23-03-2025

1001CJA101021240052 JA

PART-1 : PHYSICS

SECTION-I

1) Find electric field due to uniformly charged hemispherical cap having charge density σ at point P

:-

(A)

(B)

(C)

(D)

2) A smooth and vertical circular wire frame of radius 2m is fixed inside water as shown. A small
bead of specific gravity 0.5 is threaded on the wire and is kept at the origin. If the bead is imparted
velocity V0 towards positive x axis, it moves on the wire frame then neglecting effect of viscosity,
minimum value of V0 so that it completes vertical circle will be :-

(A) m/s
(B) m/s
(C) m/s
(D) m/s
3) Statement-1 : Experiments revealed that the distance of closest approach to a gold nucleus of an
∝ particle of kinetic energy 5.5 MeV is about 4 × 10–14 m.
Statement-2 : Rutherford's calculations take into account both coulombic repulsion force as well as
short ranged nuclear force.

(A) Statement-1 is true, statement-2 is true and statement-2 is correct explanation for statement-1.
Statement-1 is true, statement-2 is true and statement-2 is NOT the correct explanation for
(B)
statement-1.
(C) Statement-1 is true, statement-2 is false.
(D) Statement-1 is false, statement-2 is true.

4) A system of capacitors and resistors are connected to an ideal battery of emf V as shown in figure.
Initially all the capacitors are uncharged and switch is open. Now switch S is closed at t = 0.
(Capacitance of each capacitor is 'C' and resistance of each resistor is R and all of the symbols have
their usual meaning). Current through battery just after switch is closed, is

(A)

(B)

(C)

(D) None of these

5) Transverse waves are set in a thin rod of length ℓ clamped at one end O and free at other end.
The wave velocity is v. The rod vibrates in the 4th overtone mode with amplitude y0. The equation of

motion of the point at x = is

(A)

(B)

(C)

(D) y = 0

6) Four wire A, B, C and D each of length ℓ = 10cm and each of area of cross section is 0.1 m2 are
connected in the given circuit. Then, the position of null point is :- (Given that resistivity : ρA = 1Ω -
m, ρB = 3Ω - m, ρC = 6Ω - m, ρD = 1Ω - m)

(A) mid point of wire B or wire C when both the switches S1 and S2 open.
(B) mid point of wire B when both the switches S1 and S2 are closed.
(C) mid point of wire D when both the switches S1 and S2 are open.
(D) None of these

7) Uniform, smooth, thin, fairly long rod of mass M and length L is in weightlessness in the distant
space as shown. A small bead is placed on the rod, the mass m of which is much less than the mass
M of the rod (m << M). Find the period T of small oscillations of the bead near the center rod.

Gravitational constant is G.

(A)

(B)

(C)

(D)

8) Consider three identical uniform disc each of mass M and radius 'R'. System is kept in x-y plane.

Match the moment of inertia about axis in List I to answer in List II :-

 List–I List–II

(I) About x axis (P)

(II) About y axis (Q)

About an axis passing

through centre of mass
(III) of system and (R)
perpendicular to its
plane

About axis passing

(IV) through point A and (S)
perpendicular to plane

(T) None of these

(A) (I) - (S) ; (II) - (Q) ; (III) - (R) ; (IV) - (T)
(B) (I) - (T) ; (II) - (Q) ; (III) - (R) ; (IV) - (S)
(C) (I) - (S) ; (II) - (R) ; (III) - (Q) ; (IV) - (T)
(D) (I) - (P) ; (II) - (Q) ; (III) - (S) ; (IV) - (R)

9) A wire of length L, mass m and carrying a current I is suspended from point O as shown. An
another infinitely long wire carrying the same current I is at a distance L below the lower end of the
wire. The angular acceleration of the wire just after it is released from the position is :- (given I = 2

A, L = 1m and m = 0.1 kg, loge 2 = 0.7)

