13-01-2025

1201CJA101021240081 JA

PART-1 : PHYSICS

SECTION-I

1) With rise in temperature, the Young's modulus of elasticity

(A) changes erratically

(B) decreases
(C) increases
(D) remains unchanged

2) If R is the radius of the earth and the acceleration due to gravity on the surface of earth is g = π2
m/s2, then the length of the second's pendulum at a height h = 2R from the surface of earth will be :

(A)

(B)

(C)

(D)

3) In the given circuit if the power rating of Zener diode is 10 mW, the value of series resistance Rs

to regulate the input unregulated supply is :

(A) 5kΩ
(B) 10Ω
(C) 1kΩ
(D) 10kΩ

4) The reading in the ideal voltmeter (V) shown in the given circuit diagram is :

(A) 5V
(B) 10V
(C) 0 V
(D) 3V

5) Two identical capacitors have same capacitance C. One of them is charged to the potential V and
other to the potential 2V. The negative ends of both are connected together. When the positive ends
are also joined together, the decrease in energy of the combined system is :

(A)

(B) 2 CV2

(C)

(D)

6) Two moles a monoatomic gas is mixed with six moles of a diatomic gas. The molar specific heat of
the mixture at constant volume is :

(A)

(B)

(C)

(D)

7) A ball of mass 0.5 kg is attached to a string of length 50 cm. The ball is rotated on a horizontal
circular path about its vertical axis. The maximum tension that the string can bear is 400 N. The
maximum possible value of angular velocity of the ball in rad/s is :

(A) 1600
(B) 40
(C) 1000
(D) 20

8) A parallel plate capacitor has a capacitance C = 200 pF. It is connected to 230 V ac supply with
an angular frequency 300 rad/s. The rms value of conduction current in the circuit and
displacement current in the capacitor respectively are :

(A) 1.38 μA and 1.38 μA

(B) 14.3 μA and 143 μA
(C) 13.8 μA and 138 μA
(D) 13.8 μA and 13.8 μA

9) The pressure and volume of an ideal gas are related as PV3/2 = K (Constant). The work done when
the gas is taken from state A (P1, V1, T1) to state B (P2, V2, T2) is :
(A) 2(P1V1 – P2V2)
(B) 2(P2V2 – P1V1)
(C)
(D)

10) A galvanometer has a resistance of 50 Ω and it allows maximum current of 5 mA. It can be
converted into voltmeter to measure upto 100 V by connecting in series a resistor of resistance

(A) 5975 Ω
(B) 20050 Ω
(C) 19950 Ω
(D) 19500 Ω

11) The de Broglie wavelengths of a proton and an α-particle are λ and 2 λ respectively. The ratio of
the velocities of proton and α-particle will be :

(A) 1 : 8
(B) 1 : 2
(C) 4 : 1
(D) 8 : 1

12) 10 divisions on the main scale of a Vernier calliper coincide with 11 divisions on the Vernier
scale. If each division on the main scale is of 5 units, the least count of the instrument is :

(A)

(B)

(C)

(D)

13) In series LCR circuit, the capacitance is changed from C to 4C. To keep the resonance frequency
unchanged, the new inductance should be :

(A)
reduced by
(B) increased by 2L

(C)
reduced by
(D) increased to 4L

14) The radius (r), length (ℓ) and resistance (R) of a metal wire was measured in the laboratory as
r = (0.35 ± 0.05) cm
R = (100 ± 10) ohm
ℓ = (15 ± 0.2) cm
The percentage error in resistivity of the material of the wire is :

(A) 25.6%
(B) 39.9%
(C) 37.3%
(D) 35.6%

15) The dimensional formula of angular impulse is :

(A) [M L–2 T–1]

(B) [M L2 T–2]
(C) [M L T–1]
(D) [M L2 T–1]

