List of XII Chemistry Papers 2025 1 Model Paper 2025 2 D.J. SINDH GOVT. SCIENCE COLLEGE, KARACHI 3. GOVERNMENT DEHLI INTER COLLEGE 4. GOVT. COLLEGE FOR MEN, NAZIMZBAD 5. Shaheed-e-Millat Degree College, Azizabad Karachi 6. SIR SYED GOVERNMENT GIRLS COLLEGE z BAMM PECHS Govt. College for Women é GOVT. DEGREE COLLEGE FOR WOMEN BLOCK-M NORTH NAZIMABAD 9. Shaheed Flying Officer Marlum Mukhtiar Govt. Girls Degree College Liaqatabad 10. | SINDH MUSLIM GOVT. SCIENCE COLLEGE, KARACHI 11. | Liaquat Government Girls Degree College 12, | GOVT. DEGREE GIRLS COLLEGE, A! Noor, Block 19 13. | ADAMJEE GOVT. SCIENCE COLLEGE KARACHI 14. | APWA GOVT COLLEGE FOR WOMEN KARIMABAD 15. | KHURSHEED GOVT GIRLS DEGREE COLLEGE 16, GOVT. DEGREE GIRLS COLLEGE BUFFER ZONE, KARACHI 17. | COMMECS COLLEGE 18. | BAHRIA COLLEGES 19. | Practical Centre CHEMISTRY COMPILED PAPERS-XIT COMPILED RY: SIR OWAIS FAYYAZBOARD OF INTERMEDIATE EDUCATION, KARACHI INTERMEDIATE EXAMINATION MODEL PAPER-2025 saccononc ro nesucen eviiasus 2019 a CHEMISTRY PAPER = II Max. Marts: 17 T According to New Book 1 (Science Pre-Engineering & Pre-Medical Groups) Time: 20 minutes TTT SECTION ‘A’ i 1 mete aamnalsQtlapiled by a i cy » » vi) vi) vil) i” 2 » i) sit) xv) ~» xi) (MULTIPLE CHOICE QUESTIONS) — (V.C.0s) (Marks : 17) 3. Retin Ree 7 GREENE REE Eel AiR eRe. 4) Done copy the part questions in sour ansrertook. Write ony the tse h fal ant the foper number ofthe question and its par. ‘uy Thewse oF sciemine eleuator is alow Sir Owais Fayyaz In IITA group of pried table, he ionization of elim (Ga) ic higher than atuminium (Al) du to insuticent shialding ofthe auclear charge in gallium (Ga) by: This metals essential for growth of bones and teat: ee Calciare Magnesium + Sodium © Potassium The boiling pot and viscosity of HSO, is igh because + itis song oxidizing agent * Geis ighly vataite . has song yrogen boning —jtform stable sofer-oaygen tons ‘Te coonision namber of “Prin [Pr (en), JC, 7 3 +4 - 6 - 44 ‘This metal ha naxnmn numberof empire electron in 34 orbital: * Copper(Cu) > Manganese (Min) * Cobuit(Co) * tron (Fe) ‘The general formula ef the homologous series of cyclo alkane is: 2 CH, OH, * Gd = Ge ‘The final product obtained when hydrogen bromide (HBP) is added toanethyne molecule: = 1a-Dibemo ate een 1 bibs efare + EIST eetmoethne ici as dr ts ia tb an be esate > agement The catonyl caon of adhy es: sr aphybedand—* sp hytlaed * ap yb * dap" yb resraapeaeremaiee Compiled by: Sir Owais Fayyaz ora fig ZaChans HCI Noam fig * CaO ana NGOH ie ipa gen ese Rea wm ve tanya day testo eriayakstat © ser ieee meals oem a ee a es 1 ar RR UN ° i = R-CH=N-NH, > R-C=NH,* R-CH=N-OH> — R-CH-OH cw Aimar drag song he followings si oer so" Corogire Paracel * ——_~inhomyhycamine zone dearoyed by = Salpurosite (SO,) + Carbon dioxide (CO,) = Chlorotluorocasbon (CFCS) + Hydkoflorocatbous (HFCs) ‘The IUPAC mame for Formic aii 2 poate cid * Mathanocacid * —‘Ethanoieasid * © Benznic acid ‘The pllofacld ia SP ’seween 708 = Betweenoio7 = — elows == —atoves Page No. 42 76T According New Book SECTION, BOARD OF INTERMEDIATE EDUCATION, KARACHI INTERMEDIATE EXAMINATION. MODEL PAPER-2028 sccozonc 0 sesuceo sruasus 205 CHEMISTRY PAPER (Science Pre-Engineering & Pre-Me Max. Marks: 68, Groups) Time: 2 Hours 40 minutes ae (SHORT-ANSWER QUESTIONS) Marks : 36 Nino pat questions, Selec Rour prt question fm Inorganic — Ceneral Chersistry and Five pat questions fom crgne comin: COMPO by: Sir Owais Fayyaz d » » a) wy ) ‘Whats fame cst? Why alli and allalne earth metals give colowed fame? Mention te colour of fae of aay 10 alla meu on Give reasons forthe fllowine: © -H,S0, behave as oxiciring age. © Gallium has smaller atomic rai then aluminum, Acidity of hydrogen halides increases from HF to HI + Binding energy of inc is leas in 3d seis ‘Woite te IUPAC name ofthe folowi + nale(on),] + Ton] [colem,]" = [co(n,),(¥0,),] ‘Why the compounds of d— block elements colored? Explain ia term of crystal fld theory esctbe how 99.99% pure copper i sind fom sopper mat Describe the preparation and uses of Nylon ané Polyvinyl chloride, What ae greechouse gusts? Expluin reeabouseelfect Define the following +" Cale Convener * Celues * Diagonal Relalonship * —_Andpyretic Medicine oR ‘Write at east one significant use of folowing metas: 6 Sodise Calciom © iron © Copper ORGANIC CHEMISTRY, ‘Benin say our UF oe Not Reforming of Peoleum * —Catenation = Fnctonal Group * — HomolozousSeries. = * Peptide Bond or Define Bucky Ball? Explain its structure (digram isnot required. Writ its tw proper and wo wis ‘Writ the TUPAC names of any four af the folowing: © (CH,),C-CH,-CH(CH,), CH, C ~CH, c=cH Compiled aye air unis Rapper cn, i © cc -cH-cH,-C-0n “ CH,—CH-CH- CH -CHO toto Cl Br CH, cu, + Ci C -Ni, cH, Give the wnat of Bice vaca ation beimven methane i re weseane uf sunlight oR [Define Chiral Carbon and Plane Polarized Light. Explain optical isomers with example 4) Why temminal alkynes ae acidic In nase? Write one chemical reaction to suppor your answer 1D) Why does the —NO, group atacted to a benzene ring det incoming elecrophilesto the meta postion in ectopic subtiton reactions of benzene? Explin bri. Continued on the next page. Page No. 400876Compiled by: Sir Owais Fayyaz we iy a of he lowing wit en abort ‘kere ‘Alcohol = Phenot = Aldenyde i), Weite the nomex of four dervnive of Carboxylic acd and give the equation fr thei preparation from acetic acid 1x) Define amines: Why they or asc tre? Write the chomica guations forthe preparation ofthe flowing compounds ram an anne (R—NH, ) = Amite * —— Diaconium Sa oR ‘Waite the names of two organometallic compounds except Grignard reagent). Write the reactions of Grignard with the fllowing: Amine Carbon dois (DETAILED-ANSWER QUESTIONS) Marks: 32 Answer any Two questions — One question ftom Inorganic ~ General Chemistry and One from Organic Chemistry. Both questions cary equal mars INORGANIC — GENERAL CHEMISTRY. 8) Complete and balance the following chemictleqvations: 2 CEN, + Peo, taste = Ca(oct),+#C1—> * NaOH +Z—> + K+0—> + Mn+0,—> = ChO243H,C0,18H" > + Cn HNO, oR Discs te group rend of Aton rai nization energy letra conduct, tng ae bing pint of Alkali tal 1) Draw ow sec diagram of conta proces and desks varios scp involved the manic ting of ufc acid sho wit wo chemi! essen i which souk seid boa as dehydrating agent 2) What ic Tmpenpre? Dec the cheiy inclu dt he presence of ore of tyes acaba in tropoepere 1) Defined — block elements. Why red ~ block elements called transiion elements? Explain end of following properties of 3d series of transition elements. (aay three): 9a ney aly Form * Vata oxdsion swe * Map Rehvier ORGAME cueanrEeY 1 igi arcane aa oR A a ln i bre raw teh as ustuted hyocaon, ©) Outi sacs ra te lowing eect ay ee ee Neweytnyes ¢ Tecracuas + pees Seasons esc : fositnemta tied bys ompile. SU, Owais Fe Fayyaz Seine pom ee a STE sincera >) What eatotytas? Csi on he tas sac pin he Oe oF owing cares ea a ee * wos oR ith ion time te ne nr a exon of ye nh one + Renton of ements sit aka salon of KOH + Rens ofthnal win ecing agente AUT, © naire rc rei aA HC = ouiaton omer wt £.C7.0, m pase of 50, + tarot ics wit tionltiieinpresae of tde