10. Science 9 Module
10. Science 9 Module
Unit 10
Introduction to
Carbon
Compounds
Prepared By:
Organic compounds are different from most compounds you have already studied.
Most ionic compounds such as table salt (NaCl), muriatic acid (HCl) and washing
soda (Na 2 CO 3 ) are called inorganic compounds . Inorganic compounds have high
melting and boiling points and are generally soluble in water. Organic compounds, on
the other hand, have low melting and boiling points and are generally soluble in less
polar solvents. These differences in properties arise from the differences in the type of
their chemical bonds.
But what makes organic compounds special? What properties of carbon allow the
formation of a variety of organic compounds? In this unit, you will learn why carbon
is the element of life, and how it manages to produce a lot of organic compounds.
You will also encounter some of the organic compounds you use in many of your
activities.
Essential Questions
At the end of this unit, you should be able to answer the following questions.
Review
Almost all the important substances essential to everyday life involve the carbon
atom. From the protein used in cellular processes, to the gas used to fill car tanks
and the mefenamic acid used as painkillers, carbon serves to be the main element in
this set of organic compounds. What gives carbon the ability to bond in a variety
of ways and form a diverse group of compounds?
Warm-Up
Carbon! Carbon! Carbon everywhere!
The ability of carbon to produce a diverse group of compounds lies in its properties.
Let us start listing down the properties of carbon by answering the following
questions.
_____________________________________________________________________
___________ Suppose carbon is made to react with N, O and F. Given below
are the chemical names for each covalent compound. Draw their Lewis
structures on each spaces provided.
Reacts with Chemical Name Lewis Structure
F carbon tetrafluoride
O carbon dioxide
N carbon nitride
Learn about It
Also recall from Unit 8 that the orbitals of non-metals can actually undergo
hybridization, or the process of mixing orbitals in order to provide more bonding
opportunities for the atom. If carbon uses its pre-hybridized orbitals for bonding, the
maximum bond that it can have will be two. This is because there are only two
unpaired electrons in the p -orbitals which are readily available for bonding (see
Figure 2). Once the s and p orbitals undergo hybridization, the electrons will all
become unpaired and will be distributed to the new orbitals (called sp 3 orbitals ).
Because of this, carbon can now accommodate a maximum of four bonds. This type
of hybridization is also responsible for the single bonds formed by carbon to another
carbon atom, and the most basic form of hybridization.
Carbon can also form two more complex types of hybridization called sp 2 and sp
orbitals . The former is responsible for C=C bonds, while the latter helps out in the
formation of C≡C bonds. Below are the representations of the carbon compounds in
different bond formations.
Aside from the types of bonds that they can form, carbon atoms also have the ability to
create linear, branched , and cyclic structures.
Fig. 4. The different structures formed by carbon.
While carbon typically bonds with another carbon atom and hydrogen, it can also
form covalent bonds with a wide range of other nonmetals such as oxygen, sulfur,
nitrogen, and phosphorus.
Another factor that makes carbon a very diverse element is its relatively small size.
This property enables carbon atoms to be linked closely together. As a result, strong
covalent bonds are formed.
The strong covalent bonds allow the formation of long chains of carbon as can be
seen in biological molecules such as fats and sugars. Figure 6 shows an example of
a compound that consists of a long carbon chain.
Fig. 6. Carbon can form very long chains like those found in lipids
Configurational isomers, on the other hand, have the same molecular and structural
formulas but different three-dimensional structures. This is a result of the four bonds of
carbon which are directed to the four corners of a tetrahedron.
Shown in Figure 9 is the ball-and-stick model of ethane. In this model, the atoms
are represented as balls while the bonds are represented as sticks. Focus on the
second carbon (labelled 2) of ethane;the structure of ethane in Figure 9a shows the
staggered conformation. In this conformation, the hydrogen atoms of the second
carbon are oriented in between the hydrogen atoms of the first carbon. Meanwhile,
the structure of ethane in Figure 9b shows the eclipsed conformation. In this
conformation, the hydrogen atoms of the second carbon are oriented parallel to the
hydrogen atoms of the first carbon. To clearly see the difference between the two
conformations, one can look closer at the axis where the carbons 1 and 2 are
located.
Allotropes of Carbon
The unique properties of carbon give rise to the formation of its allotropes.
