Chapter 1

Solutions
SECTION -A 6. Consider 0.1 M solution of two solutes X and Y.
Solute X dissociates in two ions whereas Y
Objective Type Questions dimerises in the solution. Which of the following is
1. If Hg2Cl2 is 100% ionised then its van't Hoff factor
will be false? (X and Y represents solution containing X
(1) 2 and Yrespectively)
(2) 4
(3) 6 (4) 3 (1) (AT.), >(AT,),
2. Lowering of vapour pressure for 1m aqueous
solution is 1.08 mm of Hg at 25°C. The vapour (2) (B-P), >(B-P),
pressure of pure liquid at 25°C is 1Ox mm of Hg. (3) (F.P), >(F.P),
The value of x will be, assuming very dilute solution
(1) 4 (2) 6 (4) (AT,), >(AT,),
(3) 8 (4) 3 7. An ideal solution was found to have a vapour
3. How many terms will have negative value for a pressure of 80 torr when the mole fraction of non
solution showing -ve deviation? volatile solute is 0.2. Find vapour pressure of pure
AGmbmix AS.m AHmbx AVmix solvent at same temperature.
(1) 2 (1) 64 torr (2) 72 torr
(2) 3
(3) 4 (4) 1 (3) 80 torr (4) 100 torr
4. 8. The freezing point of a 4% (wlv) aqueous solution
Dry Air> of 'A' is equal to the freezing point of 10% (wlv)
EMOist Air
aqueous solution of 'B'. The molecular weight of A
is 60, find out the molecular weight of B. Assume
both A and B are non electrolyte and
molarity = molality
The above set up has been repeated four times (1) 150ht (2) 90
with 4 different aqueous solution of same non (3) 45 (4) 180
volatile solute with differeit concentrations. The 9. When mercuric iodide is added to the aqueous
loss in weight of solution in container is in order solution of Kl, then the:
D> B>C> A. Arrange A, B, C, D in terms of (1) Freezing point is raised
concentration of solute
(2) A>B> C>D (2) Freezing point is lowered
(1) D> B> C>A
(3) A> C>B>D (4) A> D > C> B (3) Freezing point does not change
(4) Boiling point does not change
5. Azeotropic mixture of water and CzH5OH boils at
351 K. By distilling the mixture, it is possible to 10. Henry law constant of N2 in water is 104 atm. Find
obtain the molality (Approx) of N2 in water when pressure
(1) Pure CzHsOHonly of N2 over water surface is 5 atm (consider
(2) Pure water only temperature remains constant)
(3) Both water and CzHsOH in pure state u (1) 0.10 (2) 0.028
(4) Neither CzHsOH nor water (3) 0.05 (4) 0.12

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Momentum Booster for NEET Solutions 11
132. Asolution containing 30g of anon-volatile solute (3) Plots of freezing point versus
molal
exactly in 90 g water has a vapour pressure of concentration for ethyl alcohol, propyl alcohol
2.8 KPa at a given temperature. When 18g of water and butyl alcohol dissolved in water will all be
is added to the solution, the new
vapour pressure linear with different slopes
becomes 2.9 KPa at the same temperature, the (4) Allare incorrect
molar mass of the solute is
(1) 34 g mol-! 139. Which of the following is the correct order of boiling
(2) 23 g mol-1 points of the following solutions? (Assume
(3) 46 g mol (4) 17g mo-1 complete dissociation of salts)
133. Solution A is 1 M of toluene in benzene but B a. 0.15 M NaCI
is 1 m of toluene in benzene having density b. 0.4 Mglucose solution
0.85 g/cc, then correct statement C. 0.15 M CaClh solution
(1) b.p. of A<b.p. of B d. 0.15 M urea solution
(2) b.p. of A> b.p. of B (1) d<a<c<b (2) d<b <a<c
(3) b.p. of A = b.p. of B (3) d<a<b<c (4) d<c<b<a
(4) f.p. of A=fp.of B 140.When you dissolve sugar in a glass contaíning ice
134. If t moles of a solute which dimerises is dissolved and water in equilibrium, and assurning that no
in one L-water, then degree of association a is heat enters or leaves the system
given by (1) Some of the íce should melt and the
Kb 2(K,t-AT,) temperature of waterfice mixture should
(1) a= (2) a= increase
AT, K,t (2) Some of the ice should melt and the
(3) a=22AT,
(4) a ATH temperature of the waterlice mixture should
decrease
K;t 2K,t
135. Solvent which is better to be used during (3) Some of the water should freeze and the
ebullioscopic measurement has temperature of the waterfice mixture should
increase
(1) High Ko
(2) Low Ko (4) Some of the water should freeze and the
temperature of the water-ice mixture should
(3) K= Kb decrease
(4) Unpredictable 141. At 323 K, the vapour pressure in millimeters of Hg
36. 0.9 gm of a hydrocarbon with molecular formula of a methanol-ethanol solution is represented by
H2(CH2)n when dissolved in 180 gm of solvent the equation p = 120 xA + 140, where xA is the mole
freezes at 8.48°C. If freezing point of pure solvent fraction of methanol. Then the value of lim A is
is 9°C, then the formula of hydrocarbon is A1XA
(K= 12 Kkg mol-1)
(1) CsHs
(1) 250 mm Hg (2) 140mm Hg
(2) CaH18
(3) 260 mm Hg (4) 20 mm Hg
(3) CeH16 (4) CiHs 142. x mole of KCI and y mole of BaCh are both
37. 0.5% (wlv) aqueous solution of KCI was found to dissolved in 1kg of water. Given that x +y= 0.1
freeze at- 0.24°C. The degree of dissociation of and K: for water is 1.86 Kmolal. What is the
the solute at this concentration will be (Kr for observed range of AT: if the ratio of x and y is
H20 = 1.86 Kkg mo-1). varied?
o (1) 74.5% (2) 19.2% (1) 0.37° to 0.55° (2) 0.185° to 0.93°
(3) 92% (4) 48% (3) 0.56° to 0.93° (4) 0.37° to 0.93°
38. Select the correct statement 143. Equal moles of benzene and toluene are mixed.
(1) Freezing point, boiling point and vapour The vapour pressures of benzene and toluene in
pressure are all colligative properties pure state are 700 and 600 mm Hg respectively.
(2) The freezing point, boiling point and vapour The mole fraction of benzene in vapour state is
pressure all decrease when a solute is (1) 0.50 (2) 0.7
dissolved in a solvent (3) 0.53 (4) 0.6

