JEE-MAIN 2025

Session - 2
Mock Practice Test - 2
PHYSICS Max Marks: 100
(SINGLE CORRECT ANSWER TYPE)
This section contains 20 multiple choice questions. Each question has 4 options (1), (2), (3) and (4) for its answer, out of which ONLY ONE option can be
correct.
Marking scheme: +4 for correct answer, 0 if not attempted and –1 in all other cases.

1. A ball is thrown upwards from the ground with an initial speed of u. The ball is at a height
of 80 m at two times, the time interval being 6 s. Find u. Take g  10 m / s 2 .
1) 50 m/s 2) 20 m/s 3) 25 m/s 4) 75 m/s
2. Acceleration – time graph of a particle moving in a straight line is shown in fig . Velocity of
particle at time t=0 is 2 m/s. Find velocity at the end of fourth second.

1) 5 m/s 2)10 m/s 3) 15 m/s 4) 20 m/s

3. The relation between time t and displacement x is t   x 2   x where  and  re constants.
The retardation is
1) 2 v3 2) 2 v 3 3) 2 v3 4) 2 2v3
4. An aeroplane is flying in a horizontal direction with a velocity 600 km/h at a height of 1960
m. When it is vertically above the point A on the ground, a body is dropped from it. The
body strikes the ground at point B. Calculate the distance AB.
1) 5.55 km 2) 3.33 km 3) 4 km 4) 2.5 km
5. Average velocity of a particle in projectile motion between its starting point and the highest
point of its trajectory is (projection speed = u, angle of projection from horizontal =  )
u u u
1) u cos  2) 1  3cos 2  3) 2  cos 2  4) 1  cos 2 
2 2 2
6. At certain moment of time, velocities of 1 and 2 both are 1 m/s upwards. Find the velocity of
3 at that moment.

1) 2.5 m/s 2) 5.0 m/s 3) -3 m/s 4) -4.5 m/s

7. A particle is moving along a straight line whose velocity-displacement graph is as shown in
the figure. What is the magnitude of acceleration when displacement is 3 m?

4
1) 4 3 ms 2 2) 3 3 ms 2 3) 3 ms 2 4) ms 2
3

8. Assertion(1): Two frames S1 and S2 are non-inertial. Then frame S2 when observed from S1
is inertial.
Reason(R ): A frame in motion is not necessarily a non-inertial frame
1) If both Assertion and reason are true and the reason is correct explanation of the assertion.
2) If both assertion and reason are true but reason is not the correct explanation of assertion
3) Assertion is true, reason is false.
4) Assertion is false, reason is true.
9. A block of mass m is resting on a wedge of angle  as shown in the figure. With what
minimum acceleration a should the wedge move so that the mass m falls freely ?

1) g 2) g cos 3) g cot  4) g tan 

10. A smooth inclined plane of length L having inclination  with the horizontal is inside a lift
which is moving down with a retardation a. The time taken by a body to slide down the
inclined plane from rest will be.
2L 2L 2L 2L
1) 2) 3) 4)
 g  a  sin   g  a  sin  a sin  g sin 

11. Two masses m1  10 kg and m2  8 kg tied to a string are hanging over a light frictionless

pulley. What is the acceleration of the masses when left free to move ?  g  9.8 m / s 2 

1) 5 m / s 2 2) 9.8 m / s 2 3)1.08 m / s 2 4) 4.8 m / s 2

12. A block of 3kg is attached to a string whose other end is attached to the wall. An unknown
force F is applied so that the string makes an angle of 300 with the wall. The tension T is :
(Given g  10 ms 2 )

1) 20 N 2) 25 N 3) 10 N 4) 15 N
R
13. A particle of mass m is acted upon by a force F given by the empirical law F  v  t  . If this
t2
law is to be tested experimentally by observing the motion starting from rest, the best way is
to plot :
1 1
1) log e v  t  against 2) v  t  against t 2 3) log e v  t  against 4) log e v  t  against t
t t2
14. A block of mass M placed inside a box descends vertically with acceleration ‘a’. The block
exerts a force equal to one third of its weight on the floor of the box. The value of ‘a’ will be
g g 3g 2
1) 2) 3) 4) g
4 2 4 3
15. A balloon has mass of 10 g in air. The air escapes from the balloon at a uniform rate with
velocity 2.5 cm/s. If the balloon shrinks in 5 s completely. Then, the average force acting on
that balloon will be (in dyne)
1) 3 2) 9 3) 5 4) 18
16. An object is thrown vertically upwards. At its maximum height, which of the following
quantity becomes zero ?
1) Momentum 2) Potential energy 3) Acceleration 4) Force
17. Two projectiles are thrown with same initial velocity making an angle of 150 and 300 with
the horizontal respectively. The ratio of their respective ranges will be
1) 1: 2 2) 2 :1 3)1: 3 4) 3 :1
  
18. Statement I: If three force F 1 , F 2and F 3 are represented by three sides of triangle and
  
F 1  F 2   F 3 , then these three forces are concurrent forces and satisfy the condition for

equilibrium.
  
