1 x C;

 (4 )
1
If  ( x ) = 2 sin t − 3 ' ( t ) dt , x  0 ,
x 
4
'( x ) =
1 
x ( ) 
1
4 2 sin x − 3 ' ( x )  1 − 0 − x − 3 2
2
 x
then  '   is equal to:
4  (4

)
2 sin t − 3 ' ( t ) dt
4

 2    
'  =  4 − 3 '    + 0
4   4 
 6   8
1 +  '  =
   4 
 8
 '  =
4  +6
8

4
6+ 
8
6+ 
4
6− 
2 If a point P (  , ,  ) satisfying D;
2𝛼 + 4𝛽 + 3𝛾 = 5 . . . (1)
 2 10 8 
2𝛼 + 9𝛽 + 8𝛾 = 0 . . . (2)
(  , ,  )  9 3 8  = (0 0 0) lies on 10𝛼 + 3𝛽 + 4𝛾 = 0 . . . (3)
8 4 8 8𝛼 + 8𝛽 + 8𝛾 = 0 . . . (4)
 
the plane 2𝑥 + 4𝑦 + 3𝑧 = 5, then Subtract (4) from (2)
6 + 9 + 7 is equal to: −6𝛼 + 𝛽 = 0
𝛽 = 6𝛼 . . . (5)
From equation (4)
8𝛼 + 48𝛼 + 8𝛾 = 0
𝛾 = −7𝛼 . . . (6)
From equation (1)
2𝛼 + 24𝛼 − 21𝛼 = 5
5𝛼 = 5
𝛼=1
𝛽 = +6, 𝛾 = −7
∴ 6𝛼 + 9𝛽 + 7𝛾
= 6 + 54 − 49
= 11
−1
11
5
5
4
11
3 Let 𝑎1 , 𝑎2 , 𝑎3 , … … be an A.P. If 𝑎7 = 3, the A;
product 𝑎1 𝑎4 is minimum and the sum of 𝑎 + 6𝑑 = 3,
𝑍 = 𝑎(𝑎 + 3𝑑)
 its first n terms is zero, then n! − 4an(n+2) = (3 − 6𝑑)(3 − 3𝑑)
is equal to: = 18𝑑 2 − 27𝑑 + 9
Differentiating with respect to d
⇒ 36 d − 27 = 0
3 −3
⇒ d = 4, from (1) a = 2 , (Z =
minimum)
n 3
Now, Sn = 2 (−3 + (n − 1) 4) = 0
⇒n=5
Now,
𝑛! − 4𝑎𝑛(𝑛+2) = 120 − 4(𝑎35 )
= 120 − 4(𝑎 + (35 − 1)𝑑)
−3 3
= 120 − 4 ( + 34 ⋅ ( ))
2 4
−6 + 102
= 120 − 4 ( )
4
= 120 − 96 = 24
24
33
4
381
4
9
4 Let (a, b) ⊂ (0,2𝜋) be the largest interval D;
for which sin−1 (sin 𝜃) − cos −1 (sin 𝜃) > 𝜋
sin−1 sin 𝜃 − ( − sin−1 sin 𝜃) > 0
0, 𝜃 ∈ (0,2𝜋), holds. If 2
𝜋
𝛼𝑥 2 + 𝛽𝑥 + sin−1 (𝑥 2 − 6𝑥 + 10) + cos −1 −1
⇒ sin sin 𝜃 >
(𝑥 2 − 6𝑥 + 10) = 0 4
1
and 𝛼 − 𝛽 = 𝑏 − 𝑎, then 𝛼 is equal to: ⇒ sin 𝜃 >
√2
𝜋 3𝜋
So, 𝜃 ∈ ( , )
4 4
𝜋 3𝜋
𝜃 ∈ ( , ) = (𝑎, 𝑏)
4 4
𝜋
⇒ 𝑏−𝑎 = = 𝛼−𝛽
2
𝜋
⇒𝛽 =𝛼−
2
⇒ α𝑥 2 + 𝛽𝑥 + sin − 1 [(𝑥 − 3)2 + 1]
+ cos −1 [(𝑥 − 3)2
+ 1] = 0
𝜋
𝑥 = 3, 9𝛼 + 3𝛽 + + 0 = 0
2
  
 9 + 3  −  + = 0
 2  2
 12 −  = 0

=
12
𝜋
48
𝜋
16
𝜋
8
 𝜋
12
5 Let 𝑦 = 𝑦(𝑥) be the solution of the A;
differential equation ( ) ( )
3 y2 − 5x 2 y  dx + 2x x 2 − y2 dy = 0
( ) ( )
3 y2 − 5x 2 ydx + 2x x 2 − y2 dy = 0 such
dy y (5x − 3 y )
2 2

 =
( y (2)) − 12 y (2)
3
that 𝑦(1) = 1 then is dx 2x ( x − y )
2 2

equal to: Put 𝑦 = 𝑚𝑥

 m+ x =
(
dm m 5 − 3m
2
)
dx (
2 1 − m2 )
dm (5 − 3m ) m − 2m (1 − m )
2 2

x =
dx 2 (1 − m ) 2

dx 2 ( m − 1 )
2

 = dm
x m ( m − 3)
2

 4 4m 
dx  2 3 
 =  − + 23  dm
x  m m m −3
 
 
2
dx 3 2 2m 
 =  +  2  dm
x m 3 m −3
2 2
 ln x = ln m + ln m2 − 3 + C
3 3
2
2 y 2  y
Or, ln x = ln + ln   − 3 + C
3 x 3 x
2
Put ( x = 1, y = 1) : we get c = − ln (2)
3
2
2 y 2  y 2
 ln x = ln + ln   − 3 − ln (2)
3 x 3 x 3

 y   y  
2

     − 3 = 2  x 3 2
 x   x 
( )

Put x = 2 to get y (2)
( )
 y y2 − 12 = 4  2  2  2 2
 y3 − 12 y = 33 2
 y3 (2) − 12 y (2) = 32 2
32√2
64
16√2
32
6 The set of all values of 𝑎 2 for which the A;
line x + y = 0 bisects two distinct chords
1+a 1−a
drawn from a point P ( 2 , 2 ) on the
circle 2x 2 + 2y 2 − (1 + a)x − (1 − a)y =
x 2 + y2 −
(1 + a ) x − (1 − a ) y = 0
0 is equal to:
2 2
1+a 1−a
Centre  ,  ( h, k )
 4 4 
1+a 1−a
P ,  ( 2h, 2k )
 2 2 

Equation of chord  T = S1
2h ( x +  ) (2k )( y −  )
 (x − y) − −
2 2
= 2 − 2h (  ) + 2k
2

Now,  ( 2h, 2k ) satisfies the chord

( 2h − 2k )  − h ( x +  ) − k ( y −  )
 22 + 4k − 4h + h − k + hx + ky = 0
 22 +  (3k − 3h) + ky + hx = 0
 D0
 9 ( k − h) − 8 ( ky + hx )  0
2