16) A simple pendulum of length 1 m has a wooden bob of mass 1 kg. It is struck by a bullet of mass
10–2 kg moving with a speed of 2 × 102 ms–1. The bullet gets embedded into the bob. The height to
which the bob rises before swinging back is. (use g = 10 m/s2)

(A) 0.30 m
(B) 0.20 m
(C) 0.35 m
(D) 0.40 m

17) A particle moving in a circle of radius R with uniform speed takes time T to complete one
revolution. If this particle is projected with the same speed at an angle θ to the horizontal, the
maximum height attained by it is equal to 4R. The angle of projection θ is then given by :

(A)

(B)

(C)

(D)

18) Consider a block and trolley system as shown in figure. If the coefficient of kinetic friction
between the trolley and the surface is 0.04, the acceleration of the system in ms–2 is :
(Consider that the string is massless and unstretchable and the pulley is also massless and
frictionless) :

(A) 3
(B) 4
(C) 2
(D) 1.2

19) The minimum energy required by a hydrogen atom in ground state to emit radiation in Balmer
series is nearly :

(A) 1.5 eV
(B) 13.6 eV
(C) 1.9 eV
(D) 12.1 eV

20) A monochromatic light of wavelength 6000Å is incident on the single slit of width 0.01 mm. If the
diffraction pattern is formed at the focus of the convex lens of focal length 20 cm, the linear width of
the central maximum is :

(A) 60 mm
(B) 24 mm
(C) 120 mm
(D) 12 mm

SECTION-II

1) The radius of a nucleus of mass number 64 is 4.8 fermi. Then the mass number of another nucleus

having radius of 4 fermi is , where x is _____.

2) The identical spheres each of mass 2M are placed at the corners of a right angled triangle with
mutually perpendicular sides equal to 4 m each. Taking point of intersection of these two sides as

origin, the magnitude of position vector of the centre of mass of the system is , where the value
of x is ________

3) A tuning fork resonates with a sonometer wire of length 1 m stretched with a tension of 6 N.
When the tension in the wire is changed to 54 N, the same tuning fork produces 12 beats per second
with it. The frequency of the tuning fork is _______ Hz.
4) The current in a conductor is expressed as I = 3t2 + 4t3, where I is in Ampere and t is in second.
The amount of electric charge that flows through a section of the conductor during t = 1s to t = 2s is
_______ C.

5) A particle is moving in one dimension (along x axis) under the action of a variable force. It's initial
position was 16 m right of origin. The variation of its position (x) with time (t) is given as x = –3t3 +
18t2 + 16t, where x is in m and t is in s. The velocity of the particle when its acceleration becomes
zero is _________ m/s.

PART-2 : CHEMISTRY

SECTION-I

1) If one strand of a DNA has the sequence ATGCTTCA, sequence of the bases in complementary
strand is:

(A) CATTAGCT
(B) TACGAAGT
(C) GTACTTAC
(D) ATGCGACT

2) Given below are two statements : one is labelled as Assertion (A) and the other is labelled as
Reason (R). Assertion (A) : Haloalkanes react with KCN to form alkyl cyanides as a main
product while with AgCN form isocyanide as the main product.
Reason (R) : KCN and AgCN both are highly ionic compounds.
In the light of the above statement, choose the most appropriate answer from the options given
below:

(A) (A) is correct but (R) is not correct

(B) Both (A) and (R) are correct but (R) is not the correct explanation of (A)
(C) (A) is not correct but (R) is correct
(D) Both (A) and (R) are correct and (R) is the correct explanation of (A)

3) In acidic medium, K2Cr2O7 shows oxidising action as represented in the half reaction

X, Y, Z and A are respectively are:

(A) 8, 6, 4 and Cr2O3

(B) 14, 7, 6 and Cr3+
(C) 8, 4, 6 and Cr2O3
(D) 14, 6, 7 and Cr3+

4) Which of the following reactions are disproportionation reactions?

