Organic Chemistry

Amines

Lecture - 01 By – Rohit Agarwal (RA sir)

Topics
Questions
 HOME WORK 1001yield AgPowder

pants
s Is L
Cygm 29m
regm BELL
Mgs
4.29m 350
KMnO4KOH Lint 4
B Excess 0
Wgm
Which will
prussianbluecolour NHU kW Nanozke
give
Δ
n Qualitative analysis 49.20 Natural
Isomer
HOME WORK
420
Nannathenabt ff.ve
492 12504
I NAOH map
5042 48m01
Ph id
HCNNACN
2
É É.EE 2

esce
V
IRO
Question

Carboxylic acid is not obtained in the reaction

A B

C D
3
Question

During hydrolysis, in which acid derivative the rate determining step is step-II

A Ester

B Acid halide

C Amide

D Acid anhydride
Question

Acetyl chloride is not obtained as a product when PCl5 is treated with

A Acetic acid

B Acetamide

C Acetic anhydride

D Methyl ethanoate
Question

Which compound on reaction with ammonia in 1 : 1 ratio can give racemic

mixture as a product?

A B

D
C
Question

Sodium salt of which carboxylic acid on electrolysis gives organic product which
can show steroisomerism?

A B

C D
Question

The final major product ‘Q’ obtained in the following reaction is

A CH3–CH2–OH

B CH3–CHO

C CH3–COOEt

D Both (A) and (B)

Question

The unknown compound ‘T’ is

A B

C D
Question

(i) (P) and (R) are aromatic in nature

(ii) Rate of soda lime decarboxylation is (P) > (R) > (S) > (Q)
Choose the incorrect option:

A Acidic strength order will be: (R) > (P) > (S) > (Q)

(P), (Q), (R), (S) can be obtained by reacting their corresponding aldehydes with
B
Fehling solution

If one mole of each product is reacted with excess of Na metal, 2 moles 2 moles
C
of H2 gas will release.

D (P) And (S) is obtained by cleavage of C2–C3 bond

Question

There are fundamentally different mechanism possible for following reaction. If

O18 is present once in phenolic OH and once in carboxylate group of product on
𝟏𝟖 𝟏𝟖
using 𝐍𝐚𝐎 𝐇Τ𝐇𝟐 𝐎 then mechanism used by following reaction both cases
are respectively:

A Ester hydrolysis, Nucleophilic aromatic substitution

Nucleophilic aromatic substitution, Base catalysed aacyloxygen cleavage
B
mechanism

C Electrophilic aromatic substitution, Base catalysed acyloxygen cleavage

mechanism
D Nucleophilic aromatic substitution, Nucleophilic aromatic substitution
Question

For the following reaction sequence, the product R is

A B

C D
Question

The product obtained in the following reaction is

A B

C D
Question

Which reaction is not correctly matched with reaction name?

A
Hoffmann Bromamide degradation

B
Bayer’s villiger oxidation

C Schmidt reaction

D Reimer-Tiemann reaction
Question

If product ‘P’ is obtained as acid derivative, the correct statement regarding ‘Q’
is/are

2
A Reduces Tollen’s reagent

B Reduces NaOBr

C Reduces Fehling solution

D Cannot reduce PhCO3H

Question

The product Y in the following reaction sequence is

Br2 NH3 H
CH3CH2COOH ⎯⎯⎯
Rad P
→ ⎯⎯⎯ →[X] ⎯⎯
→[Y]

A B
Go

C D
Question

The compound which are soluble in hot aq. NaOH is/are

A B

3
C D
Question

The possible product obtained in the following reaction is

A B

C D
Question

The major product obtained in the following reaction is

NHz

A B

C D
Question

The reaction in which primary amine is obtained as one of the product is

A B

C D
Question

The major product obtained in the following reaction is

A B

C D
Question

The final product ‘Q’ obtained in the reaction is

ME

A B

C D
Question

A container containing two acid amides CH3 − C − NH2 (X) and CH3 − C − NH − CH3(Y)
|| ||
O O
Following sequence of reaction are made on amides:
(i) LiAlH (i) LiAlH
Amide − (X) ⎯⎯⎯⎯
+→P
4
Amide − (Y) ⎯⎯⎯⎯
+→Q
4
(ii) H3O (ii) H3O

(i) CHCl /KOH

The product obtained in the following reaction is P ⎯⎯⎯⎯⎯⎯ 3
→
(ii) LiAlH 4
+
(ii) H3O

A X B Y

C P D Q
Question

Total number of organic compounds obtained as a major product in the reaction

is

A 1

B 2

C 3

D 4
Question

The final product of reaction sequence is/are

A B

C D
Question

The product U in the following reaction sequence is

Na CH − I NBS P Alc R − NH
HC  CH ⎯⎯→
1 eq
P ⎯⎯⎯
3
→ Q ⎯⎯→ R ⎯⎯
→ S ⎯⎯⎯
KOH
→ T ⎯⎯⎯→
2
U

A B

C
D
Question

Correct option(s) regarding reaction, reactant and product respectively given is:

A Schmidt reaction Acid Primary amine

B Hoffmann bromamide Primary acid amide Primary amine

C Schmidt reaction Ketone Secondary acid amide

D Beckmann rearrangement Ketoxime Secondary acid amide

Question

The correct statement is/are:

A Formation of Q is Schmidt reaction

B Electron density in ring : (R) > (Q) >(P)

C Q is more basic than P

D Formation of P is Hoffmann bromamide degradation

Question

Choose the correct statement(s)

A (R) Can be obtained by reacting (P) with HNO2

B (Q) And (P) can be differentiated by CHCl3 and alc. KOH

C (Q) Can be obtained by reaction of (P) with NaOBr

D (P) On reaction with LiAlH4 forms homologue of (Q)

Question

W is less basic amine than NH3 whereas T is less acidic than HOOH.
Question

The correct statement is/are

A R and S both are metamers

B P and Q both are geometrical isomers

C U is more basic than W

D V is more acidic than T

Question

The compound which is isolable in aq. HCl is/are

A P

B R

C W

D T
HOME WORK

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