(
 9 ( k − h) − 8 2k 2 + 2h2  0
2
)
 − 7k 2 − 7h2 − 18kh  0
 7k 2 + 7h2 + 18kh  0
2 2
1−a 1+a  1 − a2 
 7  + 7  4  + 18  0
 4     16 

7
( )
 2 1 + a2  18 1 − a2
+
( 0,
) a2 = t
 16  16

7 18 (1 − t )
 (1 + t ) + 0
8 16
14 + 14t + 18 − 18t
 0
16
 4t  32
t 8 a2  8
(8, ∞)
(4, ∞)
(0,4]
 (2,12]
7 Among the relations B;
a For relation T = a2 − b2 = −I
S = {(a, b): a, b ∈ ℝ − {0},2 + > 0}
b Then, (b, a) on relation R
And T = {(a, b): a, b ∈ ℝ, a2 − b2 ∈ Z}, ⇒ b2 − a2 = −I
∴ T is symmetric
𝑎
𝑆 = {(𝑎, 𝑏): 𝑎, 𝑏 ∈ 𝑅 − {0},2 + > 0}
𝑏
𝑎 𝑎 𝑏 −1
2 + > 0 ⇒ > −2, ⇒ <
𝑏 𝑏 𝑎 2
If (𝑏, 𝑎) ∈ 𝑆 then
𝑏
2 + 𝑎 not necessarily positive
∴ S is not symmetric
S is transitive but T is not
T is symmetric but S is not
Neither 𝑆 nor 𝑇 is transitive
Both S and T are symmetric
8 The equation 𝑒 4𝑥 + 8𝑒 3𝑥 + 13𝑒 2𝑥 − A;
8𝑒 𝑥 + 1 = 0, 𝑥 ∈ 𝑅 has: 𝑒 4𝑥 + 8𝑒 3𝑥 + 13𝑒 2𝑥 − 8𝑒 𝑥 + 1 = 0
Let ex = t
Now, 𝑡 4 + 8𝑡 3 + 13𝑡 2 − 8𝑡 + 1 = 0
Dividing equation by 𝑡 2 ,
8 1
𝑡 2 + 8𝑡 + 13 − + 2 = 0
𝑡 𝑡
1 1
𝑡 2 + 2 + 8 (𝑡 − ) + 13 = 0
𝑡 𝑡
1 2 1
(𝑡 − ) + 2 + 8 (𝑡 − ) + 13 = 0
𝑡 𝑡
1
Let 𝑡 − 𝑡 = 𝑧
𝑧 2 + 8𝑧 + 15 = 0
(𝑧 + 3)(𝑧 + 5) = 0
𝑧 = −3 or 𝑧 = −5
1 1
So, 𝑡 − t = −3 or t − t = −5
𝑡 2 + 3𝑡 − 1 = 0 or 𝑡 2 + 5𝑡 − 1 = 0
−3±√13 −5±√29
𝑡 = 2 or 𝑡 = 2
as t = ex so t must be positive,
√13 − 3 √29 − 5
t= or
2 2
√13−3 √29−5
So, 𝑥 = ln ( ) or 𝑥 = ln ( )
2 2
Hence two solution and both are
negative.
two solutions and both are negative
no solution
four solutions two of which are negative
two solutions and only one of them is
negative
9 The number of values of 𝑟 ∈ {𝑝, 𝑞, ∼ 𝑝, ∼ B;
𝑞} for which ((p ∧ q) ⇒ (r ∨ q)) ∧ ((p ∧ ((𝑝 ∧ 𝑞) ⇒ (𝑟 ∨ 𝑞)) ∧ ((𝑝 ∧ 𝑟) ⇒ 𝑞)
r) ⇒ q) is a tautology, is: We know, p ⇒ q is equivalent to ∼
p∨q
 (∼ (p ∧ q) ∨ (r ∨ q)) ∧ (
∼ (p ∧ r)) ∨ q))
⇒ (∼ p ∨∼ q ∨ r ∨ q) ∧ (∼ p ∨
∼ r ∨ q)
⇒ (∼ p ∨ r ∨ t) ∧ (∼ p ∨∼ r ∨ q)
⇒ (t) ∧ (∼ p ∨∼ r ∨ q)
For this to be tautology, (∼ p ∨∼ r ∨
q) must be always true which follows
for 𝑟 =∼ 𝑝 or 𝑟 = 𝑞.
3
2
1
4
10 Let f: ℝ − {2,6} → ℝ be real valued A;
𝑥 2+2𝑥+1 𝑥 2+2𝑥+1
function defined as 𝑓(𝑥) = 𝑥 2−8𝑥+12
. Then Let 𝑦 = 𝑥 2 −8𝑥+12
range of 𝑓 is By cross multiplying
𝑦𝑥 2 − 8𝑥𝑦 + 12𝑦 − 𝑥 2 − 2𝑥 − 1 = 0
𝑥 2 (𝑦 − 1) − 𝑥(8𝑦 + 2) + (12𝑦 − 1)
=0
Case 1, y ≠ 1
D≥0
⇒ (8y + 2)2 − 4(y − 1)(12y − 1)
≥0
⇒ y(4y + 21) ≥ 0

−21
y ∈ (−∞, ] ∪ [0, ∞) − {1}
4
Case 2, y = 1
𝑥 2 + 2𝑥 + 1 = 𝑥 2 − 8𝑥 + 12
10𝑥 = 11
11
𝑥= So, 𝑦 can be 1
10
−21
Hence y ∈ (−∞, 4 ] ∪ [0, ∞)
21
(−∞, − ] ∪ [0, ∞)
4
21
(−∞, − ) ∪ (0, ∞)
4
21 21
(−∞, − ] ∪ [ , ∞)
4 4
21
(−∞, − ] ∪ [1, ∞)
4
11
( ) +( B;6
)
6
3x + 1 + 3 x − 1 3x + 1 − 3x − 1
( ) +( )
6 6
lim x 3 3x + 1 + 3 x − 1 3x + 1 − 3x − 1
(x + ) + (x − )
x → 6 6
x2 − 1 x2 − 1 lim x3
( ) + (x − )
x → 6 6
x + x2 − 1 x −1
2
   6
   
