangs from a silk thread S which makes an the batteries A and B have negligible internal resistance,
angle  with a large charged conducting sheet P, as shown the value of the resistor R will be –
in the figure. The surface charge density  of the sheet is
proportional to - 500
G

12V B R A 2V

(A) 200  (B) 100 


(C) 500  (D) 1000 
Q.37 Two sources of equal emf are connected to an external
resistance R. The internal resistances of the two sources
(A) cos  (B) cot  are R1 and R2(R2 > R1). If the potential difference across
(C) sin  (D) tan  the source having internal resistance R2 is zero, then –
Q.31 Two point charges +8q and –2q are located at x = 0 and x=L (A) R = R2 × (R1 + R2)/(R2 – R1)
respectively. The location of a point on the x axis at which (B) R = R2 – R1
the net electric field due to these two point charges is zero (C) R = R1R2/(R1 + R2) (D) R = R1R2/(R2 – R1)
is Q.38 An energy source will supply a constant current into the
(A) 2 L (B) L/4 load if its internal resistance is –
(C) 8 L (D) 4 L (A) equal to the resistance of the load
Q.32 Two thin wire rings each having a radius R are placed at a (B) very large as compared to the load resistance
distance d apart with their axes coinciding. The charges (C) zero
on the two rings are +q and –q. The potential difference (D) non-zero but less than the resistance of the load
between the centres of the two rings is Q.39 In a potentiometer experiment the balancing with a cell is at
1  length 240 cm. On shunting the cell with a resistance of 2
Q 1
(A) QR/40d2 (B) 2     , the balancing length becomes 120 cm. The internal
0  R R  d2
2  resistance of the cell is –
(A) 1  (B) 0.5 
Q 1 1  (C) 4  (D) 2 
(C) zero (D) 4    
 R Q.40 Two concentric coils each of radius equal to 2 cm. are
0 R  d2
2 
placed at right angles to each other. 3 ampere and 4 ampere
Q.33 A fully charged capacitor has a capacitance 'C'. It is are the currents flowing in each coil respectively. The mag-
discharged through a small coil of resistance wire embedded netic induction in Weber/m2 at the centre of the coils will
in a thermally insulated block of specific heat capacity 's' be (µ0 = 4 × 10–7 Wb/A.m)
and mass 'm'. If the temperature of the block is raised by (A) 5 × 10–5 (B) 7 × 10–5
'T', the potential difference 'V' across the capacitance is – (C) 12 × 10–5 (D) 10–5
m C T
Q.41 A uniform electric field and a uniform magnetic field are
2m CT
(A) (B) produced, pointed in the same direction. An electron is
s s projected with its velocity pointing in the same direction
msT
(A) The electron will turn to its right
2msT
(C) (D) (B) The electron will turn to its left
C C (C) The electron velocity will increase in magnitude
Q.34 A parallel plate capacitor is made by stacking n equally (D) The electron velocity will decrease in magnitude
spaced plates connected alternatively. If the capacitance
between any two adjacent plates is 'C' then the resultant

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Q.42 A charged particle of mass m and charge q travels on a Q.49 The phase difference between the alternating current and
circular path of radius r that is perpendicular to a magnetic emf is /2. Which of the following cannot be the constituent
field B. The time taken by the particle to complete one of the circuit ?
revolution is – (A) C alone (B) R L
(C) L C (D) L alone
2qB 2m 2mq 2 q 2 B Q.50 A fish looking up through the water sees the outside world
(A) (B) (C) (D)
m qB B m contained in a circular horizon. If the refractive index of
Q.43 Two thin, long, parallel wires, separated by a distance ‘d’ water is 4/3 and the fish is 12 cm below the surface, the
carry a current of ‘i’ A in the same direction. They will radius of this circle in cm is
(A) 367 (B) 36/7
(C) 365 (D) 45
 0i2 Q.51 Two point white dots are 1 mm apart on a black paper. They
(A) Attract each other with a force of
2d 2 are viewed by eye of pupil diameter 3 mm. Approximately,
what is the maximum distance at which these dots can be
0 i 2 resolved by the eye ? [Take wavelength of light = 500 nm]
(B) Repel each other with a force of (A) 5 m (B) 1 m
2d 2
(C) 6 m (D) 3 m
0 i 2 Q.52 A Young's double slit experiment uses a monochromatic
(C) Attract each other with a force of source. The shape of the interference fringes formed on a
2d
screen is -
0 i 2 (A) hyperbola (B) circle
(D) Repel each other with a force of (C) straight line (D) parabola
2d
Q.53 If I0 is the intensity of the principle maximum in the single
Q.44 A magnetic needle is kept in a non-uniform magnetic field.
slit diffraction pattern, then what will be its intensity when
It experiences–
the slit width is doubled ?
(A) a torque but not a force
(A) 2I0 (B) 4I0
(B) neither a force nor a torque
(C) I0 (D) I0/2
(C) a force and a torque
Q.54 When an unpolarized light of intensity I0 is incident on a
(D) a force but not a torque
polarizing sheet, the intensity of the light which does not
Q.45 A coil of inductance 300 mH and resistance 2 is connected
get transmitted is -
to a source of voltage 2 V. The current reaches half of its
steady state value in 1 1
(A) I I (B)
(A) 0.05 s (B) 0.1 s 2 0 4 0
(C) 0.15 s (D) 0.3 s (C) 0 (D) I0
Q.46 The self inductance of the motor of an electric fan is 10 H. Q.55 The diagram shows the energy levels for an electron in a
In order to impart maximum power at 50 Hz, it should be certain atom. Which transition shown represents the
connected to a capacitance of – emission of a photon with the most energy ?
(A) 4µF (B) 8µF n=4
(C) 1µF (D) 2µF n=3
Q.47 One conducting U tube can slide inside another as shown n=2
in figure, maintaining electrical contacts between the tubes.
The magnetic field B is perpendicular to the plane of the
figure. If each tube moves towards the other at a constant n=1
I II III IV
speed V, then the emf induced in the circuit in terms of B,  (A) III (B) IV
and V where  is the width of each tube, will be – (C) I (D) II
Q.56 If the kinetic energy of a free election doubles, its deBroglie
wavelength changes by the factor
(A) 1/2 (B) 2
1
(C) (D) 2
(A) BV (B) –BV 2
(C) zero (D) 2BV 27
Q.57 If radius of the 13 Al nucleus is estimated to be 3.6 Fermi
Q.48 A circuit has a resistance of 12 ohm and an impedance of
15 ohm. The power factor of the circuit will be – then the radius of 125 nucleus be nearly
52 Te
(A) 0.8 (B) 0.4 (A) 6 fermi (B) 8 fermi
(C) 1.25 (D) 0.125 (C) 4 fermi (D) 5 fermi

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7 (C) body C
Q.58 A nuclear transformation is denoted by X(n, ) 3 Li . (D) body B
Which of the following is the nucleus of element of X ? Q.68 Consider a car moving on a straight road with a speed of
10 100 m/s. The distance at which car can be stopped is
(A) 12C6 (B) 5 B
[µk = 0.5]
(C) 95 B (D) 11
4 Be
(A) 800 m (B) 1000 m
Q.59 A photocell is illuminated by a small bright source placed 1 (C) 100 m (D) 400 m
m away. When the same source of light is placed 1/2 m Q.69 Two simple harmonic motions are represented by the
away, the number of electrons emitted by photocathode  
would – equation y1  0.1sin 100t   and y2 = 0.1 cos t. The
3
(A) decrease by a factor of 4 (B) increase by a factor of 4
phase difference of the velocity of particle 1 w.r.t. the
(C) decrease by a factor of 2 (D) increase by a factor of 2
velocity of the particle 2 is –
Q.60 The intensity of gamma radiation from a given source is I.
(A) –/6 (B) /3
On passing through 36 mm of lead, it is reduced to I/8. The
(C) –/3 (4) /6
thickness of lead which will reduce the intensity to I/2 will
Q.70 A thin glass (refractive index 1.5) lens has optical power of
be
– 5D in air. Its optical power in a liquid medium with refractive
(A) 6 mm (B) 9 mm
index 1.6 will be
(C) 18 mm (D) 12 mm
(A) 1 D (B) –1D
Q.61 Starting with a sample of pure 66Cu, 7/8 of it decays into
(C) 25 D (D) – 25 D
Zn in 15 minutes. The corresponding half-life is
Q.71 Two voltameters one of copper and another of silver, are
(A) 10 min (B) 15 min
joined in parallel. When a total charge q flows through the
(C) 5 min (D) 7½ min
voltameters, equal amount of metals are deposited.If the
Q.62 The electrical conductivity of a semiconductor increases
electrochemical equivalents of copper and silver are z1 and
when electromagnetic radiation of wavelength shorter than
z2 respectively the charge which flows through the silver
2480 nm is incident on it. The band gap in (eV) for the
voltameter is –
semiconductor is
(A) 1.1 eV (B) 2.5 eV q q
(C) 0.5 eV (D) 0.7 eV (A) (B)
z z
Q.63 In a full wave rectifier circuit operating from 50 Hz mains 1 1 1 2
z2 z1
frequency, the fundamental frequency in the ripple would
be z1 z2
(A) 50 Hz (B) 25 Hz (C) q (D) q
z2 z1
(C) 100 Hz (D) 70.7 Hz
Q.64 In a common base amplifier the phase difference between Q.72 A heater coil is cut into two equal parts and only one part
the input signal voltage and output voltage is is now used in the heater. The heat generated will now be
(A) /4 (B)  (A) doubled (B) four times
(C) 0 (D) /2 (C) one fourth (D) halved
Q.65 A projectile can have the same range R for two angles of Q.73 When two tuning forks (fork 1 and fork 2) are sounded
projection. If t1 and t2 be the times of flights in the two simultaneously, 4 beats per second are heard. Now, some
cases, then the product of the two time of flights is tape is attached on the prong of the fork 2. When the
proportional to – tuning forks are sounded again, 6 beats per seconds are
(A) R2 (B) 1/R2 heard. If the frequency of fork 1 is 200 Hz, then what was
(C) 1/R (D) R the original frequency of fork 2?
Q.66 A bullet fired into a fixed target loses half of its velocity (A) 200 Hz (B) 202 Hz
after penetrating 3cm. How much further it will penetrate (C) 196 Hz (D) 204 Hz
before coming to rest assuming that it faces constant Q.74 An observer moves towards a stationary source of sound,
resistance to motion? with a velocity one fifth of the velocity of sound. What is
(A) 3.0 cm (B) 2.0 cm the percentage increase in the apparent frequency?
(C) 1.5 cm (D) 1.0 cm (A) zero (B) 0.5%
Q.67 A body A of mass M while falling vertically downwards (C) 5% (D) 20%
under gravity breaks into two parts; a body B of mass Q.75 The resistance of hot tungsten filament is about 10 times
1/3 M and a body C of mass 2/3 M. The centre of mass of the cold resistance. What will be the resistance of 100 W
bodies B and C taken together shifts compared to that of and 200 V lamp when not in use?
body A towards (A) 40  (B) 20 
(A) depends on height of breaking (C) 400  (D) 200 
(B) does not shift

