Inks contain different coloured substances called dyes, ‘student used chromatography to investigate the coloured dyes contained in six different inks. ‘The student drew a baseline on a sheet of chromatography paper. ‘The student then placed a spot of each ink on the chromatography paper and set up the apparatus as shown in Fig. 1.1 The student made two errors. lid chromatography q paper baseline - oe © 7 yellow orange green blue purple black ae tke ink vin ink ink _ink Fig. 1.1 (a). Identify the two errors the student made. 1 2 (b) State the name of the equipment used to draw a baseline on chromatography paper. (] l OUCLES 2025 osz0162/emw25 | FINNIOMAONOAMMTA 2 a 1 i ts oe oo mor Wai i Se,* 0020692203103 * z © MUON: g (c) The student corrects the errors and then carries out the chromatography. f The chromatogram in Fig. 1.2 shows the student's results. g 5 ® e e 9 8 ° Ca e e 9 9 z yellow orange green blue purple black 3 ink ink ink ink ink _ink 2 = Fig. 1.2 < E (i) Identify an ink which could contain only one coloured dye. 5 2 8 (ii) Deduce which ink could be mixed with the blue ink to make the black ink. ttl 8 (lil) Deduce the colour of one dye that is contained in all three of the orange, green and ¢ black inks. E 1] E [Total: 6] |e , 5 8 i ite |e z\2 wie 5 |e 515 5 2 g 8 2 he 2\8 a 213 z\E B\2 g\§ els 3 a | OUCLES 2025 & osz0ie2rrna2s= 0020692203105 * © NMI i UN 2 2 Astudent investigates the temperature change when aqueous copper(II) sulfate reacts separately é with two different metals, zinc and iron. z The student does two experiments. 8 Experiment 1 8 Use a 50cm? measuring cylinder to pour 30cm° of aqueous copper(II) sulfate into a 100m? beaker. | ‘* Use a thermometer to measure the temperature of the contents of the beaker. iF This is the temperature at time = Os, ig © Add 3g of zinc powder to the beaker. At the same time start a stop-watch. = © Using the thermometer, continually stir the mixture in the beaker. Ve © Measure the temperature of the mixture every 30 seconds for 210 seconds. ye © Empty and rinse the beaker with distilled water. je ‘|e Experiment 2 | : © Repeat Experiment 1, using 3g of iron powder instead of 3g of zinc powder. lz i 8 | 2/8 8 8 JDO NOT WRITE 00 Tree DO NOT WRITE IN THIS MARGIN. DO NOT WRITE IN THIS MARGIN DO NOT WRITE IN THIS MARGIN l SUCLES 2025 eee [Turn over |TM © (a) Complete Table 2.1 by using the thermometer diagral changes from the temperature at 0s. Table 2.1 iment 2 Experiment 1 | Experi | temperature | temperature hi a time | thermometer | temperature | change since | thermometer largest ka ne | ins diagram in°C time = 0s diagram in lide Is | in°C | in°’C Y30 | HHs30 0 24.0 0.0 =| 22.0 20 | {20 {40 [30 30 5 4 mE 30 520 {40 | 60 = 530 -|50 90 =| i 540 _|50 120 4 Hao 450 150 Hs | i qe / #8 (d) State 180 4 answe =|50 [ explanat 210 | Ho ! _* 0020692203107 * |i 7 i OMIT 2 (b) Complete a suitable scale on the y-axis, and plot your results for Experiment 1. and é Experiment 2 on Fig. 2.1. The point at (0, 0) has been plotted for you. E Draw two curves of best fit. Both curves must start at (0,0). § Label both curves. 8 z= 5 jz : = temperature change 2 since time = Os in °C 8 lz i # g 80 100 150 200 250 \5 time in s 8 Fig. 2.4 (5) = (c) Extrapolate the curve for Experiment 1 on your graph in Fig. 2.1 to deduce the temperature 3 change since time = Os in Experiment 1 after 240 seconds, | 2 ‘Show clearly on Fig. 2.1 how you worked out your answer. 2 : é € temperature change os eS 8) f (8 (d) State which experiment, Experiment 1 or Experiment 2, is the more exothermic. Explain your answer. z more exothermic experiment seven oO 3 explanation 12 é = a) je § KE | 13 ©UCLES 2025 0620/62/F/M/25me a (e) Predict the temperature of the solution in Experiment 1 after 3 hours temperature after 3 hours = “ct (f) Explain why using a copper container instead of the beaker would not be an improvement in this investigation. a (g) Describe two changes to the apparatus that will improve the results ofthis investigation, For each change, explain why it will improve the results. change 1 explanation 1 change 2 .... explanation 2 (4) [Total: 19} l uctES 2025 oszo1s2iFn25+ 002062208100 * TMT d 3 Astudent tests two substances: solution A and solid B. Tests on solution A Solution A is aqueous chromium(III) chloride. DO NOT WRITE IN THIS MARGIN: DO NOT WRITE IN THIS MARGIN The student divides solution A into three approximately equal portions, Complete the expected observations. Ra (a) To the first portion of solution A, the student adds aqueous sodium hydroxide dropwise until it g } 3 is in excess, 2\2 ‘observations a Ye $ 5 (2) 8 8 (b)_ To the second portion of solution A, the student adds about 1 cm® of dilute nitric acid followed by a few drops of aqueous barium nitrate. Pa observations 3 22 om ze (c) To the third portion of solution A, the student adds about 1cm° of dilute nitric acid followed by zz a few drops of aqueous silver nitrate. eg observations Bok 1 8 8 a id 22 BE gs Bye 2\8 CUCLES 2025 & osz0e2rF M25 [Turn over ats a Pe sa 38 28SUCLES 2025 + 0020652203110 TM Tests on solid B (itt = Table 3.1 shows the tests and the student's observations for solid B Table 3.4 test Carry out a flame test on solid B. ‘observations red coloured flame test2 Dissolve the remaining solid B in distilled water to form solution B. Divide solution B into three Portions. To the first portion of solution B, add a few drops of acidified aqueous potassium manganate(VIl), | tests To the second portion of solution B, add about ‘Tem? of aqueous sodium hydroxide, test4 Warm the product of test 3 and test any gas given. off with damp red litmus paper. ‘To the third portion of solution B, add about 1 cm? of, dilute nitric acid followed by a few drops of aqueous barium nitrate. test pale purple solution solution remains colourless a damp red litmus paper remains red white precipitate (d) Describe how to carry out the flame test used in test 1 {e)_ Identify the ion that is tested for in test 4, osaois2r nwa ical 10)(00 NOT WRITE IN THIS MARGIN OO NOT PUTS Ot re ee (DO NOT WRITE IN THIS MARGIN: D0 NOT WRITE IN THIS MARGIN cr wwii WN " 'dentify the two ions which are in solid B. l uctes 2025 osz0162 025 5 a [Total: 9} rm oae |+ oozosszz03112* Vis J 2 15 ig Metal spoons can be electroplated wit sive ia Describe how a metal spoon can be electroplated with siver Include in your answer Row you fg ‘could determine the mass of the silver electroplated onto the metal spoon. i ; ‘You are provided with solid silver nitrate, a metal spoon, a piece of solid silver, distilled water and 5 E Common laboratory apparatus alt You must include a diagram in your answer: 3 i ED 5 3 8 5 i 5 3 . “ Lo l ©UCLES 2025, & osao82F 025 |