6
 1 1
 x  3 + + 3 −  +  3 + − 3 −  
3 1 1
  x x   x x  
  
lim x  
3
x →
 

6
1  
6
1   
 x 6  1 + 1 − 2  +  1 − 1 − 2  
  x   x  


(2 3 )
6
+0
= = 33 = (27 )
26 + 0
is equal to 9
is equal to 27
does not exist
27
is equal to
2
12 Let 𝑃 be the plane, passing through the C;
point (1, −1, −5) and perpendicular to Equation of Plane:
the line joining the points (4,1, −3) and 2(𝑥 − 1) − 3(𝑦 + 1) − 6(𝑧 + 5) = 0
(2,4,3). Then the distance of 𝑃 from the Or 2𝑥 − 3𝑦 − 6𝑧 = 35
point (3, −2,2) is |2(3) − 3(−2) − 6(2) − 35|
⇒ Required distance =
√4 + 9 + 36
=5
6
4
5
7
13 The absolute minimum value, of the A;
function 𝑓(𝑥) = |𝑥 2 − 𝑥 + 1| + [𝑥 2 − 𝑥 + 𝑓(𝑥) = |𝑥 2 − 𝑥 + 1| + [𝑥 2 − 𝑥 + 1]; 𝑥
1], where [𝑡] denotes the greatest integer ∈ [−1,2]
function, in the interval [−1,2], is: Let 𝑔(𝑥) = 𝑥 2 − 𝑥 + 1
1 2 3
= (𝑥 − ) +
2 4
∵ |𝑥 2 − 𝑥 + 1| and [𝑥 2 − 𝑥 + 2]
Both have minimum value at x = 1/2
3
⇒ Minimum 𝑓(𝑥) = + 0
4
3
=
4
3
4
3
2
1
4
5
4
14 Let the plane 𝑃: 8𝑥 + 𝛼1 y + 𝛼2 z + 12 = 0 A;
be parallel to the line L: 2 = 3 = 5 . If P: 8x + 𝛼1 y + 𝛼2 z + 12 = 0
x+2 y−3 z+4
x+2 y−3 𝑧+4
the intercept of P on the 𝑦-axis is 1, then L: = =
the distance between P and L is: 2 3 5
∵ P is parallel to L
⇒ 8(2) + 𝛼1 (3) + 5(𝛼2 ) = 0
⇒ 3𝛼1 + 5(𝛼2 ) = −16
 Also y-intercept of plane P is 1
⇒ 𝛼1 = −12
And 𝛼2 = 4
⇒ Equation of plane 𝑃 is 2𝑥 − 3𝑦 +
𝑧+3 = 0
⇒ Distance of line L from Plane P is =
0−3(6)+1+3
| |
√4+9+1
= √14
√14
6
√14
2
√
7

7
√
2
15 The foot of perpendicular from the origin C;
O to a plane P which meets the co- Equation of Plane:
ordinate axes at the points A, B, C is (2î + aĵ + 4k̂) ⋅ [(x − 2)î + (y − a)ĵ
(2, a, 4), a ∈ N. If the volume of the + (z − 4)k̂] = 0
tetrahedron OABC is 144 unit 3 , then ⇒ 2x + ay + 4z = 20 + a2
which of the following points is NOT on 20 + a2
P? ⇒A≡( , 0,0)
2
20 + a2
B ≡ (0, , 0)
a
20 + a2
C ≡ (0,0, )
4
⇒ Volume of tetrahedron
1
= [a⃗b ⃗ c]
6
1
= a⃗ ⋅ (b ⃗ × c)
6
1 20 + a2 20 + a2
⇒ ( )⋅( )
6 2 a
20 + a2
⋅( ) = 144
4
⇒ (20 + a2 )3 = 144 × 48 × a
⇒a=2
⇒ Equation of plane is 2x + 2y + 4z
= 24
Or x + y + 2z = 12
⇒ (3,0,4) Not lies on the Plane
x + y + 2z = 12
(2,2,4)
(0,4,4)
(3,0,4)
(0,6,3)
16 Let the mean and standard deviation of A;
marks of class A of 100 students be
 respectively 40 and 𝛼(> 0), and the mean A B A+B
and standard deviation of marks of class x1 = 40 x2 = 55 x = 50
B of n students be respectively 55 and
30 − 𝛼. If the mean and variance of the 1 =  2 = 30 −  2 = 350
marks of the combined class of 100 + n n1 100 n2 = n 100 + n
students are respectively 50 and 350, 100  40 + 55 n
then the sum of variances of classes 𝐴 and x=
100 + n
𝐵 is:
5000 + 50 n = 4000 + 55 n
1000 = 5 n
n = 200

2
=
x 2
i
− 402
1
100

22 =
 x 2j − 552
100

350 = 2 =
 x +  x − (x )
2
i
2
j 2

300
(1600 +  )  100 + (30 −  )
2 2
+ 3025  200

350 = − (50
300
2850  3 =  + 2 (30 −  ) + 1600 + 6050
2 2

8550 = 2 + 2 (30 −  ) + 7650

2

2 + 2 (30 −  ) = 900
2

2 − 40  + 300 = 0
 = 10, 30
12 + 22 = 102 + 202 = 500
500
650
450
900
17 Let a = iˆ + 2 ˆj + 3kˆ , b = iˆ − ˆj + 2kˆ and C;
c = 5iˆ − 3 ˆj + 3kˆ be three vectors. If r is a
vector such that, r  b = c  b and r  a = 0 .
2
Then 25 r is equal to
 a = iˆ + 2 ˆj + 3kˆ
b = iˆ − ˆj + 2kˆ
c = 5iˆ − 3 ˆj + 3kˆ
( r − c )  b = 0, r a =0
 r − c = b
(
Also, c + b  a = 0 )
(
 a c +  a b =0 )
a c − 8
 = =
ab 5

r=
( ) (
5 5iˆ − 3iˆ + 3kˆ − 8 iˆ − ˆj + 2kˆ )
5
ˆ ˆ ˆ
17i − 7 j + k
r=
5
1
r = ( 289 + 50 )
2

25
2
25 r = 339
449
336
339
560
18 Let H be the hyperbola, whose foci are A;
(1 ± √2, 0) and eccentricity is √2. Then 2ae = |(1 + √2) − (1 + √2)| = 2√2
the length of its lat us rectum is ae = √2
a=1
⇒ b = 1 ∵ e = √2
⇒ Hyperbola is rectangular
2 b2
⇒L⋅R= =2
a
2
3
5
2
3
2
19 𝛼
Let 𝛼 > 0. If ∫0
x
dx =
16+20√2
, A;
√x+𝛼−√x 15 After rationalising,
then 𝛼 is equal to:  x
0  ( x +  + x )
1
0  (x + ) − (x + ) + x 
3/2 1/2 3/2