(A) Cu+ → Cu2+ + Cu
(B)
(C) 2KMnO4 → K2MnO4 + MnO2 + O2
(D)
Choose the correct answer from the options given below:

(A) (A), (B)

(B) (B), (C), (D)
(C) (A), (B), (C)
(D) (A), (D)

5) In case of isoelectronic species the size of F–, Ne and Na+ is affected by:

(A) Principal quantum number (n)

(B) None of the factors because their size is the same
(C) Electron-electron interaction in the outer orbitals
(D) Nuclear charge (z)

6) According to the wave-particle duality of matter by de-Broglie, which of the following graph plot
presents most appropriate relationship between wavelength of electron (λ) and momentum of
electron (p)?

(A)

(B)

(C)

(D)

7) Given below are two statements:

tatement (I): A solution of [Ni(H2O)6]2+ is green in colour.
Statement (II): A solution of [Ni(CN)4]2– is colourless.
In the light of the above statements, choose the most appropriate answer from the options given
below:

(A) Both Statement I and Statement II are incorrect

(B) Both Statement I and Statement II are correct
(C) Statement I is incorrect but Statement II is correct
(D) Statement I is correct but Statement II is incorrect

8) Given below are two statements: one is labelled as Assertion (A) and the other is labelled as
Reason (R).
Assertion (A) : PH3 has lower boiling point than NH3.
Reason (R) : In liquid state NH3 molecules are associated through vander waal’s forces, but PH3
molecules are associated through hydrogen bonding.
In the light of the above statements, choose the most appropriate answer from the options given
below:

(A) Both (A) and (R) are correct and (R) is not the correct explanation of (A)
(B) (A) is not correct but (R) is correct
(C) Both (A) and (R) are correct but (R) is the correct explanation of (A)
(D) (A) is correct but (R) is not correct

9) Identify A and B in the following sequence of reaction

(A)

(B)

(C)

(D)

10) Given below are two statements:

Statement (I) : Aminobenzene and aniline are same organic compounds.
Statement (II) : Aminobenzene and aniline are different organic compounds.
In the light of the above statements, choose the most appropriate answer from the options given
below:

(A) Both Statement I and Statement II are correct

(B) Statement I is correct but Statement II is incorrect
(C) Statement I is incorrect but Statement II is correct
(D) Both Statement I and Statement II are incorrect

11) Which of the following complex is homoleptic?

2–
(A) [Ni(CN)4]
(B) [Ni(NH3)2Cl2]
+
(C) [Fe(NH3)4Cl2]
+
(D) [Co(NH3)4Cl2]

12) Which of the following compound will most easily be attacked by an electrophile?

(A)

(B)

(C)

(D)

13) Ionic reactions with organic compounds proceed through:

(A) Homolytic bond cleavage
(B) Heterolytic bond cleavage
(C) Free radical formation
(D) Primary free radical
(E) Secondary free radical
Choose the correct answer from the options given below:

(A) (A) only

(B) (C) only
(C) (B) only
(D) (D) and (E) only

14) Arrange the bonds in order of increasing ionic character in the molecules. LiF, K2O, N2, SO2 and
ClF3.

(A) ClF3 < N2 < SO2 < K2O < LiF

(B) LiF < K2O < ClF3 < SO2 < N2
(C) N2 < SO2 < ClF3 < K2O < LiF
(D) N2 < ClF3 < SO2 < K2O < LiF

15) We have three aqueous solutions of NaCl labelled as ‘A’, ‘B’ and ‘C’ with concentration 0.1 M,
0.01M & 0.001 M, respectively. The value of vant’ Haff factor (i) for these solutions will be in the
order.