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Momentum Booster for NEET
154. 200 mL of an Solutions 13
aqueous
contains 0.63 g of the solution of a protein
160. Which of the following solution has maximum
pressure of such a solution protein.
at
The osmotic boiling point?
2.57 x 10 bar. VWhat will 27°C is found to be (1) 0.1 M KNO
be the approx molar
mass of the protein? (2) 0.01 MCH3COOH
(R=0.083 Lbar mo- K-) (3) 0.5 Murea
(1) 61022g mol-1 (4) 0.2 MKA(Fe(CN)|]
(2) 30520 g mol-1 161.0.5 molal aqueous solution of KCI, MgClz and
FeCls have freezing points T, T2 and T3
(3) 15255.5 g mol-1 respectively. Which of the following is correct?
(4) 122044 g mol-1 (1) T1> T; >T3
155. 31 g of ethylene glycol (CaHeO2) is (2) T3 >T2> T1
500 g of water. What will be the mixed with
freezing (3) T2> T; > T3
water? [K for water =1.86 Kkg mo-] point of (4) T1> T3> T2
(1) 269.14 K SECTION -B
(2) 271.29 K Assertion -Reason Type Questions
(3) 275.01 K In the following questions, a statement of assertion
(4) 273.95 K (A) is followed by a statement of reason (R).
156. The magnitude of heat of solution on (1) If both Assertion & Reason are true and the
addition of reason is the correct explanation of the
solvent to solution
assertion, then mark (1).
(1) Decreases (2) If both Assertion & Reason are true but the
(2) Increases reason is not the correct explanation of the
(3) Remains constant assertion, then mark (2).
(4) Increases or decreases (3) If Assertion is true statement but Reason is
157. If mole fraction of the solvent in a solution false, then mark (3).
decreases, then (4) If both Assertion and Reason are false
(1) Vapour pressure of solution increases
statements, then mark (4).
1. A: Ethanol water mixture forms minimum boiling
(2) Boiling point decreases azeotropes.
(3) Osmotic pressure increases R: 95.4% ethanol in water (by volume), the liquid
(4) All are correct statements and vapour have the same composition, and
158. Which one is isotonic with 3 M NaCl aq. solution? no further separation occurs.
(1) 3 MUrea
2 A: CaHsl and CzHsBr form ideal solution.
(2) 2 MBaClz
R: The interaction between the components are
(3) 1 MAICls (4) 2 MKCI similar to those in the pure components.
159. Consider the following 0.01 Maqueous solutions of 3 A: Azeotropes have different composition in liquid
1. KCI and vapour state depending upon the volatility
II. CaClz of components.
I|I. GlucOse R: Composition in both, liquid and vapour phase
The relative lowering of vapour pressure will be in depends upon volatility of the substance.
the order
4. A: Raout's law for the solution of non-volatile
solute can be given as
(1) II|> | >| p° -Ps Nsolute
(2) |> I| > || po nsolvent tnsolute
(3) I|>1> ||
R: Raoult's law is not applicable for the solution of
(4) I| >1> || FeCls in water.
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 38 Sottionn 'el

Momentum Booster
for
14 Solutions
over the solution can
be 9. A: In the osmosis process, the solvent NEET
frommoleculpurese
A: Total vapour pressure will flow through the membrane
5. of any one
related to the mole fraction solvent to the solution.
both components are
component when
R: The flow of solvent from solution of
volatile. concentration side across low
R: Total vapour pressureover
the solution varies
component
membrane can be stopped if Some semipermeable
extra
linearly with the mole fraction of pressure is applied on the solution.
which is more volatile. 10. A: Molecules of ethanoic acid normally
6. A: Increased pressure increases the
solubility of in solvents of low dielectric constant dimerise
atmospheric gases in blood. R: Dimerisation does not affect the
R: Decrease in temperature decreases the
properties. colligative
11. A: Mixtures of ethanol and acetone show positive
solubility of atmospheric gases in blood.
deviation.
7. A: Mass %, ppm, mole fraction and molality are R: The molecules of acetone get in
independent of temperature. ethanol molecules and break
between the
sorme of the
R: Volume depends on temperature and mass hydrogen bonds between them.
o does not. 12. A: When there is a dissociation of solute ions,into
8. A: The component that is present in largest the experimentally determined molar mass is
quantity is known as solvent. always lower than the true value.
R: Solvent determines the physical state in which R: If we dissolve 1 mole of KCI in water, 2 moles
solution exists. of particles in solution are obtained.

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