Allotropes refer to the different forms of carbon. The three common allotropes of
carbon are diamond, graphite, and fullerene.
Diamond
In diamond, each carbon atom covalently bonds with four other carbon atoms, which
also bonds to four other carbon atoms. This results in the formation of a three-
dimensional structure formed by strong covalent bonds. Diamonds are hard and have
high melting and boiling points.
Fig. 10. (a) Diamond crystal; (b) Chains of carbon-carbon bonds arranged in crystalline
formation.
Graphite
In graphite, each carbon atom covalently bonds with three other carbon atoms, which
also bonds to three other carbon atoms. This results in the formation of a continuous
layer of hexagons. Graphites are soft and slippery. They have high melting and boiling
points, and are good conductors of electricity.
Fullerene
Fullerenes are made from carbon atoms that are linked together to make hollow balls
or tubes of carbon. An example of a fullerene is the Buckminster fullerene . This is
also known as “buckyballs”. They are spherical in shape and they have the formula C
60 .
Another example of fullerenes are nanotubes . These are tube fullerenes that are
known for their strength and electrical conductivity. Just like graphite, fullerenes are
composed of a sheet of links of hexagonal rings. However, fullerenes also have
pentagonal rings which prevent them from having a planar structure.
Fig. 13. Structure of a nanotube. Nanotubes are used as reinforcement in tennis rackets.
● To achieve octet, carbon shares its electrons and forms covalent bonds with
other nonmetals.
● Hybridization is the process of mixing orbitals in order to provide more
bonding opportunities for the atom. In a carbon atom, four sp 3 hybrid orbitals
are produced to make four covalent bonds.
● Carbon atoms also has the ability to create linear, branched, and cyclic
structures.
● Isomers are compounds which have the same molecular formula but with
different arrangements of atoms. There are three types:
○ Constitutional isomers differ in their skeletal formulas.
Web Links
For further information, you can check the following web links:
● Help! Suppose you are kidnapped. How will you escape? Watch
here one did it using graphite:
Veritasium. 2011. ‘ How To Make Graphene.’ https://www.youtube.com/watch?v=PifL8bAybyc
3. For the following compounds, draw their Lewis structures and identify the type
of bond they formed.
Compound Lewis Structure Type of bond
ethylene, C 2 H 4
4. For the following pair of compounds, identify whether they exhibit allotropism
or isomerism. Write A if the pair of compounds are allotropes, and I if the
compounds are isomers. Then, if the pair of compounds exhibit isomerism,
identify the type of isomerism they exhibit.
Pair of compounds Allotropes or Isomers Type of Isomerism
Carbon and graphite
Daily living would be impossible without the presence of organic compounds. And
since there are millions of varieties of organic compounds, it would be difficult to
study these compounds without classifying them. But are all carbon-containing
compounds considered organic compounds?
Warm-Up
The Boat is Sinking! Group yourselves based on … Functionality? !
The following are organic compounds we oftentimes use in everyday life. Their
Lewis structure is described in the third column. Then, match the structures drawn
below to each of these compounds. Write your answer in the fourth column.
Organic Uses Description of its Lewis
Compound Structure
From the Lewis structures, look at similarities and differences. Group the molecules
based on similar structures. How many groups did you get?
Learn about It
Organic compounds are compounds containing carbon and other elements. But it is
important to note that not all carbon-containing compounds are considered organic
compounds. In its carbonate ion (CO 3-2 ) form for example, carbon bonds ionically
with metals such as calcium and forms an inorganic compound calcium carbonate
(CaCO 3 ). Provided below if the list all inorganic compounds with carbon it it.
The volatility and viscosity of organic compounds may also differ depending on the
functional groups attached to them. Volatility refers to the ability of a compound to
become vapor, while viscosity refers to the ability of a liquid to resist from flowing.
The size of the molecule extremely affects these two properties, as molecules in short
chains tend to be very volatile and less viscous, while molecules in long chains like to
be in liquid form and are very viscous.
Fig. 13. Perfume and honey show the volatility and viscosity of organic compounds.
There are three main classifications of hydrocarbons, namely: alkanes, alkenes, and
alkynes . These three differ in the types of bonds present in them. Alkanes contain
only single bonds between carbon atoms; alkenes contain double bonds; and alkynes
contain triple bonds between carbon atoms.