(A) 48 × 10–7 rad/s2

(B) 96 × 10–7 rad/s2
(C) 24 × 10–6 rad/s2
(D) 48 × 106 rad/s2

10) 2 identical cylinder-shaped barrels, having the same height h are placed on the horizontal
ground, one on the top of the other. Both were nearly fully filled with wine. Two holes are drilled as
shown. Find x, in order that the impact points of the wine rays fall as far apart as possible.
(A)

(B)

(C)

(D)

11) Three identical large parallel plates are fixed at separation d from each other as shown. The area
of each plate is A. Plate 1 is given charge +Q , while plates 2 and 3 are neutral and are connected to
each other through coil of inductance L and switch S. If resistance of all connecting wires is

neglected then the maximum current that will flow through coil after closing switch is (take

and neglect fringe effect)

(A)

(B)

(C)

(D)

12) Which of the following statements are correct regarding L.E.D.?

(I) Low operational voltage and less power.
(II) Fast action and no warm-up time required.
(III) The bandwidth of emitted light is 100 Å to 500 Å or in other words it is nearly (but not exactly)
monochromatic.
(IV) Short life and ruggedness.
(V) Fast on-off switching capacity.

(A) I, II, III, IV are correct.

(B) I, III, IV, V are correct
(C) I, II, III, V are correct
(D) All are correct.

13) A stone is thrown vertically upward. On its way up it passes point A with speed of v, and point B,
3m higher than A, with speed v/2. The maximum height reached by stone above point B is :

(A) 1m
(B) 2m
(C) 3m
(D) 5m

14) A particle of mass m is driven by a machine that delivers a constant power k watts. If the particle
starts from rest the force on the particle at time t is :

(A)

(B)

(C)

(D)

15) A solid sphere of mass m and radius R is gently placed on a conveyer belt moving with constant
velocity v0. If coefficient of friction between belt and sphere is 2/7, the distance travelled by the

centre of the sphere before it starts pure rolling is :

(A)

(B)

(C)

(D)

16) An object of mass 0.2 kg executes simple harmonic oscillations along X-axis with a frequency of
(25/π) Hz. At the position x = 0.04 m, the object has kinetic energy of 0.5 J and potential energy of
0.4 J. Find the amplitude of oscillations (in cm). [assume zero potential energy at equilibrium
position]

(A) 2 cm
(B) 4 cm
(C) 5 cm
(D) 6 cm

17) The de-Broglie wavelength associated with the electron in n = 4 level is :

(A) two times the de-Broglie wavelength of the electron in the ground state
(B) four times the de-Broglie wavelength of the electron in the ground state
(C) half of the de-Broglie wavelength of the electron in the ground state
(D) l/4th of the de-Broglie wavelength of the electron in the ground state.

18) A mixture of light, consisting of wavelength 590 nm and an unknown wavelength, illuminates
Young's double slit and gives rise to two overlapping interference patterns on the screen. The
central maximum of both lights coincide. Further, it is observed that the third bright fringe of known
light coincides with the 4th bright fringe of the unknown light. From this data, the wavelength of the
unknown light is :

(A) 393.4 nm
(B) 885.0 nm
(C) 442.5 nm
(D) 776.8 nm

19) An organ pipe of cross sectional area 100 cm2 resonates with a tuning fork of frequency 1000Hz
in fundamental tone. The minimum volume of water to be drained out so that the pipe again
resonates with the same tuning fork is (take velocity of wave = 320 m/s)

(A) 800 cm3

(B) 1200cm3
(C) 1600cm3
(D) 2000 cm3

20) The electric field potential in a certain region of space depends only on the x-coordinate as V =
–2x3 + 3. Find the distribution of the space charge ρ (x).

(A) 6 ∈0x
(B) 12 ∈0x
(C) 6 ∈0
(D) –12 ∈0

SECTION-II

1) As shown, the left end of an upright U-shaped glass tube of uniform cross section is sealed and
the right end is open. If the atmospheric pressure is P0 = 76 cm Hg and at T0 = I5°C, the length of
the gas column sealed by the mercury is ℓ0 = 8 cm and the height difference between the left and
the right mercury surfaces is h = 4 cm. When the temperature is raised to T1, the length of the gas
column becomes ℓ1 = 9cm, then T1 is n × 12°C. Then find value of n.