1 2 2 2 
 (x +  )5/2 −  (x +  )3/2 + x5/2 
 5 3 5 0
1 5 2 2 2 2 
=  (2)5/2 − (2)3/2 + 5/2 − 5/2 + 5/2 
2 3 5 5 3 
 1  27/2 5/2 25/2 5/2 2 5/2 
=  +  
 5 3 3 
 27/2 25/2 2 
= 3/2  − + 
 5 3 3
3/2 3/2
= (24 2 − 20 2 + 10) = (4 2 + 10)
15 15
Now,
𝛼3/2 16+20√2
(4√2 + 10) =
15 15
⇒𝛼=2
2
4
√2
2√2
20 The complex number z =
i−1
𝜋 𝜋 is A;
cos +isin
3 3 𝑖−1 𝑖 −1
equal to: 𝑍= 𝜋 𝜋 =
cos + 𝑖sin 1 √3
3 3 + 2 𝑖
2
1 3
− √ i
i−1 2 2
= ×1
1 √3
+ 2 i − √3/2i
2 2
√3 − 1 √3 + 1
= + i
2 2
Apply polar form,
√3 − 1
𝑟cos 𝜃 =
2
√3 + 1
𝑟sin 𝜃 =
2
√3+1
Now, tan 𝜃 =
√3−1
5𝜋
So, 𝜃 = 12
5𝜋 5𝜋
√2 (cos + isin )
12 12
𝜋 𝜋
cos − isin
12 12
𝜋 𝜋
√2 (cos + isin )
12 12
5𝜋 5𝜋
√2i (cos − isin )
12 12
#1,2,3,4, SINGLE ANSWER CORRECT TYPE
5,
6,7,8,9,10
,
11,12,13,
14,15,16,
17,18,19,
20
21 The Coefficient of x −6 , in the expansion of 5040;
4x 5 9
( 5 + 2x2) , is ______ 4x 5 9
( + 2)
5 2x
 4x 9−r 5 r
Now, Tr+1 = 9 Cr ⋅ ( 5 ) (2x2)
4 9−r 5 r
= 9 Cr ⋅ ( ) ( ) ⋅ x 9−3r
5 2
Coefficient of 𝑥 −6 i.e., 9 − 3𝑟 = −6 ⇒
𝑟=5
4 4
So, Coefficient of x −6 = 9 C5 (5) ⋅
5 5
(2) = 5040
22 Let the area of the region 125;
( x , y ) : 2x − 1  y  x − x , 0  x  1 be
2
 y  2x − 1 , y  x 2 − x

A. Then (6 A + 11) is equal to _____

2

Both curves are symmetric about

1
x = . Hence
2
1

 ( ( x − x ) − (1 − 2x ) ) dx
2
A=2 2

3− 5
2
1 1
2
 − x5 3 2 2
A=2  ( )
− x + 3x − 1 dx = 2  + x − x
2

3− 5  3 2 3 − 5
2
2

On solving 6𝐴 + 11 = 5√5
(6𝐴 + 11)2 = 125
23 If 2𝑛+1 𝑃𝑛−1 : 2𝑛−1 𝑃𝑛 = 11: 21, then n2 + 45;
n + 15 is equal to: (2n + 1)! (n − 1)! 11
=
(n + 2)! (2n − 1)! 21
(2𝑛 + 1)(2𝑛) 11
⇒ =
(𝑛 + 2)(𝑛 + 1)𝑛 21
2n + 1 11
⇒ =
(n + 1)(n + 2) 42
⇒n=5
⇒ n2 + n + 15 = 25 + 5 + 15 = 45
24 If the constant term in the binomial 98;
5 9 9
x2 4  52 
expansion of ( 2 − xℓ ) is -84 and the  x 4
In,  − 
Coefficient of x −3ℓ is 2𝛼 𝛽, where 𝛽 < 0 is  2 x 
 
an odd number, Then |𝛼ℓ − 𝛽| is equal to
(x )
9−r
52 r
______  −4
Tr + 1 = Cr
9
x 
29 − r  
 9 45 5r
C − − 1r
= ( − 1)
r r
9−r
4r x 2 2
2
= 45 − 5r − 21r = 0
45
r= . . . (1)
5 + 21
Now, according to the question,
9C
(−1)r 29−rr 4r = −84
= (−1)r 9 Cr 23r−9 = 21 × 4
Only natural value of r possible if
3r − 9 = 0
𝑟 = 3 and 9 C3 = 84
∴ 1 = 5 from equation (1)
45 5r
Now, coefficient of 𝑥 −31 = 𝑥 2 − 2 −lr
at 1 = 5, gives r = 5
45
∴ 9 𝑐5 (−1) 4 = 2𝛼 × 𝛽
2
= −63 × 27
⇒ 𝛼 = 7, 𝛽 = −63
∴ value of |𝛼ℓ − 𝛽| = 98
25 Let a , b , c be three vectors such that 3;
a = 31, 4 b = c = 2 and ( )
2 a  b = 3(c  a )

( )
2 a  b = 3 ( c  a ) . If the angle between b (
a  2b + 3c = 0 )
2  ac 
2
(
a =  2b + 3c )
and c is , then   is equal to ____ 2
3  ab  a = 2 2b + 3c

a
2
= 2 4 b ( 2
+9 c
2
+ 12 b  c )
31 = 312   =  1
(
a =  2b + 3c )
ac 2 bc
=
a b 2b b + 3c b
3
( )
2 2 2 2
bc = b c − b c =
4
3
ac 2
= 2 =− 3
a b 1 3
2 −
4 2
 ac 
  =3
 ab 
26 Let S be the set of all 𝑎 𝜖 𝑁 such that the 146;
area of the triangle formed by the tangent
at the point P(b, c ), b, c  N , on the
 parabola y2 = 2ax and the lines 𝑥 = 𝑏, 𝑦 =

0 is 16 unit2, then  a is equal to ___

aS

As P(b, c) lies on parabola so c 2 =

2ab
Now equation of tangent to parabola
y 2 = 2ax in point
(x + x1 )
form is yy1 = 2a , (x1 , y1 )
2
= (b, c)
⇒ yc = a(x + b)
For point B, put y = 0, now x = −b
1
So, area of △ PBA, 2 × AB × AP = 16
1
⇒ × 2 b × c = 16
2
⇒ bc = 16
As b and c are natural number so
possible values of (b, c) are
(1,16), (2,8), (4,4), (8,2) and (16,1)
c2
Now from equation (1) a = 2 b and
a ∈ N, so values of (𝑏, 𝑐) are
(1,16), (2,8) and (4,4) now values of
are 128,16 and 2 .
Hence sum of values of a is 146 .
27 The sum 6952;
12 − 2.32 + 3.52 − 4.72 + 5.92 − Separating odd placed and even
⋯ … . . +15.292 is ______ placed terms we get
S = (1.12 + 3.52 + ⋯ .15 ⋅ (29)2 )
− (2 ⋅ 32 + 4 ⋅ 72
+ ⋯ . +14 ⋅ (27)2
8