Reaction of romothone with KSH Reaction of etylenegycol wih peso ci (F110) = Reason of tenis wih ace chen he proce of Lewin ak’ (AICI) Page No. 41 076DJ. Sindh Government Science College Dr. Zia Uddin Ahmed Road Karachi ‘TIME: 3 hours: ‘Total Marks: BS: . . Shemistry XU Compiled by: Sir Owais F. ayy tanker 17 (MULTIPLE CHOICE QUESTIONS) (MCs) 1. Select the most appropriate answer for cach from the given options. ()Troposphere extends from planetary surface to bottom of. 2 (@) Stratosphere (B) Mesosphere (C)Troposphere _(D) TMermosphere (i) The atomic no of an element belonging to group VA; and 3" period is @7 (b) 13 (1s (a) 23 (lil) Lucas reagent isa mixture of: (@)Znandlig(b)ZnandHCl__(c)2nCandHCl__(d) NaOH and CaO (iv) Which of the following element forms super oxide when burned injair? @u (b) Na OK (Mg (0) Select the incorrect statement regarding alkanes. {@) Its knownas paraffin (b) It isan acyclié saturated hydrocarbon (c)Inalkanes,carbon hybridationis Sp? _(d) Alkane have the general formula CoHanez (vi) Fractional distillation of coal gives coke, coal tar, coal gas and: (@)Petroleum —(b) Natural gas. (c) Naphtha’ (4) Ammonia liquor (vii) When two moles of ethyl chloride reacts with two moles of sodium metal in the presence of ether what will be formed? {a)2moles ofethane (b) 1 moles of ethane™ (c)2moles of butane (d) 1 moles of butane (viii) Hybridization involves (a)Addition ofan electron pair (B) Mixing ofatomic orbital (b) (c) Removal of anelectron pair _(d) Separation of orbitals, (&%) The coordination number of chromium in [Ce(en);Br]' ist @ 2 @) 3 © 4 @ 6 (¥) Anisomer of acetone ist (@)Formaldehyde (b) Diethyl ether!\(c) Acetaldehyde (d) Propionalaldehyde (xi) The lame colour of which of the following alkali metal is blue violet? @u cs kK (a) Rb (il) Down the group atomic size increases due to (2) Shielding effect (b) Photoelectric effect (c) Increase in nuclear forte of attraction _(d) oxidation effect (xiii) The mostreactive molecule towards nucleophilic addition in the following i (@) Formaldehyde (b) Acetaldehyde fi AY i (Diethyl kone (acaba Ci ompiled by: Sir Owais Fayyaz (xiv) The number of unpaired electrons in gaseous species of Mn*? and Co*? respectively are: @44 )33 (43 (34 (xv) Which type of glycosidic linkage present in maltose molecule? (@, linkage (b) aBlinkage (c) B-linkage (d) _y- linkage (xvi) A zwitterion is: (a) anion thatis positively charged in solution (b) an fon that is negatively charged in solution (6) anion electrically neutral (@) a carbohydrate with an electrical charge (xvii) Asprin isa pain reliever, its chemical name is: {a)Ascorbicacid (b) Nicotinicacid (c) Acetyl salisylicacid (d) Benzoicacid bet) CamScanner= - DJ. Sindh Government Science College Dr. Zia Uddin Ahmed Road Karachi SECTION B (SHORT-ANSWER QUESTIONS) (36 MARKS) NOTE:Attempt any eight questions, Select Four part questions from inorganic chemistry and four part questions from organic chemistry and one part question from any one , All questions carry equal marks, Compiled by: Sir Owais Fayyaz f @) Write down three properties of beryliium that show its unique behavior in group J! A? (H) Explain the auto oxidizing and reducing properties of chlorine? Gil) Why chromium exits in 45°3a8 configuration but not in 45230"? (iv) write the valence shell configuration of the following groups * 1Aand 1B * VAand VB {(v) Explain the following:(Any two) * Why lonization potential decrease from top to bottom in S-block elements? * Flourine isthe strongest oxidizing agent? * Why do transition elements show variable oxidation state? (vi) What are outer and inner transition elements?, (vil) Write IUPAC names of the following * Fe(NO)q? * [Cr(en)zCh]CI * [Co(H20)s(NOs)2) * [Cu(NH:)4]SO4 ORGANIC CHEMISTRY (vill) Define the following: * Catenation * Chiral carbon * Functional Group * Hybridization (x) What is synthetic iter? Explain Nylon and Polyester. (8) Write equations of the following conversions: * Benzene to Nitro-Benzene */thyne to Ethenal * Ethanol to Ethanoic Acid * Ethene to formaldehyde (si) Write the LUP.A.C name: ** (CHs)»-C-CO-(GHa)2-COOH )* CHO-Cie-Cii(CH)-CH(Br)-CO-cH * (CHs)o-CH-COO-CHs ¥ CHsCHz-0-CH(CHs): (aif) What is Green house effett? How does human activities contribution to the enhancement of the green house effect? Gail) Give the mechanism, perme radi] ae bene pos and chlorjne in the presence of sunlight : = {av Write the chemical equate dag echsnsirbo ber ha presses be ded en CHsMgCl reacts with: —* Carbon dioxide * Acetone SECTION (DETAILED ANSWER QUESTIONS) (32 MARKS) ‘ NOTE: Attempt any two questions. One question from Inorganic Chemistry and the other from Organic Chemistry. Both questions carry equal marks. '3,(a) Describe the manufacture of sulphuric acid by contact process, Draw the flow diagram. 3. (b)Write the balance equations for the following chemical reaction: * Sodium burns in excess of air. * Magnesium is heated with nitrogen. * Zinc with sodium hydroxide. * Potassium permanganate with Oxalic acid. * Potassium dichromate with ferrous sulphate. * Iron with chlorine, * Glucose with sulphuric acid * Chlorine with water 4, (a) How is pure copper obtained from roasted pyrite ore? (b) Explain the following(Any three): * Transition elements show colour compounds. *Transition element show paramagnetic properties CB eanscannerD.J. Sindh Government Science College Dr. Zia Uddin Ahmed Road Karachi *Bleaching powder. “Diagonal Relationship of elements. 5. (a)Explain the following with types and suitable examples? “Structure isomerism CG - jled Boe Sir 5 . (ny whats otntaton in eee by Sir, Owais FVM sve vase ezch of ortho, para and meta directing groups? Explain electrophilir, substitution in henzene with reference to Friedel-Craft’s acylation. 6. (a) ()What are Elimination reactions? Write Bimolecular Elimination Reaction with its mechanism, (ii)Give equations of the following reactions. * Phenol with dilute nitric acid * Oxidation of acetone with acidified K2Cr207. * Hydration of ethyne in the presence of H2S04/HgS04 (b) what are carbohydrates? Describe the followings: * Classification of carbohydrate. * Glycosidic linkage * 9, B configuration * Furanose and Pyranose structure. bet) CamScannerGOVERNMENT DEHLI INTER COLLEGE Block 2, Hussainabad, FB, Area Karachl Preliminary Examination ~ Chemistry Papor— It tine tshinutes Compiled by: Sir Owais Fayya2yja. wats:11 SECTION “A” (MULTIPLE CHOICE QUESTION} ‘Nolo: This section consists of 17-parl questions and alTare to be answered. Exch question carries One mark. 1 Choose the correct ansaie foreach tem the phen optons: 4 remost powestl owing agent among thers tain «(O10 (aor rs |v etch he folowing dows nat belong to d block elmer? : lau hha wo 1% bic of the flowing tales! orm per oxke when burn nat tu pre (ana Puts e__Siameecolocr of potas dichromate chang ints yellow glared by sng (eto WUD, tayo tana ¥ Alkat notation dase in water form ta west have Ibi asiconde foaal teh aid +1 Svcs ot Condensation potter inthe allow: (2)Pelysini aretae (S401 ertton ()aakeite Vi The pocessunedolneease the quali of petals» (2 Refining {b) Aetorring jaceiiting (e1 Polymerization = sence a mitre et Nn ang, Uh) Paced Het