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MATHEMATICS   
Q.1 Let f : (–1, 1)  B, be a function defined by Q.12 If x =  a n , y =  bn , z =  cn where a, b, c are in
n 0 n 0 n 0
2x
f(x) = tan–1 , then f is both one-one and onto when A.P. and | a | < 1, | b | < 1, | c | < 1 then x, y, z are in -
1  x2
B is the interval - (A) GP (B) AP
(A) (0, /2) (B) [0, /2) (C) AGP (D) HP
(C) [–/2, /2] (D) (–/2, /2) Q.13 If in a ABC, the altitudes from the vertices A, B, C on
Q.2 A real valued function f(x) satisfies the functional equation opposite sides are in H.P., then sin A, sin B, sin C are in
f(x – y) = f(x) f(y) – f (a – x) f(a + y) where a is a given (A) G.P. (B) A.P.
constant and f(0) = 1, then f(2a – x) is equal to - (C) AGP (D) H.P.
(A) –f(x) (B) f(x) Q.14 If the coefficients of rth, (r + 1)th and (r + 2)th terms in the
(C) f(a) + f(a – x) (D) f(–x) binomial expansion of (1 + y)m are in A.P., then m and r
Q.3 Let R = {(3, 3), (6, 6), (9, 9), (12, 12), (6, 12), (3, 9), (3, 12), (3, satisfy the equation -
6)}, be relation on the set A = {3, 6, 9, 12} . The relation is - (A) m2 –m (4r – 1) + 4r2 – 2 = 0
(A) reflexive and transitive only (B) m2 – m (4r + 1) + 4r2 + 2 = 0
(B) reflexive only (C) an equilvalence relation (C) m2 – m (4r + 1) + 4r2 – 2 = 0
(D) reflexive and symmetric only (D) m2 – m (4r – 1) + 4r2 + 2 = 0
Q.4 In a triangle ABC, let C = /2. If r is the in-radius and R is 11
the circumradius of the triangle ABC, then 2(r + R) equals -  2  1 
Q.15 If the coefficient of x 7 in  ax     equals the
 bx 
(A) b + c (B) a + b 11
(C) a + b + c (D) c + a   1 
coefficient of x–7 in  ax   2   , then a and b satisfy
Q.5 The value of a for which the sum of the squares of the   bx  
roots of the equation x2 – (a – 2) x – a – 1 = 0 assume the the relation -
least value is- (A) a – b = 1 (B) a + b = 1
(A) 1 (B) 0 (C) a/b = 1 (D) ab = 1
(C) 3 (D) 2 Q.16 If x is so small that x2 and higher power of x may be
Q.6 If the roots of the equation x2 – bx + c =0 be two consecutive
integers, then b2 – 4c equals - (1  x)3/2  (1  x / 2)3
neglected, then may be
(A) –2 (B) 3 (1  x)1/2
(C) 2 (D) 1 approximated as –
Q.7 In a triangle PQR, R =/2, If tan (P/2) and tan (Q/2) are the
roots of ax2 + bx + c = 0, a  0 then - 3 2 3 2
(A) 1  x (B) 3x  x
(A) a = b + c (B) c = a + b 8 8
(C) b = c (D) b = a + c
3 2 x 3 2
Q.8 If both the roots of the quadratic equation (C)  x (D)  x
x2 – 2kx + k2 + k – 5 = 0 are less than 5, then k lies in the 8 2 8
interval Q.17 If the letters of the word SACHIN are arranged in all possible
(A) (5, 6] (B) (6, ) ways and these words are written out as in dictionary, then
(C) (–, 4) (D) [4, 5] the word SACHIN appears at serial number -
Q.9 If z1 and z2 are two non-zero complex numbers such that (A) 601 (B) 600
| z1 + z2 | = | z1 | + | z2 |, then arg z1 – arg z2 is equal to - (C) 603 (D) 602
6
(A) /2 (B) – Q.18 The value of 50C4 +  56 r C3 is -
(C) 0 (D) –/2 r 1

z
(A) 55C4 (B) 55C3
56 (D) 56C4
Q.10 If w  and | w | = 1, then z lies on (C) C3
1
z i Q.19 Let P be the point (1, 0) and Q be a point on the curve
3 y2 = 8x. The locus of mid point of PQ is –
(A) an ellipse (B) a circle (A) y2 – 4x + 2 = 0 (B) y2 + 4x + 2 = 0
(C) a straight line (D) a parabola 2
(C) x + 4y + 2 = 0 (D) x2 – 4y + 2 = 0
Q.11 If the cube roots of unity are 1, , 2 then the roots of the Q.20 If a vertex of a triangle is (1, 1) and the mid points of two
equation (x – 1)3 + 8 = 0, are - sides through this vertex are (–1, 2) and (3, 2), then the
(A) –1, –1 + 2, – 1 – 22 (B) –1, –1, –1 centroid of the triangle is -
(C) –1, 1 – 2, 1 – 22 (D) –1, 1 + 2, 1 + 22 (A) (–1, 7/3) (B) (–1/3, 7/3)
(C) (1, 7/3) (D) (1/3, 7/3)
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Q.21 The line parallel to the x-axis and passing through the in- following holds for all n  1, by the principle of mathematical
tersection of the lines ax + 2by + 3b = 0 and bx – 2ay–3a= 0, induction -
where (a, b)  (0, 0) is - (A) An = nA – (n – 1) I (B) An = 2n–1 A – (n – 1) I
(A) below the x-axis at a distance of 3/2 from it n
(C) A = nA + (n – I) I (D) An = 2n–1A + (n – 1) I
(B) below the x-axis at a distance of 2/3 from it Q.31 If a1, a2, a3,......, an,..... are in G.P., then the value of the
(C) above the x-axis at a distance of 3/2 from it
(D) above the x-axis at a distance of 2/3 from it log a n log a n 1 log a n  2
Q.22 If non-zero numbers a, b, c are in H.P., then the straight line log a n  3 log a n  4 log a n 5
determinant , is-
x y 1 log a n  6 log a n  7 log a n 8
+ + = 0 always passes through a fixed point that
a b c (A) 0 (B) 1
point is – (C) 2 (D) – 2
(A) (–1, 2) (B) (–1, –2) Q.32 The system equations x + y + z =  – 1, x + y + z =  – 1,
(C) (1, – 2) (D) (1, –1/2) x + y + z =  – 1 has no solution, if  is -
Q.23 If the circles x2 + y2 + 2ax + cy + a = 0 and (A) –2 (B) either –2 or 1
x2 + y2 – 3ax + dy – 1 = 0 intersect in two distinct point P (C) not – 2 (D) 1
and Q then the line 5x + by – a = 0 passes through P and Q Q.33 If a2 + b2 + c2 = – 2 and f(x) =
for -
(A) exactly one value of a (B) no value of a 1 a2x (1  b2 )x (1  c2 )x
(C) infinitely many values of a (1  a 2 )x 1  b2x (1  c2 )x
then f(x) is a polynomial of
(D) exactly two values of a (1  a 2 )x (1  b2 )x 1  c2 x
Q.24 A circle touches the x-axis and also touches the circle with
centre at (0, 3) and radius 2. The locus of the centre of the degree -
circle is- (A) 1 (B) 0
(A) an ellipse (B) a circle (C) 3 (D) 2
(C) a hyperbola (D) a parabola Q.34 Let  and  be the distinct roots of ax2 + bx + c = 0, then
Q.25 If a circle passes through the point (a, b) and cuts the circle
x2 + y2 = p2 orthogonally, then the equation of the locus of 1  cos (ax 2  bx  c)
lim is equal to -
its centre is - x  (x   )2
(A) x2 + y2 – 3ax – 4by + (a2 + b2 – p2) = 0
(B) 2ax + 2by – (a2 – b2 + p2) = 0 a2
(C) x2 + y2 – 2ax – 3by + (a2 – b2 – p2) = 0 (A) ( – )2 (B) 0
2
(D) 2ax + 2by – (a2 + b2 + p2) = 0
Q.26 If the pair of lines ax2 + 2 (a + b)xy + by2 = 0 lie along a 2 1
diameters of a circle and divide the circle into four sectors (C) ( – )2 (D) ( – )2
2 2
such that the area of one of the sectors is thrice the area of
Q.35 If f is a real-valued differentiable function satisfying
another sector then –
| f(x) – f (y) |  (x – y)2, x, y  R and f(0) = 0, then f(1) equals
(A) 3a2 – 10ab + 3b2 = 0 (B) 3a2 – 2ab + 3b2 = 0
2 2 (A) –1 (B) 0
(C) 3a + 10ab + 3b = 0 (D) 3a2 + 2ab + 3b2 = 0
(C) 2 (D) 1
Q.27 The locus of a point P(, ) moving under the condition
Q.36 Suppose f(x) is differentiable at x = 1 and
that the line y = x +  is a tangent to the hyperbola
lim 1 f(1 + h) = 5, then f(1) equals -
x2 y2 h0 h
– = 1 is-
a 2 b2 (A) 3 (B) 4
(A) an ellipse (B) a circle (C) 5 (D) 6
(C) a parabola (D) a hyperbola Q.37 If the equation anxn + an–1 xn–1 + .... + a1x = 0 ; a1  0, n 2,
y has a positive root x = , then the equation
Q.28 If cos–1x – cos–1 = , then 4x2 – 4xy cos  + y2 is equal to- nanxn–1 + (n – 1) an–1 xn–2 + .... + a1 = 0 has a positive root,
2
which is -
(A) 2 sin 2 (B) 4
(A) greater than  (B) smaller than 
(C) 4 sin2  (D) – 4 sin2 
2 (C) greater than or equal to (D) equal to 
Q.29 If A – A + I = 0, then the inverse of A is -
Q.38 The normal to the curve x = a (cos  +  sin ),
(A) A + I (B) A
y = a (sin  –  cos ) at any point '' is such that -
(C) A – I (D) I – A
(A) it passes through the origin
1 0  1 0  
Q.30 If A = 1 1  and I =  0 1  , then which one of the (B) it makes anlge +  with the x-axis
    2

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   
cos 2 x
(C) it passes through  a , a 
2 Q.45 The value of  1 ax
dx, a > 0, is -

