Custom Practice Test - 21-Jan

Contact Number: 9667591930 / 8527521718

Chemistry-Section-A 5. Which, of the following solutions has the

highest freezing point?
1. 1. 1 M Urea solution
Mixture of nitric acid and water 2. 1 M KCl solution
Assertion (A): forms maximum boiling 3. 1 M MgCl2 solution
azeotropes. 4. All have the same freezing point
Interaction between nitric acid
and water is stronger than the 6. The freezing point depression constant for
Reason (R): interaction water is 1.86 oC m-1. If 5.00 g Na2SO4 is
between nitric acid and nitric dissolved in 45.0 g H2O, the freezing point is
acid or water and water. changed by -3.82 oC. The Van’t Hoff factor for
Na2SO4 is:
Both (A) and (R) are True and (R) is the
1. 1. 2.63 2. 3.11
correct explanation of (A).
3. 0.381 4. 2.05
Both (A) and (R) are True but (R) is not the
2.
correct explanation of (A).
3. (A) is True but (R) is False. 7. What mass of urea (NH₂CONH₂) is needed to
4. Both (A) and (R) are False. prepare 2.5 kg of a 0.25 molal solution?
1. 39 g 2. 37 g
3. 41 g 4. 35 g
2. 100 mL of liquid A was mixed with 25 mL of
liquid B to give a non-ideal solution of A-B. The
volume of this mixture will be:
8. Determine the vapor pressure (in torr) of a
1. 75 mL
MgCl2 solution, given the following data:
2. Exact 125 mL
3. Between 75 mL and 125 mL a) molality: 1 m
4. Close to 125 mL but will not exceed 125 mL b) vapor pressure of pure solvent: 100 torr
c) α (degree of dissociation) = 80 %
3. Van't Hoff factor for SrCl2 at 0.01 M is 1.8. 1. 95.53 2. 78.23
Percent dissociation of SrCl2 at this 3. 68.12 4. 58.26
concentration is:
1. 70
2. 55 9. At 300 K, when a solute is added to a solvent,
3. 40 its vapour pressure over the mercury reduces
4. 80 from 50 mm to 45 mm. The value of the mole
fraction of the solute will be:
4. C6H6 freezes at 5.5°C. The temperature at 1. 0.005 2. 0.010
which a solution of 10 g of C4H10 in 200 g of 3. 0.100 4. 0.900
C6H6 will freeze is:
(The molal freezing point depression constant
of C6H6 is 5.12°C/m.) 10. If the boiling point of water at 750 mm Hg is
1. 2 °C 99.63°C, what quantity of sucrose is needed to
2. 1 °C be dissolved in 500 g of water to achieve a
3. 6 °C boiling point of 100°C?
4. 5 °C (Molal elevation constant for water is 0.52 K kg
mol−1 )
1. 128.17 g
2. 121.67 g
3. 125.57 g
4. 116.27 g

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 Custom Practice Test - 21-Jan
Contact Number: 9667591930 / 8527521718

11. A 5% (w/v) solution of cane sugar (molar 16. The osmotic pressure of a 5 % (W/V)
mass 342) is isotonic with 1% (w/v) of a solution solution of cane sugar at 150 °C is:
of an unknown solute. The molar mass of an 1. 1.45 atm 2. 5.07 atm
unknown solute in g/mol is: 3. 3.4 atm 4. 4 atm
1. 171.2
2. 68.4
3. 34.2 17. The vapour pressure of an aqueous solution
4. 136.2 of sucrose at 373 K is found to be 750 mm Hg.
The molality of the solution at the same
12. The osmotic pressure exerted by a solution temperature will be:
prepared by dissolving 10 g of protein of molar
−1
1. 0.26 2. 0.53
mass 60 g mol in 200 mL of water at 27°C
3. 0.74 4. 0.039
will be:
−1
(Use R = 0.083L bar mol K −1 )
1. 22.5 atm 18. 0.2 M aqueous solution of glucose has
2. 20.5 atm osmotic pressure 4.9 atm at 300 k. What is the
3. 18. 5 atm concentration of glucose if it has osmotic
4. 24.5 atm pressure 1.5 atm at the same temperature?
1. 0.09 M
13. The osmotic pressure of a dilute solution of 2. 0.04 M
an ionic compound XY in water is four times 3. 0.01 M
that of a solution of 0.01 M BaCl2 in water. 4. 0.06 M
Assuming complete dissociation of the given
ionic compound in water, the concentration of 19. The correct statements among the following
XY (in mol L–1 ) in solution is: is:
1. 4 × 10–4 A porous membrane used in reverse
2. 4 × 10–2 (i) osmosis is a film of cellulose acetate placed
3. 16 × 10–4 over a suitable support.
4. 6 × 10–2 To increase the solubility of CO2 in soft
(ii) drinks and soda water, the bottle is sealed
14. The boiling point of an azeotropic mixture under high pressure.
of water and ethyl alcohol is less than that of In osmosis, only the solvent moves while
(iii)
the theoretical value of a water and alcohol in diffusion both solute and solvent move.
mixture. Hence, the mixture shows:
1. That solution is highly saturated 1. Only (i) and (ii) 2. Only (ii)
2. Positive deviation from Raoult's law 3. Only (ii) and (iii) 4. (i), (ii) and (iii)
3. Negative deviation from Raoult's law
4. Nothing can be inferred
20. The osmotic pressure in pascals exerted by
15. A non-ideal solution was prepared by
a solution prepared by dissolving 1.0 g of
mixing 30 mL chloroform and 50 mL acetone.
polymer of molar mass 185000 in 450 mL of
The volume of the mixture will be:
water at 37°C is:
1. >80 mL
1. 37 Pa
2. <80 mL
2. 35 Pa
3. =80 mL
3. 31 pa
4. ≥80 mL
4. 41 Pa