2) An infinitely long wire, located on the Z-axis, carries a current I along the +Z-direction and

produces the magnetic field . The magnitude of the line integral along a straight line from

0
the point to (a, a, 0) is given by then find x. [µ is the magnetic permeability of
free space]

3) A length L = 15m of flexible tape is tightly wound. It is then allowed to unwinding as it rolls down
a fixed incline that makes an angle θ = 30° with the horizontal, the upper end of the tape being
fixed. Find the time taken (in second) by the tape to unwind completely. Neglect radius at any time

w.r.t. the length of the rope.

4) The number of photons of yellow light (λ = 575 nm) that must be absorbed by 1.0 cm2 of human
skin to raise the skin temperature by 1.0°C is 1.2 x 10n . Find n. (Assume that the photon energy is
absorbed by 1.0 cm3 of tissue. As rough estimates of the tissue's density and specific heat, use the
values for water)

5) A projectile is fired at a speed of 100 m/s at an angle of 37° above the horizontal. At the highest
point, the projectile breaks into two parts of mass ratio 1 : 3. The smaller part comes to the rest.
Find the distance (in m) from the launching point to the point where the heavier part lands [g = 10
m/s2]

PART-2 : CHEMISTRY

SECTION-I

1) During the qualitative analysis of bromide ion by chlorine water, orange brown coloration is
obtained in organic layer due to disolution of bromine.
Which organic compound is used in above test to prepare organic layer.
(P) CCl4
(Q) CS2
(R) CH2Cl2
(S) C2H5OH

(A) (P), (Q) and (S)

(B) (P) , (Q) only
(C) (P), (Q), (R), (S)
(D) (P), (Q) and (R)

2) For an ideal gas, three adiabatic processes are carried out upto same final pressure from same
initial state. If adiabatic reversible process ends up at point 'B' and adiabatic single step irreversible
process ends up at point 'C', then adiabatic free expansion upto same final pressure will end up at -

(A) A
(B) P
(C) Q
(D) R

3) (A)
Calculate total moles of CO2 evolved per mol substrate

(A) 5
(B) 4
(C) 6
(D) 7

4) When hydrated ferric chloride is dissolved in aqueous solution of oxalic acid containing potassium
hydroxide

(A) Brown ppt of Fe(OH)3 is obtained

(B) Green crystals of K3[Fe(C2O4)3] are obtained
(C) Yellow crystals of K[FeCl4] are obtained
(D) Yellow solution of [Fe(H2O)6]Cl3 & K2C2O4 are obtained

5) For a given ideal gas, the mean free path (at a particular pressure) is -
(A) Independent of temperature
(B) Decreases with rise in temperature
(C) Increases with rise in temperature
(D) Directly proportional to T2

6)

(A) C cannot exhibit GI

(B)

(C)

(D)

7) For a gaseous reaction :

CH3CHO(g) CO(g) + CH4(g)
initial pressure is 80 mm of Hg and total pressure at the end of 20 minutes is 120 mm of Hg. The
rate constant of the reaction assuming first order kinetics is - (ln2 = 0.693)

(A) 3.465 × 10–2 min–1

(B) 34.65 min–1
(C) 3.465 min–1
(D) 0.3465 min–1

8) Assertion (A) : Actinoide contraction is greater from element to element than lanthanide
contraction.
Reason (R) : The 5f electrons themselves provide poor shielding from element to element in series.

(A) A is false but R is true.

(B) A is true but R is false.
(C) Both A and R are true and R is the correct explanation of A.
(D) Both A and R are true and R is NOT the correct explanation of A.
9)

pH of the aq. solution of 0.05 M Ca(CN)2 at 25°C is :

(A) 10.63
(B) 9.37
(C) 8.63
(D) 8.37

10) Which of the following compounds has least equilibrium constant for acid catalyzed hydration :

(A)

(B)

(C)

(D)

11) In the laboratory a aqueous manganese (II) ion salts is oxidised by _______to________.
Select best option to fill the blank space respectively.