(D) it is at a constant distance from the origin.
Q.39 A spherical iron ball 10 cm in radius is coated with a layer (A) a (B) /2
of ice of uniform thickness that melts at a rate of 50 cm3/ (C) /a (D) 2
min. When the thickness of ice is 5 cm, then the rate of Q.46 Area of the greatest rectangle that can be inscribed in the
which the thickness of ice decreases, is -
x2 y2
ellipse  2 = 1 is -
1 1 a2
b
(A) cm/min. (B) cm/min.
36 18 (A) 2ab (B) ab
1 5 (C) ab (D) a/b
(C) cm/min. (D) cm/min.
54 6 Q.47 The area enclosed between the curve y = loge (x + e) and
Q.40 A function is matched below against an interval whre it is the coordinate axes is -
supposed to be increasing. Which of the follownig pairs is (A) 1 (B) 2
incorrectly matched ? (C) 3 (D) 4
interval function Q.48 The parabolas y2 = 4x and x2 = 4y divide the square region
(A) (–, ) x3 + 6x2 + 6 bounded by the lines x = 4, y = 4 and the coordinate axes.
(B) [2, ) 3x2 – 2x + 1 If S1, S2, S3 are respectively the areas of these parts
(C) (–, –4] x3 – 3x2 + 3x + 3 numbered from top to bottom; then S1 : S2 : S3 is -
(A) 1 : 2 : 1 (B) 1 : 2 : 3
 1 (C) 2 : 1 : 2 (D) 1 : 1 : 1
(D)  ,  2x3 – 3x2 – 12x + 6
3 Q.49 Let f (x) be a non-negative continuous function such that
2
the area bounded by the curve y = f (x), x-axis and the
 (log x  1)  ordinates x = /4 and x =  > /4 is
Q.41  1  (log x)2  dx is equal to -     
 
  sin   cos   2 . Then f   is -
4 2
log x x
(A) +C (B) +C  
(log x) 2  1 2
x 1  
(A)   2  1 (B)   2  1
4 4
xe x x
(C) +C (D) +C      
1 x 2 (log x) 2  1 (C) 1   2  (D) 1   2 
4 4
1 1 2 4 1
Q.42 Lim  sec2  sec 2

 .....  sec2 1 equals
Q.50 The differential equation representing the family of curves
2 2 2 2 n
n  n n n n  y2 =2c (x + c ), where c > 0, is a parameter, is of order and
1 1 degree as follows -
(A) sec 1 (B) cosec 1 (A) order 1, degree 2 (B) order 1, degree 1
2 2
(C) order 1, degree 3 (D) order 2, degree 2
(C) tan 1 (D) (1/2) tan 1
dy
1 1 2 Q.51 If x = y (log y – log x + 1), then the solution of the
x2 x3 x2 2
3 dx
Q.43 If I1 =  2 dx, I2 =  2 dx, I3 =  2 dx &I4 =  2x dx equation is -
0 0 1
1 (A) y log (x/y) = cx (B) x log (y/x) = cy
then - (C) log (y/x) = cx (D) log (x/y) = cy
(A) I2 > I1 (B) I1 > I2    
(C) I3 = I4 (D) I3 > I4 Q.52 For any vector a , | a × î |2 + | a × ĵ |2 + | a × k̂ |2 is equal to
Q.44 Let f : R  R be a differentiable function having f(2) = 6,  
(A) | a |2 (B) 2| a |2
f (x ) 
 1 4t 3 (C) 3| a |2 (D) None of these
f (2) =   . Then xLt
2
 x  2 dt equals - Q.53 If C is the mid point of AB and P is any point outside AB,
48 6 then -
(A) 24 (B) 36      
(A) PA + PB = 2 PC (B) PA + PB = PC
(C) 12 (D) 18      
(C) PA + PB + 2 PC = 0 (D) PA + PB + PC = 0

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   (A) f (6)  8 (B) f (6) < 8
Q.54 If a , b , c are non-coplanar vectors and  is a real number
(C) f (6) < 5 (4) f (6) = 5
      Q.64 If the plane 2ax – 3ay + 4az + 6 = 0 passes through the
then [ (a  b)  2 b c] = [ a b  c b ] for -
midpoint of the line joining the centres of the spheres
(A) exactly one value of  (B) no value of 
x2 + y2 + z2 + 6x – 8y – 2z = 13 and
(C) exactly three values of  (D) exactly two values of 
x2 + y2 + z2 – 10x + 4y – 2z = 8, then a equals
x  1 y 1 z  2 (A) – 1 (B) 1
Q.55 If the angle  between the line   and
1 2 2 (C) – 2 (D) 2
Q.65 An ellipse has OB as semi minor axis, F and F' its focii and
the plane 2x – y +  z + 4 = 0 is such that the angle FBF' is a right angle. Then the eccentricity of the
sin  = 1/3 the value of  is – ellipse is –
(A) 5/3 (B) –3/5
(A) 1/ 2 (B) 1/2
(C) 3/4 (D) – 4/3
Q.56 The angle between the lines 2x = 3y = – z and (C) 1/4 (D) 1/ 3
6x = – y = – 4z is-
Q.66 Let a, b and c be distinct non-negative numbers. If the
(A) 0º (B) 90º
(C) 45º (D) 30º vectors aiˆ  ajˆ  ck,
ˆ iˆ  kˆ and ciˆ  cjˆ  bkˆ lie in a plane,

Q.57 The distance between the line r = 2 î – 2 ĵ + 3 k̂ + ( î – ĵ + then c is –


(A) the Geometric Mean of a and b
4 k̂ ) and the plane r .( î + 5 ĵ + k̂ ) = 5 is - (B) the Arithmetic Mean of a and b
(C) equal to zero
10 (D) the Harmonic Mean of a and b
(A) 10/9 (B) 
3 3 
Q.67 Let a  ˆi  k,ˆ b  xiˆ  ˆj  (1  x) kˆ and
(C) 3/10 (D) 10/3
 
Q.58 Three houses are available in a locality. Three persons c  yiˆ  xjˆ  (1  x  y) kˆ . Then [a b c] depends on –
apply for the houses. Each applies for one house without (A) only y (B) only x
consulting others. The probability that alll the three apply (C) both x and y (D) neither x nor y
for the same house is - Q.68 A random variable X has Poisson distribution with mean 2.
(A) 2/9 (B) 1/9 Then P (X > 1.5) equals –
(C) 8/9 (D) 7/9
2
Q.59 Let A and B be two events such that P ( A  B ) = 1/6, (A) 2 (B) 0
e
P (A  B) = 1/4 and P ( A ) = 1/4, where A stands for
complement of event A. Then events A and B are 3 3
(C) 1  2 (D) 2
(A) equally likely and mutually exclusive e e
(B) equally likely but not independent Q.69 A lizard, at an initial distance of 21 cm behind an insect,
(C) independent but not equally likely moves from rest with an acceleration of 2 cm/s2 and pursues
(D) mutually exclusive and independent the insect which is crawling uniformly along a straight line
Q.60 If in a frequency distribution, the mean and median are 21 at a speed of 20 cm/s. Then the lizard will catch the insect
and 22 respectively, then its mode is approximately after
(A) 22.0 (B) 20.5 (A) 20 s (B) 1 s
(C) 25.5 (D) 24.0 (C) 21 s (D) 24 s
Q.70 Two points A and B move from rest along a straight line
Q.61 Let x1, x2, ..... xn be n observations such that  xi2 = 400
with constant acceleration f and f ' respectively. If A takes
and  xi = 80. Then a possible value of n among the m sec. more than B and describes n units more than B in
following is acquiring the same speed then
(A) 15 (B) 18 (A) (f - f ') m2 = ff ' n (B) (f + f ') m2 = ff 'n
(C) 9 (D) 12 1 1
   (C) (f  f ) m  ff n 2 (D) (f  f  ) n  ff m
2
Q.62 ABC is a triangle. Forces P, Q, R acting along IA, IB and 2 2
IC respectively are in equilibrium, where I is the incentre of Q.71 A and B are two like parallel forces. A couple of moment H
ABC. Then P : Q : R is lies in the plane of A and B and is contained with them. The
(A) sin A : sin B : sin C (B) sin A/2 : sin B/2 : sin C/2 resultant of A and B after combining is displaced through
(C) cos A/2: cos B/2 :cos C/2 (D) cos A : cos B : cos C a distance
Q.63 Let f be differentiable for all x. If f (1) = – 2 and f '(x)  2 for 2H H H H
x  [1, 6] , then (A) (B) (C) 2 (A  B) (D)
AB AB AB
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Q.72 The resultant R of two forces acting on a particle is at right (2) (D). Isoelectronic  SO32–, CO32–, NO3–
angles to one of them and its magnitude is one third of the 42e–, 32e–, 32e–
other force. The ratio of larger force to smaller one is – (3) (B). B < C < N < O – increasing first ionization enthalpy
(A) 2 : 1 (B) 3 : 2
(4) (A). SnO 2  4HCl
Acid

 SnCl 4  2H 2 O
Base
(C) 3 : 2 (D) 3 : 2 2
Q.73 The sum of the series SnO 2  NaOH 
 NO 2SnO3  H 2 O
Acid Base Sodium
1 1 1 stannate
1    ...........ad inf . is –
4.2! 16.4! 64.6! (5) (C).
e 1 e 1 (6) (C). Zr and Hf have about the same radius
(A) (B) (7) (C). Poorer shielding of 5d electrons by 4f electrons
e e
(8) (B). H2  1s2  do not having unpaired e– therefore it is
e 1 e 1 diamagnetic in nature.
(C) (D) (9) (D). Lattice energy depends upon
2 e 2 e
(a) size of the ion
Q.74 The plane x + 2y – z = 4 cuts the sphere (b) magnitude of charge of ion
x2 + y2 + z2 – x + z – 2 = 0 in a circle of radius size of the ion 
(A) 3 (B) 1 Lattice energy 
(C) 2 (D) 2 (10) (D). XeF4 SF4 CF4
Q.75 A particle is projected from a point O with velocity u at an two lone pair e– 1 – p e– p absent
angle of 60° with the horizontal. When it is moving in a
direction at right angles to its direction at O, its velocity (11) (C). SO32  , CO32 , NO3
then is given by – (12) (B). In calcium carbide, the no. of bonds are one sigma and
(A) u/3 (B) u/2 two pi.
(C) 2u/3 (D) u / 3 (13) (A). It is found that the fraction of molecule with the most
probable speed decreases.
(14) (A).
SOLUTIONS (15) (D). x = 2 – 4 = – 2, thus H < U.
CHEMISTRY (16) (A). Bond dissociation energy = 1 : 1 : 0.5
XY : X2 : Y
ANSW ER KEY Hf of XY = – 200 kJ
So, bond dissociation energy X2 = 200 kJ/mole (Due to
Q 1 2 3 4 5 6 7 8 9 10
same ratio (XY : X2))
A C D B A C C C B D D (17) (B). 2NO2(g) 2NO(g) + O2(g)
Q 11 12 13 14 15 16 17 18 19 20 KC = 1.8 × 10–6, T = 184°C = 184 + 273 = 475 K
A C B A A D A B C B C R = 0.0831 kJ/mol k,
KP = KC.(RT)n
Q 21 22 23 24 25 26 27 28 29 30
KP = KC.(RT)
A A B C D C A D D B B
KP
Q 31 32 33 34 35 36 37 38 39 40  RT . So, K > K
KC P C
A A A C D D B D D B D
(18) (C). Cl2(g) + 3F2(g) 2ClF3(g) ; rH = –329 kJ
Q 41 42 43 44 45 46 47 48 49 50
From the above reaction, the quantity of ClF3 increase
A B A C B D B A A A C with adding F2.
Q 51 52 53 54 55 56 57 58 59 60 (19) (B). With decrease in temperature (increase in 1/T), the
A D A A D D A D A A A value of Keq is increasing. Thus the reaction must be
exothermic.
Q 61 62 63 64 65 66 67 68 69 70
(20) (C). NH4HS(s) NH3(g) + H2S(g)
A D C B D B A B C D B x x
Q 71 72 73 74 75 Already present NH3 = NH3(g) 0.50 atm
A C B B D C So, at equilibrium total pressure = 0.5 + 2x = 0.84
x = 0.17. So, at equilibrium,
(1) (C). From the positive we can find that (d) and (e) having
n = 3 and  = 2 (d-subshell) having same energy. So, we can PNH3 = (0.50 + 0.17) = 0.67; PH 2S  0.17
describe it in absence of magnetic and electrical field.
Hence, KP = PNH3  PH2S  0.67  0.17  0.1139