Statement II: A triangle made up of three forces F 1 , F 2 and F 3 as its sides taken in the same
order, satisfy the condition for translatory equilibrium.
In the light of the above statements, choose the most appropriate answer from the options
given below:
1) Both statement I and statement II are true
2) Statement I is true but statement II is false
3) Both statement I and statement II are false.
4) Statement I is false but statement II is true
19. When a ball is dropped into a lake from a height 4.9 m above the water level, it hits the
water with a velocity v and then sinks to the bottom with the constant velocity v. It reaches
the bottom of the lake 5.0 s after it is dropped. The approximate depth of the lake is
1) 19 .6 m 2) 29.4 m 3) 39.2 m 4) 73.5 m
20. The initial mass of a rocket is 1000 kg. Calculate at what rate the fuel should be burnt so that
the rocket is given an acceleration of 20 ms 1 . The gases comes out at a relative speed of
500 ms 1 with respect to the rocket: [Use g =10 m / s 2 ]
1) 10 kg s 1 2) 60 kg s 1 3) 500 kg s 1 4) 6.0 102 kg s 1
(NUMERICAL VALUE TYPE)
Section-II contains 10 Numerical Value Type questions. Attempt any 5 questions only. First 5 attempted questions will be considered if more than 5
questions attempted. The Answer should be within 0 to 9999. If the Answer is in Decimal then round off to the nearest Integer value (Example i,e. If answer
is above 10 and less than 10.5 round off is 10 andIf answer is from 10.5 and less than 11 round off is 11).
Marking scheme: +4 for correct answer, 0 if not attempt and -1 in all other cases.
21. A uniform metal chain of mass m and length ‘L’ passes over a massless and frictionless
pulley. It is released from rest with a part of its length ‘ l ’ is hanging on one side and rest of
L
length ‘L- l ’ is hanging on the other side of the pully. At a certain point of time, when l  ,
x
g
the acceleration of the chain is . The value of x is _________. [Given, L > 2l]
2

22. A stone tied to 100 cm long string at its end is making 28 revolutions in horizontal circle in
1936 2
every minute. The magnitude of acceleration of stone is ms . The value of x is
x
22 
____________.  Take   
 7 

23. A swimmer can swim with velocity of 12 km/h in still water. Water flowing in river has
velocity 6 km/h. The direction with respect to the direction of flow of river water he
should swim in order to reach the point on the other bank just opposite to his starting
point is ___________ 0 . (Round off to the Nearest Integer)
24. The maximum height attained by projectile is increased by 10% by increasing the speed of
projection without changing angle of projection. What is the percentage increase in the
horizontal range attained by the projectile?
25. A batsman hits back a ball of mass 0.5 kg straight in the direction of the bowler without
changing its initial speed of 16 ms 1 . The impulse imparted to the ball is ________Ns.
26. Three blocks of mass 3 kg. 2 kg and 1 kg are placed side by side on a smooth surface as
shown in figure. A horizontal force of 12 N is applied on 3 kg block. Find the net force (in
N) on 2 kg block.

27. A ball is projected with velocity 20 ms 1 at an angle to the horizontal. In order to have the
maximum range, its velocity at the highest position must be_____m/s.
1
28. A ball is dropped from the top of a 100 m high tower on a planet. In the last s before
2
hitting the ground, it covers a distance of 19 m. Acceleration due to gravity (in ms 2 )
near the surface on that planet is ________.
29. A ball is projected upwards from the top of a tower with a velocity 50 ms 1 making an
angle 300 with the horizontal. The height of tower is 70 m. After how many seconds
from the instant of throwing, will the ball reach the ground.  g  10ms 2 
30. In the system shown in figure all surfaces are smooth. Rod is moved by external agent
with acceleration 9 ms 2 vertically downwards. Force exerted on the rod by the wedge
will be_____N.
CHEMISTRY Max Marks: 100
(SINGLE CORRECT ANSWER TYPE)
This section contains 20 multiple choice questions. Each question has 4 options (1), (2), (3) and (4) for its answer, out of which ONLY ONE option can be
correct.
Marking scheme: +4 for correct answer, 0 if not attempted and –1 in all other cases.