S = ∑ (2n − 1)(4n − 3)2

n=1
7

− ∑ (2n)(4n − 1)2
n=1
Applying summation formula we get
= 29856 − 22904 = 6952
28 Let A be the event that the absolute 10;
difference between two randomly |𝑥 − 𝑦| < 𝑎 ⇒ −𝑎 < 𝑥 − 𝑦 < 𝑎
choosen real numbers in the sample ⇒ 𝑥 − 𝑦 < 𝑎 and 𝑥 − 𝑦 > −𝑎
space [0,60] is less than or equal to a. If
11
P(A) = 36, then a is equal to _______
 ar (OACDEG)
P(A) =
(OBDF)
ar (OBDF) − ar (ABC) − ar (EFG)
=
ar (OBDF)
11
⇒
36
1 1
(60)2 − 2 (60 − a)2 − 2 (60 − a)2
=
3600
⇒ 1100 = 3600 − (60 − a)2
⇒ (60 − a)2 = 2500 ⇒ 60 − a = 50
⇒ a = 10
29 Let 𝐴 = [𝑎𝑖𝑗 ], 𝑎𝑖𝑗 ∈ 𝑍 ∩ [0,4],1 ≤ 𝑖, 𝑗 ≤ 2. 204;
The number of matrices 𝐴 such that the As given 𝑎 + 𝑏 + 𝑐 + 𝑑 = 3 or 5 or 7
sum of all entries is a prime number 𝑝 ∈ or 11
(2,13) is _______ if sum = 3
(1 + 𝑥 + 𝑥 2 + ⋯ … + 𝑥 4 )4 → 𝑥 3
(1 − 𝑥 5 )4 (1 − 𝑥)−4 → 𝑥 3
∴ 4+3−1 𝐶3 = 6 𝐶3 = 20
If sum = 5
(1 − 4𝑥 5 )(1 − 𝑥)−4 → 𝑥 5
⇒ 4+5−1 𝐶5 − 4𝑥 4.4+0−1 𝐶0 = 8 𝐶5 − 4
= 52
If sum = 7
(1 − 4x 5 )(1 − x)−4 → x 7
⇒ 4+5−1 C4 − 4.4+0−1 C0 = 8 C5 − 4
= 52
If sum = 11
(1 − 4x 5 + 6x10 )(1 − x)−4 → x11
⇒ 4+11−1 C11 − 4 ⋅ 4+6−4 C6
+ 6. 4+1−1 C1
= 14 C11 − 4. 9 C6 + 6.4
= 364 − 336 + 24
= 52
∴ Total matrices = 20 + 52 + 80
+ 52 = 204
30 Let 𝐴 be a 𝑛 × 𝑛 matrix such that |𝐴| = 2. 5;
If the determinant of the matrix Adj (2 ⋅ |Adj (2Adj (2 A−1 ))|
n−1
Adj (2 A−1 )). is 284 , then n is equal to = |2Adj (Adj (2 A−1 ))|
_______ = 2n(n−1) |Adj (2 A−1 )|n−1
 = 2n(n−1) |(2 A−1 )|(n−1)(n−1)
= 2n(n−1) 2n(n−1)(n−1) |A−1 |(n−1)(n−1)
1
= 2n(n−1)+n(n−1)(n−1) (n−1)2
|𝐴|
2n(n−1)+n(n−1)(n−1)
= 2
2(n−1) 2 2
= 2n(n−1)+n(n+1) −(n−1)
2
= 2(n−1)(n −n+1)
( n − 1)( n2 − n + 1)
Now, 2
( n − 1)( n2 − n + 1)
2 = 284
So, 𝑛 = 5
#21,22,2 NUMERICAL TYPE
3,24,25,
26,27,28,
29,30
31 The H amount of thermal energy is B
developed by a resistor in 10 s when a
current of 4 A is passed through it. If the
current is increased to 16 A, the thermal
energy developed by the resistor in 10 s
will be:
H
16 H
H
4
4H
32 A body is moving with constant speed, in D
a circle of radius 10 m. The body
completes one revolution in 4 s. At the
end of 3rd second, the displacement of
body (in m ) from its starting point is:
30
15𝜋
5𝜋
10√2
33 A microscope is focused on an object at A
the bottom of a bucket. If liquid with
5
refractive index is poured inside the
3
bucket, then microscope have to be raised
by 30 cm to focus the object again. The
height of the liquid in the bucket is:
75 cm
50 cm
18 cm
12 cm
34 A stone of mass 1 kg is tied to end of a A
massless string of length 1 m. If the
breaking tension of the string is 400 N,
then maximum linear velocity, the stone
 can have without breaking the string,
while rotating in horizontal plane, is:
20 ms−1
40 ms−1
400 ms−1
10 ms−1
35 For a solid rod, the Young's modulus of D
elasticity is 3.2 × 1011 Nm−2 and density
is 8 × 103 kg m−3 . The velocity of
longitudinal wave in the rod will be:
145.75 × 103 ms−1
3.65 × 103 ms−1
18.96 × 103 ms−1
6.32 × 103 ms−1
36 A long conducting wire having a current I C
flowing through it, is bent into a circular
coil of N turns. Then it is bent into a
circular coil of n turns. The magnetic field
is calculated at the centre of coils in both
the cases. The ratio of the magnetic field
in first case to that of second case is:
N: n
𝑛2 : 𝑁 2
N 2 : n2
𝑛: 𝑁
37 Heat energy of 735 J is given to a diatomic A
gas allowing the gas to expand at
constant pressure. Each gas molecule
rotates around an internal axis but do not
oscillate. The increase in the internal
energy of the gas will be:
525 J
441 J
572 J
735 J
38 Given below are two statements: D
Statement I: For transmitting a signal,
size of antenna ( 𝑙 ) should be comparable
𝜆
to wavelength of signal (at least 𝑙 = 4 in
dimension).
Statement II: In amplitude modulation,
amplitude of carrier wave remains
constant (unchanged).
In the light of the above statements,
choose the most appropriate answer
from the options given below.
Both Statement I and Statement II are
correct
Both Statement I and Statement II are
incorrect
Statement I is incorrect but Statement II
is correct
 Statement I is correct but Statement II is
incorrect
39 The number of turns of the coil of a D
moving coil galvanometer is increased in
order to increase current sensitivity by
50%. The percentage change in voltage
sensitivity of the galvanometer will be:
100%
50%
75%
0%
40 If the two metals A and B are exposed to D
radiation of wavelength 350 nm. The
work functions of metals A and B are
4.8eV and 2.2eV. Then choose the correct
option.
Metal B will not emit photo-electrons
Both metals A and B will emit photo-
electrons
Both metals A and B will not emit
photoelectrons
Metal A will not emit photo-electrons
41 A body weight W, is projected vertically B
upwards from earth's surface to reach a
height above the earth which is equal to
nine times the radius of earth. The weight
of the body at that height will be:
𝑤
91
𝑤
100
𝑤
9
𝑤
3
42 Match List-I with List-II. B
List – I List – II
(A) Angular (I) ML2T − 2 
momentum
(B) Torque (II) ML− 2T − 2 
(C) Stress (III) ML2T − 1 
(D) Pressure (IV) ML− 1T − 2 
gradient
Choose the correct answer from the
options given below.
A-I, B-IV, C-III, D-II
A-III, B-I, C-IV, D-II
A-II, B-III, C-IV, D-I
A-IV, B-II, C-I, D-III
43 An alternating voltage source 𝑉 = A
260 sin(628 𝑡) is connected across a pure
 inductor of 5 mH. Inductive reactance in
the circuit is:
3.14 Ω
6.28 Ω
0.5 Ω
0.318 Ω
44 Match List-I with List-II. C
List – I List – II
(A Microwave (I) Physiotherap
) s y
(B UV rays (II) Treatment of
) cancer
(C) Infra-red (III Lasik eye
rays ) surgery
(D X-rays (IV Aircraft
) ) navigation
Choose the correct answer from the
option given below:
A-II, B-IV, C-III, D-I
A-IV, B-I, C-II, D-III
A-IV, B-III, C-I, D-II
A-III, B-II, C-I, D-IV
45 The radius of electron's second stationary B
orbit in Bohr's atom is 𝑅. The radius of 3rd
orbit will be
𝑅
3
2.25 R
3R
9R
46 Under the same load, wire A having B
length 5.0 m and cross section 2.5 ×
10−5 m2 stretches uniformly by the same
amount as another wire 𝐵 of length 6.0 m
and a cross section of 3.0 × 10−5 m2
stretches. The ratio of the Young's
modulus of wire A to that of wire 𝐵 will
be:
1: 4
1: 1
1: 10
1: 2
47 Considering a group of positive charges, A
which of the following statements is
correct?
Net potential of the system cannot be
zero at a point but net electric field can be
zero at that point.
Net potential of the system at a point can
be zero but net electric field can't be zero
at that point.
 Both the net potential and the net field
can be zero at a point.
Both the net potential and the net electric
field cannot be zero at a point.
48 A body of mass 10 kg is moving with an D
initial speed of 20 m/s. The body stops
after 5 s due to friction between body and
the floor. The value of the coefficient of
friction is:
(Take acceleration due to gravity g =
10 ms−2 )
0.2
0.3
0.5
0.4
49 A hypothetical gas expands adiabatically A
such that its volume changes from 08
litres to 27 litres. If the ratio of final
pressure of the gas to initial pressure of
16 𝐶
the gas is 81. Then the ratio of 𝐶𝑃 will be:
𝑉
4
3
3
1
1
2
3
2
50 Given below are two statements: C
Statement I: In a typical transistor, all
three regions emitter, base and collector
have same doping level.
Statement II: In a transistor, collector is
the thickest and base is the thinnest
segment.
In the light of the above statements,
choose the most appropriate answer
from the options given below.
Both Statement I and Statement II are
correct
Both Statement I and Statement II are
incorrect
Statement I is incorrect but Statement II
is correct
Statement I is correct but Statement II is
incorrect
#31,32,3 SINGLE ANSWER CORRECT TYPE
3,34,35,
36,37,38,
39,40,
41,42,43,
44,45,
46,47,48,
49,50
51 A series LCR circuit consists of R = 25
80ΩXL = 100Ω, and XC = 40Ω The input
voltage is 2500cos (100𝜋t) V. The
amplitude of current, in the circuit, is
________ A.
52 Two light waves of wavelengths 800 and 48
600 nm are used in Young's double slit
experiment to obtain interference fringes
on a screen placed 7 m away from plane
of slits. If the two slits are separated by
0.35 mm, then shortest distance from the
central bright maximum to the point
where the bright fringes of the two
wavelength coincide will be _______ mm.
53 A water heater of power 2000 W is used 300
to heat water. The specific heat capacity
of water is 4200 J kg −1 K −1. The
efficiency of heater is 70%. Time required
to heat 2 kg of water from 10∘ C to 60∘ C is
________ s.
(Assume that the specific heat capacity of
water remains constant over the
temperature range of the water).
54 A ball is dropped from a height of 20 m. If 5
the coefficient of restitution for the
collision between ball and floor is 0.5,
after hitting the floor, the ball rebounds
to a height of _______ m.
55 Two discs of same mass and different 5
radi1 are made of different materials
such that their thicknesses are 1 cm and
0.5 cm respectively. The densities of
materials are in the ratio 3: 5. The
moment of inertia of these discs
respectively about their diameters will be
𝑥
in the ratio of 6 . The value of 𝑥 is _______
56 If the binding energy of ground state 136
electron in a hydrogen atom is 13.6eV,
then, the energy required to remove the
electron from the second excited state of
Li2+ will be: 𝑥 × 10−1 eV. The value of 𝑥 is
_____
57 For the given circuit, in the steady state, 1
|VB − VD | = _______ V
58 Two parallel plate capacitors 𝐶1 and 𝐶2 55
each having capacitance of 10𝜇F are
individually charged by a 100 V D.C.
source. Capacitor C1 is kept connected to
the source and a dielectric slab is inserted
between it plates. Capacitor C2 is
disconnected from the source and then a
dielectric slab is inserted in it. Afterwards
the capacitor 𝐶1 is also disconnected from
the source and the two capacitors are
finally connected in parallel combination.
The common potential of the
combination will be ______ V. (Assuming
Dielectric constant = 10 )
59 The displacement equations of two 20
interfering waves are given by
𝜋
𝑦1 = 10sin (𝜔𝑡 + ) cm,
3
𝑦2 = 5[sin (𝜔𝑡) + √3cos 𝜔𝑡]cm
respectively. The amplitude of the
resultant wave is ______ cm.
60 Two bodies are projected from ground 80
with same speed 40 𝑚𝑠 −1 at two different
angles with respect to horizontal. The
bodies were found to have same range. If
one of the body was projected at an angle
of 60°, with horizontal then sum of the
maximum heights, attained by the two
projectiles, is ____ m.
(Given 𝑔 = 10 𝑚𝑠 − 2 )
#51,52,5 NUMERICAL TYPE
3,54,55,
56,57,58,
59,60
61 In the following halogenated organic B;
compounds the one with maximum
number of chlorine atom in its structure
is:
 Chloral
Gammaxene
Chloropicrin
Freon-12
62 Incorrect statement for the use of A;
indicators in acid-base titration is: Indicator pH range