(A) iA < iB < iC

(B) iA < iC < iB
(C) iA = iB = iC
(D) iA > iB > iC

16) In Kjeldahl’s method for estimation of nitrogen, CuSO4 acts as :

(A) Reducing agent

(B) Catalytic agent
(C) Hydrolysis agent
(D) Oxidising agent

17) Given below are two statements :

Statement (I) : Potassium hydrogen phthalate is a primary standard for standardisation of sodium
hydroxide solution.
Statement (II) : In this titration phenolphthalein can be used as indicator.
In the light of the above statements, choose the most appropriate answer from the options given
below:

(A) Both Statement I and Statement II are correct

(B) Statement I is correct but Statement II is incorrect
(C) Statement I is incorrect but Statement II is correct
(D) Both Statement I and Statement II are incorrect

18) Match List – I with List –II.

List – I (Reactions) List – II (Reagents)

(A) (I) CH3MgBr, H2O

Zn(Hg) and conc.

(B) C6H5COC6H5 → C6H5CH2C6H5 (II)
HCl
+
(C) C6H5CHO → C6H5CH(OH)CH3 (III) NaBH4 , H

(D) (IV) DIBAL-H, H2O

Choose the correct answer from options given below :

(A) A-(III), (B)-(IV), (C)-(I), (D)-(II)
(B) A-(IV), (B)-(II), (C)-(I), (D)-(III)
(C) A-(IV), (B)-(II), (C)-(III), (D)-(I)
(D) A-(III), (B)-(IV), (C)-(II), (D)-(I)

19) Choose the correct option for free expansion of an ideal gas under adiabatic condition from the
following :

(A) q = 0, ΔT ≠ 0, w = 0
(B) q = 0, ΔT < 0, w ≠ 0
(C) q ≠ 0, ΔT = 0, w = 0
(D) q = 0, ΔT = 0, w = 0

20) Given below are two statements:

Statement (I) : The NH2 group in Aniline is ortho and para directing and a powerful activating
group.
Statement (II) : Aniline does not undergo Friedel-Craft’s reaction (alkylation and acylation).
In the light of the above statements, choose the most appropriate answer from the options given
below :

(A) Both Statement I and Statement II are correct

(B) Both Statement I and Statement II are incorrect
(C) Statement I is incorrect but Statement II is correct
(D) Statement I is correct but Statement II is incorrect

SECTION-II

1) Number of optical isomers possible for 2 – chlorobutane ………

2) The ratio of in a piece of wood is part that of atmosphere. If half life of 14C is 5730 years,
the age of wood sample is ….. years.

3) Total number of deactivating groups in aromatic electrophilic substitution reaction among the
following is

4) Among the following oxide of p - block elements, number of oxides having amphoteric nature is
Cl2O7, CO, PbO2, N2O, NO, Al2O3, SiO2, N2O5, SnO2

5) Ka for CH3COOH is 1.8 × 10–5 and Kb for NH4OH is 1.8 × 10–5. The pH of ammonium acetate
solution will be
 PART-3 : MATHEMATICS

SECTION-I

1) A bag contains 8 balls, whose colours are either white or black. 4 balls are drawn at random
without replacement and it was found that 2 balls are white and other 2 balls are black. The
probability that the bag contains equal number of white and black balls is :

(A)

(B)

(C)

(D)

2) The value of the integral equals :

(A)

(B)

(C)

(D)

3) If , , C = ABAT and X = ATC2A, then det X is equal to :

(A) 243
(B) 729
(C) 27
(D) 891

4) If tan A = and
then A + B is equal to:

(A) C
(B)
(C)
(D)

5) If n is the number of ways five different employees can sit into four indistinguishable offices
where any office may have any number of persons including zero, then n is equal to:

(A) 47
(B) 53
(C) 51
(D) 43

6) Let S = and . Let z1, z2 ∈ S be such that

and . Then equals :

(A) 1
(B) 4
(C) 3
(D) 2

7) Let the median and the mean deviation about the median of 7 observation 170, 125, 230, 190,

210, a, b be 170 and respectively. Then the mean deviation about the mean of these 7
observations is:

(A) 31
(B) 28
(C) 30
(D) 32

8) Let and Then is equal to

(A) –12
(B) –10
(C) –13
(D) –15

9) Let . Then the number of elements in S is :