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(21) (A). For the salt,
2 H O/H
MX2 M+2 + 2X– (33) (C). CH 2  CH 2  CH3CH 2 OH
(s) (2s)
Ksp = 4s3 2 H O/H
CH3  CH  CH 2  CH3CHCH3
4 × 10–12 = 4s3 |
s = 1 × 10–4 M OH
[M+2] = s = 1 × 10–4 M 
(22) (B). [Cr(NH3)4Cl2]+ (2° alcohol) through 2° carbocation CH3 C HCH3
x + 4 × 0 + 2 × (–1) = + 1

x – 2 = +1 ; x = + 3 H 2O/H
CH3  C  CH 2  (CH3)3COH
(23) (C). Cr2O72– + 14H+ + 6I– –––– 2Cr+3 + 7H2O + 3I2 |
CH3
H
H 
H B (3° alcohol) through 3° carbocation (CH3 )3 C
B
(24) (D). H H
A A
H Banana bond B
A
Four 2C – 2e– bonds and two 3C – 2e– bond in B2H6. A

 B B
(25) (C). AlCl3  H 2O 
 Al(OH)3 
 Al2 O3 (34) (D). B
Dryness A
A B
A A

Number of A ion per unit cell = 8/8 = 1


---- Si – O – Si – O – Si ---- Number of B ion per unit cell = 6/2 = 3
Empirical formula = AB3.
O O O (35) (D). Na2SO4 dissociate to give three particle.
i 1
---- Si – O – Si – O – Si ----  = or C = 1 + 2
3 1
(26) (A).
O O O 78 46
(36) (B). n b   1 , nt   0.5
78 92
---- Si – O – Si – O – Si ----
1 0.5 0 75  1
xb  , xt  ; Pb  Pb .x b  = 50 torr..
1.5 1.5 1.5
Each silicon atom is surrounded by four oxygen atom and (37) (D). M1V1 + M2V2 = M3 (V1 + V2)
each oxygen atom to banded to two silicon atom. 720  624
(27) (D). M3  = 1.344 M
1000
(28) (D). If acid is weak its nucleophile is strong.
(38) (D). Equimolar solution in the same solvent have same
(29) (B). Cl is a good leaving group.
boiling and same freezing point.
(30) (B). Benzyl is electron repulsive group hence increase
basicity. 5.12  103
(39) (B). nAl to be deposited = = 189.63
CH3 27
Current required = 3 × 189.63 × 96500 = 5.49 × 107 C
(31) (A). H – C – Cl Optical (40) (D). 0HOAc  0HCl  0NaOAc   0NaCl
= 426.2 + 91.0 – 126.5 = 390.7 S cm2 mole–1
Cl – C – H
(41) (B). A reaction with two different reactants is always a
bimolecular reaction.
CH3
(42) (A). For the first order reaction
(32) (A). CH2 = CHCH = CH2 + HBr  CH3  CHCH  CH 2 2.303 [A ]
t log 0 or t  2.303 log [A 0 ]
| k [A] 1/4
k 3 / 4 [A0 ]
Br
+ CH3CH = CHCH2Br 2.303 4
= log = 2.303 × 0.1249 = 0.2877 = 0.29
k 3

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VC 3 CH3
(43) (C). V  10
S
(44) (B). The disperse phase in colloidal iron (III) hydroxide H+/HOH
and colloidal gold is positively and negatively charged
respectively. MgCl2 solution coagulates, the gold sol move CH(OH)–COOH
readily than the iron (III) hydroxide sol. (54) (D). Chromic anhydride in glacial acetic acid
(45) (D). In electrolytic refining of copper, anode mud having (55) (D). Wurtz reaction for alkanes.
Ag and Au. (56) (A).
(46) (B). Cu2O + Cu2S –––– Cu + SO2
H
(47) (A). In hypophosphorus acid two hydrogen directly at- R R
tach with phosphorus. O+HN N
R R
O
(57) (D). In both DNA and RNA, heterocyclic base and phos-
P phate ester linkage are at C'1 and C'5 respectively of the
H H sugar molecules.
OH O
(48) (A). H = Ef – Eb 5
For H = Positive, Eb < Ef HO – P – O – CH2 O Base-I
4 H 1
(49) (A). We know that, spin only moment = n(n  2) BM. H H
The value of 2.84 correspond to the presence of 2 unpaired H H
3 2
e–. So, d4 system in strong field will adopt this arrange- OH OH
ment as : (58) (A). Antipyretic  Reduce the temp.  Reduce the fever.
eg
eg. Aspirin.
t2g
F F
(50) (C). (59) (A). C=C
(51) (D). Corey-House synthesis F F
Li CuI
(60) (A). Teflon is a fully fluorinated polymer.
RX  R  Li 
 R 2 CuLi (61) (D). pH = – log (H+)
(Alkyl halide) Et 2O (Gilman reagent) (62) (C).
Methyl,1alkyl,
(63) (B). Although lattice energy of LiCl higher than NaCl but
2cycloalkyl R  R   R  Cu  LiX LiCl is covalent in nature and NaCl ionic there after , the
 (Alkane)
R X melting point decreases as we move NaCl because the
(52) (A). lattice energy decreases as a size of alkali metal atom
increases (lattice energy to melting point of alkali metal
CH3 halide).
(64) (D). OH– O–2 + H+
(65) (B).
(53) (A). + CHCl3 + NaOH (66) (A).
Hg2Cl2 + 2NH4OH Hg + Hg (NH2) Cl + NH4Cl + 2H2O
OH (67) (B).

CH3 -3 -3
CH3 OX OX

HCN OH
OX Cr Cr OX
C– CN (68) (C).
CHO
OH OX
OH H OX

(69) (D).

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Br v = ft’
(70) (B). H3C  CH  CH 2  CH3  Br2  |
 H3C  C  CH2  CH3
| a=0 a = –f/2
|
CH 3
CH3 a=f
Major (3) (A). u = 0 S time = t 2S v=0
(71) (C). (72) (B).
15S
CH3 CH3 CH 2 Cl CH3
| | If time taken in first part is t', then
h | |
(73) (B). H3C  C  C  CH3  H C  C — C  CH 
| | 3 3 1
| | S  0  ft 2 .......(i)
H H H H 2
then distance traveled in last part would be = 2S
CH3 CH3 So the distance up to which particle move with constant
| | velocity = 15S – 3S = 12S
H3C  C — C  CH3
| |  1 2
Cl H So, 12S = (ft') t ; 12  ft '  = f tt' ; 6t' = t
2
(74) (D). (75) (C). 2
1  t ft 2
PHYSICS From equation (i), S  f   
2  6 72
ANSW ER KEY 
(4) (B). Initial velocity vi  5iˆ
Q 1 2 3 4 5 6 7 8 9 10

A C A A B C D D A C A Final velocity v f  5jˆ
 
Q 11 12 13 14 15 16 17 18 19 20 v r  vi
Average acceleration a 
A A A C D D C A C D B t
Q 21 22 23 24 25 26 27 28 29 30
 5iˆ  5jˆ 1 ˆ ˆ | a | 1
A B A B D C B A C A D a  ( j  i) ; , direction = N – W
10 2 2
Q 31 32 33 34 35 36 37 38 39 40 (5) (C). v2 = u2 + 2 as v2 = 0 + 2(g) (50)
A A B D A D B B B D A v2 = u2 + 2 as
Q 41 42 43 44 45 46 47 48 49 50 100g = (3)2 + 2(–2)s. So s = 293 m
(6) (D).
A D B C C B C D A B B
If particle is in equilibrium N
Q 51 52 53 54 55 56 57 58 59 60 ma cos  = mg sin 
A A A B A A C A B B D a = g tan  ma
Q 61 62 63 64 65 66 67 68 69 70
(7) (D). F = – kx
A C C C C D D B B A no ne
F  kx
Q 71 72 73 74 75 a 
m m mg
A B A C D A
(1) (C). Moment of inertia [I] = [M1L2T0] (15) (20  102 )
a ; a = –10m/s2
Moment of force [] = [M1L2T–2] 0.3
(2) (A). t = ax2 + bx
1 2
dt 1 (8) (A). On rough surface s = ut + at
So, = 2ax + b. So velocity v = .....(1) 2
dx 2ax  b
1
2a s=0+ [g sin  – g cos ] (nt)2 .........(i)
dv (2a) dx a   v 2
and a   ;
dt (2ax  b) 2 dt (2ax  b) 2 On plane surface
From equation (1), a = –2av3 1
s=0+ (g sin )t2 ....... (ii)
2
1
From (i) and (ii),  1–
n2

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m cm1

cm1
(9) (C). 2s (16) (C).

By work energy theorem Position of cm from O


Wg + Wf = K = 0
m1x1  m 2 x 2 m(2)  (2m) 4
–mg (2s sin ) – (mg cos )s = 0 Xcm    
2 sin – cos = 0 m1  m 2 m  2m 3
= 2 tan  (17) (A). g depends on density of earth, but the reverse is not true.
u=0  2h   d
(10) (A). P = Fv v
time (18) (C). g h  1   ; g d  1  
R R
P = ma v'd gh = gd ; 2h = d
 v  v v
P  m    t a GMm 6.67  1011  100  10  103
 T   T T (19) (D). W = =
R 10  102
v W = 6.67 × 10–10 J
v' = 0 + at ; v '  t
T
1  cos 2t
(11) (A). By energy conservation law, TEi = TEf (20) (B). x = sin2 t ; x 
2
1  k2 
mgh  mv2  1  2   mgh ' 2  
2  R  Frequency f   ; Time period =
2  
But acceleration is not directly proportional to displace-
1 2  2 ment.
(10) (100)  v 1    10  20
2  5
d2 x
7 2 7 2 (21) (B).  x  0
80 dt 2
100  v  200 ; v  800 ; v  10
10 10 7
(12) (A). By energy conservation law Acceleration = – x. So,   
(22) (A). C.M. comes down and then reaches to its initial value.
P2 1 2 1
 KL ; P  MK L
2M 2 (23) (B). Stored energy = × stress × strain × volume
2
(13) (C). By conservation of momentum, pi = pf
stress stress
v ˆ Y  strain 
mv ˆi  m j  mv ' strain Y
3
stored energy 1 S S2
 S 
 ˆj   1 2v volume 2 Y 2Y
v '  v  ˆi   ; | v ' | v 1  
 3 3 3 (24) (D). When g = 0 then water rises up to maximum height.