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 Custom Practice Test - 21-Jan
Contact Number: 9667591930 / 8527521718

21. Which of the following changes would 26. The boiling point of water at 750 mm Hg is
result in greater solubility of a gas in a liquid? 99.63°C. How much sucrose is to be added to
1. Increasing temperature 400 g of water such that it boils at 100°C?
2. Increasing the amount of liquid ( Kb H2O = 0.52 K kg mol−1)
3. Decreasing temperature 1. 97.33g
4. Reducing gas pressure 2. 121.67g
3. 145.14g
4. 124.79g
22. 3% (W/V) solution of glucose is isotonic with
1% (W/V) solution of a non-volatile and non- 27. Which condition is not satisfied by an ideal
electrolyte substance. The molecular mass of solution?
the substance would be: 1. Δmix V = 0
2. Δmix S = 0
1. 180 g/mol 3. Obeyance to Roult's Law
2. 360 g/mol 4. Δmix H = 0
3. 420 g/mol
4. 60 g/mol 28. The van’t Hoff factor (i) for a dilute aqueous
solution of a strong electrolyte barium
23. Which of the following pairs exhibit positive hydroxide is:
deviation from Raoult's law? 1. 0
2. 1
(i) Chloroform and Acetone 3. 2
(ii) Carbon disulphide and Acetone 4. 3
(iii) Ethanol and Acetone
(iv) Phenol and Aniline 29. The freezing point of depression constant
1. i and ii (Kf ) of benzene is 5.12 K kg mol–1. The freezing
2. ii and iii point depression for the solution of molality
3. i and iv 0.078 m containing a non-electrolyte solute in
4. ii and iv benzene is:
(rounded off up to two decimal places)
24. The relative lowering of vapor pressure 1. 0.80 K
upon dissolving a non-volatile solute in a 2. 0.40 K
solvent is equal to: 3. 0.60 K
1. Mole fraction of the solute 4. 0.20 K
2. Mole fraction of the solvent
3. Concentration of the solute in grams per liter
4. Concentration of the solute in grams per 100 30. Acetic acid dimerises in benzene . The
mL value of Van't Hoff factor (i) for the
dimerisation of acetic acid is 0.7. The percetage
25. The vapour pressure of chloroform and dimerisation of acetic acid will be-
ethylene glycol at 400 K is 300 mm Hg and 500
1. 30% 2. 60%
mm Hg, respectively. The vapour pressure of
the solution prepared by mixing 50 g of 3. 70% 4. 90%
chloroform and 25 g of ethylene glycol at 400 K
will be:
31. Van't Hoff factor of centimolal solution of
1. 397 mm Hg K3 [F e(CN )6 ] is 3.333. Percent dissociation of

2. 424 mm Hg K3 [F e(CN )6 ] will be:

3. 229 mm Hg 1. 33.33 2. 0.78

4. 501 mm Hg 3. 78 4. 23.33

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 Custom Practice Test - 21-Jan
Contact Number: 9667591930 / 8527521718

32. When two liquids A and B mix together,

the boiling point of solution is found higher Chemistry-Section-B
than that of the individual liquids. The nature 36. The mole fraction of glucose (C6H12O6) in an
of the solution is: aqueous binary solution is 0.1. The mass
1. Ideal solution. percentage of water in it to the nearest integer
2. Positive deviation with a non-ideal solution. is:
3. Negative deviation with a non-ideal solution. 1. 44% 2. 49 %
4. Normal solution. 3. 47 % 4. 41 %

33. The correct formula of Roult's law for non- 37. Which of the following aqueous solutions
volatile and electrolyte solute is: exhibits the highest boiling point?
(P = Vapour pressure of pure solvent 1. 1.0 M NaOH 2. 1.0 M N a2 SO4
Ps = vapour pressure of solution 3. 1.0 M N H4 N O3 4. 1.0 M KNO3
i = Van't Hoff Factor
n = Moles of solute
N = Moles of solvent) 38. The molarity of NaNO3 solution is 2M. The
P −P n
1. = i ( )
s

