ABC-1, 2, 3 & 4

ONLY ONE OPTION CORRECT TYPE

PART-A (Alkane)
1. Which of the following catalyst can be used for the given conversion ?

?

(A) H2/Ni (B) H2/Pd (C) H2/Pt (D) All of these

H2 / Ni
2. X    ; X may be
(A) (B) (C) (D) All of these

H2 / Ni
3.    Product
room temp.

(A) (B) (C) (D)

Re agent
4.   , Reagent is

(A) H2/Pd (B) LiAlH4 (C) Zn–Hg/conc. HCl (D) All of these
5. In which case Clemensen reduction should be avoided.
OH O O O
(A) (B) (C) O (D) All of these
6. For the given conversion A should not be
O

Zn–Hg / Conc.HCl
 


A A
(A) Halogen (B) Alcohol (C) Carboxylic acid (D) All of these
O

NH2 –NH2 / KOH

7.   P, Product P is

(A) (B) (C) (D)

OH

NH2 –NH2 / KOH

8.    P
O
Product P is
OH OH
(A) (B) (C) (D)
O
 ABC-1, 2, 3 & 4
reagent
9. CH3COONa   CH4 ; reagent is

(A) NH2–NH2 / KOH (B) Zn–Hg / HCl (C) NaOH + CaO (D) All of these
NaOH  CaO
10. A 
 CH3–CH2–CH3 ; A can be

(A) CH3CH2COONa (B) CH3CH2CH2COONa
(C) (D) CH3CH2CH2ONa
COONa

NaOH  CaO
COONa 
11.    P ; Product P is

(A) Butane (B) 2-Methylbutane (C) 3-Methylbutane (D) Pentane

Na / Dry ether
12. CH3–CH2–Cl    P ; Product P is
(A) Ethane (B) Propane (C) Butane (D) Pentane
Na / Dry ether
13. A    ; A may be
(A) Chloromethane (B) Chloroethane (C) 1-Chloropropane (D) 2-Chloropropane
14. Preparation of alkane by Wurtz reaction the reactant used is
(A) Alkyl halide (B) Acid halide (C) Both A & B (D) None of these
2Li CuI CH3 – Cl
15. CH3–CH2–Cl 
 X   Y   Z ; Final product Z is
(A) Ethane (B) Propane (C) Butane (D) Pentane

2 Li CuI Re agent
16.  X  Y   , reagent is
Cl
(A) CH3–Cl (B) CH3–CH2 (C) CH3–CH–CH3 (D) CH3–CH2–CH2
Cl Cl Cl

17. CH4 + X2 h  CH3–X
or high temp

Order of reactivity of halogen is

(A) I2 > Br2 > Cl2 > F2 (B) F2 > Cl2 > Br2 > I2 (C) Br2 > Cl2 > I2 > F2 (D) Cl2 > Br2 > F2 > I2
Cl2 / h
18.    P
Product may be
Cl
(A) (B) (C) (D) All of these
Cl Cl
19. Reactivity order of Hydrogen for the given reaction is

h
+ Br2  
Hy
Hx Hz
(A) X > Y > Z (B) Z > X > Y (C) Y > Z > X (D) Z > Y > X

Cl2 / h
20.    P

P may be
CH3 CH3 CH2–Cl CH3
Cl
(A) (B) (C) (D)
Cl
Cl
 ABC-1, 2, 3 & 4

Anhy. AlCl3
21.  
HCl
This reaction is known as
(A) Isomerisation of alkane (B) Polymerisation of alkane
(C) Wurtz reaction (D) None of these
reagent
22.  
reagent may be
(A) NH2–NH2 / KOH (B) Zn–Hg / HCl (C) Anhy. AlCl 3 / HCl (D) Na / Dry ether
Anhy. AlCl3
23.   P
HCl
P may be

(A) (B) (C) (D) A & B both

PART-B (Alkene)
H , Pd, BaSO , S
24. CH3–CC–CH2–CH2–CH3 
2 4
Product
(A) CH3–CH=CH–CH 3 (B) CH3–CH2–CH2–CH2–CH2–CH3
(C) CH3–CH=CH–CH 2–CH2–CH3 (cis) (D) CH3–CH=CH–CH2–CH2–CH3 (trans)