ferfnate and Her (2) M208 and C20 "iriyes &hetenes ae catalytically converted na thane ty process known 36 + G Ceninersen Retion {i} wath ince Redcton Ad) Wilamtontencton {i} eat rat Reaction 2» _theregien af the atmosphere where otene a pesentn: (A troponntem 10) Sratosshove {el Mewrphere {dh heemosohiove Zi fedtnteneon weatment wth a mistue of Nine ee) ane Sule all onc) at 190°C pies Taftmuntencene (ip {Eh 2- Deltona dl m-introbeniene Phe mala pod formed on Oxon of enenein presence af Det leva eft “Dyes! {a)ebenot Only nora he ramon ven brow abeys AahowretPesuleon faction with NC te focwcn (sone cnet ts poduced hom {cession Netfecndeostinn roe when nese wth ery ser Cade ve ‘ah ansttenyse iwanether fe Anakohot “ho ahone 4 Cranpourd Xs reat with Soda line and gies Chane. The compourd Xi (a) thane at thinetrok aad i) Propane sed 00th and sav Terlene ina condensation toc, neers ae (INIMOA 2 niles {D1 Phonat Fxmtdchye (eine 8 clyine Nitherene stot sd ctmienegyect SECTION ~ I {short Answered Questions) 36 Marksy G2. Attempt mie pare questions trom this section, lou (8) 9 Five (08) pap ‘onapiled on. aches ipais Fayyaz Avesions fom Inoieanie- General section, ad (1 Copa toe gel soup te and gullies a owe in pero tal. [Any 1) “atone Rade ‘oruration tnevgy “Neting& alkene am eve ur hase of Bey hum ingroup HA ON DSc he teal behave Hlagens (ema ate ats ey WtedowA the namesel tm erthae Poynery cts itow way Of ayo lonmned? Explain the conve f deletion of Oaone lye. pew ave Greenhouse gives B Gornhowneellec? What eaves the pba wating? (i) Write UPAC ramnes of Flowing compenes: Os (Ch foto (thd oncanic cucnsisrny ‘wre da the mechan of Chron of Methane i) "Cell liraetilsiabonal ANyIMshlesDR Mylan with amenable ot esc cai dew the name ‘of camposse Wat eign wet Dnt ws Adin ra Fa wth ie Abn ol onan wn 4 on we after et can? Ne IPECIAIKY Of Oreano-metage oe own? Home Une Lllowne EQmpcunds prepaved lar eethy ‘techni! Compiled by: Sir Owag.Panvas * Terbuty alcubot AA | Chemicaiy conve tnetotowng: “thank at 1 propanol ta astane stamutttyletoonrceul — 1 Acetylene 19 Glyaeat ‘+ nyne to fthanal @ Xe we AB Wie the HC Runge atowgayunctonpm e +, et " sa4,-<4y-C00~CG Teale CH=CH KCK, we tiltstcaten, stammeiseimcrtom, _& etic owen pW ateaan fate at nmethm, and cuss 2, OR Oats Chiral Caton B Optical ‘homers What ae Stereohiomers?. A bAF Glee eaten a rhe date o Fons. SECTION ~¢ (Detailed Answer Questions) (32 Marks} tte mer any te guest Oe om pa ental Cem and we om Oran hr ath Sesion rear IMOAGANIC-GENERAL CHEMISTY 9 (a Deurbethe munlacure tpn acs conse’ tt (lieth auc cei onan he foe proeie fn somite « "agen seth Gupeninrparece efemat ‘ hot aqueous xeon sttausvesoos — CQ * Mhotssrectthems CI" + Clo,’ + 3H.0 Traraltonslments have ability ofr aay, a NH) acts as ligand and NH", does not, HD) a)whas bleaching powder? How prepared? Give the reactions of bleaching powder with following oo ite Ab) What cen ya agonal elationship Give the diogonal relationship bsteen Be and A 1) Hoy wold you oat Ulster copper fom rensicd pyle? ie) Writedown the 1UPAC names of te following complexes: . SKAPICL] * [ZnCN]? —* [Colen,ChICl* (Cut id” v) Write a nite on any one of the following *Synthetie poly: *Acid rain Sy Whats Cataiytic eonverter? What are the in politon targeted by ctaiyte converter? Wi) Whitis drug and explain ny four stage with he tee ofeommen lif Explain appearance of colour in transition meth! complexes in term of Crystal field theory ORGANIC CHEMISTRY. wilt) Define (ony fou + Calenation “Homologous series *Reforning _*Funetional group 4 * Zwitter ion *Glycosidic linkage OR Define Bucky Ball explain its suracture and mention its some properties 1X) The structure of two organic compounds “Y” and!*Z’ are shown below H ; a KR a ®u—c=Bc—H = 7 Ne H + Draw and explain the orbital structure of Y. * Welle ie equatiois, when y and Z rect with ozone. OR How ean you prepare the following compounds (only e (Any Four) + Ethanal fromethyne *iliene from ethanol *Bramohydrin from ethene * White solid from acetylene *Etiyne from ethene n) Write the IUPAC mame of the following orennic compounds: * [cts cH —coo— (cH), * CH; = CH, = C(CH, GH = Ch, =CH-~CC~ CH=CH, “CH; ~ CH = CH — CH, — Coon si) Does benzene behave as oth saturated ond! unsaturated hydrocarbon? Support your answer with Sherien! equntions for ench ease : ae : one a or Compiled by: Sir Owais Fayyaz What is meant by stereo isomerism? Define chiral eavbor aid pwical isomerism, wii) izes the acidie nature of earboxulis acid, How can se prepare te fllowng compound from mee Aestunie * Acetie anhydride *Methane amines. Explain why secondary aminesiare more basic than xiii) Define primary, secondary ams (rtiar a compounds? How ean we prepare the Following are organo metallig compounds? prepare the following compounds from methy A) enor iodide? *2: propanol Methane Acetone magnes' ae atest to differentiate between following pair of ompound a 9 Alkane arid alkene * tyne and 2 butyne Give a chemict + Ajeoho! and phenol ‘ Hexane and benzeneSECTION *C (DETAILED-ANSWER QUESTIONS) Hotes Alteptay Twa questions — One question fom luorganic- Getetal Chemistry andthe other om Organic Chemistry. Both questions carry equal marks INORGANIC - GENERAL CHEMISTRY *) a) Explain with the help of a diagram Castnér Kelines’s eet), how caustic soda fs obtained by the slesolssis of bine? Alo wiie wowsesorcwnic oi Compiled by: Sir Owais Fayyaz ') What is troposphere? Desoribe the chemisiry involved due to présence of oxides of nitrogen and carbon inthe troposphere 4) Draw a flow diagram of contact process and deseribe various steps involved in the manufacture of oil Of vitriol Write the reactions of concentrated Sulphuric acid with the following. “Aluminum *sticrose 1b) Write the balance chemical equations for the following. * Sodium burns in excess of air. *Potnssiuim is pit into ethyl alcoho! * Carbon heated with nitrogen at high fempereture, Manganese reacts with air * Phosphorous is put in water. “Nitrogen reacts with oxygen in the presence of catalyst Permanganate ton reacts with oxalic acid. *Potassium dichromate dissolved in water at neuiral P' ‘OR ‘Explain the trerd the following properties of 3d series of transition elements Binding energy * Variable Oxi ORGANIC CHEMISTRY * Catalytic Activity * Magnetic behaviour 5) a) What is meant by orientation of benzene? Explain Orth-para and meta directing group, Write the ‘equation forthe preparation of TNT: and msnitro toluene from benzene OR Describe the molecular orbital Structure of Benzene. Write the mestianisin of chlorination of benzerie wolecules. ) Drawthe structure of eny eizhit ofthe following organi + Resorsinol * Adipic acid * Cyelo pentane * Teobuityralchy * 123 benzentriol * leopropy! bute * Diphenyl acetylene * Benzoguinone + 2methoxy-2methyt butane 4a, 8 - dimethyl valerie avid 6) a) Whatis p~ei ination reactions? Disetss the mech Feet Esa: Berecito OR Compiled by: Sir Owais Fayya Eaeee fan renstr guciiniord mes tedauerwst ecu oo Sy Wee eenieien forthe talovate sacs (any Bight) * Oxidation of Acsialdehyde with K,Cr,0,H,S0, * Formation of diazonium sali from amine. * Formation of preric acid from phenol *Reaction