Sri Chaitanya Educational Institutions, India
Sri Chaitanya Educational Institutions, India.,
A.P T.S KARNATAKA TAMILNADU MAHARASTRA DELHI RANCHI
A right Choice for the Real Aspirant
Central Office – Bangalore, Karnataka
Sec: ALL SENIORS(OUTGOING) Date: 10-04-2025
Time: 70Mins KCET GRAND TEST Max. Marks: 60M
==============================================================================================
KCET GT_CHEMISTRY KEYSHEET
121)4 122)2 123)3 124)3 125)4 126)4 127)2 128)2 129)3 130)4
131)1 132)4 133)4 134)1 135)2 136)2 137)4 138)2 139)3 140)1
141)1 142)4 143)2 144)2 145)3 146)4 147)1 148)1 149)4 150)2
151)3 152)3 153)4 154)4 155)4 156)3 157)2 158)2 159)2 160)1
161)2 162)3 163)3 164)1 165)3 166)3 167)3 168)1 169)3 170)2
171)1 172)3 173)2 174)2 175)4 176)1 177)4 178)4 179)3 180)3
HINTS
CHEMISTRY
121. 32g of oxygen contains 6.022 1023 molecules of oxygen
6.022 1023 16 g
16g of oxygen contains = 3.011 1023 molecules
32 g
28g of CO contains 6.022 1023 molecules
16 g
16g of CO contains 6.022 1023 = 3.4411 1023 molecules of CO
28 g
28g of N 2 contains 6.022 1023 molecules of N 2
2g of H 2 contains 6.022 1023 molecules of hydrogen.
6.022 1023 1g
1g of H 2 contains
2g
= 3.011 1023 molecules of hydrogen.
16g of oxygen has same number of molecules as in 1g of H 2 .
122.
Sl. Element % by mass Atomic Relative no.of Simplest Simplest whole
No mass moles molar ratio number ratio
1 C 93.71 12 93.71 7.809 5
= 7.809 = 1.24
12 6.29
2 H 6.29 1 6.29 6.29 4
= 6.29 =1
1 6.29
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Empirical formula is C5 H 4 .
123. Given h = 6.6 10−34 JS = 6.6 10−34 kgm2 s −1, = 2.2 10−11 m
h
=
p
h 6.6 10−34 kg m2 s −1
p= =
2.2 10−11 m
= 3 10−23 kg ms −1
124. The electronic configuration of Cl atom is 1s 2 2 s 2 3s 2 3 p5 . Unpaired electron is present
in 3p subshell.
1
n = 3, l = 1, m = 0, s =
2
125. Along the period metallic character decreases and down the group metallic character
increases in general.
Metal oxides are basic; non-metal oxides are acidic. K 2O & MgO are basic. Al2O3 is
amphoteric, B2O3 is acidic.
126. For O22− :
Total number of e − s = 18
10 − 8
Bond order = = 1.0
2
For O2− :
Total number of e − s = 17
10 − 7
Bond order = = 1.5
2
For O2 :
Total number of e − s = 16
10 − 6
Bond order = =2
2
For O2+ :
Total number of e − s = 15
10 − 5
Bond order = = 2.5
2
127. The type of hybrid orbitals of nitrogen can be decided by counting bond pairs and lone
pairs.
Number of hybrid orbitals = Number of monovalent groups bonded to the central atom +
½ (group number to which central atom belongs – Number of monovalent spices bonded
to the central atom electrical charge on the spices)
NO2+ = 2bps + 0 Lp = sp hybridisation
NO3− = 3bps + 0 Lp = sp 2 hybridisation
NH 4+ = 4bps + 0 Lp = sp3 hybridisation
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128. Number of hybrid orbitals = Number of monovalent groups bonded to the central atom +
½ (group number to which central atom belongs – Number of monovalent spices bonded
to the central atom electrical charge on the spices)
For H 3O + :
central atom is oxygen.