(A) 4
(B) 0
(C) 2
(D) 1

10) The area enclosed by the curves xy + 4y = 16 and x + y = 6 is equal to :

(A) 28 – 30 loge2
(B) 30 – 28 loge2
(C) 30 – 32 loge2
(D) 32 – 30 loge2

11) Let f : R → R and g : R → R be defined as

and

.
Then, gof : R → R is :

(A) one-one but not onto

(B) neither one-one nor onto
(C) onto but not one-one
(D) both one-one and onto

12) If the system of equations

2x + 3y – z = 5
x + αy + 3z = –4
3x – y + βz = 7
has infinitely many solutions, then 13 αβ is equal to

(A) 1110
(B) 1120
(C) 1210
(D) 1220

13) For 0 < θ < π/2, if the eccentricity of the hyperbola x2 – y2cosec2θ = 5 is times eccentricity of
the ellipse x2 cosec2θ + y2 = 5, then the value of θ is :

(A)

(B)

(C)

(D)

14) Let y = y(x) be the solution of the differential equation = 2x (x + y)3 – x (x + y) – 1, y(0) = 1.

Then, equals :

(A)
(B)

(C)

(D)

15) Let f : R → R be defined as

If f is continuous everywhere in R and m is the number of points where f is NOT differential then m
+ a + b + c equals :

(A) 1
(B) 4
(C) 3
(D) 2

16) Let = 1, a > b be an ellipse, whose eccentricity is and the length of the latus rectum

is . Then the square of the eccentricity of is :

(A) 3

(B)

(C)

(D)

17) Let 3, a, b, c be in A.P. and 3, a – 1, b + 1, c + 9 be in G.P. Then, the arithmetic mean of a, b and
c is :

(A) –4
(B) –1
(C) 13
(D) 11

18) Let C : x2 + y2 = 4 and C' : x2 + y2 – 4λx + 9 = 0 be two circles. If the set of all values of λ so that
the circles C and C' intersect at two distinct points, is R– [a, b], then the point (8a + 12, 16b – 20)
lies on the curve :

(A) x2 + 2y2 – 5x + 6y = 3
(B) 5x2 – y = – 11
(C) x2 – 4y2 = 7
(D) 6x2 + y2 = 42

19) If and y = 9x2 f(x), then y is strictly increasing in :

(A)

(B)

(C)

(D)

20) If the shortest distance between the lines and is 1,

then the sum of all possible values of λ is :

(A) 0
(B)
(C)
(D)

SECTION-II

1) If the coefficient of x30 in the expansion of is α, then |α|

equals ________.

2) Let the line pass through the point of the intersection P (in the first quadrant) of
the circle x + y = 3 and the parabola x2 = 2y. Let the line L touch two circles C1 and C2 of equal
2 2

radius . If the centres Q1 and Q2 of the circles C1 and C2 lie on the y-axis, then the square of the
area of the triangle PQ1Q2 is equal to ___________.

3) Let and . Let in , |z – 3 +

2i| be maximum and minimum at z1 and z2 respectively. If , where α, β are
integers, then α + β equals ________.

4) If , where α, β are integers, then α2 + β2

equals ___________.
5) Let A = {1, 2, 3, .... 20}. Let R1 and R2 two relation on A such that
R1 = {(a, b) : b is divisible by a},
R2 = {(a, b) : a is an integral multiple of b}.
Then, number of elements in R1 – R2 is equal to ________.
 ANSWER KEYS