P n+N density of solution is 1.2 gram/ml. The molality

2.
P −P
= i ( n+N )
s n of the solution will be:
sP
(Molar weight of NaNO3 = 85)
P −P
3. = ​
in
1. 1.94 m
s

P in+N
P −P in 2. 2 m
4. = in+N
s

sP 3. 2.06 m
4. 1.85 m
34. A certain non-volatile electrolyte contains
40% carbon, 6.7% hydrogen, and 53.3% oxygen. 39. The vapour pressures of benzene and
An aqueous solution containing 5% by mass of toluene in pure states are 700 mm of Hg and
the solute boils at 100.15°C. The molecular 600 mm of Hg respectively. If equal masses of
formula of the compound is: benzene and toluene are mixed together then
(Kb = 0.51°C/m) the total vapour pressure of the solution will be
1. HCHO approximately.
2. CH3 OH 1. 620 mm of Hg 2. 640 mm of Hg
3. C2 H5 OH 3. 654 mm of Hg 4. 674 mm of Hg
4. C6 H12 O6

35. The molarity of 28% KOH solution (d = 1.2

g/ml) is:
1. 3 M
2. 6 M
3. 9 M
4. 12 M

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 Custom Practice Test - 21-Jan
Contact Number: 9667591930 / 8527521718

40. 43. The freezing point of a solution

The freezing point of 0.05 M containing 8.1 g HBr in 100 g water assuming
urea solution is different from the acid to be 90% ionised is:
Assertion (A):
that of 0.05 M sodium chloride (kf for water = 1.86 K mol-1)
solution. 1. 0.85 °C
The depression in the freezing 2. -3.53 °C
point is directly proportional to 3. 0 °C
Reason (R):
the number of species present 4. -0.35 °C
in the solution.
44. When 12.2 g of benzoic acid is dissolved in
Both (A) and (R) are true and (R) is the 100 g of water, the freezing point of the solution
1. was found to be
correct explanation of (A).
Both (A) and (R) are true but (R) is not the –0.93 °C. The number (n) of benzoic acid
2. molecules associated (assuming 100%
correct explanation of (A).
association) is:
3. (A) is true but (R) is false.
(Kf(H2O) = 1.86K kg mol–1)
4. Both (A) and (R) are false.
1. 3
2. 1
3. 2
41. Consider the following statements:
4. 5
Components of an Azeotropic binary
(A) mixture cannot be separated by fractional
45. 18 g glucose (C6H12O6) is added to 178.2 g
distillation.
water. The vapour pressure of aqueous solution
Ethanol-water azeotropic mixture contains
(B) in torr is:
approximately 95% by volume of ethanol.
1. 7.6
A solution containing components A and B 2. 752.4
follows Raoult's law if A-B attraction force 3. 76.0
(C)
remains the same as A-A and B-B attraction 4. 780.0
forces.
The correct statements are: 46. For an aqueous solution, freezing point is
1. A and B only. -0.186oC . Elevation of the boiling point of the
2. B and C only.
same solution is (Kf =1.86o mol-1 kg and Kb =
3. A, B, and C.
4. A and C only. 0.512o mol-1 kg)
1. 0.186o
42. Select the correct statements: 2. 0.0512o
A raw mango placed in a concentrated salt 3. 1.86o
(A) solution loses water via osmosis and 4. 5.12o
shrivels into a pickle.
The value of van’t Hoff factor for ethanoic 47. The vapour pressure of a solution is 2% less
(B)
acid (acetic acid) in benzene is more than 1. than the vapour pressure of pure water. The
68% nitric acid and 32% water is an molality of the solution is approximately
(C)
example of a minimum boiling azeotrope. 1. 0.92
Tanks used by scuba divers are filled with 2. 1.11
(D) 3. 1.26
air and helium to avoid bends.
1. Only B and D are correct. 4. 1.52
2. Only A, B, and D are correct.
3. Only C and D are correct.
4. Only A and D are correct.

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 Custom Practice Test - 21-Jan
Contact Number: 9667591930 / 8527521718

48. A solution is prepared by dissolving 0.6 g of

urea (molar mass = 60 g mol–1) and 1.8 g of
glucose (molar mass = 180 g mol–1) in 100 mL of
water at 27 ºC. The osmotic pressure of the
solution is:
(R = 0.08206 L atm K–1mol–1)
1. 8.2 atm
2. 2.46 atm
3. 4.92 atm
4. 1.64 atm

49. The boiling point of 1M Urea solution is

101oC. At the same temperature, the boiling
point of 1M KCl solution will be:
1. 101oC
2. 102oC
3. 202oC
4. Cannot be predicted (Insufficient Data)

50. 1.00 g of a non-electrolyte solute (molar

mass 250g mol) was dissolved in 51.2 g of
benzene. If the freezing point depression
constant, Kf of benzene is 5.12 K kg mol-1, the
freezing point of benzene will be lowered by:
1. 0.4 K
2. 0.3 K
3. 0.5 K
4. 0.2 K

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