1
Number of hybrid orbitals = 3 + ( 6 − 3 − 1) = 3 + 1
2
3 B.P and 1 lone pair pyramidal shape.
For ClO2− :
1
Number of hybrid orbitals = 2 + ( 7 − 4 + 1) = 2 + 2
2
2 B.P and 2 lone pair angular shape.
For NH 4+ :
Central atom is nitrogen.
1
Number of hybrid orbitals = 4 + ( 7 − 4 − 1) = 4 + 0
2
4 B.P and 0 lone pair tetrahedral.
C2 H 2 is linear with ‘C’ in sp hybridization.
129. CH 4 g + 2O2 g → CO2 g + 2 H 2O(l )
( ) ( ) ( )
ng = ( n p − nr ) = 1 − 3 = −2
H 0 = U 0 + ng RT
As ng −2
H 0 U 0
130. H 0 = B.E( Reactants ) − B.E( products )
H 2( g ) + Br2( g ) → 2HBr( g )
H 0 = ( 433 + 192 ) − ( 2 364 ) kJ
= ( 625 − 728) kJ = −103kJ
131. For the reaction,
H 2S H + + HS − → (1)
H + HS −
Ka1 =
H 2S
For the reaction, HS − H + + S 2− ( 2)
H + S 2−
Ka2 = −
HS
When, equation (1) and (2) are added, their equilibrium constant for the final equation is
2
H + S 2−
which is obtained by multiplying Ka with Ka . Thus,
H 2S 1 2
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H + HS − H + S 2−
Ka1 Ka2 =
H 2S HS
−1
2
H + S 2−
Ka1 Ka2 = = Ka
H 2S 3
Ka3 = Ka1 Ka2
132. 1M H 2 SO4 and 1M HCl , both are highly acidic in nature, so, pH will be very less.
1M NaOH
NaOH ( aq ) → Na(+aq ) + OH ( aq )
0.1M 0.1M
pOH = − log10 OH
pH = − log 10−1 = 1
WKT, pH + pOH = 14
pH = 14 − pOH = 14 − 1 = 13
1M NaOH
NaOH ( aq ) → Na(+aq ) + OH ( aq )
0.1M 0.1M
pH = − log10 OH
= − log (1) = 0
WKT, pH + pOH = 14 = 14 − 0 = 14
133. G 0 = − RTlnKC
(or) G 0 = −2.303RT log10 KC
When G 0 0 means G 0 is positive.
This can be only when log10 KC is negative i.e., KC 1 .
134. Each Cr2O72− → 2Cr 3+
Cr atom is present in +6 oxidation state in Cr2O72−
Cr2O72− + 6e − → 2Cr 3+
1 mole of Cr2O72− requires 6 moles of e −
0.2 moles of Cr2O72− requires : 6 0.2 moles of e − = 1.2 moles of electrons
O O
135. C H 3 − C − C H 2 − C H 2 − C − O − H
5 4 3 2 1
O
−COOH group should be given high priority, so − C − group is provided with prefix oxo.
IUPAC name is 4 – oxopentanoic acid.
4−
136. 6 CN − + Fe 2+ → Fe ( CN )6
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4−
3 Fe ( CN )6 + 4 Fe3+ → Fe4 Fe ( CN )6
3
Pr ussian
blue
137. a) CH 3 − O − CH 3 and C2 H 5OH are functional isomers.
O
b) CH 3COOH and H − C − O − CH 3 are functional isomers.
CH 3
|
c) CH 3 − CH 2 − CH 2 − CH 3 and CH 3 − C H − CH 3 are chain isomers
OH
|
d) CH 3 − CH 2 − CH 2 − OH and CH 3 − C H − CH 3 are position isomers.
138. To prepare trans-alkene from alkyne Na in Liq.NH 3 is used. [Controlled reduction]
139.