Methyl orange 3.2 − 4.5

Phenolpthalein 8.3 − 10.5

Methyl orange may be used for a

strong acid vs strong base and strong
acid vs weak base titration.
Phenolpthalein may be used for a
strong acid vs strong base and weak
acid vs strong base titration.
Methyl orange may be used for a weak
acid vs weak base titration.
Methyl orange is a suitable indicator for a
strong acid vs weak base titration.
Phenolphthalein is a suitable indicator for
a weak acid vs strong base titration
Phenolphthalein may be used for a strong
acid vs strong base titration
63 Which of the following compounds are A;
not used as disinfectants? Veronal is neurological medicine,
(A) Chloroxylenol Prontosil is antibiotic, rest all are
(B) Bithional disinfectants.
(C) Veronal
(D) Prontosil
(E) Terpineol
Choose the correct answer from the
options given below:
𝐴, 𝐵, 𝐸
 𝐴, 𝐵
B, D, E
𝐶, 𝐷
64 A hydrocarbon ' X ' with formula C6 H8 D;
uses two moles of H2 on catalytic
hydrogenation of its one mole. On
ozonolysis, ' X ' yields two moles of
methane dicarbaldehyde. The
hydrocarbon ' X ' is:
hexa-1, 3, 5-triene
1-methylcyclopenta-1, 4-diene
cyclohexa-1, 3-diene
cyclohexa-1, 4-diene
65 Cyclohexylamine when treated with B;
nitrous acid yields (P). On heating (P)
with PCC results in (Q). When (Q) is
heated with dil. NaOH we get (R). The
final product (R) is:

66 Given below are two statements: C;

Statement I: Upon heating a borax bead (Borax Bead Test)
dipped in cupric sulphate in a luminous On treatment with metal salt, boric
flame, the colour of the bead becomes anhydride forms metaborate of the
green. metal which gives different colours
Statement II: The green colour observed in oxidising and reducing flame. For
is due to the formation of copper(I) example, in the case of copper
metaborate. sulphate, following reactions occur.
In the light of the above statements, Non − lu min ous flame
CuSO4 + B2O3 ⎯⎯⎯⎯⎯⎯→(oxidisisng )
Cu(BO2 )2 + SO3
choose the most appropriate answer Cupric metaborate
blue−green

from the options given below: Two reactions may take place in
reducing flame (Luminous flame)
(i) The blue-green Cu(BO2 )2 is
reduced to colourless cuprous
metaborate as:
 2Cu(BO2 ) + 2NaBO2 + C ⎯⎯⎯⎯
Luminous
flame
→ 2CuBO2 + Na2B4O7 +
(ii) Cupric metaborate may be
reduced to metallic copper and bead
appears red opaque.
2Cu(BO2 ) + 4 NaBO2 + 2C ⎯⎯⎯⎯
Luminous
flame
→ 2Cu + 2Na2B4O7 +
Both Statement I and Statement II are
true
Statement I is true but Statement II is
false
Both Statement I and Statement II are
false
Statement I is false but Statement II is
true
67 Evaluate the following statements for D;
their correctness. (A) ΔTb ∝ i × c
(A) The elevation in boiling point (B) Azeotropic mixtures have same
temperature of water will be same for composition in both liquid and
0.1MNaCl and 0.1M urea. vapour phase.
(B) Azeotropic mixtures boil without (C) Osmosis always takes place
change in their composition from hypotonic to hypertonic
(C) Osmosis always takes place from solution.
hypertonic to hypotonic solution (D) M =
30×10×1.26
≈ 4.09M
98
(D) The density of 32%H2 SO4 solution
(E) When KI solutions is added to
having molarity 4.09M is approximately
AgNO3 solution, positively
1.26 g mL−1
charged solution results due to
(E) A negatively charged sol is obtained adsorption of Ag ∘ ions from
when KI solution is added to silver nitrate
dispersion medium
solution.
AgI/Ag +
Choose the correct answer from the Positively charged
options given below:
B, D, and E only
A, B, and D only
A and C only
B and D only
68 Compound A, C5H10O5, given a tetra A;
acetate with Ac2O and oxidation of A with (i) Formation of tetraacetate with
Br2 – H2O gives an acid, C5H10O6. Reduction Ac2O means compound A has four –
of A with HI gives isopentane. The possible OH linkage.
structure of A is: (ii) Reduction of A with HI gives
Isopentane i.e., molecule contains
five carbon atoms.
69 Arrange the following orbitals in B;
decreasing order of energy? (A) n = 3; 1 = 0; m = 0; 3 s orbital
(A) n = 3,1 = 0, m = 0 (B) n = 4; 1 = 0; m = 0; 4 s orbital
(B) n = 4,1 = 0, m = 0 (C) n = 3; 1 = 1; m = 0; 3p orbital
(C) n = 3, l = 1, m = 0 (D) n = 3; 1 = 2; m = 0; 3 d orbital
(D) n = 3,1 = 2, m = 1 As per Hund's rule energy is given by
The correct option for the order is: (n + 𝑙) value. If value of (n + 𝑙)
remains same then energy is given
by n only.
B>D>C>A
D>B>C>A
A>C>B>D
D>B>A>C
70 The Lewis acid character of boron tri D;
halides follows the order: Extent of back bonding, reduces
down the group leading to more
Lewis acidic strength.
BF3 > BCl3 > BBr3 > BI3 (extent of
back bonding)
(2𝑝 − 2𝑝)(2𝑝 − 3𝑝)(2𝑝 − 4𝑝)(2𝑝
− 5𝑝)
BF3 < BCl3 < BBr3 < BI3 (Lewis
acidic nature)
BBr3 > BI3 > BCI3 > BF3
BCl3 > BF3 > BBr3 > BI3
BF3 > BCl3 > BBr3 > BI3
BI3 > BBr3 > BCl3 > BF3
71 Match List-I with List-II. D;
List – I List – II (A) Physisorption = 20 − 40 kJ/mol
( Physisorption (I Single and Chemisorption
A ) layer = 80 − 240 kJ/mol
) adsorptio (B) Physisorption is multi-layered
n and chemisorption is
( Chemisorption (I 20–40 kJ unimolecular layered.
B I) 𝑚𝑜𝑙 − 1 (C) In heterogeneous catalysis,
) medium and catalyst are in
( N2(g) + 3H2(g) ⎯⎯⎯ →
Fe(s)
(I 2NH
Chromat different phases.
3(g)
C II ography (D) Chromatography uses
) ) adsorption to purify/separate
mixtures.
 ( Analytical (I Heteroge
D Application or V) neous
) Adsorption catalysis
Choose the correct answer from then
options given below.
A-II, B-III, C-I, D-IV
A-III, B-IV, C-I, D-II
A-IV, B-II, C-III, D-I
A-II, B-I, C-IV, D-III
72 Given below are two statements: one is A;
labelled as Assertion (A) and the other is From Sc to Mn ionization energy is
labelled as Reason (R) less than that of Mg
Assertion (A): The first ionization
enthalpy of 3 d series elements is more
than that of group 2 metals
Reason (R): In 3d series of elements
successive filling of d-orbitals takes place.
In the light of the above statements,
choose the correct answer from the
options given below:

Both (A) and (R) are true and (R) is the

correct explanation of (A)
Both (A) and (R) are true but (R) is not
the correct explanation of (A)
(A) is false but (R) is true
(A) is true but (R) is false
73 The element playing significant role in B;
neuromuscular function and Calcium plays important role in
interneuronal transmission is: neuromuscular function,
interneuronal transmission, cell
membrane etc.,
Be
Ca
Li
Mg
74 Given below are two statements: A;
Statement I: H2 O2 is used in the synthesis It is used in the synthesis of
of Cephalosporin hydroquinone, tartaric acid and
Statement II: H2 O2 is used for the certain food products and
restoration of aerobic conditions to pharmaceuticals (cephalosporin) etc.
sewage wastes. Restoration of aerobic conditions to
In the light of the above statements, sewage wastes etc.,
choose the most appropriate answer
from the options given below:
Both Statement I and Statement II are
correct
Statement I is incorrect but Statement II
is correct
 Statement I is correct but Statement II is
incorrect
Both Statement I and Statement II are
incorrect
75 The normal rain water is slightly acidic A;
and its pH value is 5.6 because of which We are aware that normally rain
one of the following? water has a pH of 5.6 due to the
presence of H + ions formed by the
reactions of rain water with carbon
dioxide present in the atmosphere.
H2 O(l) + CO2 ( g) ⇋ H2 CO3 (aq)
H2 CO3 (aq) ⇋ H+ (aq) + HCO− 3 (aq)
CO2 + H2 O → H2 CO3
4NO2 + O2 + 2H2 O → 4HNO3
2SO2 + O2 + 2H2 O → 2H2 SO4
N2 O5 + H2 O → 2HNO3
76 When a hydrocarbon A undergoes A;
complete combustion it requires 11 y y
Cx Hy + (x + ) O2 → xCO2 + H2 O
equivalents of oxygen and produces 4 4 2
y
equivalents of water. What is the =4∴y=8
molecular formula of A? 2
8
x + = 11
4
∴x=9
∴ Hydrocarbon will be = C9 H8
C9 H8
C11 H4
C5 H8
C11 H8
77 An organic compound  A  ( C4H11N ) , D;
C4 H11 N releases N2 with HNO2 i.e., it
shows optical activity and gives N2 gas on
is primary amine.
treatment with HNO2 . The compound [A]
After reacting with Hinsberg reagent
reacts with PhSO2Cl producing a it forms a compound which is soluble
compound which is soluble in KOH. The in KOH, Hence, the amine is primary.
structure of A is:

78 Which one of the following statements is B;

incorrect? Van - Arkel process is used for
purification of Ti, Zr, Hf and B.
 Boron and Indium can be purified by
zone refining method.
Van- Arkel method is used to purify
tungsten.
Cast iron is obtained by melting pig iron
with scrap iron and coke using hot air
blast.
The malleable iron is prepared from cast
iron by oxidising impurities in a
reverberatory furnace.
79 Which of the following elements have A;
half-filled f-orbitals in their ground state? 1 62 Sm: 4f 6 6 s2
(Given: atomic number Sm = 62; Eu = 2 64 Gd: 4f 7 5 d1 6 s2
63; Tb = 65; Gd = 64, Pm = 61) 3 63 Eu: 4f 7 6 s2
A. Sm 4 65 Tb: 4f 9 6 s2
B. Eu 5 61 Pm: 4𝑓 5 6 s2
C. Tb
D. Gd
E. Pm
Choose the correct answer from the
options given below:
B and D only
A and E only
A and B only
C and D only
80 In Dumas method for the estimation of B;
N2 , the sample is heated with copper Duma's method.
oxide and the gas evolved is passed over: The nitrogen containing organic
compound, when heated with CuO in
a atmosphere of CO2 , yields free N2
in addition to CO2 and H2 O.
y
Cx Hy Nz + (2x + 2) CuO → xCO2 +
y z y
H O+2 N2 + (2x + 2) Cu
2 2
Traces of nitrogen oxides formed, if
any, are reduced to nitrogen by
passing the gaseous mixture over
heated copper gauze.
Ni
Copper gauze
Pd
Copper oxide
#61,62,6 SINGLE ANSWER CORRECT TYPE
3,64,65,
66,67,68,
69,70,
71,72,73,
74,75,
76,77,78,
79,80
81 If the CFSE of [Ti(H2 O)6 ]3+ is −96.0 kJ/ 480;
mol, this complex will absorb maximum (Ti+3 (H2 O)6 )3+
at wavelength _____ nm. (nearest integer) Ti+3 : 3 d′
 Assume Planck's constant (h) = 6.4 × C.F.S.E. = −0.4 × Δ0
10−34 Js Speed of light (c) = 3.0 × 108 m/ 96 × 103
s and Avogadro's constant (NA ) = 6 × =− J
N0
1023 /mol. 96 × 103
Δ0 =
0.4 × 6 × 1023
hc 96 × 103
⇒ =
𝜆 0.4 × 6 × 1023
𝜆
0.4 × 6 × 1023 × 6.4 × 10−34 × 3 × 108
=
96 × 103
−6
= 0.48 × 10 m
= 480 × 10−9 m
= 480 nm
82 Amongst the following, the number of 5;
species having the linear shape is ______.
XeF2 , I3+ , C3O2 , I3− , CO2 , SO2 , BeCl and BCl2

83 The resistivity of a 0.8M solution of an 25;

electrolyte is 5 × 10−3 Ωcm. Its molar 𝜅 × 1000
Λm =
conductivity is ________ × M
104 Ω−1 cm2 mol−1 . (Nearest integer) 1 1000
Λm = ×
𝜌 M
1 1000
×
5 × 10−3 0.8

25 × 104 Ω−1 cm−2 mol−1

84 At 298 K, the solubility of silver chloride 10;
in water is 1.434 × 10−3 g L−1 . The value AgCl(s) → Ag + (aq. ) + Cl− (aq.)
S
of −log K sp for silver chloride is ________ S
2
1.43
(Given mass of Ag is 107.9 g mol−1 and K sp = S2 = ( × 10−3 )
mass of Cl is 35.5 g mol−1 ) 143.4
= 10−10 − log K sp
= 10
85 A sample of a metal oxide has formula 59;
M0.83 O1.00. The metal 𝑀 can exist in two
oxidation states +2 and +3 . In the sample
of M0.83 O1.00, the percentage of metal ions
existing in +2 oxidation state is _____ % 2𝑥 + 3(0.83 − 𝑥) = 2
(nearest integer) 𝑥 = 0.49
0.49
%𝑀2+ = × 100
0.83
= 59%
86 Assume carbon burns according to 227;
following equation: 2C(s) + O2 ( g) → 2CO(g)
2C(s) + O2( g) → 2CO(g) 1 mol 1.5 mol
When 12 g carbon is burnt in 48 g of Limiting reagent is carbon. One mole
oxygen, the volume of carbon monoxide carbon produces one mole CO.
produced is______ × 10−1 L at STP Hence, volume at STP is 227 × 10−1
[nearest integer] litre
[Given: Assume CO as ideal gas, Mass of C
is 12 g mol−1 , Mass of O is 16 g mol−1 and
molar volume of an ideal gas at STP is
22.7 L mol−1 ]
87 The number of alkali metal(s), from 2;
Li, K, Cs, Rb having ionization enthalpy K, Rb and Cs form stable super oxides
greater than 400 kJ mol−1 and forming but Cs has ionisation enthalpy less
stable super oxide is ______ than 400 kJ.
88 Enthalpies of formation of 173;
CCl4 ( g), H2 O(g), CO2 ( g) and HCl(g) are Δr H = ∑Hp − ∑HR
−105, −242, −394 and −92 kJ mol−1 = (−394 + 4 × −92) − (−105
respectively. The magnitude of enthalpy + (2 × −242))
of the reaction given below is _______ = −173 kJ/mol
kJmol−1
(nearest integer)
CCl4 ( g) + 2H2 O(g) → CO2 ( g) + 4HCl(g)
89 The number of molecules which gives 3;
haloform test among the following
molecules is _______

90 The rate constant for a first order 17;

reaction is 20 min−1. The time required Co Co
C= =
for the initial concentration of the 2n 32
1 n =5
reactant to reduce to its 32 level is
t = 5t1/2
_________ × 10−2 min. (Nearest integer)
5 × 0.693 0.693
(Given: ln 10 = 2.303 log 2 = 0.3010) = =
20 4
= 0.17325 min = 17.325 × 10−2 min
#81,82,8 NUMERICAL TYPE
3,84,85,
86,87,88,
89,90