of ethylene glycol sith periodic acid + Ethancic acid is reduced in the presence of LiAIM, *Oxi tion of leohol with PCE * Reaction of acsinkdchvde with hydroxy amine. ** Reduction of ethonal by minture of zine amalgam and Goncenirated HCL OR Whaat are proteins? Cha various types of prxteins on the basis oftheir fnetion and structures, Also significance of proteins. give their biolShaheed-e-Millat Degree College Azizabad Karachi PRELIMINARY EXAMINATION 2025 Xl Chemistry Total Marks: 85 Time: 3hrs SECTION “A” 1-Multipie Gare customs Orn piled by: Sir Owais Fayyaz () The moststable carbocation fon is: (a) Primary {b) Secondary (c)Terilary (W)/- Butyricacid is found in: (a) Vinegar (b) Almond (c} Butter (4) Quaternary (a) Red ant (ii) ‘Sugars classified as: (3) Fats - [b)Proteins (c)Carbohydrates (4) Fibre (iv) ‘The region of the atmospheric sphere at a height from $0 km to 85 km from the Earth's surface is: (2) Troposphere —_(b) Stratosphere (c) Mesosphere (d) Thermosphere ‘Smog is a mixture of, ‘aerosals, and volatile organic compounds, fa) NOx {b) SO; {e)1No, {s) co Which of the following is an oxidizing agent? ey LAI. (b) NaBHe {c) KMino. (a) He (wi) Urea.was first synthesized by Wahler from an inorganic material named as: sbYanning nitrate —_{b) Ammonium chloride Ww) wit » (©) Ammonium cyanate (4) Ammonium bicarbonate (vil) The general formula of the! homologous series of alcohol is: (2) CH, WW) GHiee (0) Qian (8) G11 fix) Which of the following is a tritydric phenol? > la) Resorcino! —{b)Cresol_—_{c) Pyrogaliol {¢) Catechol te Which of the following molecules cannot form a hydrogen bond with water molecules? {a} Phenol (oi Resorcinol (c) Ethylchloride ——_(¢) Ethyl aleahol (xi) ‘The highest oxidation state of chromium is: (a) 4 toys (e)45 (aa? (2H) “Oil of vitrio refers to: (2) Borax + (8) Sulphuricacd = (e} lun (6) Caustic soda (xii) The s-block clement that forms superoxide when burned in air is; @)u {b) Na fk (Mg (xiv) The chemical commonly used in fireworks is: (a) Sodium bicarbonate {b) Bleaching powder (6) Potassium nitrate (d) Potash atum (ev) The knocking in an internal combustjon engine can be followin 7, es srolemmoens: COmpiled bys Sil OWI Fi ayyaz (a) Reforming (b) Refinir {e) Distillation (d) Condensation (rv) The IUPAC name of isopropyl sleohol is: (a) 2-propanol Ab) 2-propanol (c)1-butanol (a) 2-butanot {ruil The formuta of a saturated hydrocarbon is Cit. should be: (a)Butane (b) Butene {)Butyne (4) CyciobutaneShaheed-e-Millat Degree College Azizabad Karachi PRELIMINARY EXAMINATION 2025 Xi Chemistry Total Marks: 85 Time: 3hrs SECTION - B (SHORT ANSWER QUESTIONS) (Marks - 36) Answer any nlne-part questions. Select Four-Part questions from Inorganic - General Chemistry and Five-Part questions from Onganic Ch (All part questions carry equal marks. 6 INORGANIC - GENERAL CHEMISTRY 82° —UNGive the composition and applications of stainless steel, brass, and bronze. at is diagonal relationship? Explain with two examples. (ii) What are synthetic polymers? Write the names of two synthetic and one natural SIRT on reruns LLERE led by: Sir Owats Fayyaz = ICO)!" © NI(CO}L © [Culen) INO), © KelFe(CM)d Give reasons for any four of the following: {a)___lonization energy Increases from ieft to right in a period. (b) Elements of IA and NIA groups are good conductors of electricity. (©) Berytlium differs markedly from other members of the group. (4) Electronegativity decreases from tap to bottom down the group. (e) Chromium shows configuration 4s' 3d" instead of 4s? 3d", (Give chemical equations for any four of the following: (2) Potassiumnis put in ethanol. (b) Manganese Is burned In alr {2 Chromiumis reacted with steam. (4) Slaked lime is reacted with chlorine gas. {e}, Iran is exposed to alr, ys Explain Acid Rain and industrial Smog. ORGANIC CHEMISTRY Define the following: Saponification * Catenation »Functlanal Group + Reforming ww is te a mesa oo ef EN on a oe C-HECH, @ Cty CH:-EH-cH, coon . fey CoH © CHyCHCONH: «= HOOC-CH=CH-COOH Go ered Compiled b 1 by: Sir ¢ Owais Fayyaz menitrobenaolc acid from benzene. {x1)_g Explain the orbital structure of ethane and write two methods of its preparation. we Write the importance of carbohydrates and proteins. (i simple chemical tests to distinguish between the following: (a) Ethene and Ethyne (b) Aldehyde and Ketone (c) Ethanol and Phenol (d) Benzene and Hexane (xiv) Give any four chemical equations of the follawing: * Ethene is heated at 100°C in the presence of zinc with azone. © Ethyl chloride is heated with magnesium metal.PRELIMINARY EXAMINATION ZU25 XII Chemistry Total Marks: 85 Time: 3hrs SS Ear HEEEEeEEEEE ‘Ethyne is heated with AgNOs In the presence of NH. . © 1,1,2,3-Tetrabromo ethane is heated with Zn dust. ° Ethyne Is treated with H20 In the presence of HsSQ,/Hgs0«, + _1,2-dibromo butane ls heated with alcoholic potasslum hydroxide. SECTION - (Detailed Answer Questions) Total Marks: 32 Note: Attempt any Two questions, One from Inorganle-General Chemistry and one from Organic: Chemistry. Both questions carry equal marks. - INORGANIC - GENERAL CHEMISTRY 3a} Describe the manufacturing of H,S0 by the Contact process and prove that by chemical equation it acts as an oxidizing and dehydrating agent. (b) Explain any four of the folowing properties of the first series of outer transition elements: © Catalyticactivity.» Colour formation « Electronic configuration » Paramagnetic behavior ‘= Variable oxidation state Compiled by: Str, Owais Fayyaz 4. (a) Explain the metallurgy of 99.5% pure copy ‘composition and use of four alloys. (b) Write the balanced chemical equations for the following: Ferrie chloride is mixed with an aqueaus solution of caustic soda, Bleaching powder Is dissolved in water. Phosphorus Is put In water. Boron is reacted with Nitrogen. Sodium burns in excess alt. Potassium is aut into ethyl alcohol. Ne Silieon is reacted with hydrogen at high temperature. Chiorine gas is passed through an aqueous solution of caustic soda. caren, nih IRGANIC CHE! 5/(a), Explain the SN1 and SN2 mechanlsm using the examples of ter-buty bromide and methyl bromide with NaOH. How can you obtain the following from Grignard reagent: + Ethanolcacid + 1-bitanol « 2-methyl-2-propanol {b) Draw the structures ofthe following molecules: Isopropyl butanoate * Pyrogaliol « Neopentyl alcohol + p-Cresol « Ethyl neo-penty ether ‘© Benzamide « Tartaric acid + Benzene-1,4-dioic acid 5 = (a). Write equations of the following reactlons: (i) Reaction of phenol with conc. HNO,“ 8 {ip Reaction of 2" atcahal with KiGriOx/H:S0. (i) Reaction of ethyl acetatewith UAIH,, |, tL liv) Reaction of alcohol with ethanoleacid OM cao Clo By ~<-0- {v) Reaction of chiorobenzene with NaGH_ a 4 4, {) Reaction of Toluene with HNO, at 100°C - . \ {ui Reaction of thylamine with nitrous acid in the presence of Hl {vi) Reaction of aldehyde with'2n/Hg amalgam and HC} (bl What is meatit by ortho, para, aqd meta directing groups? Explain the inffuence of OW) substituent on benzene to the inca ipoeite. ne) fy) +N 2S ~ We, Shy Oh, 1 Ae no ay on ISM, Nu ao 3 Bio kK eb use : engrey ey Cot ? + Seow(ea aa oe ae eee epee Sy lear Cuemsrey PAreeail | (pat 1S.onaes Max