(b) (c)
(a)
Fig. 15. Examples of alkane, alkene, and alkyne.
Organic compounds are grouped into different families and can be classified based
on the functional groups they contain.
A functional group is an atom ( or a group of atoms) which that is mainly
responsible for the characteristic behavior and properties of a molecule. Thus,
compounds belonging to the same functional group share common properties. Table
10.2 shows some of the common families of organic compounds and their
corresponding functional groups.
Organic compounds belonging to the same family have the same functional group.
They have similar properties, and there is a gradual change in their physical
properties as more carbon atoms are added to their chain.
Table 10.2 Organic compounds and their functional groups.
Example
Organic Functional
Compound Group Name Structure Use
Alkanes none butane Fuel for
(contains single C- cigarette
C bonds) lighters
Key Points
● Organic compounds consist of both carbon and hydrogen atoms as its base
elements.
● Organic compounds have low melting and boiling points, and high
flammability.
● The size of the molecule extremely affects these two properties, as molecules
in short chains tend to be very volatile and less viscous, while molecules in
long chains like to be in liquid form and are very viscous.
● Fractional distillation is used when mixtures of liquids have narrow
differences in their boiling point.
● A functional group is an atom (or a group of atoms) that is mainly
responsible for the characteristic behavior and properties of a molecule.
Web Links
For further information, you can check the following web links:
● Sing along with these guys and have fun remembering the families of organic
molecules:
Mark Rosengarten. 2009. ‘ Chemistry Music Video 29: It's a Family Thing.’
https://www.youtube.com/watch?v=mAjrnZ-znkY
1.
2.
3.
4.
5.
B. Group the following compounds based on their functional group.
A B C D E
F G H I J
C. Research examples for each functional group listed. Draw its Lewis structure on the
second column. Then, provide its use on the third column.
Functional Group Example Uses
Ketones
Alkyl halide
Thiol
Amine
Amide
Challenge Yourself
1. Suppose you are a scientist eager to discover the possibility of life on other
planets. Given the chance to explore other planets first hand, what would be
the top three things/criteria that the planet must have in order to support life.
Explain your answer.
2. Organic and inorganic compounds are classified based on their properties. Cite
major differences between organic and inorganic compounds.
3. Given below is the structure of caffeine, a compound found in tea and coffee.
Is this an organic or inorganic compound? Justify your answer.
Goal
● Your task is to verify whether locally available cosmetic products are safe to
human health.
● The problem/challenge is how will you be able to explain if these cosmetic
products are safe using your knowledge on basic organic chemistry and related
literatures.
Role
● You are a part of a group of brilliant student scientists who study basic
organic chemistry and are interested in cosmetic products.
Audience
● Your audience is the people in your barangay.
Situation
● You need to choose three cosmetic products locally available and list down at
least five ingredients you can see at its back.
(Lewis structures) presented structures, but structures but structures that meet
most are contains minor the rules in writing
incorrectly drawn errors in bond correct Lewis
formation and lone structures
pairs
Communication Was not able Was able to Was able to Was able to
skills to communicate some communicate, but communicate,
communicate thoughts some are not well presented the report in
his thoughts explained a manner well
understood by the
audience
Self Check
After studying this unit, can you now do the following?
Check I can…
Reflect
I find __________________________ the most interesting because
______________________.
I got ____ checks because
_______________________________________________________.
I need to improve on _______________________because
_____________________________.
I need to practice _________________________ because
_____________________________.
I plan to
_____________________________________________________________________ .
Key Words
Alkanes These are hydrocarbons that contain only single bonds.
Configurational isomers These are type of isomers that have the same molecular and
structural formulas but different three-dimensional structures.
Conformational isomers These are type of isomers that differ in their shapes due to the
rotation of C–C single bonds.
Constitutional isomers These are type of isomers that differ in their skeletal formulas.
Isomers These are compounds with the same molecular formula, but with
different arrangements of atoms.
Organic chemistry It is the study of the structure, composition, properties, and
chemical reactions of organic compounds.
Organic compounds These are compounds made up of both carbon and hydrogen
atoms as its base elements.
Viscosity It refers to the ability of a liquid to resist from flowing.
Wrap Up
Organic Chemistry