F1 R1 T2
(14) (D). Force F = m2r ; F  R
2 2 T1
(T1 > T2)
1
(15) (D). Mr 2 r1
2 (25) (C).
r2

In variable cross section case heat flow rate


dQ  dT 
 KA 
dt  dx 

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dQ +
In steady state condition  H  constant
dt +
+
Take "dx" thickness portion at distance +
"x" from centre +
(30) (D). + qE
+
dQ K (4x 2 ) dT +
H  + mg
dt dx
r2 dx 4K T2
r1 T2
H T1
2
 dT  
x dx q 
qE   0    tan 
tan   
 1 1  4K T1 mg mg
 r  r   H (T2  T1 ) r1
2 1
r2
4 K (T1  T2 )
H
 r2  r1 
 r r  +8q –2q E2q E8q
12
(31) (A).
 rr   rr  x
H  4K (T1  T2 )  1 2  ; H   1 2 
 r2  r1   r2  r1 
For net electric field to be zero
m He 16 E2q = E8q
(26) (B). mHe = 16gm  nHe =  4
m WHe 4 K(2q) K (8q)
 2

(x  L) x2
mO 2 16 1
mO2  16gm  n O2    x = 2L
M wO 32 2
2 (32) (B). Potential difference = V1 – V2

n He (C P )He  n O2 (C P )O2 1
(33) (D). CV 2  msT
 mix  2
n He (C V )He  n O2 (CV )O2
(34) (A). This is (n – 1) capacitors in parallel.
So Ceq = (n – 1) C
5 1 7
4 R   R Vg
 2 2 2 =  = 1.62
mix (25) (D). Ig = 15mA, Vg = 75mV R g   5
3 1 5 Ig
4 R   R
2 2 2
Required range of voltmeter = 150V
(27) (A). It is not applicable to any cyclic process.
(28) (C). V
 R  I  R g  9995
g
Q1  Q2
 (36) (B). Galvanometer shows zero if dro across R is 2V
Q1
 R 
1 3    (12V)  2V R = 100
Q1  (T0 S0 )  T0S0  T0S0 500  R 
2 2
Q2 = T0S0 2E
(37) (B). I  R  R  R
3 1 2
T0S0  T0S0 1
1
 2  ;  3 VR 2  E  IR 2
3 3
T0S0
2  2E 
0 = E – IR2 ; 0  E   (R 2 )
(29) (A). Internal energy path independent  R  R1  R 2 
U I  U II R = R2 – R1
E
(38) (B). I 
Rr
if r > > R Variation in R does not affect the current.
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2
    sin     ay 
(39) (D). r   1 2  R  2 (53) (B). I  I 0   and     D 
 2  
for principal maximum y = 0  = 0
 0 (3) Hence, intensity will remain same.
(40) (A). B1 
2 (2  10 2 ) (54) (A). I = I0 cos2 
Intensity of polarized light = I0/2
0 (4) I0 I0
B2  B2
2 (2   10 2 )  Intensity of untransmitted light  I0  
2 2
(55) (A). I  n = 1 to n = 3 shows absorption
 B  B12  B22  5  105 T II  n = 4 to n = 3 emission of energy 0.6 eV
B1 III n = 2 to n = 1 emission of energy 10.2 eV
(41) (D). Magnetic force = 0
Due to electric force in opposite direction velocity will de- IV n = 4 to n = 2 emission of energy 2.5 eV
crease. h
(56) (C).  
2m 2mE
(42) (B). T  (57) (A) R = R0 A1/3 ; R = R0 (125)1/3
qB
 0 i1i 2 5
(43) (C). Force per unit length = 3.6 = R0 (27)1/3 ; R = × 3.6 = 6 fermi
2 d 3
(44) (C). A force and a torque. (58) (B). X + n  + 3Li7
X + 0n1  2He4 + 3Li7. So X is 5B10
R  2t 
  t I0  1
(45) (B). I  I0 1  e L  ; 
 I0 1  e 300 10 3  (59) (B). Intensity 
  2   distance 2
  Distance is halved intensity becomes four times, so emit-
t = 0.1 sec. ted electron becomes four times.
1 I0
(46) (C). Frequency  (60) (D). I  ;
2 LC 2n
(47) (D). 2BV 1 1 x 36
 n n  3  3   3  x1/2  12mm
R 12 8 2 x1/ 2 x1/2
(48) (A). cos     0.8
Z 15 N0
(49) (B). RL has acute angle phase difference. (61) (C). N  Remaining fraction
2n
(50) (B). The situation is shown in figure.
1 N0 7 1
 1 
8 2n 8 8
A R
t 15
12cm n3  3   3  T  5min .
T T
O
12420  10 10 12420  10 10
(62) (C). E  ; E   0.5eV
(ev)  2480  10 9
1 AB (63) (C). Frequency of ripple in full wave rectifier
sin C  ; tan C  AB = OA tan C
 AO = 2 × input frequency= 2 × 50 = 100 Hz.
(64) (C). Zero
OA 12 36
or AB    2u 2 sin 2 2R
2 2 7 (65) (D). t1t 2  
 1  4 g 2 g
   1
3
1 1 v2 1 2
(66) (D). F.3  mv 2  m ; F (3  x)  mv ; x = 1 cm.
Y  2 2 4 2
(51) (A). We know  1.22 (67) (B). No horizontal external force is acting
D d
 acm = 0 ; since vcm = 0  xcm = 0
Yd 10 3  3  10 3 30
 D     5m ; Dmax = 5m
1 u2
1.22 1.22  5  10 7 6.1 mu 2 ; s   1000m
(68) (B).  k mgs 
(52) (A). Hyperbola 2 2 k g
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(69) (A). Phase difference () = 99t + /3 – /2 for f to be both one-one and onto B must be equal to range
at t = 0,  = –/6. Let x = tan 
–1 < x < 1
   –1 < tan  < 1 –/4 <  < /4
Pm    1 –/2 < 2 < /2 .......... (1)
a
 5
(70) (none). Pair     ; Pm  D  tan 1 (tan x)  x ;   / 2  x   / 2
   1 8
a  1
 tan (tan 2)  2
   / 2  2   / 2
q and   / 2  2   / 2
(71) (B). q1Z1 = q2Z2 ; q = q1 + q2  q 2  z
1 2 2x 2 tan 
z1 Now, f (x) = tan 1 2
 tan 1
1 x 1  tan 
2 2
V t V = tan–1 (tan 2) = 2
(72) (A). H  ; H  t , Given R' = R/2
and –/2 < 2 < /2 from (1)
R R
(73) (C). | f1– f2 | = 4 Range of f (x) = (–/2, /2)
Since mass of second tuning fork increases so f2 decrease  B (–/2, /2)
and beats increase so f1 > f2. (2) (A). f (x – y) = f (x) f (y) – f (a – x) f (a + y) ......... (1)
f2 = f1– 4 = 196 Put x = 0, y = 0
f (0) = f (0) . f(0) – f (a) f (a) {f (0) = 1 given}
vv/5 6f 1 = 1 – [f (a)]2 f (a) = 0 ......... (2)
(74) (D). f  f ; % increase in frequency = 20%
v 5 Now if we put in (1) x = a and y = x – a we get
f (2a – x) = f (a) f (x – a) – f (0) f (x)= 0 × f (x – a) – f (x)
V 2 200  200
(75) (A). R hot    400  f (a)  0 from (2)
P 100 = – f (x) and f (0)  1 given
R hot 400 (3) (A). A = {3, 6, 9, 12}
Cold resistance =   40
10 10 R = {(3, 3), (6, 6), (9, 9), (12, 12), (6, 12), (3, 9), (3, 12), (3, 6)}
R is relation on set A
MATHEMATICS (3, 3) (6, 6), (9, 9) (12, 12) R  R is reflexive
(6, 12) R and (12, 6) R  R is not symmetric
ANSW ER KEY (3, 6) and (6, 12) R
(3, 12) R etc.  R is transitive
Q 1 2 3 4 5 6 7 8 9 10
(4) (B). r –– in radius
A D A A B A D B C C C R –– circumradius A
Q 11 12 13 14 15 16 17 18 19 20
a b c
A C D B C D C A D A C  R   
2sin A 2sin B 2sin C
Q 21 22 23 24 25 26 27 28 29 30
c 
A A C B D D D D C D A R but  C 
2sin C 2
Q 31 32 33 34 35 36 37 38 39 40
c c B
A A A D A B C B BD B D  R  2sin ( / 2)  2 .... (1) C
Q 41 42 43 44 45 46 47 48 49 50
A D D B D B A A D D C 
and r = (s – c) tan C/2   C 
Q 51 52 53 54 55 56 57 58 59 60 2
A C B A B A B B B C D = (s – c) tan (/4)
=s–c .... (2)
Q 61 62 63 64 65 66 67 68 69 70 Adding eq. (1) and (2)
A B C A C A A D C C D
c
Q 71 72 73 74 75 Rr sc
2
A B D D B D
c  2s  2c
(1) (D). f : (–1, 1) B Rr {2s = a + b + c}
2
2x 2 (R + r) = c + a + b + c – 2s = a + b
f (x) = tan–1
1  x2
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(5) (A). Let roots of equation x2 – (a – 2) x – a – 1 = 0 are  and k2 – 9k + 20 > 0 (k – 5) (k – 4) > 0
. k < 4 or k > 5 ........ (1)
 +  = a – 2 ........... (1) but equation has two roots D > 0
= – a – 1 ........... (2) 4k2 – 4.1 (k2 + k – 5) > 0 – 4k + 20 > 0
again 2 + 2 = ( + )2 – 2 k < 5 ........... (2)
= (a – 2)2 – 2 (– a – 1) From eq. (1) and (2),k (–, 4)
= a2 + 4 – 4a + 2a + 2 (9) (C). | z1 + z2 | = | z1 | + | z2 | {Let arg z1 = 1 and arg z2 = 2}
= a2 – 2a + 6 = a2 – 2a + 1 + 5 | z1 + z2 |2 = ( | z1 | + | z2 | )2
2 + 2 = (a – 1)2 + 5 | z1 |2 + | z2 |2 + 2 | z1 | | z2 | cos (1 – 2)
2 + 2 will be minimum if a – 1 = 0 a = 1 = | z1 |2 + | z2 |2 + 2 | z1 | | z2 |
(6) (D). Roots of equation x2 – bx + c = 0 are two consecutive cos (1 – 2) = 1
integer. 1 – 2 = 0 or 2n; n I
Let roots are  and  + 1 arg z1 – arg z2 = 0 or 2n ; n I
sum of roots =  +  + 1 = b
z z
b 1 (10) (C).   and |  | = 1  
1 1
2+ 1 = b  = ......... (1) z i z i
2 3 3
and product of roots
 ( + 1) = c 2 +  = c ......... (2)
on putting value of from (1) in (2) z |z| i
 |  |  1 
1  z   | z |
1 3
(b  1)2 (b  1) b 1  b 1 
 1  c
z i z i
   c  3
4 2 2  2  3

i
b  1  b  1 b2  1  z   | z  0 | { z is equidistant from i/3 & 0}
    c   c b2 – 1 = 4c 3
2 2 4
Locus of z is perpendicular
b2 – 4c = 1
Bisector of line joining i/3 and 0
(7) (B). In a triangle PQR, R = /2
{if | z – z1 | = | z – z2 | z lies on bisector of line joining
P + Q + R = 
z1 and z2}
P + Q = /2 {R = /2}
(11) (C). 1, , 2 are cube roots of unity
P Q  P Q  (x – 1)3 + 8 = 0
      [P = P,, Q = Q]
2 2 4 2 2 4 (x – 1)3 = – 8
(x – 1) = (–8)1/3{ if x = (–1)1/3 x = –1, – and –2}

tan (P/2 + Q/2) = tan x – 1 = – 2, –2 or – 22
4 x – 1 = – 2 x = – 1
tan (P / 2)  tan (Q / 2) x – 1 = –2x = –2 + 1
 1 ............ (1) x – 1 = – 22 x = – 22 + 1
1  tan (P / 2).tan (Q / 2)

