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Kinetics WS03a-more differential rate law questions

The document contains a series of questions related to differential rate laws for various chemical reactions, requiring the estimation of reaction orders and rate constants based on experimental data. Each question presents specific reaction scenarios with given concentrations and initial rates, asking for derivation of rate laws and calculations of rates under certain conditions. The questions cover multiple reactions, including those involving H2O2, F2, and S2O8, among others.

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45 views2 pages

Kinetics WS03a-more differential rate law questions

The document contains a series of questions related to differential rate laws for various chemical reactions, requiring the estimation of reaction orders and rate constants based on experimental data. Each question presents specific reaction scenarios with given concentrations and initial rates, asking for derivation of rate laws and calculations of rates under certain conditions. The questions cover multiple reactions, including those involving H2O2, F2, and S2O8, among others.

Uploaded by

vrittee.rao
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© © All Rights Reserved
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ANUE Kinetics Worksheet 03: More Differential Rate Law Questions

Q1. Estimate the orders and rate constant k from the results observed for the reaction? What is the rate
when [H2O2] = [I-] = [H+] = 1.0 M?

H2O2 + 3 I- + 2 H+ ® I3- + 2 H2O

Experiment [H2O2] [I-] [H+] Initial rate M s-1


1 0.010 0.010 0.0050 1.15e-6
2 0.020 0.010 0.0050 2.30e-6
3 0.010 0.020 0.0050 2.30e-6
4 0.010 0.010 0.0100 1.15e-6

Q2. From the following reaction rates observed in 4 experiments, derive the rate law for the reaction
A + B + C ® products
where reaction rates are measured as soon as the reactants are mixed.

Expt 1 2 3 4
[A]o 0.100 0.200 0.200 0.100
[B]o 0.100 0.100 0.300 0.100
[C]o 0.100 0.100 0.100 0.400
rate 0.100 0.800 7.200 0.400

Q3. For the following reaction, determine the rate law, including the value of k.

F2 (g) + 2ClO2 (g) → 2FClO2 (g)

Rate Data for the Reaction between F2 and ClO2


Initial concentration [ClO2] o
Initial concentration [F2]o (M) Initial rate (M/s)
(M)
-3
0.10 0.010 1.2 x 10
-3
0.10 0.040 4.8 x 10
-3
0.20 0.010 2.4 x 10

Q4.

Run Initial Initial Initial


# [A] [B] Rate
([A]0) ([B]0) (v0)
-2
1 1.00 M 1.00 M 1.25 x 10 M/s

-2
2 1.00 M 2.00 M 2.5 x 10 M/s
-2
3 2.00 M 2.00 M 2.5 x 10 M/s

For the above data,


a. What is the order with respect to A?
b. What is the order with respect to B?
c. What is the overall order of the reaction?
Q5.

-3 -3 Initial Rate
[NO(g)] (mol dm ) [Cl2(g)] (mol dm ) -3 -1
(mol dm s )

-6
0.250 0.250 1.43 x 10
-6
0.250 0.500 2.86 x 10
-5
0.500 0.500 1.14 x 10

For the above data,

a. What is the order with respect to Cl2?


b. What is the order with respect to NO?
c. What is the overall order of the reaction?

Q6.

Determine the rate law and calculate the rate constant for the following reaction from the following data:

S2O82- (aq) + 3I- (aq) → 2SO42- (aq) + I3- (aq)

2- -
Experiment [S2O8 ] [I ] Initial Rate (M/s)

-4
1 0.080 0.034 2.2 x 10

-4
2 0.080 0.017 1.1 x 10

-4
3 0.16 0.017 2.2 x 10

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