THE ANONYMOUS
INSTITUTE
XI-XII
PHYSICS-I
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MATHEMATICS-I
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BIOLOGY-I
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BOARD OF INTERMEDIATE EDUCATION, KARACHI
INTERMEDIATE EXAMINATION
MODEL PAPER-2025 (ACCORDING TO REDUCED SYLLABUS – 2025)
SOLVED BY SIR NASIM ZULFIQAR
CHEMISTRY PAPER – II Max. Marks: 17
According to New Book (Science Pre-Engineering & Pre-Medical Groups) Time: 20 minutes
SECTION ‘A’
(MULTIPLE CHOICE QUESTIONS) – (M.C.Qs.) (Marks : 17)
NOTE: i) This section consists of 17 part questions and all are to be answered. Each part question carries one mark.
ii) Do not copy the part questions in your answerbook. Write only the answer in full against the proper number
of the question and its part.
iii) The use of scientific calculator is allowed
1. Choose the correct answer for each from the given options:
i) In III A group of periodic table, the ionization of gallium (Ga) is higher than aluminium (Al) due to insufficient
shielding of the nuclear charge in gallium (Ga) by:
* 4s electrons * 4p electrons * 3d electrons * 3p electrons
ii) This metal is essential for growth of bones and teeth:
* Calcium * Magnesium * Sodium * Potassium
iii) The boiling point and viscosity of H2 SO4 is high because:
* it is strong oxidizing agent * it is highly volatile
* it has strong hydrogen bonding * it form stable sulfur-oxygen bonds
iv) The coordination number of ' Pt ' in Pt (en)3 Cl4 is:
* 3 * 4 * 6 * +4
v) This metal has maximum number of unpaired electrons in 3d orbitals:
* Copper (Cu) * Manganese (Mn) * Cobalt (Co) * Iron (Fe)
vi) The general formula of the homologous series of cyclo alkane is:
* Cn H2n * Cn H2n+2 * Cn H2n−2 * Cn H2n+4
vii) The final product obtained when hydrogen bromide (HBr) is added to an ethyne molecule:
* 1,2 – Dibromo ethane * Bromoethene
* 1,1 – Dibromo ethane * 1,1,2,2 – Tetrabromo ethane
viii) The sooty flame observed when benzene burns is due to:
* high percentage of carbon atoms * low molecular weight
* high percentage of hydrogen atoms * high density of benzene
ix) The carbonyl carbon of aldehyde is:
* sp hybridized * sp2 hybridized * sp3 hybridized * dsp3 hybridized
x) Lucas reagent is a mixture of:
* Zn and Hg * ZnCl2 and HCl * Na and Hg * CaO and NaOH
xi) When a Grignard reagent reacts with Ketone it produces:
* primary alcohol * secondary alcohol * tertiary alcohol * Ester
xii) An example of transport protein is:
* Albumin * Haemoglobin * Lipase * Casein
xiii) This compound among the following is known as oxime:
O
||
* R − CH = N − NH2 * R − C = NH2 * R − CH = N − OH * R − CH − OH
|
CN
xiv) Antimalarial drug among the following is:
* Ibuprofen * Chloroquine * Paracetamol * Diphenyl hydramine
xv) Ozone is destroyed by:
* Sulphurdioxide (SO2 ) * Carbon dioxide(CO2 )
* Chlorofluorocarbon (CFCs) * Hydroflorocarbons (HFCs)
xvi) The IUPAC name for formic acid is:
* Acetic acid * Methanoic acid * Ethanoic acid * Benzoic acid
xvii) The pH of acid rain is:
* Between 7 to 8 * Between 6 to 7 * Below 5 * above 8
xxxxxxxxxx
BOARD OF INTERMEDIATE EDUCATION, KARACHI
INTERMEDIATE EXAMINATION
MODEL PAPER-2025 (ACCORDING TO REDUCED SYLLABUS – 2025)
CHEMISTRY PAPER – II Max. Marks: 68
(Science Pre-Engineering & Pre-Medical Groups) Time: 2 Hours 40 minutes
According to New Book SECTION ‘B’
(SHORT-ANSWER QUESTIONS) Marks : 36
Note: Answer any Nine part questions. Select Four part questions from Inorganic – General Chemistry and Five part questions
from Organic Chemistry. All part questions carry equal marks.