CH 3 − CH 2 − CH 2 − Cl + AlCl3 → AlCl4− +
CH 3 − C H − C H 2
|
H
1, 2 - hydride shift
−H + CH 3 − C H − CH 3
⎯⎯ ⎯ + 20 carbocation
more stable
140. H 3C − HC = CH − CH 3
H CH3
H H
C =C C =C
CH3 CH3 H CH3
Cis - But - 2 -ene trans-But-2-ene
141. C2 H5Cl + KOH( aq ) ⎯⎯ →C2 H5OH + KCl
H
|
142. CH 3 − CH 2 − C − CH 3 minimum no of carbon atoms required is ‘4’, to show optically
|
OH
activity and to have one chiral center.
143. Carbonyl compound having − hydrogen shows aldol condensation reaction.
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144. N-ethyl N- methyl butanamine
145. CH 3CN ⎯⎯⎯⎯⎯
1.CH 3MgBr
+ → CH 3COCH 3 ⎯⎯⎯⎯
2. H 3 O
dil NaOH
→ ( CH3 )2 C = CHCOCH3
4- methyl pent-3-en-2-one
146. Aromatic amines are least soluble in water due to hydro phobic nature of phenyl group.
147. C6 H12O6 ⎯⎯
HI
→ CH 3 − CH 2 − CH 2 − CH 2 − CH 2 − CH 3
Glu cos e n −hexane
148. The glycosidic linkage present in sucrose is between C1 of - glucose and C 2 of –
fructose.
149. Vitamin K helps in clotting of blood.
O
150. Iodoform test is given by ketones with CH 3 − C − group pentan -2-one
CH 3 − C − CH 2CH 2CH 3 has CH 3 C− group it will answer Iodoform test.
O O
151. C2 H 5ONa + C2 H 5 I → C2 H 5OC2 H 5 + NaI is Williamson’s ether synthesis.
152. Electron with drawing groups increases the acidic strength of phenol while electron
donating groups decreases the acidic strength.
OH OH OH
OCH3 CH3 NO2
2
153. In S N mechanism tertiary alkylhalide shows steric hindrance due to presence of bulkyl
alkyl groups.
154. Isomeric alcohols with formula C4 H10O are four
Butan 1- ol ; 2 methyl propan -1 -ol
Butan-2-ol ; 2 methyl propan -2-ol
155. CH3 NC ⎯⎯⎯ +⎯
LiAlH 4
→CH 3 NHCH 3
H3O
20 a min e
Remaining all reactions will give primary amine.
CH3CONH 2 ⎯⎯⎯ +⎯
LiAlH 4
→CH3CH 2 NH 2
H3O
10 a min e
CH3CONH 2 ⎯⎯⎯⎯
Br2 KOH
→ CH 3 NH 2
10 a min e
CH 3CN ⎯⎯⎯
LiAlH 4
⎯→CH 3CH 2 NH 2
10 a min e
156. A) CH CH ⎯⎯⎯→
HgSO4
H SO
CH 3CHO
2 4
B) CH3CH 2OH ⎯⎯⎯
→CH3CHO PCC
C) CH 3CN ⎯⎯⎯⎯⎯ → CH 3CHO
SnCl2 HCl
+
H3 O
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157. RCOOH ⎯⎯⎯
NH3
→ RCOONH 4 ⎯⎯ → RCONH 2 ⎯⎯⎯
P2O5
→ R − CN + H 2O
( A) ( B) (C )