Maries.) Mca’s Sect A tue zo ‘Compiled by: Sir Owais Fayyaz ; Ate Choose Ke Coed omserey from open oo ‘ Deckuchiie dst Nalin eh Gah ops Coat tay, Coal Ars | tke amd |e prec He a Rholtum Napitha 4 Brmmenia Vapor | By Wee ee Ak achibit chain ismredtin IS x Gilson od GH, —oH NE Eh amd OCHO) # Mec am Gi-cH-@ Tae Ne dH EN |g Resoedne| tsa p hewel ik contains 2OK ok 3) RP ors | & Rstinn 482 ¥ Posten ARS y Position LAL » Posi 284 [ty Select suckable cheniok “0 Abdingich be basen Ethone Bee 0: : 4 Nalin KMno, # Teed KeMng te 3 5) Wich of folleoig Gust Prdice Aine wile Awecked wit ad caladez pornssiions Wy dmoxrdl yivromnde +P ‘ a Pylon Baty ae of ord Ac (, gN 20K and GO Be is Glew = Pep reg x5xy a ed by Sir Ovvais F coe " to, Te & mutans vee 4s Fayyag yo: [co(¢.0s),]ie- o> x4 * & iE uy The tic GA is: + Cutt, Ceo 4 FG HCOOH OH, (00K a GH f? ; 43) On oxidodion Aecordory alecledt ae : Setter * Ndebyde #Kebme — »/omivs ie, Kyrie 264 umcts benfed mn prion uns leodte * ets. Linkage Ether lin lee eptide Linksge % Ty dren bridge a) hu Le ee aero. lastic jc. xy Polyetineme x PVC Ryle « Bakelite (ews clement is vel used nm elecKrpla an en Sw we cy «Mn “J ie Compiled by: Sir Owais Fayyaz \s) Aekophenence is membey cane fanily it~ conta ¥ [Wo ne ak Be N one aryl gen k One an one oe i 1% NMR Spectosery is Contormed wit ec 1 les che woth: ~ + Utbaviolet vadi tums x Visible yadictiay . ane dRil= Pq i pacaaiated : Gr Max Marts, 69 ? Ye 2H¢ Uo nun RS \, What bpoilgtnese Sir Quant ‘ayy entse D. ‘er are prpodies: Esse Cael eNeaialle Oyldation stab % Gaur formnabina oN eee Ay write the TUPAC vaires oo Lo tlewus a [ouceny J x [Nx xy," aN Ci], Jone KL ech] ii, What ane Satttadi potgmes 2 Explain tvc ov Nylene Ww Give eases Onn four of Sey % Elecivenertbiity decreases fom p “erties imencyas Terrain Unerense, from ek fo nani im anne d K ium dens wankedly Lye othe a tien bens, x shes Cenlsuratiin Ys aa'© instead ef HE ad? i oe lenendts 4,0" [a TVA cue aeed Card Stave | \ ae Sul pa Hea. y WR { eure: H 4 . ts Youwned mm alte - aya % Potessiven xeoded wry as ram x Lr Lepore jy ary K Slaked lime ic Yeaded witv ars x ory» Veadted vo'rtn Aare ee! stfe, NOMS: Nit, Define tre -folle oe ; \ odin w, Of iah iserreviom Ww ily Nuckeoy cop lite W) Po t eS by: fat Creed NE To i syst Aili Name ne wy compos | = ry Jee) Wac- ee) ae ya Hee CH= Pe. oe : iy v a Co- CAH, SY aytegyncone, Np Ny GH. = Ca. oto Ni) a DY Ww Wak \s Seaiggg s Pee My Wreke Capectinn of Beet fetid: ( >t) Onleude Kedad with alesbolic Artaasivn hujdre xidle & Ein ‘a\abe\ Weatted Witty, Srdium melal, * pad Je poarted port “Zine merry armelqan Neck add reacts voit eo chtoride hated, « aad ak 25°C 4 Premed Ab oahlioa Bye 8 Sir, ‘Owan Fa te : yi, what i yntal len 500) enificin ve ee ahs pati i Una rhe hen b ott wslecter 2 ae ef. mettout loutyratdelyde ~ 150 Pp! Sataaehie & (-Brvme 3- mettyt hevame 2 One * ae ac a 7 ai deriva: vex of Cankovulis d eayustiion a Thew pe airetien, ol ad ? f i fon acchie aud 23. 0, Desonbe the wdusta stad : - Bods by Caster Kellver? proces wi rere Cidaycarn Wate ad tere air Seen vailagin and dsobvad: Bats by Wink a valomced Chemical Cathar © wes e al a Nihngtin ads wie Omen inthe siege 4 of “cag - Bi om yee ¥ Blech yeadton ustin ict. * Readison of pewsoee wrn Xn aol. & AS pee capes SERA ion Cone: Seb Pcie ated we Ee ignion se puck vite Waser K Cnyemiunn Cen diinn usin, shea 4 Perdomo My wrin Oar + Fentc Dnlaride Yeadon with Nant . 44.4]. He ec ee pore py Frmen. sik werd fours alleys ? | ew ‘ z Hew x is pre axed explo with % Séiorram .) Give its WoO oud cl. ORGANIC ChemisteyBAMM PECHS GOVT. COLLEGE FOR WO CHEMISTRY PAPER IT jum Examination 2025 (Science Pre-Enginecring and Pre-Medical Groups) Marks: Ww Time: 20 minutes SECTION ‘A* This section consists of 17 part questions and all are td be answered. Each question carries one mark. Compiled by: Sir Owais Fayyas @ Melting and boiling points regularly decrease down the group in (a) Group 1A (b) Group IIA (c) Group VIIA (d) Group VIIA Gi) Cathode in Castner Kellner cell is: (@) Titanium blocks (b) Carbon rods (c) Mercury (d) Iron container Gi) A highly paramagnetic ion among the following is | (a) Fe? (b) Fe? (c) Co"? (d) Cr? (iv) Which of the following S-block element form Supe: oxide when burn in air (@)Mg (b)K (€)Na (d) Li (v) Alkanes are also called (@) Olefins (b)Paraffins (c) Acetylene (4) Proteins (vi) The number of five membered and six membered rings in Ceo Bucky ball are respectively (a) 12and 12 (b)Sand15 — (c) 12and 20 (a)40 and 20 (vii) The functional group that contains a Nitrogen atom is (a)Alcohol (b) Ketone (c) Ester (d) Amide (viii) Lipid which is a major component of cell membrane is (@) Triglyceride (b) Phospholipid (€) Glycotipid_(d) Steroid (ix) The formula of saturated hydrpea rbon is Calle ft should be (a) Propane (b)Propene (c)Propyne (d) Cyclo propane (x) Grignard reagent with ester produces (a) Aldchyde (b) Carboxylic acid (c) Ketone © Ether BeunseannerCompiled by: Sir Owais Fayyaz (xi) Amines act as bases Decase : sont (a) They donate H (b) They donate: OH” (c) They accent HT (@ They scceP! (i) The Green house gas ist 2 (Ax) (@) Carbon dioxide (COa) {0} Oxygen (Ox) (b) Nitrogen (Ni) (Argon (sil) Lueas reagent is a mixture of A a (o)Znand Hig (@) Zn and HC (©) ZnClz and HCL (@NsOH and CO (xiv) This one does not contain Carboxyl group (@ Acetic ac (a) Picric acid (0) Benzoic acid (¢) Butyric acid (? (i) SOs+ H1SO1-+? (sii) Cpu >? 4.) Explain why transition elements and reactions? (b) How can you define a coordinat ligands with examples. their compgunds serve as catalysts in many chemical ‘on complex and a chelating ligand? Explain various types of (ORGANIC CHEMIS: 5a) Describe the molecular orbital structure of benzene, ' (©) Givea comparative study between nuctcophilic substitution reactions and elimination reaction ofaikylhalides. Compiled by: Sir Owais Fayyaz, I 6,0) What are Proteins? Classify various types of proteins on the basis of their function. (&) Draw the structures of each of the following. i (i) 2,3,5-Trimethyl hexane \ (ji) 3-Chlorobenzene amide ¥ \y (iii) Resoreinol a | (iv) Pierie acid “| (¥) 3-Chloro benzamide | (Wi) 1,23-benzentriol (vii) Ethyl isopropyl ketone (vii) Butyraldehyde Becanscaoneif [7 SOVEDEGRED COLLEGE FORWOMEN BLOCK: NORTH NAZIMABAD } PRELIMINARY EXAMINTATON-2625 J XI-CHEMISTRY | Section ‘A’ (Multiple Choice Questions) TIME:20 MINS MAX.MARK Compiled by: Sir Ovais Fayyaz | GENERAL INSTRUCTIONS: if contains 17 multiple choice questions and all of them are to be \ ‘answered. | (1)T-butene and 2-butene show this type of isomerism | “chain sition _* metamerism “functional group (2) this isthe least stable carbo cation ‘methyl _yftimary secondary —_* tertiary (G) the number of five and six member drinks in bucky bally C-60 respectively “W2and12 242and20 *5 and 15 *40 and 26 (4) an example of thermosetting plastic is 2 A olyethene *PVC ‘nylon * Bakelite 1 (5) formic acta is naturally found in -€ “root ‘vinegar butter bee's sting A (the Fezion oF sphere which extends from 1 lkm to 50 km fiom eartn is known as Aioposphere ‘stratosphere *mesosphere thermosphere (7) high purity: metal obtained by “carbon reduction * hydrogen