31. The ion that has sp 3d hydridisation for the central atom, is
1)  ICl4  2)  ICl2  3)  IF6  4)  BrF4 
   

32. Number of lone pair of electrons central element of iodine in I 3 is

1) 3 2) 6 3) 9 4) 12
33. Which of the following are isoelectronic and isostructureal?
1) ClO3 , SO3 2) SO3 , NO3 3) ClO3 , CO32 4) NO3 , CO32
34. The type of hybrid orbitals used by the chlorine atom in ClO4 is
1) sp3 2) sp 2 3) sp 4) None of these
35. The bond order and magnetic behavior of O22 ion are, respectively:
1) 1.5 and paramagnetic 2) 1.5 and diamagnetic
3) 2 and diamagnetic 4) 1 and diamagnetic
36. Stability of the species Li2 , Li2 and Li2 increases in the order of :
1) Li2  Li2  Li2 2) Li2  Li2  Li2 3) Li2  Li2  Li2 4) Li2  Li2  Li2
37. The octet rule is not valid for the molecule
1) CO2 2) H 2O 3) O2 4) BH 3
38. Assertion (1) : Acetylene is formed when ethylene chloride or ethylidene chloride is heated
with alcoholic KOH
Reason (R ) : Both gem dihaldes and vicinal dihalides on dehydrohalogenation form alkyne
1) Both A and R are true R is the correct explanation of A
2) Both A and R are true R is not the correct explanation of A
3) A is true but R is false
4) A is false but R is true
39. Assertion (A): Reaction of but-2-yne by Na / liqNH 3 gives trans But-2-ene
Reason (R ) : It is syn addition
1) Both A and R are true R is the correct explanation of A
2) Both A and R are true R is not the correct explanation of A
3) A is true but R is false
4) A is false but R is true
40. Toluene on oxidation with dilute HNO3 give
1) Benzaldehyde 2) phenol 3) Nitrotoluene 4) Benzoic acid
41. Assertion (1): The compound cyclooctatetraene has the following structural formula :

It is cyclic with 8 -electron system but it is not an aromatic compound.

Reason (R ) : (4n+2)  electron rule does not hold good and ring is not planar.
1) Both A and R are true R is the correct explanation of A
2) Both A and R are true R is not the correct explanation of A
3) A is true but R is false
4) A is false but R is true
42. Assertion (A) : Both Benzene & ethyne give same product on ozonolysis
Reason (R ) : Ethyne & benzene possess same empirical formula.
1) Both A and R are true R is the correct explanation of A
2) Both A and R are true R is not the correct explanation of A
3) A is true but R is false
4) A is false but R is true
43. In correct statement about the structure of PCl5

1) axial P  Cl bonds have more bond length than equatorial P  Cl bonds

2) d Z2 orbital is involved in Sp 3d hybridization.

3) The no. of planar atoms in PCl5 is 4.
4) Phosphorous is in second excited state.
44. In the preparation of alkyl halide from alkene and halogen which of the following reaction is
involved
1) Electrophilic addition 2) Nucleophilic addition
3) Electrophilic substitution 4) Nucleophilic substitution
45. In the preparation of alkyl halide from alkane and halogen which of the following reaction is
involved
1) Free radical substitution 2) Nucleophilic addition
3) Electrophilic substitution 4) Nucleophilic substitution
Br