PART-1 : PHYSICS

SECTION-I

Q. 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20
A. B B C C A A B D A C D D C B D B A C D B

SECTION-II

Q. 21 22 23 24 25
A. 27 3 6 22 52

PART-2 : CHEMISTRY

SECTION-I

Q. 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45
A. B A D A D A B D B B A D C C A B A B D A

SECTION-II

Q. 46 47 48 49 50
A. 2 17190 2 3 7

PART-3 : MATHEMATICS

SECTION-I

Q. 51 52 53 54 55 56 57 58 59 60 61 62 63 64 65 66 67 68 69 70
A. B C B A C D C A C C B B C D D C D D B B

SECTION-II

Q. 71 72 73 74 75
A. 678 72 36 8 46
 SOLUTIONS

PART-1 : PHYSICS

1) Conceptual questions

2) g' =

T = 2π
Since the time period of second pendulum is 2 sec.
T = 2 sec

2 = 2π

3)
Pd across Rs
V1 = 8 – 5 = 3V
Current through the load resistor

I= = 5mA
Maximum current through Zener diode

Izmax. = = 2mA
And minimum current through Zener diode
Iz min. = 0
∴ Is max. = 5 + 2 = 7mA

And Rs min =
Similarly
Is min. = 5mA

And Rs max. = = kΩ

∴ < Rs < kΩ

4) i =
I = 25A
V = E – ir
= 5 – 0.2 × 25
=0

5) VC =

VC =
Loss of energy

6) CV =

7) T =
400 = 0.5ω2 × 0.5
ω = 40 rad/s.

8) I = = 230 × 300 × 200 × 10–12 = 13.8 μA

9)

For PVx = constant

If work done by gas is asked then

W=

Here x =

∴W=
= 2(P1V1 – P2V2) ….. Option (1) is correct
If work done by external is asked then
W = –2(P1V1 – P2V2) ….. Option (2) is correct
10)
= 20000 – 50
= 19950Ω

11) λ = ⇒v=

=4×2=8

12) 10 MSD = 11 VSD

1 VSD = MSD
LC = 1MSD – 1VSD

= 1 MSD MSD

= units

13) ω’ = ω

∴ L’C’ = LC
L’(4C) = LC

L’ =

∴ Inductance must be decreased by

14) ρ = R

= 39.9%

15)

Angular impulse = change in angular momentum.

[Angular impulse] = [Angular momentum] = [mvr]
= [M L2 T–1]

16)
mu = (M + m)V
10–2 × 2 × 102 ≅ 1 × V
V ≅ 2m/s

h= = 0.2 m

17) =V

Maximum height H =

4R =

sinθ =

θ=

18) fk = μN = 0.04 × 20g = 8 Newton

a= = 2m/s2

19) Transition from n = 1 to n = 3

ΔE = 12.1eV

20) Linear width

W=
= 2.4 × 10–2 = 24 mm

21)

R = R0A1/3
R3 ∝ A
=

= 27

22)

Position vector

x=3

23) f =

f1 = f2 =

f2 – f1 = 12
f1 = 6HZ

24) q =

q=
q = 22C

25) x = 3t3 + 18t2 + 16t

v = –9t2 + 36 + 16
a = – 18t + 36
a = 0 at t = 2s
v = –9(2)2 + 36 × 2 + 16
 v = 52 m/s

PART-2 : CHEMISTRY

26) Adenine base pairs with thymine with 2 hydrogen bonds and cytosine base pairs with

guanine with 3 hydrogen bonds.

27)
AgCN is mainly covalent in nature and nitrogen is available for attack, so alkyl isocyanide is
formed as main product.

28) The balanced reaction is,

X = 14
Y=6
A=7

29)

When a particular oxidation state becomes less stable relative to other oxidation state, one
lower, one higher, it is said to undergo disproportionation.
Cu+ → Cu2+ + Cu

30) In F–, Ne, Na+ all have 1s2, 2s2, 2p6 configuration. They have different size due to the
difference in nuclear charge.

31)
⇒ λp = h (constant)
So, the plot is a rectangular hyperbola.
32)

[Ni(H2O)6]+2 → Green colour solution due to d-d transition.

[Ni(CN)4]–2 → is diamagnetic and it is colourless.

33) Unlike NH3, PH3 molecules are not associated through hydrogen bonding in liquid state.
That is why the boiling point of PH3 is lower than NH3.