reduction *¢fectrolytic reduction * the {8) the number of unpaired electrons in Mn"? is A234 (9) which of the following compounds does not rea rite reduction svith Bromine *ethyl amine * propane "phenol “chloroform 7 (10) a mixture of iron sulphide and copper sulphide is called “angie Jae taller, residue (11) iso propyl Scoholoneaianten Fyiel Ugh commas nig a ras err ether “acetone *ethylene acetaldehyde (12) this drug is used as anti fiigal medicine *cholroquine *penicillin *aspirin fluconazole (13) itis meta esa “OH *R OR “CHO (14) chlorination of benzene in presence of sun light prodtices “chlorobenzene cyclohexane *hexachloro benzene * hexachloroeyelo hexane 15) this element has the maximum number of unpaired electrons ini 3d orbital dmium — *zine ¢¢hramium ~*yanadium lowing. mineral is used (o build strony bones and teeth iron zine *magnesium ‘calcium (I7jamino acids are building material of Compiled bys Sir Owais FPayyac “fats *Lipids protein carbohydrates (16) thi | iee CHEMISTRY PA AX.MARKS:6! | Sore Ee story ANSWER OUEST aay i MARI J ana rive pest ne prt questions. Stet for part questions from organi general | wstions from organi chemistry. All questions earry equatl marks. To INORGANIC. i Compiled by: [QD Describe the gre r toe the group trends of lonization potential andElectrical conductivity in s-block. Boive Feasons of any FOUR of he flowing: ; Bs yillium differs markedly from other members of the group, + Electro negativity decreases from to} lonization energ ‘ from top to bottom down thegroup. ae nergy increases from left to right in. period, ' ~ Multi-demtate ligands are krown as chelating agent, Chrontium shows configuration 4s', 3dSinstead of 4s", 3d. ~ ,, Boiling point of halogens increases down the group in the periodic table, "luorine is the strongest oxidizing agent, * Transitioncleme: sitionclementshuvetendencytotormalloy. > ae fi) Whatisatloy? ie . ' a 'sAlloy? Writeshencmedfthreeal oysofiransitionelementalongwith their composition. | Gd) Whatisindustrialsmogandlsowisit formed? | «® i petra chemical formulaancuseso ffourSynthetictertilizers, ORDescribe the role of CCS in lesti0¥ing ozone layer in the stratosphere, Compiled by: Sir Owais Faypas a { (x) SWhavis drug? Write the names of five important drugs. Explain any two of them. *[Co(C200xP *[Puen):(NO:)2]S0, | (i) WritethsiGPAChamesctthefollowing(ANYFOUR) \ *NaslCO(NC2}4] * [CHH2O}NOss | * Washing soda *Baking sede i ORGANIC CHEMISTRY | \Write three general properties of homologues. Vill) Enlist the characteristics of organic compounds and explain any three ofthese. ORDefine homologous | \ GxpPraw the orbital suucture of ethylene or acetylene. Also ‘explain acidie behavior of acetylene with the help | Shino reactions OR Definesterio-isomerism. Fxplain geometrical or optical isomerism with example, | \) Give equations and write the names of products formed in the following chemical processes, * Dehydrohalogenation of ethyl chloride. * Ozonolysis of ethene. * Dehalogenation of 1.1,2,2-tetrabromo ethane *Hydration of propyne under speeifie conditions. (SDWrite IUPAC names of any four of the following organic compounds. » Ce CHs-COOCH (CH3):* HOOC-CHs-CH:-COOH * CHs-CO-(CHa)-CHO *c (CHC * CHs=CH-CH=CH-CHs*CH3-CH=CH-CH>-COOH Cli O-CHs-CH(OCHS)-CHe-CoHs ACH CH REET : } site only equations to show tht benzene behuve a saturated hydrocrbon and give any one ection ‘sth mechanism which shows that benzene is saturated hydrocarbon.ORwhat are organometallic compounds? Write the equation of Grignard’s reagent with any three of the following. * HCHO *C1 *CHLCOCH, * CO>| eS) | | | 4.) Detine Metallurgy. Describe how 99.99% pure copper is abtained fr ‘ons of earbuxylic acids into any four of the following + Alcohol * Alkane Avrite down the eg ster cyt halide "Amide * Avid anhydride: tions far the eonye Aldehydes and ketones * I-butyne and 2- Liv) Give the laboratory test to distinguish benween any two of the following: aleohols and phenols * alkane and alkyl halide * aliphatic and aromatic compounds bulyne Compited bys Sir Owais Fayre MARKS:32 SECTION ‘@ (DETAILED-ANSWER QUESTIONS) ral chemistry and the other from Note: Attempt any tyo questions- one question from iuorganic- gener organic chemistry. Both questions carry equal marks. TNORGANIC-GENERALCHEMISTRY) 3.ay Desesibe the manufacture af Sulphurie acid by Contact process and show that withthe help of one eualion, itacts as dehydrating agent and osidizing agent. $b) Write the balanced equiations jor Any Eight ofthe following chemical processes: edisitiAluminiommetal + Causticsodaisrea * Bleachingpowderdissolveinwater. * Renctionofonalicseldwithk MnO jinthepresenceol SOs. Boronisreactedw ith Nitogen. Siliconisrenctedwwithly drogenathightemperature. * Chlorinegasispassedthroughhotsolutionofeodiumhydroxide, * Slakedlimeisreaciedyithehlorinegas. * Manganeseisburmedinair. * Coppertezctedwitheane.Niticasid, * KMn@ureactswithFeSO, inthepresencenfHzSOy, * KC 10 tesotswith!#eSO.inthepresenceof4SOy its chalcopyrite ore. Esplain their adverse effets on mankind. A) Vi hat are the main eauses of Global warming and Acid Rain’ ont Compited by: Sir Owais Fay What is Green-house effect? Hoyy does human activate contributes to the enhancement of the greenhouse efleet? - ORGANIC CHEMISTRY Gade splain the moleoular orbital treatment of Benzene, Also deserbe the orientation in monosubstituted “Benzene, Starting from Benzene. how would you prepare any two of the following: ® picric acid * p-nitro benzoic acid *m-nitro toluene: by Write the struetural formula of any eight of the following. a * Resoreinol * pXylene * Adipit acid * neo pentyl hicohol * ter butyl formate * iso propyl neo pentyl einer *wiphens! bromo methane 4 diphenyl cosiylene * aniline * valeriessid * pyrogallol * benzamide * civinglagetvlene o Compiled by: Sir Owais Fayyas 6.) What is fclimination? Explain the mechanfsin of E] and £2 reactions with suitable example. OR What are Carbohydrates ORProteins? Cive theinelasstication on the basis of thelr structure. And discuss their biological sinnificance, = by Arte the equation for the following reaetions, Any sight. + reaction of ethylene glycol with periodic acid * oxidation of secondary alcohol * oxidative cleavage of glycol reduction of carboxylic acid oxidation of phenol * sulphonation of phenol at 100°C sty drolysis of benzene dlazonium salt * ceiyation of excess of alcohol * reaction of ethyl acetate with LiAIH * reaction of eleohol with ethanoic acid. * reaction of chlorobenzene with NaOH. eoGOVT. DEGREE SCIENCE & COMMERCE COLLEGE BLOCK 7, GULSHAN-E-IQBAL, KARACHI. ary Examination-2025 Chemistry Paper Time: 3 hours cHoice Qui Total Marks (MCQ'S) (Marie ON! 1) Qu. Choose the w i First memberor each one ofp-tok is: Compiled by: Sir Owais Fayyaz eet answer for each from the given options #2 solid at onlinary temperauire +A typical metal atypical nom A Radioactive element Ji. When Potassium combines with ox “Normal Oxid Parowidle *Sub oxides *Super oxides ‘The strongest oxiixong agent amongst halagens: “Fy “ely “Bry *h iv. An example of polycentate *0,0;7 "oH on" *EDTA nds sof Mi inding eneral id Fe oe highesy heeausethey possess maximum number