46. IUPAC name of

1) 2-bromo-3-methyl pentane 2) 2-bromo-3,3-dimethyle butane
3) 4- bromo-3,3-dimethyl butane 4) 2- bromo-3, 3-dimethyl pentane
47. Thionyl chloride is preferred in the preparation of chloro compound from alcohol since
1) Both the byproducts are gases and they escape out leaving product in pure state
2) It is a chlorinating agent
3) It is a oxidising agent
4) All other reagent are unstable
48. Correct statement about Hunsdiecker reaction is
1) number of carbon atoms decrease 2) number of carbon atoms increase
3) number of carbon atoms remains same 4) carbocation intermediate is formed
49. Benzene on nitration gives nitrobenzene in presence of HNO3 and H 2 SO4 mixture, where:
1) Both H 2 SO4 and HNO3 act as a bases
2) HNO3 acts as an acid and H 2 SO4 acts as a base
3) Both H 2 SO4 and HNO3 act as an acids
4) HNO3 acts as a base and H 2 SO4 acts as an acid
50. Which of the following compounds does not dissolve in conc. H 2 SO4 even on warming?
1) Ethylene 2) Benzene 3) Hexane 4) Aniline
(NUMERICAL VALUE TYPE)
Section-II contains 10 Numerical Value Type questions. Attempt any 5 questions only. First 5 attempted questions will be considered if more than 5
questions attempted. The Answer should be within 0 to 9999. If the Answer is in Decimal then round off to the nearest Integer value (Example i,e. If answer
is above 10 and less than 10.5 round off is 10 andIf answer is from 10.5 and less than 11 round off is 11).
Marking scheme: +4 for correct answer, 0 if not attempt and -1 in all other cases.
51. Based on VSEPR theory, the number of 90 degree bond angles in SF6 is
52. According to molecular orbital theory, the number of unpaired electron(s) in O2 is:
53. Among H 2 , He2 , Li2 , Be2 , B2 , C2 , N 2 , O2 , O22 and F2 , the number of diamagnetic species is (Atomic
numbers: H  1, He  2, Li  3, Be  4, B  5, C  6, N  7, O  8, F  9 )
x
54. The difference between bond orders of CO and O2 is where x = ______
2
55. The number of sigma bonds in allyl chloride is ______.

56. 
Consider the following chemical reaction. CH  CH 
1 Red hotFe tube,873k
 product. The number
 2CH -Cl ,AlCl 3 3

of sp 2 hybridized carbon atom(s) present per molecule of the product formed is _________.
57. In the following series of reactions the maximum number of atoms present in molecule ‘C’
in one plane is _______.
3  
C (A is a lowest molecular weight alkyne)
Red hot CH Cl 1.eq.
A 
Cu tube
 B 
Anhydrous AlCl3

58. Among the following, the number of aromatic compound(s) is







59. Identify number of substituents which are deactivating but ortho and para directing in EAS
reaction
O
.. ||
 F : ; CF3 ;  C  NH 2 ;  Cl
..

..
 N  O,  CH  CH  Cl , OH , OCH 3 , CH 2Cl

60. Examine the structural formulas shown below and find out how many compounds cannot
give Friedel crafts reaction


O H

N H3 CN CH 3 NH2 C

1) 2) 3) 4) E)

NO2
O
O OH  ||
C : O : C  CH 3

(F) F) G) H)
MATHEMATICS Max Marks: 100
(SINGLE CORRECT ANSWER TYPE)
This section contains 20 multiple choice questions. Each question has 4 options (1), (2), (3) and (4) for its answer, out of which ONLY ONE option can be
correct.
Marking scheme: +4 for correct answer, 0 if not attempted and –1 in all other cases.
61. The radius of a right circular cylinder increases at the rate of 0.1 cm/min, and the height
decreases at the rate of 0.2 cm/min. The rate of change of the volume of the cylinder, in
cm3 / min, when the radius is 2 cm and the height is 3 cm is

8 3 2
1) 2 2)  3)  4)
5 5 5

62. If m is the minimum value of k for which the function f  x   x kx  x 2 is increasing in the

interval  0,3 and M is the maximum value of f in [0,3] when k  m, then the ordered pair

 m, M  is equal to
1)  4, 2 2  2)  4,3 3  3)  3,3 3  4)  5, 2 6 

63. If at each point of the curve y  x3  ax 2  x  1 , the tangent is inclined at an acute angle with
the positive direction of the x-axis, then
1) a  0 2) a  3 3)  3  a  3 4) a  3

If the absolute maximum value of the function f  x    x 2  2 x  7  e  in the

4 x3 12 x 2 180 x 31
64.

interval  3,0 is f   , then

1)   0 2)   3 3)    1,0  4)    3, 1

65. The value of c in the Lagranges mean value theorem for the function f  x   x3  4 x 2  8 x  11 ,

when x  0,1 is

2 4 7 4 5
1) 2) 3 3) 4)
3 3 6
 x2
2
66. The local maximum value of the function f  x     , x  0,
 x
e
2 1
 4 4
1) 2  e 2)   3)  e  e 4)  2 e  e
 e
67. The surface area of a balloon of spherical shape being inflated, increases at a constant rate. If
initially, the radius of balloon is 3 units and after 5 seconds, it becomes 7 units, then its
radius after 9 seconds is
1) 9 2) 20 3) 21 4) 12
68. Let f be a twice differentiable function on (1,6). If f  2   8 , f '  2   5, f '  x   1 and f " x   4,
for all x  1,6  , then
1) f  5  10 2) f '  5  f " 5  20
3) f  5  f '  5  28 4) f  5  f '  5  26