(A) Sulphate ; Manganate

(B) Peroxydisulphate ; Manganate
(C) Thiosulphate ; Permanganate
(D) Peroxydisulphate ; Permanganate

12) Compound is a hydrated complex. If 1 molal aqueous solution of this complex has
freezing point of 269.28 K (assuming 100% ionization of this complex), then formula of the complex
is :
(Kf for water = 1.86 K kg mol–1)

(A)
(B)
(C)
(D)
13)
Select the correct statement about final nitrogen containing compound [D].

(A) It is less basic than aniline.

(B) Formal charge of N is +1.
(C) It gives bad smelling compound on treatment with CHCl3/KOH.
(D) On treatment with NaNO2 + HCl followed by β–napthol in alkaline medium, it forms red dye.

14)

Consider Be, B, C, N, O, F, Cl, S atoms and identify atom which has maximum E.A. and atom which
has lowest ionization energy.
What is the shape of binary molecule formed by them.

(A) Linear
(B) Tetrahedral
(C) T-pyramidal
(D) Triangular planar

15) Product (P)

Choose the correct statement regarding 'R' and 'P'.

(A) When R = dil.HNO3, number of Stereoisomers of P = 10

(B) When R = Br2 / H2O, number of enantiomeric pair of P = 6
(C) When R = Red P + HI, number of structural isomers of P = 6
(D) When R = HIO4 (5 moles), number of moles of acid product obtained per mole substrate is 6.

16) Select the p-block non metallic atoms present in chalcopyrite, cryolite and pyrolusite
respectively.

(A) Sulphur, Fluorine, Oyxgen

(B) Iron, Aluminium, Manganese
(C) Sulphur, Fluorine, Sulphur
(D) Sulphur, Chlorine, Fluorine

17) In the following reaction sequence

The IUPAC name of 'P' is.

(A) 1-Phenylpropanone
(B) 1-Phenylpropanoic acid
(C) 1-Phenylethanal
(D) 1-Phenylethanoic acid

18) Select the set in which atleast two complexes are heteroleptic and contain chelate rings.

Set-1
Pentaammineaquacobalt(III) chloride
(A)
Tris(ethylenediamine)cobalt(III) nitrate
Sodium trioxalatoaluminate(III)
Set-2
Diamminebis(ethylenediamine)cobalt(III) chloride
(B)
Bis(ethylenediamine)difluoridocobalt(III) nitrate
Sodium trioxalatoaluminate(III)
Set-3
Pentaammineaquacobalt(III) chloride
(C)
Bis(ethylenediamine)difluoridocobalt(III) nitrate
Sodium trioxalatoaluminate(III)
Set-4
Diamminebis(ethylenediamine)cobalt(III) chloride
(D)
Pentaammineaquacobalt(III) chloride
Tris(ethylenediamine)cobalt(III) nitrate

19) Statement -1 : The SRP of three metallic ions A+, B2+, C3+ are –0.3, –0.5, 0.8 volt respectively, so
oxidising power of ions is C3+ > A+ > B2+.
Statement -2 : Higher the SRP, higher the oxidising power.

(A) Statement-1 is true, statement-2 is true and statement-2 is correct explanation for statement-1.
Statement-1 is true, statement-2 is true and statement-2 is NOT the correct explanation for
(B)
statement-1.
(C) Statement-1 is true, statement-2 is false.
(D) Statement-1 is false, statement-2 is true.

20) is made to react with various reagents as follows

List-I List-II
(Reagent) (Product)

(P) (1)
 (Q) HBF4, Δ (2)

(R) Cu, HCl (3)

(S) CuCN/KCN (4)

Match List I with List II and choose the correct answer from the options given below:
(A) P→4, Q→3, R→2, S→1
(B) P→1, Q→3, R→4, S→2
(C) P→3, Q→1, R→2, S→4
(D) P→3, Q→1, R→4, S→2

SECTION-II

1) Find sum of the bond order of species which must have atleast one π bond among :- H2 , , ,
, F2 , C2

2) Wavelength of electron waves in two Bohr orbits of a H-like species is in ratio 3 : 5. The ratio of
kinetic energy of electron in these two Bohr orbits is 25 : x, hence x is :

3)

Calculate enthalpy of precipitation of CaCO3(s) (in kcal mol–1).

