Sample Paper-05 Dropper NEET (2024)

CHEMISTRY
ANSWER KEY
1. (1) 26. (1)
2. (3) 27. (1)
3. (1) 28. (2)
4. (1) 29. (4)
5. (4) 30. (1)
6. (3) 31. (3)
7. (3) 32. (1)
8. (1) 33. (2)
9. (1) 34. (2)
10. (1) 35. (1)
11. (1) 36. (4)
12. (1) 37. (4)
13. (4) 38. (3)
14. (2) 39. (3)
15. (3) 40. (4)
16. (3) 41. (1)
17. (1) 42. (3)
18. (4) 43. (4)
19. (3) 44. (4)
20. (3) 45. (3)
21. (1) 46. (3)
22. (1) 47. (1)
23. (2) 48. (3)
24. (1) 49. (4)
25. (1) 50. (4)

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 HINTS AND SOLUTION
1. (1) 6. (3)
Number of moles of Cl– ions ionized from one
mole of CrCl3.6H2O
2.665 Molecular mass of 
= = 0.01  
266.5 CrCl3 .6H 2 O = 266.5
 Moles of AgCl obtained
= Moles of Cl– ionized
2.87
= = 0.02
143.5 Each chiral centre generates two optically active
 0.01 mole of complex CrCl3.6H2O gives compounds.
0.02 mole of Cl– on ionization. Thus, total number of optically active compounds
Thus, the formula of the complex is will be 2 × 3 = 6.
CrCl ( H 2 O )  Cl2 .H 2 O
 5
7. (3)
2. (3) Mass of solute
Mass percentage =  100
(A) O−2 = 8 + 8 + 1 = 17 : Paramagnetic Mass of solution
(B) CN– = 6 + 7 + 1 = 16 : Diamagnetic
=
( 3  60 ) g 100
(C) CO = 8 + 6 = 14 : Diamagnetic ( 3  60 ) g + 1000g
+
(D) NO = 7 + 8 – 1 = 14 : Diamagnetic 180g
=  100
180g + 1000g
3. (1)
180g
In third period, 3s and 3p-orbitals are filled. Total =  100 = 15.25%
1180g
orbitals to be filled = one s + three p = 4. Thus,
number of elements = 4 × 3 = 12 [Moles of solute = 3, mass of solvent = 1000 g]

4. (1) 8. (1)
0.5 molal aqueous solution means 0.5 mol of
solute is present in 1000 g of water.
1000
Hence, mole of water = = 55.5
18 3,4-Dimethylhex-3-ene
n solute
Thus, mole fraction of solute = 9. (1)
n solute + n solvent
X(g) → X + (g) + e–
0.5
= If I.E. is ionization enthalpy, then
0.5 + 55.5
NA
0.5 
= 2
56
(I.E.) = E1
5 1
= = 2E
560 112  I.E. = 1
NA
5. (4)
Correct matches are: X(g) + e– → X –(g)
List-I List-II If eg H is election gain enthalpy, then
(A) Phenol Reimer-Tiemann  2NA ( E.A.) = −E 2
(B) Acetic acid Hell-Volhard-Zelinsky E2
(C) Formaldehyde Cannizzaro   eg H = −
2N A
(D) Toluene Etard
10. (1)
Internal energy is a state function.

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11. (1) 18. (4)
Sc3+ has zero unpaired electrons.

19. (3)
Only s and d-orbitals have center of symmetry.
ClCH = CHCH(OH)COOH &
CH2 = C(Cl)CH(OH)COOH : Position isomers 20. (3)
ClCH = CHCH(OH)COOH & Any species containing odd number of electrons.
O = CH – CH(Cl)COOCH3 : Functional isomers
21. (1)
12. (1) A0 – At = kt
Addition of inert gases at constant volume will
not affect the equilibrium. When an inert gas is 22. (1)
added to the system at constant temperature In an ideal reversible process, the system
equilibrium will shift towards the direction in maintains equilibrium at every intermediate step
which there is increase in number of moles of and the process is extremely slow. Thus, from a
gases. theoretical point of view, an ideal reversible
process should require an infinite time for its
13. (4) completion.
It is SN2 reaction.
23. (2)
14. (2) Reaction of phenyl benzoate with an excess of
methyl magnesium bromide gives a mixture of 2-
phenylpropan-2-ol and phenol.

24. (1)
Allylic cation undergoes rearrangement to give
least substituted bromide.