of: election and proton proton and neutno pained electrons “unpaired electrons Mi. Nylon 66 is condensation polymer of hexamethylene diamine and: *Benzonic acid adipic ace *Pathalicaca Valerie acid vii, Li” is powerful reducing agent due to its lange value for: ionization potent “hydration enthalpy “electron allinity, eleetronegativity deliyeles und ketones (more than Cay are): vill, At roam temp highe +Solid FLiquid x _si, Butane aund Methyl Propane are isomers.whieh formula is ditforent for two isomers *Semi-solides *Bmapereal Formula General Forma Sirtural formula Both bande x Kerasene is eomposed of hytiracirbons conning muinber of erent ato tC MG MS $C sal ofthe lowing operas omy Ow Benzene ay a *Ethanol di peien genes hgiegae ter il “104° 120° 095° sii The General formula foraleohol is: "Cian a5 $C Hay 8 sv. Tho organic compound whieh is eowrosive in nature and to *Phonol *tenzene *Ammmenia *None of them 1 Anlbities which play a very important oe in he immune system oF the body ae: sProicins—*Glucose Lipids Carbohydrates avi. Amine acts as bases because: * They avcept OFF They donate OW" "They accept H "hey donate i" uti Theavenen temnnmire nPeart fe a)IS b).S0 94sSECTION "BY (SHORT ANSWER QUESTIONS) (Marks36) Q2. Note: Answer any NINE questions. Select fourgulestions from Inorganic and five questions from Organic Chemistry.All questions carry equal marks, Compiled by: Sir Owais Fayyaz lio Ke ¥ (i) Define any two of the following: a) industrial smox_ b) Ozone depletion Substances ©) Chemistry of Steel d) Chemistry of KM,O, Gi) Give scien reasons for any FOUR of the following: a, Boiling points of halogens inerease down the group in the periodic table b. Acidity of hydrogen halides inereases from HE to HL ¢. Gallium has smaller atomic radii than aluminum. 4, Chlorine can displace bromi ind iodide from their salts but Muorine cannot? e. Ligands are generally called Lewis Bases. Why’? 1 H:SOy has high boiting point and viscosity. Why g. Transition metals form non-stoiehiomettic eompouncs, Why? (iii) How caustic soda is obvtina! by electrolysis of aqueous sodium chloride? OR What is bleaching powder? How it prepared? (iv) Write down three properties of Beryllium that show its unique behavior in uroup HeA (¥) What is a eaialytic converte «I how does it help fo reduce harm fel emissions from vehicles? (V)Give IUPAC names ofthe following: “Compiled by: Sir Owais Fayyaz a.[Co(NHs!s (NOws] b. Nas [CoCCN)d] c. [PH O}s CI (NOs Ks [Cu CNG) (sii) Discuss four segments of earth's atmosphere und mention in whieh we live? OR Give the eauses and adverse effeets or acid rain, ORG. CHEMIS Write the IUPAC names of the follow i) HOOC-CHECH-COOH i). CH) -CHECD-CI(CH! CHO iii) HC=C-C(CHI) yh-cH=-CH) and 3° aleohats ropa l (x) What ae organic compounds? Distinguish between organi conipounals and inorganic compounds bviety 24) Ouline the structures ofthe following Molecules: a. Salicylic Acid b. Toluene e. Methyl Amine. Teitiry Phenyl C1 8. @Chloro-Methyl Va 4Wow Be ne is prepaeat from Coal Tar 0, from Phenol, froin Sou Bervoate ud. trom polymerization of Acetylene (avi) Write the equation for the preparation of Acctablehyde by a, Hydration of Bthyne '& Onidation of Ethanot Compiled by: Sir Owais Fayyaz xvii) Why Alby nes are Known ashi iy unsaturated compounds? Also es plain their chemical and physical Pr OR What are carbohyalntes” Classified on the busts of SECTION *C” (DESCRIPTIVE ANSWER QUESTIONS) (Marks 32) Note: Auempt any TWO questions, sele ine from exe of inorganic and organic chemistry. (Inorganic Chemistry) QUO. a) What is metall 2 Mow is pure eopper extracted Irom its sulphide ore? OR Describe in detail the manulieturing process of Q10. by Es i. Complex Formation ii-Binding Energy QU1:4) Give th 0, by contact process. in the trend of following properties of transition elements: ii, Mlaguetie Properties Hoy Formation pe of pharmaceutical industries in Paibisisa? Am vive the cole of the followi a drugs in curing human diseases: {Anti Inflammatory fi.Antibioties oR What are alkati and alkaline earth metals? Compare thier following preperties Electrical condwetivity i leetioneyativity ililonization potential iy.Hydration enthalpies. Q11. b) Complete and hake the following reactions (any eight) i. Bleaching powder with hydnchlewie aeid ii, Sodium with CsH.OH iii, Phosphorus burns in excess of oxygen iv. M wgnesiumr heated with Nyy, Iron oxide with silica vi, Dichromte with FeSO, vii, Manganese with diLH,80, of Alumni rested with Chlovine 2846 18 Ronan with Oyen 3. Zine with (Organic Chemistry) Q12. a) What are Alkyl halides? Expiain their molecular orbital structure with physical and chemi properies? Compiled by: Sir Owais Fayyaz Q12. b) How ean you differentiate between total aux! partial thesis of organie compounds? OR What is meant by reforming? Why is it considered as « useful webnique? Q13. a) Desoribe the molecular osbital structure of Benzene, Give the mechanisin of any bvo of the following, ation EBlecivophilic substitution reaction: i, Niuaaion i, Aeylation ii, Sulphonation iy, Chor QI3. b) Write a note of any two: i. somerism ane! polymerization i. SNI re ons and SN2 reaetions ifi, Orientation of Benzene iv. Bucky BallQi: Select the most appropri vil SHAHEED FLYING OFFICER MARIUM MUKHTIAR GOVT. GIRLS DEGREE COLLEGE LIAGATABAD PRELIMINARY EXAMINATION (202429) CHEMISTRY Papor I SECTION‘AY uliplo Cholce Question) - (cae) Marks: 17 fe aNEWOr for bach from the gar opt (Compiled by Sir Outs Fag The general configuration af p Bock lemons rere pea 6 bigek elomenis wre els caled a Outer transtion elements Rare Earth motals “Inver ansivon elements “Both Outer transition and Rare Earth metals Which of he following pale of compounds represent uneianal group lometam SAisoutene and 2eutene "Ethanol and dimethyl ether ‘hdbutane and leo butano Diethyl ketone and methyl propyl Ketono sloront forme por oxi wit 3/90 “Unum Galclum w“Polaeslum ——* Barun Ths compound used for area pering of ft, “Ethane *Ethyne “ethene * Ethyl Alcohol Licas reagents amit of = *znandHg *ZnandHCl “*Znch and Hcl * NaOH and C20 ‘zomele compounds burns wilh soa bocause of Py They net \Slabiiity "Alternate double and single bond *High porcontage of Carbon * Ring structure [Drugs that war the body temperatura to normal are known as: \-“Antibjotics —*Antipyretic*Anthallerglc* Antl-istamine Sodium "Potassium *Calelum x xl xl, Acetic acid is naturally found In: xiv. Itmeintan the pH level in the body. Magnesium Ozone layer is presenti. repion of almosphere: roposphore ‘Stratosphere “Mesosphere _* Thermosphere CClemmensen reduction isthe convarsion of aldehydes and ketones int: “alkanes “Alkenes “Alkyl halides “Alcohols, The human body stores a par of glucose Iver inthe tvm ot “Cellulose "Amylopectin — * \Siycogen by: Sir Owais F ‘Valerian root -Bees sting nagar “Butter ‘An example of tertary structure of protoin is: Albumin <7Hemogiobin — *Myeglobin “Globulin Kinetics of Elimination Blmolecular reaction I: ‘Zero order “Firstorder_\-*Sacond Order “Third order ‘The coordination number of nickel in Na, [NI(OH). CI] i: oe eee oa m2 “The region of sphere which oxtona from SCkm lo B5km from our Earths is known