34)

35) Aniline is also known as amino benzene.

36) In Homoleptic complex all the ligand attached with the central atom should be the same.
Hence [Ni(CN)4]2– is a homoleptic complex.

37) Higher the electron density in the benzene ring more easily it will be attacked by an
electrophile. Phenol has the highest electron density amongst all the given compound.

38) Heterolytic cleavage of Bond lead to formation of ions.

39)

Increasing order of ionic character

N2 < SO2 < ClF3 < K2O < LiF
Ionic character depends upon difference of electronegativity (bond polarity).

40) Question is Asking About :

Order of van't haff factor (i) for solution on the basis of ostwald's dilution law.

Concept :
Ostwald's dilution law states the degree of dissociation of weak electrolyte is inversely
proportional to the square root of its concentration. This means that as the dilution of a

substance increases, the degree of ionization increases (α)

Vant haff factor i :→ Number of solute particles dissociation increases, i increases for strong
electrolytes and dissociation increases (α), i increases and also dilution increases or
concentration decreases, α increases and i also increases.

Solution / Explanation :
CA = 0.1 M, CB = .01 M, CC = .001 M
Concentration min for C so i values is max for C
Order is iA < iB < iC

41) Kjeldahl’s method is used for estimation of Nitrogen where CuSO4 acts as a catalyst.

42)

Statement (I) : Potassium hydrogen phthalate is a primary standard for standardisation of

sodium hydroxide solution as it is economical and its concentration does not changes with
time.
Phenophthalin can acts as indicator in acid base titration as it shows colour in pH range 8.3 to
10.1

43)

44) During free expansion of an ideal gas under adiabatic condition q = 0, ΔT = 0, w = 0.

45)

The NH2 group in Aniline is ortho and para directing and a powerful activating group as NH2
has strong +M effect.
Aniline does not undergo Friedel-Craft’s reaction (alkylation and acylation) as Aniline will form
complex with AlCl3 which will deactivate the benzene ring.

46)
There is one chiral centre present in given compound.
So, Total optical isomers = 2

47)
As per the question,

So,
 t = 3 × t1/2 = 17190 years

48)

49)

Acidic oxide: Cl2O7, SiO2, N2O5

Neutral oxide: CO, NO, N2O
Amphoteric oxide: Al2O3 , SnO2 , PbO2

50)
pKa = pKb

PART-3 : MATHEMATICS

51) P(4W4B/2W2B)

52)

Let then
Let tant = y then sec2t dt = dy

Put

53)

T 2
Now C = ABA ⇒ det(C) = (dct (A)) x det(B)

Now |X| = |ATC2A|

= |AT| |C|2 |A|
= |A|2 |C|2
= 9 × 81
= 729

54)

Finding tan (A + B) we get

⇒ tan (A + B) =

⇒ tan (A + B) =
A+B=C

55) Total ways to partition 5 into 4 parts are :

5, 0, 0, 0 ⇒ 1 way

4, 1, 0, 0 ⇒ 5 ways

3, 2, 0, 0 ⇒ ways

ways

ways

ways
Total ⇒ 1 + 5 + 10 + 15 + 10 + 10 = 51 ways

56)

Let Z = x + iy
Then (x – 1)2 + y2 = 1 ……(1)

&
……(2)
Solving (1) & (2) we get

Either x = 1 or ……(3)
On solving (3) with (2) we get
For x = 1 ⇒ y = 1 ⇒ Z2 = 1 + i & for

Now

=2

57)

Median = 170 ⇒ 125, a, b, 170, 190, 210, 230

Mean deviation about
Median =

⇒ a + b = 300

Mean =
=175
Mean deviation

About mean =
= 30

58)

59)

Let

t2 – 10t + 1 = 0

x = 2 or x = –2
Number of solutions = 2

60) xy + 4y = 16, x+y=6

y(x + 4) = 16 …..(1), x + y = 6 …..(2)
On solving, (1) & (2)
We get x = 4, x = –2
Area =