Now roots of equation ax2 + bx + c = 0 are tan (P/2) and tan
(Q/2) (12) (D).  x   an = a0 + a1 + a2 + ..... 
n 0
 tan (P/2) + tan (Q/2) = – b/a
and tan (P/2) tan (Q/2) = c/a = 1 + a + a2 + ..... 
Put these values in (1), we get 1 x 1
x  a ........ (1)
b / a b c 1 a x
 1   1
1 c / a a a 
– b = a – c a + b = c and y   bn = b0 + b1 + b2 + ..... 
(8) (C). Equation x2 – 2kx + k2 + k – 5 = 0 has two roots (ac- n 0
cording to question)
1 y 1
If we consider the expression y b ......... (2)
f (x) = x2 – 2kx + k2 + k – 5 = 0 1 b y
Coeff. of x2 is 1 which is positive 
graph of f (x) will
let ,  are roots of equation
and z   cn = c0 + c1 + c2 + ..... 
n 0
both roots are less than 5  
f (5) > 0 1 z 1
z c ......... (3)a, b, c are in in A.P..
52 – 2k (5) + k2 + k – 5 > 0 1 c z
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x 1 y  1 z  1 1
 , , are also in A.P.. +
x y z (m  r  1)! (r  1) r (r  1)!

1 1 1 2 1 1
 1  ,1  ,1  are also in A.P.. =  
x y z (m  r) r (m  r  1) (m  r) (r  1) r

1 1 1 2 (r  1) r  (m  r  1) (m  r)
  ,  ,  are in A.P. (subracting 1from each) = 
x y z (m  r) r (m  r  1) (m  r) (r  1) (r)
1 1 1 2 (m – r + 1) (r + 1) = r2 + r + m2 + r2 – 2mr + m – r
 , , are in A.P. (multiplying with – 1 each) 2 [mr – r2 + r + m – r + 1] = m2 + 2r2 – 2mr + m
x y z
m2 – 4mr – m + 4r2 – 1 = 0
x, y, z are in H.P. m2 – m (4r + 1) + 4r2 – 2 = 0
(15) (D). If xm comes in (r + 1) th term in expansion of
A
n
  b n  m
 ax    then r =   
x
F E
Let x7 comes in (r + 1)th term in expansion of
(13) (B).
11
 2 1  11  2  7 15
 ax  bx   r 
2 1

3
 5 r=5
B D C
5
1 2 11 2 11 5  1 
  BC.AD  AD  Now, T51  C5 (ax )  
2 BC bx
Here, BC = a, AC = b, AB = c 6
 Coefficient is 11 C  a  ....... (1)
 5  5
Altitude AD = b 
a
and let x–7 comes in (r + 1)th no. term in expansion of
 
Similarly altitude BE = and CF = 11
b c  1  11  1  (7) 18
AD, BE, CF are in H.P.  ax  2   r  6
bx 1 2 3
   1 1 1 6
 , , are in H.P.  , , are in H.P..  1 
a b c a b c Now, T6+1 = 11C6 (ax)11–6  
a, b, c are in A.P.  bx 
sin A, sin B, sin C are in A.P.
11
 a5 
 sin A sin B sin C   Coefficient is C6   ....... (2)
     b6 
 a b c 
(14) (C). (1 + y)m = C0 + C1y + C2y2 + ....... + Cmym According to question,
Coefficient of rth term is mCr–1 a6 a5
11
and Coefficient of (r + 1)th term is mCr C5  11C6
a = 1/b ab = 1
and coefficient of (r + 2)th term is mCr+1 b5 b6
According to question they are in A.P. (16) (C). x is so small that x3 and higher power of x may be
2 mCr = mCr–1 + mCr+1 neglected
n (n  1) 2
2.m! m! m! (1 + x)n = 1 + nx + x
 (m  r)! r!  (r  1)! (m  r  1)!  (m  r  1)! (r  1)! 2!
3
 1 
2.1 (1  x)3/2  1  x 
=  2 
(m  r) (m  r  1)! r (r  1)! Now,
(1  x)1/2
1
= 2
(r  1)! (m  r  1) (m  r) (m  r  1)!  3 3 / 2 (3 / 2  1) 2   x 3 2 x  x 
1
 2 x  x    1   3.1  3.1   
2! 8 2  2 
  
(1  x)1/2
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(20) (C). Let other two vertices are B = (x1, y1) and C = (x2, y2)
 3 3 2  3 3 2  and mid point of AB is (–1, 2)
 1  2 x  8 x   1  2 x  4 x   A(1,1)
 
= (1  x)1/2 
 
D(–1,2) F (3, 2)
{x3/8 neglected}
= (–3/8 x2) (1 – x)–1/2

 1  1   B C
   1 (x2,y2)
 3 2   x 2 2  
2
(x1 ,y1 )
=  x  1  ( x)
 8  2 2!  1  x1 1  y1
   1  –2 = 1 + x1 x1 = – 3 and 2 
2 2
4 = 1 + y1 y1 = 3
 3 2   x 3 2 3 2 3 3 9 4 (x1, y1) = (–3, 3)
=  x 
8 1  2  8 x  =  8 x  16 x  64 x and mid point of AC is (3, 2)

3 2 1 x2 1  y2
=  x {term containing x3 and higher power are ne-  3 x2 = 5 and 2  y2 = 3
8 2 2
glected} (x2, y2) = (5, 3)
(17) (A). In SACHIN order of alphabets is A, C, H, I, N, S  1  (3)  5 1  3  3 
 Number of words starting with A = 5! Centroid of ABC is  ,  = (1, 7/3)
3 3 
Number of words starting with C = 5!
(21) (A). Line passing through the intersection of
Number of words starting with H = 5!
ax + 2by + 3b = 0 and bx – 2ay – 3a = 0
Number of words starting with I = 5!
equation of line is
Number of words starting with N = 5!
(ax + 2by + 3b) +  (bx – 2ay – 3a) = 0
Now words start with 5 and after that ACHIN are in as-
x (a + b) + y (2b – 2a) + 3b – 3a = 0 ..... (1)
cending order of position.
 5 × 5! = 600 words are in dictionary before words with 5 (a  b)
Slope of this line is
start and position of this word is 601. 2b  2a
6 line is parallel to axis
50 56  r
(18) (D). C4   C3 its slope is zero
r 1
= 50C + 55C + 54C + 53C + 52C + 51C + 50C  a  b  a
4 3 3 3 3 3 3      0 a + b = 0 =
2b  2a  b
= 50C4 + 50C3 + 51C3 + 52C3 + 53C3 + 54C3 + 55C3
= 51C4 + 51C3 + 52C3 + 53C3 + 54C3 + 55C3 Put this in (1) we get
= 52C4 + 52C3 + 53C3 + 54C3 + 55C3   a     a  
= 53C4 + 53C3 + 54C3 + 55C3 x a    b   y  2b  2a    + 3b  3a  a   0
  b     b   
= 54C4 + 54C3 + 55C3 b
= 55C4 + 55C3 y (2b2 + 2a2) + 3 (b2 + 3a2) = 0 y = –3/2
= 56C4 {nCr + nCr–1 = n+1Cr } Required line is below the x-axis and at a distance of
(19) (A). P (1, 0) (given) 3/2 from it.
Let coordinate of Q is (a, b) and mid point of PQ is (h, k) (22) (C). a, b, c are in H.P.
a 1 2ac 1 a c 1 1 1
 h a = 2h – 1 ....... (1)  b      
2 ac b 2ac b 2a 2c
b0 1 1 1 1 2 1
and k  b = 2k ....... (2)     0     0 ........ (1)
2 2a b 2c a b c
Q is on curve y2 = 8x x y 1
 It will satisfy it Given equation of line is   0 ........ (2)
a b c
b2 = 8y
If we put (1, –2) in (2) we get
4k2 = 8 (2h – 1) k2 = 2 (2h – 1)
k2 = 4h – 2 1 2 1
  which is true from (1)
locus of (h, k) is y2 = 4x – 2 a b c
y2 – 4x + 2 = 0 given line passes through fixed point (1, –2)

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(23) (B). Given equation of circles are (26) (D). Equation of pair of lines is
x2 + y2 + 2ax + cy + a = 0 ax2 + 2 (a + b) xy + by2 = 0
and x2 + y2 – 3ax + dy – 1 = 0
and their intersection point are P and Q
equation of line passing through P and Q is

S1 – S2 = 0
3
5ax + (c – d) y + a + 1 = 0
 c  d a 1
5x +   y  0 ....... (1)
a a
Given line is 5x + by – a = 0 ....... (2)
Comine eq. (1) and (2) we get Area of one sector is thrice of the area of other section
4 =  = /4
a 1
  a a + 1 = – a2 a2 + a + 1 = 0 {d is c > 0}
a 2 h 2  ab   
tan    tan   tan  1 and h  a  b 
which is not possible. |ab|  4 