as: ‘ScTroposphere “Stratosphere "Mesosphere “Thermosphere [SECTION 6" (SHORT: ANSWER QUESTIONS) Marks: 36 Th lots: Attempt any nine questions. Four questions from gach section. All queations earry equal marks. Cs i. How was bzone layer formed? Expleln the causes of depletion of ozone layer. ~Chioro benzene reacted wi INORGANIC CHEMISTRY. Define and explain the general group trend and rreguiarves of lonizalion energy OR Electro negativity in the periodtc table. UK. Give reasons for (any four) of the following: "Boling point falogens netesses down the group inthe period table + Carsonnes high meting pol than nitrogen. + Alka melas are good conductor of elect * Fluorine is the svongest oxiczing agent + Nalisdeniaio igands are known as chelating agents + Akal metals cannol be used in vole cle saline earth metals are harder than skal meal ‘Moai propery Ineresses down the grup. ~ Why Gu on is blue wile 2nfon is eoloriess? “Whychromium ext ae 48°9G rather than 45°20"? Gy Blasonal elaonship on ofthe folowing paic*Li and Mg “Be end Al" B and Si Mints ares vee ener erm iether fre if enten elmer oa wih et Hee CLOR Explain why Borylum behave dferenty irom other member of group Co Or aanae prepared fn ekssilyam of sodium cher (Nec), OF Wik chor not en Bleaching pod ‘ite Cour tre LUPAC ramas of any four of te flowing complexes: MAg(NHQJOH + [Fe(CN)d-* *Ki{Cr(C.0.), Ch] *[PIen)s(NOs)]8. STCUHOM(NO}) *(AUGO)]* *NadNiS,O)3]— AINISCN)* He a eae preparation ad ued of Non and pol vin tei Bel eten uate ssh ‘OR What Is meant by acid rain describe its causes and oveo ofc on human SHI ewisrey az xy, 22 je coal produced under the bart crust? Wille the ame of four types of coal and mention ths Yeage of carbon content inter. OF Fee ea ecus series and wrt is thee general propates. OR Define Benzene and Aromatic, Give Twe examples of chemieal ton In which benzene ring is distorted, : # ital attucture of Ethyne OR Ethene and expiain how attyne distinguished from ethene by a simple the equations of Radical subsituon of Matane vith Chiorine and also step wise mechanism. ‘of final product inthe folowing process. (any four) Draw and exclain briefly the o Chemical esl, OR Give all Give the equations and write the name 7 Etiyne ie trated with hydrogen bromide. 4) Baborinocthene is heeled wih alcohol KOH + 411;22 leita bromo ethane reacted with Zing + Eliyne treated wih ouproous choride OR Siver nitate Adon EtrjT cohol tested with thony| chloride OR Phosphrous Wi Chlorice fi sgdium hydroxide at 350°C and 45Caim + Acelaldenye trealed with Hydrazie in prsance of ald“Ethane reacted wit Bromine water xx Whatls Grignard reagent? Wit the equation of Methyl Magnesiam Chleride reaction with (any threo) THO *CO; "CHINH, ‘CHCOOCH, ‘HCHO *CH,GOGHy _* CH.CHO srk. Why te styl amines basic in nature? How a primary alkyl aio e prepared rom aly halo and how Ke converted ne sacondony tiny eteanramane® Gh the equation, OR. Bethe aly aides and ts fypes wih one example, OR Dafne aleonol and is Pes win ono oxamla Compiled by: Sir Owais Kaya: xi, Wite the UPAG name ofthe flownng organte compound: (any four ° IL + (CH), CHC CH (Citi), * CH) CH. 0-6 (CH) Calle HoG=C—CH=CH-CH, — *CH,-CH-CH, CH = CH—CH,-cH (ol) (OH)— COOH iGTGate) corey —CoOc.H,, *CH, -CH (ICH (Nth) ~CHICH))CH,- CH,-€ (Br) CH(CH.)CHO ti, Name four Gervalive of earboxyle ald and vite the equations ofthe preparation. OR (a). Stale Markonkoff ule wih ono example. {8} Wile Cistinguish test between the following: (any 2) “Ethane end Ethyl Chlerido “Aldohyde and Ketone "4 Butyne and 2 Butyne, 24,3" alcohol ‘xv. Ge two reactong ofeach i deny Alcohol and Phenol. OR Show wih tho help of equaten why aleahol and phanol is ace n (DETAILED QUESTION ~ ANSWER) Note: Alem! aay two questions from this section. One from Inorganic Chemistry and ‘equal marks. INORGANIC CHEMISTRY. 4G (e) Describe in deta the process of manufacturing FSO. by Contact's process. Also show by eauation how H.Svaet 2 oxidizing, Suiphonating and dehydrating agent (Any two) (08) TO) Wile the balance chomical equations for the following. (08) 7 Amite of eatbon and silicon Is heated under eevated temperature Phosphorus is put into water 2 Bleaching powders reated with hydrochloric acid ‘Chlorine gas is pass through hot aqueous solution of caustic soda Copper s realed with concentration nic acid P°q plece of chron fut inte diate hysrochlorie acid Reacts botnesn KMinO, and FeSO. in the presence of H.SO. wrt nie equation) * Rearton batween K(GhGy end FeSOqih the presence of H.S0, (writ ionic equation) Sodium hycronde reactes with aluminum in presence of water Reaction between KNnO, and H.C.0. In the presence of H.SO. (wnt nie equation) Fei) Desenbe vanous slaps involve in the ex-acton of 98.29% pure copper rom fs chalcopyrite ere, (08) {b) Sepa ihe following properties of ansiton elements. (Any Four) eric pepery)¥= Paramagnetic propery Variable oxiaton site * Color formation “Alay formation (08) OR ‘Compiled by: Sir Owais Fayyaz Jassifealon on basis of erugs bro (8) ee (ORGANIC CHEMISTRY Ei oat mean by oration of benzene? Expl aterpara and meta roving orun. ire te aquatin fr preparation ef 7NT 08 ane ni tvene from benzene. OR. ) Fre i her molecular ors structure of benzene. Why benzene show stably towards addon reaction ritston OR alkyialon OR acylation OR sulphonation cf benzene <6) Draw te stracture ofthe folowing organic molecules: (any Eight) (08) Ora cunoats-ely| nacpenty thor" Dp araenn real Pfeaalll = Paty uric aed *Bensaraoe «cor Fee esas Ganchyden Plaie acd “INT” Anne” Cafbake ad Toulene * White acatyide “syors!" suviave b=! SRasone © Catechol’ Hydroqunone.“Dipheny| ether * Benzophenone i oR. ene cae slr! Cael ther on te a of dus and gett boil sgiianen, OR What re Proteins? Classy aera bass of stlure and walle is properties and biloica Importance {G6 la) Yat is meant by Nucleophile? Give the mechanism of (0) oe ti esha ond NaOH SN? roaclans botwaen {* al halide and NACN, OR. Whats mean y Elrinstion caution? Describe the mechanism of E* and E'with one example. {) Define isomerism and describe Rs al types with one example. oR (08) sine equabon forte owing reactions. (Any Elght) + Onidaton of 2-alcohol with KsCr,OxH5O, + Reaction of pheno) with SO, at 20°C cBesenton of aestldefyde wih Zn (Ho) amalgam and Conc HCl “Risselon ofa aldehyse with Tollens’s reagent + Dehydration of ethyl alcohol at 170°C In cone, HsSO- + Reseton of eltylene glycol win period ac + Redueion of arate acid wih LAI. + Gyidain of -loohal a presence of POC + epoxidation of Ethene + Gronolysis of Ethene OR Azatylene a pers on of Etyne in presence of 50. and HoSO- + Reason of feamine wih Aisehyde + Rescieon of Phenol wih Cone HNO: «Benet veated wiih Cone H-SO. at 100°C { Roscton of Acate acid wilh PC 1 = Ghidatin of 2-elohl in presence of PCC etlen of Benzene Dizonium Chleride with water + Recucton of thy! Acelai® Sees a nar alechaln presence of KO; and SO. + S2ibton of Sodum Benzene Suphonate wih NaQk, «aaa of phenols prosence of C0) and H.SO. pazss of Acelc acid in presence of POs Marks: 32 the other from Organie Chernstry. Both questions cary (©) Whats Pharmaceutesl industry? Describe its c 5? Wits the mechanism of $$$ ee