69. The surface area of a cube is increasing at the rate of 2 cm 2 / sec .When its edge is 90 cm, the
volume is increasing at the rate of
1) 1620 cm3 / sec 2) 810 cm3 / sec 3) 405 cm3 / sec 4) 45 cm3 / sec
70. The global maximum value of f  x   log10  4 x 3  12 x 2  11x  3 , x   2,3 , is
3 3
1)  log10 3 2) 1  log10 3 3) log10 3 4) log10 3
2 2
71. Assertion (A) : The angle between the curves y  sin x, y  cos x is Tan 1 2 2 .
 1 1 1
Reason ( R ) : The slopes of their tangents at  ,  are and  respectively.
4 2 2 2

1) Both A and R are true R is the correct explanation of A

2) Both A and R are true R is not the correct explanation of A
3) A is true but R is false
4) A is false but R is true
 x  x  1
72. If 3x  2 y  1 is a tangent to y  f  x  at x  1/ 2 , then lim
x 0 e 2x
 e 2 x 
f   f  
 2   2 

1) 1/3 2) ½ 3) 1/6 4) 1/7

73. The number of points on the curve y  54 x5  135 x 4  70 x 3  180 x 2  210 x at which the normal
lines are parallel to x  90 y  2  0 .
1) 0 2) 1 3) 2 4) 4
4
74. If Roll’s theorem holds for the function f  x   x 3  ax 2  bx  4, x  1, 2 with f '    0, then
3

ordered pair (a,2) is equal to:

1)  5,8  2)  4,8  3)  4, 8 4) (-5,-8)

75. Statement I : If Rolle’s theorem be applied in f  x  then Lagrange’s Mean Value

theorem(LMVT) is also applied in f  x 
Statement II : Both Rolle’s theorem and LMVT cannot be applied in
  
f  x  | sin | x || in   , 
 4 4
1) Statement-I and Statement-II are true Statement-II is the correct explanation of
Statement-I
2) Statement-I and Statement-II are true Statement-II is not the correct explanation of
Statement-I
3) Statement-I is true but Statement-II is false
4) Statement-I is false but Statement-II is true
76. A variable triangle is inscribed in a circle of radius R. if the rate of change of a side is 3R
times the rate of change of the opposite angle, then the opposite angle is
   
1) 2) 3) 4)
2 6 3 4
77. Assertion (A) : The ordinate of a point describing the circle x 2  y 2  20 decreases at the rate
of 1.5 cm/s. The rate of change of the abscissa of the point in first quadrant when ordinate
equals 4 cm is 3 cm/s.
dx dy
Reason ( R ) : If x 2  y 2  r 2 then x y 0
dt dt
1) Both A and R are true R is the correct explanation of A
2) Both A and R are true R is not the correct explanation of A
3) A is true but R is false
4) A is false but R is true
4 x3  3x 2
78. The function f  x    2sin x   2 x  1 cos x :
6
1 1
1) Increases in  ,   2) Increases in  , 
2   2
1 1
3) decreases in  ,   4) decreases in  , 
2   2
1 x 
79. Let f ( x)  tan 1  
 1 x 

Statement – I : The difference between the greatest and smallest value of f ( x) on  0,1 is .
4
Statement – II : If a function g decreases on  a, b  then the greatest value of g  g  a  and

least value of g  g  b  .
1) Statement-I and Statement-II are true Statement-II is the correct explanation of
Statement-I
2) Statement-I and Statement-II are true Statement-II is not the correct explanation of
Statement-I
3) Statement-I is true but Statement-II is false
4) Statement-I is false but Statement-II is true
80. f  x    x  8   x  9  ,0  x  10, monotonically decreases in
4 5

76 76 76
1)  ,10  2)  8,  3)  0,8  4)  ,10 
 9   9   9 
(NUMERICAL VALUE TYPE)
Section-II contains 10 Numerical Value Type questions. Attempt any 5 questions only. First 5 attempted questions will be considered if more than 5
questions attempted. The Answer should be within 0 to 9999. If the Answer is in Decimal then round off to the nearest Integer value (Example i,e. If answer
is above 10 and less than 10.5 round off is 10 andIf answer is from 10.5 and less than 11 round off is 11).
Marking scheme: +4 for correct answer, 0 if not attempt and -1 in all other cases.
81. If the angle made by the tangent at the point  x0 , y0  on the curve
2   
x  12  t  sin t cos t  , y  12 1  sin t  ,  0  t   with the positive x-axis is , then y0 is equal to
 2 3