Ca2+(aq.) + CO32– (aq.) → CaCO3 (s)
0
Given : ΔfH (Ca2+, aq.) = – 130 kcal mol–1
0 0
ΔfH (CO32–, aq.) = –160 kcal mol–1 ΔfH (CaCO3, s) = – 285 kcal mol–1

4) Total number of enols for the product formed in the given reaction will be (Including
stereoisomers)

5) How many compounds show geometrical isomerism after reaction with NH2–OH?

(i) (ii)
(iii) (iv)

(v) (vi)

(vii) (viii)

(ix)

PART-3 : MATHEMATICS

SECTION-I

1) Let A be the set of all real solutions of equation x(x2 + 3|x| + 5|x – 1| + 6|x – 2|) = 0 and B be the
set of all real solutions of equation x2 – |x| – 12 = 0 then number of subsets of the set A × B is

(A) 2
(B) 4
(C) 8
(D) 16

2) Let α,β,γ be three roots of equation x3 + bx + c = 0 such that βγ = 1 = – α. If αn + βn + γn = –3

then value of n can be

(A) 9
(B) 8
(C) 5
(D) 6

3) Assertion A : The number of ways in which 3 married couples with their 4 children can sit in a
row such that no husband and wife are together, are 10! – 3. 9! + 3 . 8! – 7!.
Reason R : Number of ways of occurrence of at least one event out of three events A, B & C = n(A
∪ B ∪ C) = n(A) + n(B) + n(C) – n(A ∩ B) – n(B ∩ C) – n(C ∩ A) +n(A ∩ B ∩ C).

(A) Both A and R are correct but R is NOT the correct explanation of A
(B) Both A and R are correct and R is the correct explanation of A
(C) A is correct but R is not correct
(D) A is not correct but R is correct

4) If for the complex number z satisfying |z – 2 – 2i| ≤ 1, the maximum and minimum value of |3iz +
6| is M and m then value of (M + m) is

(A) 9
(B) 3
(C) 12
(D) 15

5) If 2 tan2θ – 5 secθ = 1 has exactly 7 solutions in the interval , then for the least value of n ∈

N value of is equal to

(A)

(B)

(C)

(D)

6) Let the first term of the series be a1 = 6 and its rth term be ar = 3.ar–1 + 6r, r = 2,3,...n. For some n

∈ N, if the sum of first n terms of the series is (n2 – 18n + 84) (4.6n – 5.3n + 1) then n is equal to

(A) 9
(B) 6
(C) 7
(D) 8

7) Consider the system of linear equations 2x + (p2 – 2)y + 6z = 8

x + 2y + (q – 1)z = 5
x + y + 3z = 4 where p,q ∈ R
which of the following statements is NOT TRUE

(A) System will have unique solution if p ∈ R – {–2,2}, q ∈ R –{4}

(B) system is inconsistent if p = 2, q = 4
(C) system will have infinite solution if p = –2,q ∈ R
(D) system is consistent if p ∈ R, q ∈ R –{4}

8) The value of + is :
(where (α > 1) and )

(A) π (α – 1) – β
(B) π α – 2 β
(C) π α – 2 (β –1)
(D) π(α – 1) – 2β

9) Match List-I with List-II and select the correct answer using the code given below the list.

List–I List–II

Let and and

(A) (I) 2
(λ , μ are scalars), then |λ| + |μ|
is (Where are pairwise non-collinear)

If the line cuts the parabola y2 = x + 2 at

A and B, given that , then

(B) (II) 7

is

(where P is and λ1, λ2 are relatively prime)

The sum (in radians) of all values of x with 0 ≤ x ≤

(C) 2π which satisfy (cos 2x – sin x – 1) = 1 + 2 sin x, is (III) 6
kπ, then k is