61)

Graph of g(f(x))
g(f(x)) ⇒ Many one into

62) Using family of planes

2x + 3y – z – 5 = k1 (x + αy + 3z + 4) + k2 (3x – y + βz – 7)
2 = k1 + 3k2, 3 = k1α – k2, –1 = 3k1 + βk2, –5 = 4k1 – 7k2
On solving we get

13αβ = 13 (–70)
= 1120

63)
64)

Let

65)

At x = 1, f(x) is continuous therefore,

f(1–) = f(1) = f(1+)
f(1) = 3 + c ….(1)

f(1+) = 2(1 + h) + 1

f(1+) = 3 + 2h = 3 ….(2)
from (1) & (2)
c = 0 at x = 0, f(x) is continuous therefore,
f(0–) = f(0) = f(0+) ….(3)
+
f(0) = f(0 ) = 2 ….(4)
–
f(0 ) has to be equal to 2

for limit to exist a – b = 0 and limit is 2b ….(5)

from (3), (4) & (5)
a=b=1
checking differentiability at x = 0
LHD :

RHD :
Function is differentiable at every point in its domain
∴m=0
m+a+b+c=0+1+1+0=2

66)

67) 3, a, b, c → A.P ⇒ 3, 3 + d, 3 + 2d, 3 + 3d

3, a – 1,b + 1, c + 9 → G.P ⇒ 3, 2 + d, 4 + 2d, 12 + 3d
a=3+d (2 + d)2 = 3(4 + 2d)
b = 3 + 2d d = 4, –2
c = 3 + 3d
If d = 4 G.P. ⇒ 3, 6, 12, 24
a=7
b = 11
c = 15

68) x2 + y2 = 4
C (0, 0) r1 = 2
C' (2λ, 0)
|r1 – r2| < CC' < |r1 + r2|

True λ∈ R .....(1)

and
 .....(2)
from (1) and (2)

as per question and

∴ required point is (–1, 6) with satisfies option (4)

69) .....(1)

Substitute

.....(2)
On solving (1) and (2)

y = 9x2f(x)
y = 5x4 – 2x2 – 4 .....(3)

for strictly increasing

4x(5x2 – 1) > 0

70) Passing points of lines L1 & L2 are

71) Coeff of x30 in

Coeff. of x36 in
General term

Case-I : (Taking r3 = 8)

Case-II : (Taking r3 = 7)

Case-III : (Taking r3 = 6)
Coeff. = 7 + (15 × 21) + (15 × 35) + (35) – (6 × 8) – (20 × 7 × 8) – (6 × 21 × 8) + (15 × 28) +
(7 × 28)
= –678 = α
|α| = 678

72) x2 + y2 = 3 and x2 = 2y
y2 + 2y – 3 = 0 ⇒ (y + 3) (y – 1) = 0
y = – 3 or y = 1
y = 1, ⇒
p lies on the line

α=3
For circle C1
Q1 lies on y-axis
Let Q1 (0, a) coordinates
(Given
Line L act as tangent
Apply P = r (condition of tangency)

⇒ |α – 3| = 6
α – 3 = 6 or α – 3 = –6
⇒α=9 α = –3
73)
Clearly for the shaded region z1 is the intersection of the circle and the line passing through P
(L1) and z2 is intersection of line L1 & L2
Circle : (x + 2)2 + (y – 3)2 =1
L1 : x + y – 1 = 0
L2 : x – y + 4 = 0
On solving circle & L1 we get

On solving L1 and z2 is intersection of line L1 & L2 we get

So α = 31
β=5
α + β = 36

74) .....(1)
Apply king

.....(2)
Adding (1) & (2)
sin x = t

α=2
β=2

75) n(R1) = 20 + 10 + 6 + 5 + 4 + 3 + 2 + 2 + 2

n(R1) = 66

= 66 – 20
R1 – R2 = 46 Pair