Alkyl
nitrile
158. Tri iodo methane act as antiseptic
159. CH3CN ⎯⎯⎯⎯ SnCl2HCl
→CH3CH = NH ⎯⎯⎯ H2O
→CH3CHO
160. In first option oxidation state of aluminium is +3, so it is the correct option.
mass
161. density =
volume
mass = 1.02 gmL−1 1000mL = 1020 g
Mass of 2.05 mole of acetic acid = 2.05 60 = 123
Mass of water = (1020 − 123) g = 879 g = 0.897kg
2.05mole
molality = = 2.28mole kg −1
0.897kg
3 45
162. No. of mole of urea nB = = 0.05 ; No. of mole of water nA = = 2.5
60 18
p 0.05
= xB = = 0.0196 = 0.02
p 0
2.5 + 0.05
163. Elevation in boiling point is directly proportional to ‘i.c’
For urea : NH 2CONH 2 → NO dissociation ; i.c = 0.01 M urea
Concentration of ions = 0.01 M
For KNO3 → K + + NO3− i = 2 & i − c = 2 0.01 = 0.02M
For Na2 SO4 → 2 Na + + SO4−2 i = 3 & i.c = 3 0.01 = 0.03M
C6 H12O6 → No dissociation ; i = 1 & i.c = 0.015M
Highest i.c is for Na2 SO4
Hence 0.01M Na2 SO4 shows the highest B.P.
164. K H = 1 105 atm
xN2 = 0.8
Partial pressure of N2 .PN2 = Ptotal xN2 = 5 0.8 = 4atm
W.K.T
PN2 = K H xN2
4 = 105 xN2
xN2 = 4 10−5
nN 2
xN 2 =
nN 2 + nH 2O
nN2
4 10−5 =
10
nN2 = 4 10−4 moles
165. Higher the concentration of Zn +2 . higher is the electrode potential.
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Hence Q > R > S > P.
166. MnO4−1 + 5e− → Mn +2
To convert one mole of MnO4−1 to Mn +2 total 5 mole of e − are needed.
167. Solvation of ions: Greater the solvation of ions of an electrolyte lesser will be the
electrical conductivity of the solution.
168. Equivalent volume of hydrogen = 11.2 L at S .T .P
5.6
No of equivalent of hydrogen = = 0.5
11.2
Mass of silver = No. of equivalent equivalent mass
= 0.5 108 54g
1
169. According to the above expression, K P ; K Z ; K T ; but K
Ea
1
If Ea decreases, then e Ea RT also decreases and E RT increases. Thus K also
e a
increases.
170. For the given reaction rate can be expressed as
1 d SO2 d O2 1d
Rate = − =− =+ SO3
2 dt dt 2 dt
r ( SO3 ) r ( O2 )
r ( rate ) = =−
2 1
r ( SO3 ) = 2 r ( O2 )
(
= 2 2 10−4 )
rate = 4 10−4 mol L−1S −1
171. Lesser the energy, more is the stability. So reactant is more stable.
172. Because a catalyst can change a reaction path and not the relative energy difference
between reactant and product.
1 d H2 1 d NH 3
173. − =+
3 dt 2 dt
174. Chromium has a higher melting point compared to manganese. It is because chromium
has abnormal electronic configuration and higher effective nuclear charge which leads
to stronger metallic bonding and higher melting temperature.
175. Fluorine forms single bond, whereas oxygen forms double bond. Due to steric hindrance,
7 fluorine atoms cannot be accommodated around 1 Mn atom. Whereas in Mn2O7 , 7
oxygen atoms are placed around 2 Mn atoms comfortably.
176. Ce +4 is a good oxidizing agent. Ce +4 readily gains an electron to from stable Ce +3 with
one half filled 4f orbital. Energy of Ce +4 is higher that makes it less stable table Ce +3 . So,
Ce +4 gets reduced to Ce +3 .
177. In CrO4−2 Cr +6 ( n = 0) diamagnetic
In Cr2O7−2 Cr +6 ( n = 0) diamagnetic
In MnO4−1 Mn+7 ( n = 0) diamagnetic
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In MnO4−2 Mn+6 ( n = 1) paramagnetic
178.
t2g g Unpaired electron
d 4 ( low spin ) 2
d 7 ( high spin ) 3
d 9 ( high spin ) 1
d 6 ( low spin ) 0
179. As the strength of ligand increases, 0 increases and of absorbed radiation decreases.
−2
180. In Ni ( CN )4 due to dsp 2 hybridization it is square planar and it has no unpaired
electron hence diamagnetic.
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