INORGANIC – GENERAL CHEMISTRY
2. i) What is flame test? Why alkali and alkaline earth metals give coloured flame? Mention the colour of flame of any two
alkali metals.
OR
Give reasons for the following:
* H2 SO4 behave as oxidizing agent.
In sulfuric acid, the oxidation state of sulfur is +6, it undergoes reduction to form SO2 which has +4
oxidation state. Due to the reduction of H2SO4 it has the ability to oxidize others. Hence, it is an
oxidizing agent.
* Gallium has smaller atomic radii then alumuinium.
Gallium has smaller atomic radii than aluminum due to the shielding effect of 3d orbitals.
* Acidity of hydrogen halides increases from HF to HI
Acidity of hydrogen halides increases from HF to HI because of decreasing bond energies. When the bond
becomes weaker than H+ ions are lost easier which increases the acidic character.
* Binding energy of zinc is least in 3d series.
Binding energy depends upon the number of unpaired electrons. Since zinc does not contain any unpaired electron
hence it has least binding energy.
ii) Write the IUPAC name of the following:
* sodiumtetrahydroxoplatinate(II)
*hexacyanoferrate(III)ion
*trisethylenediaminechromium(III)ion
*triamminetrinitrocobalt(III)
iii) Why the compounds of d – block elements colored? Explain in term of crystal field theory.
iv) Describe how 99.99% pure copper is obtained from copper matte.
v) Describe the preparation and uses of Nylon and Polyvinyl chloride.
vi) What are greenhouse gases? Explain greenhouse effect.
vii) Define the following:
* Catalytic Converter
* Chelates
* Diagonal Relationship
* Antipyretic Medicine
OR
Write at least one significant use of following metals:
* Sodium → It is used to prepare sodium extract for element detection.
* Calcium → It makes the bones strong.
* Iron → It is used to make doors and windows
* Copper → It is used to make wires.
ORGANIC CHEMISTRY
viii) Define any four of the following:
* Reforming of Petroleum
The process in which straight chain hydrocarbons are converted into branched chain hydrocarbons is called
reforming of petroleum.
* Catenation
The ability of carbon to form long chain and rings is called catenation.
* Functional Group
Atoms or group of atoms which are responsible for all the chemical and physical properties of organic compound is
called functional group.
* Homologous Series
The consecutive members of organic compounds differ with a ratio of CH2 forming a series called homologous
series.
OR
Define Bucky Ball? Explain its structure (diagram is not required). Write its two properties and two uses.
ix) Write the IUPAC names of any four of the following:
* ( )
CH3 C − CH2 − CH CH3 ( ) * CH3 − C − CH2 − C CH
3 2
2,2,4-trimethylpentane ||
CH2
2-methylpent-1-ene-4-yne
OH O
| ||
* Cl − CH2 − CH − CH2 − C− OH * CH3 − CH − CH − CH − CHO
| | |
Cl Br CH3
3-chloro-3-hydroxybutan-1-oicacid
CH3 3-bromo-4-chloro-2-methylpentan-1-al
|
* CH3 − C − NH2
|
CH3
2-methylpropan-2-amine
x) Give the mechanism of free radical reaction between methane and chlorine in the presence of sunlight.
OR
Define Chiral Carbon and Plane Polarized Light. Explain optical isomers with example.
Plane Polarized Light:
When unpolarized light is passed through a polarizer then only a single component of light passed through it. Such light
is called plane polarized light.
xi) a) Why terminal alkynes are acidic in nature? Write one chemical reaction to support your answer.
b) Why does the −NO2 group attached to a benzene ring direct incoming electrophiles to the meta position in
electrophilic substitution reactions of benzene? Explain briefly.
According to New Book
--:2:-- CHEMISTRY PAPER – II
(Science Pre-Engineering & Pre-Medical Groups)
xii) Identify each of the following with one laboratory test:
* Alkene
C2H4 + Br2 ----H2O---> C2H4Br2 (Brown color discharges)
* Alcohol
C2H5OH + HCl ----ZnCl2---> C2H5Cl + H2O (White ppt. appears)
* Phenol
Brown color of bromine water discharges.