(D) (IV) 5
Value of is equal to
(A) (A) – I, (B) – II, (C) – III, (D) – IV
(B) (A) – II, (B) – IV, (C) – III, (D) – I
(C) (A) – IV, (B) – I, (C) – III, (D) – II
(D) (A) – III, (B) – IV, (C) – II, (D) – I

10) Let y = y(x) be the solution of the differential equation (cosecx)dy + (2(1 – x) cotx + x(x – 2))dx =

0 such that . The value of y(2) is equal to

(A) 2
(B) 2(1 – cos2)
(C) 2(1 + cos2)
(D) 3

11) Consider the given data frequency distribution :

 Class interval 0-6 6-12 12-18 18-24 24-30

Frequency 4 5 3 6 2
The mean deviation from median of given data is
(A) 7
(B) 7.5
(C) 6
(D) 6.5

12) Given a real valued function f(x) defined as

where {x} represent fractional part of x. Then which of the following is INCORRECT

(A)

(B)

(C)

(D) exists.

13) A square is inscribed in the circle x2 + y2 – 10x – 6y + 30 = 0. One side of this square is parallel

to y = x + 3. If (xiyi) (where i = 1,2,3,4) are the vertices of square then is equals to

(A) 148
(B) 156
(C) 160
(D) 152

14) Let P be the point (10,–2,–1) and Q be the foot of the perpendicular drawn from the point R
(1,7,6) on the line passing through the points (2,–5,11) and (–6,7,–5). Then the length of the line
segment PQ is equal to

(A) 14
(B) 13
(C) 12
(D) 17

15) Statement-1 : If a + b + c + d = 9 and a2 + b2 + c2 + d2 = 27, where a, b, c, d are non-negative

real numbers, then d ∈ .

Statement-2 : .

(A) Statement-1 is True, Statement-2 is True

(B) Statement-1 is False, Statement-2 is False
(C) Statement-1 is True, Statement-2 is False
(D) Statement-1 is False, Statement-2 is True

16) Let unit vector is inclined at an angle θ to a unit vector and which are perpendicular to

each other. If where λ, μ be real, then θ belongs to

(A)

(B)

(C)

(D)

17) Length of focal chord of parabola y2 = 8x parallel to normal drawn to it at point with abscissa 2
is -

(A) 4
(B) 8
(C) 12
(D) 16

18) Let P be a relation defined on the set of interval such that P ={(a, b) : cosec2a – cot2b =
1}. Then P is

(A) Reflexive and symmetric but not transitive

(B) Reflexive and transitive but not symmetric
(C) Symmetric and transitive but not reflexive
(D) Equivalence relation

19) The area enclosed by y = ℓnx, y = ℓn|x|, y = |ℓnx| and y = |ℓn|x|| is

(A) 5
(B) 2
(C) 4
(D) 1
20) Let .
Then (J + K)

(A) 0
(B) 1
(C) 2
(D) 3

SECTION-II

1) The solution of the equation is of the form then k is equal to

(where [x] denotes greatest integer less than x & {x} denotes fractional part of x)

2) If , then value of k is

3) If a and b are chosen randomly from the set A = {1,2,3,4,5,6} with replacement. If probability

that is [H.C.F(p,q) = 1] then (q – p) is

4) If and A2014 = λA2013 + μA2012 then (λ + μ) is

5) The coefficient of in is
 ANSWER KEYS

PART-1 : PHYSICS

SECTION-I

Q. 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20
A. B C C C D A D A B B D C A C A D B C C B

SECTION-II

Q. 21 22 23 24 25
A. 5 7 3 19 1120

PART-2 : CHEMISTRY

SECTION-I

Q. 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45
A. D D A B C D A C B A D C C D A A A B A D

SECTION-II

Q. 46 47 48 49 50
A. 10 9 5 3 5

PART-3 : MATHEMATICS

SECTION-I

Q. 51 52 53 54 55 56 57 58 59 60 61 62 63 64 65 66 67 68 69 70
A. B A D A A A B D B D A D D B A D D D C A

SECTION-II

Q. 71 72 73 74 75
A. 2 1 8 7 13
 SOLUTIONS

PART-1 : PHYSICS

2) Let mass of bead = m

to complete vertical circle
VH ≥ 0
Apply WE therom

–mg(3) =
V2 =

Vmin =
Inside water forces acting are gravity, Buoyant force & Normal reaction.
Wa + WB + WN= ΔKE