2 (a  b) 2  ab
1 (a + b)2 = 4 [(a + b)2 – ab]
|ab|
3a2 + 3b2 + 2ab = 0
(0, 3)
2
Q R x 2 y2
k (h, k) (27) (D). y = mx + c touches 2  2  1
a b
(24) (D). P
k If c2 = a2m2 – b2
 y = x +  touches if 2 = a22 – b2

x2 y2
 a 2 x2 – y2 = b2
 2 2  1
b /a b2
PR = k and QR = 2 PR + QR = k + 2
Let centre of circle which touches x axis (h, k) which is a hyperbola.
equation of this circle is (x – h)2 + (y – k)2 = k2
Now, PQ = PR + RQ (28) (C). cos–1x – cos–1 (y/2) = 
PQ2 = (PR + RQ)2  xy y2 
(h – 0)2 + (k – 3)2 = (k + 2)2 h2 + k2 – 6k + 9 = k2 + 4  cos 1   1  x 2 1    
+ 4k h2 – 10k + 5 = 0  2 4 
Locus of (h, k) isx2 – 10y + 5 = 0 2
xy y
x2 = 10y – 5 equation of parabola   1  x 2 1   cos 
2 4
(25) (D). Let the equation of circle whose centre is (–g – f) is
xy y2
x2 + y2 + 2gx + 2fy + c = 0 ........ (1)   cos   1  x 2 1 
this circle passes through (a, b) 2 4
 a2 + b2 + 2ag + 2bf + c = 0 ........ (2) Squaring both side 2
2 
Now circle (1) cut circle x2 + y2 – p2 = 0  xy  2 y2 
   cos    1  x 1  
Orthogonally, 2g.(0) + 2f.(0) = c – p2  c – p2 = 0 2   4 
 c = p2 {if two circle cuts orthogonally then condition is x 2 y2 2xy  y2 
2 2
2g1g2 + 2f1f2 = c1 + c2}  4  cos   cos   (1  x ) 1  
2  4
 c – 4 = 0  c = 4
Put this value in (2) we get x 2 y2 y2 x 2 y2
a2 + b2 + 2ga + 2bf + p2 = 0   cos 2   xy cos   1   x2 
4 4 4
 for locus of centre replace (–g, –f) with (x, y)
y2
g = – x and f = – y  x 2   xy cos   cos 2   1  0
Locus is a2 + b2 – 2ax – 2by + p2 = 0 4
2ax + 2by – (a2 + b2 + p2) = 0 4x2 + y2 – 4xy cos  + 4 cos2 – 4 = 0
4x2 + y2 – 4xy cos  = 4 – 4 cos2 = [1 – cos2] = 4 sin2
(29) (D). A2 – A + I = 0  A–1A2 – A–1A + A–1I = 0
 A–1A . A – I + A–1 = 0
 A – I + A–1 = 0  A–1 = I – A

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1 0  1 0 1 0 
(30) (A). A     A2    and A3    1  a 2x (1  b2 )x (1  c 2 )x
1 1  2 1  3 1  2
(33) (D). f (x) = (1  a )x 1  b2 x (1  c 2 )x
n 1 0 (1  a 2 )x (1  b2 )x 1  c2 x
Similarly, A    .......... (1)
n 1
C1 C1 + C2 + C3
n 0 
Now, nA =  n n  .......... (2) 1  a 2 x  x  b 2 x  x  c 2 x (1  b 2 )x (1  c2 )x
 
f (x)  x  a 2 x  1  b 2 x  x  c 2 x 1  b2x (1  c2 )x
n  1 0 
and (n – 1) I =  n x  a 2 x  x  b 2 x  1  c 2 x (1  b 2 )x 1  c2x
 n  1 .......... (3)
Now from eq. (1), (2) and (3), An = nA – (n – 1) I 1 (1  b2 )x (1  c 2 )x
log a n log a n 1 log a n  2 1 1  b2 x (1  c 2 )x
= (1 + 2x + a2x + b2x + c2x)
(31) (A).
log a n  3 log a n  4 log a n  5
......... (1) 1 (1  b2 )x 1  c2 x
log a n  6 log a n  7 log a n  8
Applying R2 R2 – R1 R3 R3 – R1
a1, a2, a3 ........an are in G.P. = {1 + 2x + a2x + b2x + c2x)}
a2n+1 = an an+2  2 log an+1 = logan + logan+2
1 (1  b 2 )x (1  c 2 )x
again a2n+4 = an+3 an+5
0 1 x 0
2 log an+4 = log an+3 + log an+5 and a2n+7 = an+6 an+8 {a2 + b2 + c2 = – 2 (given)}
0 0 1 x
2 log an+7 = log an+6 + log an+8
Putting these in the second column of the given determi- = [1 + 2x + (–2) x] [1 {(1 – x)2 – 0}] = 1. (1 – x)2
nant (1) we get which is polynomial of degree 2.
log a n log a n  log a n  2 log a n  2 (34) (A).  and are roots of equation ax2 + bx + c = 0
1 ax2 + bx + c = 0 ......... (1)
 log a n  3 log a n  3  log a n  5 log a n  5 ax2 + bx + c = a (x – ) (x – )
2
log a n  6 log a n  6  log a n  8 log a n 8
1  cos (ax 2  bx  c)
Now, lim

1
(0)  0 {C2 is the sum of two elements, first iden-
x  (x   )2
2
tical with C1 and second with C3}  ax 2  bx  c 
(32) (A). x + y + z =  – 1 2 sin 2  
 2 
x + ay + z =  – 1 = lim
x + y+ z = – 1 x  (x   )2
System of equation has no solution
a 
 1 1 2 sin 2  (x   ) (x  )
2 1 1 2 
= lim
 1  1  0 ;C1C1+C2+C3   2  1  0 x  (x   )2
1 1  2 1 
2
1 1 1  a 
sin  2 (x   ) (x  )  2
 (  2) 1  1  0    a (x  ) 2
= 2 lim
1 1  x  a2 4
(x   ) 2 (x  ) 2
4
R1 R1 – R3 R2 R2 – R3
0 1 1  a2 a2
= 2.1. (   ) 2 = (  ) 2
 (  2) 0   1 1    0 4 2
1 1  (35) (B). | f (x) – f (y) |  (x – y)2

= ( + 2) [(1 – ) [0 – ( – 1)]] = 0 | f (x)  f (y) |


 |xy|
( + 2) (1 – )2 = 0  = – 2 & 1 |xy|
But  = 1 makes three equation same
the system of equation have infinite solution | f (x)  f (y) |
 lim  lim | x  y |
 = – 2 xy |xy| x y
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| f ' (y) |  0 { | f ' (y) | cann’t be –ve}
f ' (y) = 0 0 cos   0 sin   a
 a constant
f ' (y) is constant function cos2   sin 2 
but f (0) = 0 (given)
f (y) = 0
f (1) = 0
f (1  h)  f (1)
(36) (C). f (1)  lim 10cm x
h0 h
(39) (B).
f (1  h)  f (1) f (1) f (1  h)
= lim  lim  lim 5
h0 h h0 h h0 h
f (1)
 lim must be finite as f ' (1) exists and Let the thickness of ice is x
h0 h Now volume of sphere with ice layer is
f (1) f (1  h) 4 dv 4 dx
lim 0  f (1)  lim 5 v (10  x)3 ;   3 (10  x)2
h0 h h0 h 3 dt 3 dt
(37) (B). anxn + an–1xn–1 + ...... + a1x = 0 has one root x = .
 dx 
Let f (x) = anxn + an–1xn–1 + ...... + a1x = 0 50 = 4 ×  × 15 × 15 ×  dt 
f (0) = 0 and f () = 0 x 5
f (x) is polynomial of degree n
 dx  1
It is continuous in [0, ) and differentiable in (0, )   dt  = cm / min .
f ' (x) = 0 has at least one root in (0, ) x 5 18
nanxn–1 + (n – 1) an–1 xn–2 + ..... + a1 = 0 has at least one (40) (D). If f (x) is increasing ; f ' (x) 0
root is (0, ) Now if f (x) = x3 – 3x2 + 3x + 3
one root of nanxn–1 + (n – 1) an–1xn–2 + ...... + a1= 0 less f ' (x) = 3x2 – 6x + 3 = 3 (x2 – 2x + 1) = 3 (x – 1)2
than . if function is increasing
(38) (BD). x = a (cos  +  sin ) and y = a (sin  –  cos ) f (x)  0
dx 3 (x – 1)2 > 0 x R
= a [– sin  +  cos  + sin ] = a [ cos ] and If f (x) = 2x3 – 3x2 – 12x + 6
d
f ' (x) = 6x2 – 6x – 12 = 6 (x2 – x – 2)
dy If f (x) is increasing
= a [cos  +  sin  – cos ] = a [ sin ] f ' (x)  0
d
6 (x2 – x – 2)2  0 6 (x – 2) (x + 1)  0
dy dy / d a sin  x (–, –1] [2, )
    tan 
dx dx / d a cos  If f (x) = 3x2 – 2x + 1
this is slope of tangent f ' (x) = 6x – 2
slope of normal to the curve will be – cot  f (x) is increasing
equation of normal is f (x)  0 6x – 2  0 x  1/3
y = – a (sin  –  cos ) = – cot  [x – a (cos  +  sin )] If f (x) = x3 + 6x2 + 6 f' (x) = 3x2 + 12x [f is increasing]
x cot  + y = a cot  (cos  +  sin ) + a (sin  –  cos )  f ' (x)  0 3x2 + 12x  0 3x (x + 4)  0
x (–, – 4] [0, )
 cos 2  
=a   cos   sin    cos   2
 (log x  1) 
 sin  
(41) (D).   2
dx
1  (log x) 
 cos  2 
x cos 
 sin   y  a  sin   sin   Put log x = t x = et dx = et dt
  2
 t 1  t t 2  2t  1 t
x cos  + y sin  = a (cos2 + sin2)   1  t 2  e dt   (1  t 2 )2 e dt
x cos  + y sin  = a (cos2 + sin2)
x cos  + y sin  = a .......... (1)
y = – cot x + a = tan (/2 + ) x + a (t 2  1)  2t  1 2t  t
Clearly, m = tan (/2 + ) =  e t dt =     e dt
(1  t 2 )2  (1  t 2 ) (1  t 2 )2 
Normal make angle /2 +  with the x-axis and distance
of normal from origin is   (f (t)  f (t)) e t dt  e t f (t)  C

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1 2t f (x)  f (2)
If f (t) = 2  f ' (t) = 2 = lim lim [(f (x)) 2  62 ] lim (f (x)  6)
t 1 (t  1) 2 x 2 x  2 x 2 x 2
{f (2) = 6}
 1 2t  t 1 = f ' (2) × [f (2)2 + 36] × [f (2) + 6]
  2
 2 
e dt  e t  C
1 t (1  t )  1 t2 1 1
= × (62 + 36) × (6 + 6) = × 72 × 12 = 18
48 48
x
= C  
1  (log x) 2 cos 2 x cos 2 x
(45) (B).  x
dx, a  0 . Let I =  x
dx ...... (1)
 1  1  a  1  a
2 1 2 2 4 1 2 
(42) (D). lim  2 sec 2  2 sec 2  .....  n sec 1
n   n n n n  
cos2 x
n
I  1  a  x dx ...... (2)
r 2 r2 r 
lim 
n  r 1 n 2
sec
n2
Replace   ;
n
x
Adding eq. (1) and eq. (2)
 
1 (1  a x ) cos 2 x 2
If r = 1 and n , x = 0 and r = n then x = 1 and  dx 2I   dx =
n 1 ax
 cos x dx
 
n 2 1
 r 1 2 r 2 2
 nlim 
 r 1
  sec     x sec x dx
n n n
 cos2 x is even function
 a
0 a