25. CH3–CH2–CC–CH2–CH3 Na/NH3() Product

(A) (B) (C) Both A & B (D) None of these

Br
KOH(alc)
26. CH3–CH–CH–CH 2–CH–CH 3 Product
CH3 CH3

Product is:

(A) CH3–C=C=CH–CH–CH 3 (B) CH3–CH–CHCH–CH–CH 3

CH3 CH3 CH3 CH3

(C) CH3–C=CH–CH2–CH–CH3 (D) None of these

CH3 CH3

Br
Zn dust, Alcohol 
27. CH3–CH–CH–CH–CH–CH 3  Product
CH3 Br CH3
Product is:

(A) CH3–C=C=CH–CH–CH 3 (B) CH3–CH–CHCH–CH–CH3

CH3 CH3 CH3 CH3

(C) CH3–CH–CH2–CH2–CH–CH3 (D) None of these

CH3 CH3
 ABC-1, 2, 3 & 4
28. Ph–CHCH2 + HBr  Product
(A) Ph–CH2–CH2 (B) Ph–CH=CH (C) Ph–CH–CH 3 (D) Ph–CH 2–CHBr2
Br Br Br
+
H2O/H
29. CH3–CH=CH–CH3 Product
(A) CH3–CH–CH2–CH3 (B) CH3CH=CH–CH 2–OH

OH
(C) CH 3–CH 2–CH 2–CH 2–OH (D) None of these
CCl4
30. CH3–CHCH2 + Br2   Product

(A) CH2–CH2–CH2 (B) CH3–CH–CH3

Br Br
(C) CH3–CH–CH2 (D) None of these
Br Br
CH3
Hg(OAc)2 ,H2O
Product
31. NaBH4
OH
CH3 CH3 CH3 H
OH CH3
(A) (B) OH (C) (D)
OH

A
32. CH3–CH2–CH=CH2 CH3–CH2–CH–CH3
OH
Reagent A will be ?
(A) Hg(OA)2, H2O / NaBH 4 (B) B2H6, H2O2 + OH–
(C) Both (A) and (B) (D) None of these

A
33. CH3–CH2–CH=CH2 CH3–CH2–CH2–CH2
OH
Reagent A will be ?
(A) Hg(OA)2, H2O / NaBH 4 (B) B2H6, H2O2 + OH–
(C) Both (A) and (B) (D) None of these
peroxide
34. Ph–CHCH2 + HBr Product

(A) Ph–CH–CH2 (B) Ph–CH=CH (C) Ph–CHBr–CH 3 (D) Ph–CH 2–CH2Br

Br Br Br
peroxide
35. Ph–CHCH2 + HCl Product

(A) Ph–CH2–CH2 (B) Ph–CH=CH (C) Ph–CH–CH 3 (D) Ph–CH 2–CHCl2

Cl Cl Cl
 ABC-1, 2, 3 & 4

PART-C (Alkyne)
H H
2NaNH2
36. CH3–CH2–C–C–CH 2–CH3   Product
Br Br
Product is:
(A) CH3–CC–CH2–CH2–CH3 (B) CH3–CH2–CC–CH2–CH3
(C) CHC–CH2–CH2–CH2–CH3 (D) CH3–CH=CH–CH 2–CH2–CH3
2NaNH2
37. A   Ph–CC–Ph ; A is:
H H
(A) CH3–CH=CH–Ph (B) Ph–C–C–Ph
Br Br
(C) CH3–CH2–CH2–CH3 (D) None of these
Br Br
Zn dust, Alcohol 
38. CH3–C–C–CH2–CH3  Product is :
Br Br
(A) CH2=C=CH–CH 2–CH3 (B) CH3–CC–CH2–CH3
(C) CH3–CH2–CH2–CH2–CH3 (D) CHC–CH2–CH2–CH3