–mg(1) + 2mg(1) + 0 =

4) At t = 0 all the capacitors are short circuited. So current at t = 0 can be calculated as

below.

i=
5)
n = 1, 3, 5, 7, 9

0
Fourth overtone f = ;

∴ Equation of the standing wave

For x =

6) Both open.
RA = 1Ω, RB = 3Ω, RC = 6Ω, RD = 1Ω
Current in upper circuit when S1 is open is I1 = 1A
Null point is mid point of B or C when S2 and S1 both open
When both closed, current in upper circuit
I1 = 2A
Current in lower circuit I2 = 1A
ΔV = 2 – I2 (1) = 1V
null point is mid point of A.

7) Since, according to the condition, the mass of the rod M is much greater than the mass of
the bead m (m << M), then we can assume that the rod is practically motionless, and a bead
moves along it.

9) Consider an element of length dx (of the suspended by wire) at a distance x from the
horizontal wire. If dτ is the torque on this element due to the magnetic force Fm , then

11)
 ⇒

21) Pi in gas column = p0 – ρgh

= 76 – 4 ⇒ 72 cm of Hg
Pf in gas column = 76 – 2 = 74 cm of Hg
vi = A × 8, vf = A × 9

= constant.

23)

PART-2 : CHEMISTRY

27)

In adiabatic expansion Tf < Ti

But in adiabatic free expansion Tf = Ti
Tf(free expansion) > Tf (adiabatic irr.)
So for same final pressure Vf(free) > Vf(adia. irr.)

30)

λ=

where N* =
31)

32) CH3CHO(g) → CH4(g) + CO(g)

t=0 80 0 0
t = 20min 80 – x x x
(80 –x) + x + x = 120 ⇒ x = 40
t1/2 = 20min

K= = 3.465 × 10–2 min–1

34)

37) ΔTf = i × Kf × m
(273 – 269.28) = i × 1.86 × 1
3.72 = i × 1.86
i=2

or n = 2

38)

40) A : Saccharic acid →No. of stereoisomers = 10

B : Gluconic acid →No. of enantiomeric pair = 8
C : n-hexane → No. of structural isomers = 5
D : 5 moles of acid is obtained

42) CH3–CH2–C≡N + C6H5MgBr

44) (Fact)

45)

(P)

(Q)

(R)

(S)

47)

48)
 = – 285 – {–130 – 160}
= 5 Kcal/mol.

50) iii, iv, v, viii, ix

PART-3 : MATHEMATICS

51)

x(x2 + 3|x| + 5|x – 1| + 6|x – 21) = 0

x = 0 is only real solution n(A) = 1
For x2 – |x| – 12 = 0
|x|2 – |x| – 12 = 0
(|x| – 4) (|x| + 3) = 0
x = ±4 n(B) = 2
n(A × B) = 1 × 2 = 2
Number of subsets = 22 = 4

52) α + β + γ = 0, αβγ = –C
–1 = –C ∴ C = 1
β+γ=1
αβ + βγ + γα = b
α(β + γ) + βγ = b
(–1) (1) + 1 = b ∵ b = 0
Equation reduces to x3 + 1 = 0
α = –1, β = –w, γ = –w2

53) Total ways = 10! – 3. 9! . 2! + 3 . 8! × 2! . 2! – 7! . 2! . 2! . 2!