Put x2 = t ; 2x dx = dt x dx = dt/2  
 f (x) dx  2  f (x) dx
  a 0
1
1 2 1 1 1 1
= 2  sec t dt  2 [tan t]0 = [tan1  tan 0] = tan1  
1  cos 2x 
2 2 2
0
= 2 cos x dx = 2  2  dx
0 0  
1 1
x 2 x 3
(43) (B). I1   2 dx, I 2   2 dx  sin 2x 

sin 2  sin 0 
0 0
= x      2  0  2  = 2I = 
 2 0  
2 2
2 3 I = /2
I3   2x dx, I4   2x dx
1 1 2 2
(46) (A). Equation of ellipse is x  y  1
For 0 < x < 1, we have x2 > x3
a 2 b2
For 1 < x < 2, we have x3 > x2
2 3
 2x  2x for 0 < x < 1 x=b (acos , bsin )
D A
2 3
and 2 x  2 x for 1 < x < 2
2 2 bsin
1 1
x2 x3 x2 x3
 2 dx   2 dx and 2 dx   2 dx
0 0 1 1
acos
 I1 > I2 and I3 < I4 x=a
(44) (D). f : R R and f is differentiable function x = –a
C B
f (x)
1 4t 3
f (2) = 6 and f ' (2) =
48
 xlim
2
 x2
dt
6
Let polar coordinate of point A on ellipse is
f (x) x = a cos  and y = b sin 
 4t 4  (f (x)) 4  64
= lim  4 (x  2)  = lim Area of rectangle ABCD = 2a cos  × 2b sin  = 2ba sin
x  2  6 x 2 x2 2
it will be max. if 2 = /2  = /4
(f (x)  6) Area = 2ab sin /2 = 2ab
= lim (f (x)) 2  (6) 2 ) (f (x)  6)
x 2 x2

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0 
(47) (A). Required area = 
 log e (x  e) dx (49) (D).  f (x) dx   sin  
4
cos   2
1 e  /4
Differentiate with respect to  on both side
f () . 1 – f (/4) × 0 = sin . 1 +  cos  – /4 sin  + 2
x=–e f () = sin  +  cos  – /4 sin  + 2
(0,1)
   
f (/2) = sin   cos  sin  2
2 2 4 2
(–e,0)  
1 0   2 = 1  2
{(1, –e), 0} (0,0) 4 4
(50) (C). y2  2c (x  c) ...... (1)

dy
2y  2c c = yy1 ...... (2)
dx
From (1), y2 = 2cx + 2c3/2
y2 – 2cx = 2c3/2
y2 – 2yy1x = 2(yy1)3/2 [From (2)]
e (y2 – 2yy1x)2 = 4 (yy1)3 = 4y3y13
e
Put x + e = t dx = dt ;  log e t dt  [t loge t  t]1 This is of order 1 and degree 3.
1
dy
= [e log e – e – 1 log 1 + 1] = (e – e – 0 + 1) = 1 (51) (C). x  y (log y  log x  1)
dx

4
dy y  y 
x2   log  1 ..... (1)
dx x  x 
(48) S
(D). 1  S 3 
 dx
4
0
y dy dz
Put  z y = xz  x  z.1
3 4 x dx dx
1 x 1 16
=     64  sq. unit dz
4  3  12 3  z  x  z (log z  1) [from (1)]
0
dx
S1 + S2 + S3 = 4 × 4 = 16
dz
16 x  z log z
S2 = 16 – (S1 + S3) {S1 = S3 = sq. unit } dx
3
dz dx
 16  16
= 16   2   = sq. unit
 z log z  x
 3 3
log (log z) = log x + log c
 S1 : S2 : S3 = 1 : 1 : 1 {S1 = S2 = S3} log z = cx
log (y/x) = cx

y2 =4x (52) (B). Let a  a ˆi  a ˆj  a kˆ
1 2 3
y=4  
 | a |  a12  a 22  a 32  | a |2  a12  a 22  a 32
(4,4)
(0,4)
S1 
x2=4y Now, a  ˆi   a 2 kˆ  a 3ˆj
S2
S3 x=4
 
(4,0)  | a  ˆi |  a 22  a 32 = | a  ˆi |2  a 22  a 32

a  ˆj  a1kˆ  a 3ˆj

| a  ˆj |  a12  a 32

 | a  ˆj |2  a12  a 32

and a  kˆ  a1ˆj  a 2ˆi
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  x  x1 y  y1 z  z1
 | a  kˆ |  a12  a 22 = | a  kˆ |2  a12  a 22  
If equation of line is a1 b1 c1
  
 | a  iˆ |2  | a  ˆj |2  | a  kˆ |2 and equation of plane ax + by + cz + d = 0 and  is angle
between them, then
= a 22  a 32  a12  a 32  a12  a 22
 aa1  bb1  cc1
= 2(a12  a 22  a 32 )  2 | a |2 sin  
a 2  b2  c 2 a12  b12  c12
P
Now from eq. (1) and eq. (2)

1.2  ( 1)(2)  (  ) 2
sin  
12  22  2 2 2 2  ( 1)2  (  )2
(53) (A).
2  2    (2) 1
  {from (3) sin  = 1/3}
A 1 C 1 B 3 5  3
Let P is the reference point 2 
    1
(PA)  (PB)  (1  1) PC 5
   4 = 5 + 
 PA  PB  2 PC
3 = 5  = 5/3
from m – n theorem (56) (B). The given lines can be written as
O x y z
  ......... (1)
1 / 2 1 / 3 1
x y z
and   ......... (2)
1 / 6 1 1 / 4
Angle beween them is
(1 / 2)  (1 / 6)  1 / 3(1)  (1)(1 / 4)
cos  =
A m C n B (1 / 2)2  (1 / 3)2  ( 1) 2  ( 1) 2  (1 / 4) 2
   cos = 0  = 90°
n (OA)  m (OB)  (m  n) OC 
(57) (B). Equation of line is r  2iˆ  2jˆ  3kˆ   (iˆ  ˆj  4k)
ˆ and
Here, m : n = 1 : 1

        equation of plane is r.(iˆ  5jˆ  k)
ˆ  5 is –
(54) (B). [ (a  b)  2 b  c]  [a b  c b]
      Vector parallel to line is ˆi  ˆj  4kˆ and vector normal to
 4 [a  b b c]  [a b b]  [a c b]
       plane is ˆi  5jˆ  kˆ
 4 {[a b c]  [b b c]}  [a c b]
    and (iˆ  ˆj  4k).(i
ˆ ˆ  5jˆ  k)ˆ =1–5+4=0
 4 {[a b c]  0}   [a b c]
 Line is parallel to the plane and point whose position
   
 4 [a b c]  [a b c]  0 vector is 2iˆ  2jˆ  3kˆ lies on line
  perpendicular distance of plane from this point is
[a b c] ( 4  1)  0
  (2iˆ  2ˆj  3k).(i
ˆ ˆ  5ˆj  k)
ˆ 5
[a b c]  0 then  4  1  0 { a b c are non-coplanar} =
No real value of  exist. | ˆi  5jˆ  kˆ |

x  1 y 1 z  2 2  10  3  5 10
(55) (A). Equation of line is   ......... (1) = 
1 2 2 27 3 3
and equation of plane is 2x  y   z  4  0 ......... (2) (58)
(B). Person 1 has three option to apply similarly person 2
has three option to apply and person 3 has three option to
1 apply.
Angle between line and plane is  and sin  = ...... (3)
2 Total cases 33
Now favourable cases = 3 (either all the three apply for 1 or
2 or for 3)
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Applying Lagrange fs mean value theorem
3 1
Probability = 3  f (6)  f (1)
3 9  f  (c)  2
5
1 f (6)  10 + f (1)
(59) (C). Given, P(A  B) 
6 f (6)  10 – 2 f (6)  8.
1 1 (64) (C). Plane 2ax – 3ay + 4az + 6 = 0 passes through the mid
P (A B) = ; P(A)  point of the centre of spheresx2 + y2 + z2 + 6x – 8y – 2z = 13
4 4
and x2 + y2 + z2 – 10x + 4y – 2z = 8 respectively.
1 3 Centre of spheres are (–3, 4, 1) & (5, - 2, 1)
 P(A)   P(A)  ........ (1) Mid point of centre is (1, 1, 1)
4 4
Satisfying this in the equation of plane, we get
1 2a – 3a + 4a + 6 = 0  a = –2
Now, P(A  B) 
6 (65) (A).
FBF' = 90°
1
1 – P (A B) =
6 B (0,b)
1
1 – P (A) – P (B) + P (AB) =
6
3 1 1 F'(–ae, 0) O F(ae, 0)
 1   P(B)  
4 4 6
1
 P(B)  .......... (2)
3
Clearly from (1) & (2), P (A) × P (B)  ( a 2 e 2  b2 )2  ( a 2 e2  b 2 )2  (2ae)2
2 (a2e2 + b2) = 4a2e2
3 1 1
  = P (A B)
= e2 = b2/a2
4 3 4 Also, e2 = 1 – b2/a2 = 1 – e2
Event are independent but no equally likely.
(60) (D). Mode = 3 Median – 2 Mean 2 1
 2e  1, e 
Mode = 3 (22) – 2 (21) = 66 – 42 = 24 2
(61) (B). AM of mth power > mth power of AM (If m > 1) (66) (A).
x12  x 22  ....x n2  x1  x 2  ....x n 
2 Vector aiˆ  ajˆ  ck,
ˆ iˆ  kˆ and ciˆ  cjˆ  bkˆ are coplanar
 
n  n
a a c
n 2 1 0 1  0 c2 = ab
 n 
 x i2   xi  2 c c b
400  80 
 i 1
  i 1  =   a, b, c are in G.P.
n  n  n  n
   
  (67) (D). a  ˆi  k,ˆ b  xiˆ  ˆj  (1  x) kˆ and

n 2 6400 n2 c  yiˆ  xjˆ  (1  x  y) kˆ
 ;  16 ; n > 16
n 400 n    
[a b c]  a.(b  c)
A
ˆi ˆj kˆ
 
P b c  x 1 1 x
y x 1 x  y
(62) (C). Q R
I
(1  x  x  x 2 )  ˆj (x  x 2  xy  y  xy)  kˆ (x 2  y)
B C
  
a.(b  c)  1
Using Lami’s Theorem
P : Q : R = cos A/2 : cos B/2 :cos C/2 which does not depend on x and y.
(63) (A).
As f (1) = – 2 & f ' (x)  2 for x  [1, 6]
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k
(68) (C). P (x  k)  e 
k!
P (x 2) = 1 – P (x = 0) – P (x = 1) (75) (D). 30°
  3 60° 30°
 1  e   e     1  2
 1! e u cos 60° = v cos 30°
1 2 u
(69) (C). 2t  21  20 v
2 3
t = 21
(70) (D). v2 = 2f (d + n) = 2f 'd
v = f '(t) = (m + t) f
Eliminate d and m we get
1
(f  f  ) n  ff m 2
2
(71) (B). (A + B) = d = H
 H 
d
 A  B 

F
3F

(72) (D).

F'
F' = 3F cos 
F = 3F sin 
 F  2 2F

F : F  :: 3 : 2 2
(73) (D).

ex  e x x 2 x 4 x6
 1    ......
2 2! 4! 6!
Putting x = 1/2 we get
e 1
2 e
(74) (B). Perpendicular distance of centre (1/2, 0, –1/2) from
x + 2y – 2 = 4
1 1
 4
2 2 3

6 2

5 3
radius =  1
2 2

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