Br Br
Zn dust, Alcohol 
39. Ph–C–C–CH 3  Product is :
Br Br
(A) Ph–CC–CH3 (B) Ph–CH=C=CH 2 (C) Ph–CH 2–CCH (D) Ph–CH 2–CH2–CH3
Zn dust, Alcohol 
40. A   Ph–CC–Ph ; A is:
Br Br
(A) Ph–CH=CH–Ph (B) Ph–C–C–Ph (C) Ph–CH 2–CH2–Ph (D) None of these
Br Br
41. 2Ph–CCl3 + Ag  Product
Product is:
(A) Ph–CH=CH–Ph + AgCl (B) Ph–CH2–CH2–Ph + AgCl
(C) Ph–CC–Ph + AgCl (D) Ph–CC–CH3 + AgCl
CCl4
42. C2H5–CC–C2H5 + Cl2   Product
Final product is:
(A) C2H5–CH–CH2–C2H5 (B) C2H5–CH–C2H5
Cl Cl
(C) C2H5–CH–CH–C2H5 (D) C2H5–CCl2–CCl2–C2H5
Cl Cl
Br Br
CCl4
43. A + 2Br2 
 Ph–C–C–Ph ; A is:
Br Br
(A) PhCH=CHPh (B) PhCH2CH2Ph (C) Ph–CC–Ph (D) None of these
44. CH3–CCH + HBr  Product
Product is:
Br
(A) CH3–CH–CH3 (B) CH3–CH2–CHBr2 (C) CH3–CBr2–CHBr2 (D) CH3–C–CH3
Br Br Br
 ABC-1, 2, 3 & 4
45. Alkyne react with water to form _____ compounds.
(A) carboxylic (B) ester (C) carbonyl (D) Anhydride
B2H6
46. CH3–CCH 
–
Product
H2O2 / OH

Product is:
(A) CH3–C–CH3 (B) CH3CH2–CHO (C) CH3–C–CH 3 (D) CH3–CH2–CH2
OH O OH
HgSO4
47. CH3CH2CCCH2CH3 + H2O   Product
Product is:
O
(A) CH3CH2CCH2CH2CH3 (B) CH3CH2CH2CH2CH2CH3
(C) both A & B (D) None of these

PART-D (Benzene)
CH2–CH3

48. x HCCH + y CH 3–CH2–CCH  ; Find the value of 'x' and 'y' ?

(A) x = 1, y = 2 (B) x = 2, y = 1 (C) x = 2, y = 2 (D) x = 1, y = 1

49. Which of the following will not form in the following reaction ?
Red hot
2CH3–CC–H + HCCH  ?
tube

CH3 CH3 CH3 CH2–CH2–CH3

(A) CH3 (B) (C) (D)

CH3
CH3
50. Phenol upon distillation with zinc dust leads to the formation of ……………… .
(A) Toluene (B) Benzene (C) Cyclohexane (D) n-hexane
OH
H3C CH3
Zn powder
51. ?
distillation
HO OH
CH3
OH
H3C CH3
(A) (B)
HO OH
CH3
OH OH
H3C CH3 H3C CH3
(C) (D)
OH
CH3 CH3
 ABC-1, 2, 3 & 4
COONa

CH3 CH3
Reagent
52. + Na2 CO3
CH3 CH3

CH3 CH3
Reagent may be -
(A) Soda lime (B) Zinc dust (C) Red hot tube (D) none of these

53. Benzene upon addition with the mixture of conc. HNO 3 and conc. H 2SO4 undergoes …………..
(A) nitration (B) sulphonation
(C) both nitration and sulphonation (D) neither nitration nor sulphonation
54. Benzene forms ……………….with hot concentrated sulphuric acid (80°C temperature)
(A) Benzene sulphonic acid (B) Benzoic acid
(C) Both (D) None of the above
55. Identify the product :
CH3

Conc. H2SO4
80°C

CH3
CH3 SO3H CH3 CH3
SO3H
(A) (B) (C) (D)
CH3
SO3H SO3H CH3 SO3H

1. (D) 2. (D) 3. (B) 4. (C) 5. (D)

6. (B) 7. (B) 8. (C) 9. (C) 10. (B)
11. (B) 12. (C) 13. (C) 14. (A) 15. (B)
16. (B) 17. (B) 18. (D) 19. (C) 20. (C)
21. (A) 22. (C) 23. (D) 24. (C) 25. (B)
26. (C) 27. (B) 28. (C) 29. (A) 30. (C)
31. (B) 32. (A) 33. (B) 34. (D) 35. (C)
36. (B) 37. (B) 38. (B) 39. (A) 40. (B)
41. (C) 42. (D) 43. (C) 44. (D) 45. (C)
46. (B) 47. (A) 48. (B) 49. (D) 50. (B)
51. (B) 52. (A) 53. (A) 54. (A) 55. (C)