54)
|3iz + 6| = |3i| |z – 2i| = 3|z – 2i|
maximum of |z – 2i| = 3 and minimum = 0

55) For 7 solution n = 13

56) ar = 3ar – 1 + 6r
a2 = 3a1 + 62
a3 = 3a2 + 63 = 3(3a1 + 62) + 63
a3 = 32.6 + 3.62 + 63

ar = 3r – 1.6
ar = 6.3r – 1 [1 + 2 + 22 ... + 2r – 1]

ar = 6.3r – 1

Sn =

n2 – 18n + 84 = 3 (n – 9)2 = 0
n=9

57) D = (p2 – 4) (q2 – 4) Dx = (p2 – 4) (4q – 19)

Dy = 0
Dz = p2 – 4

58)

= 2β
 I1 = π (α – 1)
I = I1 – I2
I = π (α – 1) – 2β

59) (A)

(B) Parametric equation of line is

(C) (cos 2x – sin x – 1) = 1 + 2 sin x

(1 – 2 sin2x – sin x – 1) = 1 + 2 sin x
– sin2x – sin x = 1 + 2 sin x
2
sin x + (2 + ) sin x + 1 = 0
sin x [2 sin x + 1] + 2 sin x + 1 = 0
⇒ ( sin x + 1)(1 + 2 sin x) = 0
sin x = – 1/2 or sin x = –

sum = 6π

(D)

60) dy = d((x2 – 2x) cosx) y(x) = (x2 – 2x) cosx + 3

y(2) = 3

61)

Class di = |xi –
fi xi fi di
Interval median|

0–6 4 3 4 11 44

6 – 12 5 9 9 5 25

12 – 18 3 15 12 1 3

18 – 24 6 21 18 7 42

24 – 30 2 27 20 13 26
 Σ fidi =
140

Median =

Mean deviation =

62)

63) one side of the square is y = x + k Distance of (5, 3) to line y = x

+k

k = 0, k = –4
so lines are y = x and y = x – 4
solving these lines with circle
(3, 3) ; (5, 5) ; (5, 1) ; (7, 3)

64) Given line

Q(2λ – 6, 7 – 3λ, 4λ – 5)
= (2λ – 7, –3λ, 4λ – 11)
QR is perpendicular to line
4λ – 14 + 9λ + 16λ – 44 = 0
λ=2
Q(–2, 1, 3) ∴ PQ = = 13

65) Statement-2 is obviously true

From statement 2,

or or d(2d – 9) ≤ 0
⇒ ⇒ Statement 1 is also true.

66)

cosθ = λ

1 = λ2(1 + 1 + 0) + μ2
1 = 2λ2 + μ2
1 = 2cos2θ + μ2
µ2 = 1 – 2cos2θ ≥ 0

cosθ ∈

67) mT =
⇒ mn = –1 = tanα
⇒ α = 135°
LFC = 4 × 2 × cosec2(135°) = 16

68) Check for (a, a)

cosec2a – cot2a = 1 ⇒ Reflexive
check for (a, b) ∈ R
cosec2a – cot2b = 1
(1 + cot2a) – (cosec2b – 1) = 1
2 + cot2a – cosec2b = 1
cosec2b – cot2a = 1
∵ (b, a) ∈ R ∴ it is symmetric
Now (a, b) ∈ R, (b, c) ∈ R
cosec2a – cot2b = 1
cosec2b – cot2c = 1
Adding Both
cosec2a – cot2c = 1
⇒ (a, c) ∈ R
Hence given relation is equivalence

69)
70)
Put x + 5 = t

Put x + 2 = z in K

J+K=0

71) [x] = t {x} = y x=t+y

8t2 – 11ty – 10y2 = 0

8t2 – 11t – 10 < 0

t = 1, y =

x=

72)
73)

ℓn y = ℓn (ab) ∴ y = ab = 6
So possible cases (a, b) = (6, 1), (1, 6) (2, 3) (3, 2)

Required probability =
q–p=8

74) Characterstic equation x2 – 5x – 2 = 0

∵ A2 – 5A – 2I = 0
A2 = 5A + 2I
A2014 = 5A2013 + 2A2012
∴λ+μ=7

75) Coefficient of
Now for coefficient of xa – 7 we can
have (x7 – 7), (x – 1) (x6 – 6), (x2 – 2) (x5 – 5),
(x3 – 3) (x4 – 4), (x – 1) (x2 – 2) (x4 – 4)
∴ –7 + 6 + 10 + 12 – 8 = 13
∴ coefficient of xα – 7 is 13