25. (1)
15. (3)
As stability of conjugate bases by more The monomers of DNA are called nucleotides.
dispersion of negative charge increases, the Nucleotides have three components: a base, a
acidity of conjugate acids increases. Hence the sugar (deoxyribose) and a phosphate residue.
correct order of stability of conjugate base is
ClO−4  ClO3−  ClO2−  ClO− and acidity is 26. (1)
HClO4 > HClO3 > HClO2 > HClO. Most natural sugars are D and most natural
amino acids are L. One method for determining
16. (3) whether a molecule is D- or L- by looking at the
Haemoglobin acts as oxygen carrier in the blood Fischer projection of a molecule.
for Fe2+ ions of each hemoglobin can bind with
four molecules of O2 and form oxy-haemoglobin.
Hb 4 O8 27. (1)
4Hb + 4O 2 → Oxy − haemoglobin Hydroboration-Oxidation is a two-step pathway
used to produce alcohols. The reaction proceeds
17. (1) in an Anti-Markovnikov manner, where the
In CCl4 carbon atom does not have d-orbitals to hydrogen (from BH3 or BHR2) attaches to the
accommodate a lone pair of electrons and hence more substituted carbon and the boron attaches to
is not a Lewis acid. In PCl3, SbCl3 and BiCl3 the least substituted carbon in the alkene double
central atom has empty d-orbitals in each case
bond.
but electronegativity of P is maximum, hence
PCl3 is the strongest acid.

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28. (2) 36. (4)
Dextro-isomers are represented by putting (+) Total number of N–Co–O bonds = 8.
before their name.
37. (4)
29. (4) (i) NO2 is an ambidentate group. It can show
In CS2 pπ–dπ multiple bonding exists. linkage isomerism.
(ii) The complex can show ionization isomerism
30. (1) with the complex
O− Co ( NH3 ) NO 2 (Cl)  NO 2 .
 4 
|
NaBH 4
CH3CH 2 .CO.CH 2CH 2CH3 ⎯⎯⎯⎯ → CH3CH 2CHCH 2CH 2CH(iii)
3
The complex shows geometrical isomerism.
OD
|
D 2O
⎯⎯⎯ → CH3CH 2CHCH 2CH 2CH3

31. (3)
Acidity is decided by stability of conjugate base.

32. (1) 38. (3)

Gº = −nFEcell
º
= Hº −TSº Molten sodium chloride conducts electricity due
to the presence of free ions. In order to conduct
−TSº = −nFEcell
º
= Hº
electricity a substance must have charged

−Sº =
( 2  9687  4.315 − 825.2  103 ) particles, such as electrons and ions, that are free
298 to move freely through it. In the solid state, ionic
compounds such as sodium chloride have their
Sº = 25 J K –1
ions fixed in position and therefore these ions
cannot move so solid ionic compounds cannot
33. (2)
conduct electricity. However in the molten state,
In solid state, PCl5 is an ionic solid with [PCl4]+
ions in ionic compounds are free to flow and
tetrahedral and [PCl6]– octahedral.
therefore molten sodium chloride can conduct
electricity.
34. (2)
We have to calculate the partial pressure of
39. (3)
solution which is ideal. So, Ps = P(A) + P(B)
WB = 6.5 g. WA = 100 g,
Now we have to use Raoult’s law to calculate the
Ps = 732 mm, Kb = 0.52,
partial pressure of A and B.
PA =XAPAo and PB = XBPBo Tbo = 100º C,Pº = 760mm
So, PA = 21 × 1/3 = 7 kPa
and PB = 18 × 2/3 = 12 kPa
So, Psolution = 7 + 12 = 19 kPa 760 − 732 n2
 =
760 100 / 18
35. (1)
28  100
20  n2 = = 0.2046mol
pNH3 = pH 2S = atm 760  18
2
Tb = Kb × m
K p = pNH3  pH 2S = 100atm2 n  1000
Tb − Tbº = K b  2
K p = K c ( RT )
n WA ( g )
0.52  0.2046 1000
100 = K c  ( 0.0821 400 ) Tb − 100º C =
2
100
K c = 0.092M 2

[4]
40. (4) 46. (3)
Here OH and double bond in reactant should be For 1st reaction, rGº < 0 that means the process
untouched in the product. is spontaneous and reaction is feasible, so, for
Hence, Wolf-Kishner reduction reaction will lead more characteristic oxidation state will be
proceed. +2. For II reaction, rGº < 0 that means the
process is non-spontaneous and reaction is not
41. (1) feasible, so, for tin more characteristic oxidation
Pyridoxine state will be +4.

47. (1)
42. (3) As the temperature increases pH and pOH both
will decrease.

48. (3)
Reaction of oxygen with Al will be as:

43. (4) According to stoichiometry coefficient, 4 mole

Structure of benzyl acetate and phenyl acetate is of Al react with = 3 mole of O2.
as follows: So, 1.5 mole of O2 react with
4
= 1.5  moleof Al
3
So, mole of Al = 0.5 × 4 = 2 mole
Molar mass of Al = 27 g/mol
So, mass of Al = 2 × 27 = 54 g

E = E 2 – E1 49. (4)
When k1 = k 2 ,
44. (4) 1015.e –2000/T =1014.e –1000/T
10 = e –1000/T
 13.6   13.6 
= – 2 –– 2  1000
 2   1  2.303log10 =
T
 1 3 T = 434.2K
=13.6 1 –  =  13.6 = 10.2 eV
 4 4
50. (4)
45. (3) As we move down the group, electronegativity of
Methane, ammonia and water, the respective central atom decreases so bond angle decreases.
central atoms are sp3 hybridized but they have
different bond angles.

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