* Aldehyde
Vinger like smell releases.
xiii) Write the names of four derivatives of Carboxylic acid and give the equation for their preparation from acetic acid.
xiv) Define amines. Why they are basic in nature? Write the chemical equations for the preparation of the following
compounds from an amine (R − NH2 ) :
* Amide * Diazonium Salt
OR
Write the names of two organometallic compounds (except Grignard reagent). Write the reactions of Grignard with
the following:
* Amine * Carbon dioxide
Tetraethyl lead and dimethyl Zinc are two organometallic compounds.
SECTION ‘C’
(DETAILED-ANSWER QUESTIONS) Marks : 32
Note: Answer any Two questions ––– One question from Inorganic – General Chemistry and One from Organic Chemistry.
Both questions carry equal marks.
INORGANIC – GENERAL CHEMISTRY
3. a) Complete and balance the following chemical equations:
Cu + HNO3 → Cu(NO3)2 + NO2 + H2O
OR
Discuss the group trend of Atomic radii, ionization energy, electrical conductivity, melting and boiling point of
Alkali metal.
b) Draw a flow sheet diagram of contact process and describe various steps involved in the manufacturing of sulfuric acid.
also write two chemical reactions in which sulfuric acid behave as dehydrating agent.
4. a) What is Troposphere? Describe the chemistry involves due to the presence of oxides of nitrogen and carbon in
troposphere.
b) Define d – block elements. Why are d – block elements called transition elements? Explain trend of following properties
of 3d – series of transition elements. (any three):
* Catalytic activity * Alloy Formation * Variable oxidation state * Magnetic Behavior
D-Block Elements:
The elements in which the valence electrons enters in d-orbital are called d-block elements.
d-block elements are also called transition elements because their electrons are in transition state.
ORGANIC CHEMISTRY
5. a) Explain the structure of benzene according to molecular orbital treatment. Also write two chemical reactions in which
behave as unsaturated hydrocarbon.
UNSATURATED NATURE OF BENZENE
SATURATED NATURE OF BENZENE
b) Outline the structures of each of the following molecules: (any eight)
Divinyl Acetylene
CH2=CH-C≡C-CH=CH2
Neo butyl butyrate
O CH3
H3C CH2 CH2 C C CH3
CH3
Neocaproic acid
O
H3C CH2 CH2 CH2 CH2 C OH
p-Cresol
3-chlorobenzamide
1,2,3-benzenetriol
Hexamethylene di amine
H 2N CH2 CH2 CH2 CH2 CH2 CH2 NH2
−chloroisovaleraldehyde
CH3 Cl O
H3C CH CH C H
Methandiol
OH
H C OH
6. a) What are Nucleophilic substitution reactions. Compare in detail SN1 and SN 2 reactions with mechanism.
b) What are carbohydrates? Classify on the basis of structure. Explain the role of the following carbohydrates in health
and disease:
* Fructose * Glucose
OR
Write the chemical equations of the following: (any eight)
* Reaction of ethyne with ozone.
* Reaction of bromoethane with alcoholic solution of KOH .
* Reaction of ethanal with reducing agent like LiAlH4 .
* Reaction of propanone with mixture of zinc amalgam and concentrated HCl .
* Oxidation of phenol with K2Cr2O7 in presence of H2 SO4 .
* Ethanol reacts with thionylchloride in presence of pyridine.
* Reaction of bromoethane with KSH .
C2H5Br + KSH → C2H5SH + KBr
* Reaction of ethyleneglycol with periodic acid (HIO4 )
* Reaction of benzene with acetyl chloride in the presence of Lewis acid ( AlCl3 )
THE ANONYMOUS
INSTITUTE
XI-XII
PHYSICS-I
PHYSICS-II
MATHEMATICS-I
MATHEMATICS-II
CHEMISTRY-I
CHEMISTRY-II
BIOLOGY-I
BIOLOGY-II
COMPUTER-I
COMPUTER-II
ENGLISH-I
ENGLISH-II
URDU-I
URDU-I
ISLAMIAT-I
PAKISTAN STUDIES-II
FOR EVERY SUBJECT SOLVED MODEL PAPER CONTACT AT: 03368089166
SCAN HERE FOLLOW OUR OFFICIAL
CHANNEL
SCAN THE QR CODE THROUGH YOUR WHATSAPP CAMERA &
FOLLOW OUR CHANNEL OR CLICK AT THE ICON