82. If the curves x  y 4 and xy  k cut at right angles, then 2   4k  is equal to ______________.
6

83. If the tangent to the curve y  x3  x 2  x at the point  a, b  is also tangent to the curve

y  5 x 2  2 x  25 at the point  2, 1 , then 3a  9b is equal to ___________.

84. If a rectangle is inscribed in an equilateral triangle of side length 2 2 as shown in the figure,
then the square of the largest area of such a rectangle is ____________.

85. If the tangent to the curve, y  e x at a point  c, ec  and the normal to the parabola. y 2  4 x at

the point (1,2) intersect at the same point on the x-axis, then the value of c is __________.
86. The length of the sub-tangent to the hyperbola x 2  4 y 2  4 at a point where slope of the
1
normal is unity is , then k is equal to ____________
k
87. A curve is defined parametrically by the equation x  t 2 and y  t 3 . A variable pair of
perpendicular lines through the origin O meet the curve at P and Q. If the locus of the point
of intersection of the tangents at P and Q is ay 2  bx  1, then the value of  a 2  b 2  is

___________
88. Consider p  x  to be a polynomial of degree 5 having extremum at x  1, 1 and

 p  x 
lim  3  2   4 . Then the value of  P (2)  is (where[.] represents greatest integer function)
x0
 x 

89. If water is poured into an inverted hollow cone whose semi-vertical angle is 300 , its depth
(measured along the axis) increases at the rate of 1 cm/s. Find the rate at which the volume
of water increases when the depth is 24 cm is k cm3 / sec then k 
90. A given right circular cone has a volume p , and the largest right circular cylinder that can
8p
be inscribed in the cone has a volume q . Then 
9q
 KEY SHEET

PHYSICS

1) 1 2) 2 3) 1 4) 2 5) 2
6) 3 7) 1 8) 4 9) 3 10) 1
11) 3 12) 1 13) 1 14) 4 15) 3
16) 1 17) 3 18) 4 19) 3 20) 2
21) 4 22) 225 23) 120 24) 10 25) 16
26) 4 27) 14 28) 8 29) 7 30) 200

CHEMISTRY

31) 2 32) 1 33) 4 34) 1 35) 4

36) 3 37) 4 38) 1 39) 3 40) 4
41) 1 42) 2 43) 4 44) 1 45) 1
46) 4 47) 1 48) 1 49) 4 50) 3
51) 12 52) 2 53) 7 54) 2 55) 8
56) 6 57) 13 58) 5 59) 5 60) 6

MATHEMATICS

61) 4 62) 2 63) 3 64) 2 65) 3

66) 3 67) 1 68) 3 69) 4 70) 2
71) 1 72) 1 73) 4 74) 1 75) 2
76) 2 77) 1 78) 1 79) 1 80) 2
81) 27 82) 6 83) 198 84) 3 85) 4
86) 3 87) 25 88) 67 89) 192 90) 2
 SOLUTIONS
PHYSICS
1. Here, u  u m / s, a  g  10 m / s 2 and s  80 m
1
Substituting the values in s  ut  ar 2 , we have
2
80  ut  5t 2
5t 2  ut  80  0
u  u 2  1600 u  u 2  1600
t and
10 10
u  u  1600 u  u 2  1600
2
Now, it is given that  6
10 10
u 2  1600
6 or u 2  1600  30
10
u 2  1600  900
 u 2  2500
u  50 m / s
Ignoring the negative sign, we have u  50 m / s
2. change in velocity = area under a-t graph
1
Hence, v f  vi   4  4   8 m / s
2
 v f  vi  8   2  8  m / s  10 m / s
dt
3.   2 x   
dx
dx  1 
 v 
dt  2 x   
dv  1  dx
a  2  .
dt  2 x    dt
2  v 2   v   2 v 3
4.

1
From h  gt 2
2
2h0 A 2 1960
We have, tOB    20 s
g 9.8
5
Horizontal distance AB  utOB   600  m / s   20 s   3333.33 m  3.33 km
18  
5. s  H 2  R2 / 4

u 2 sin 2 
H
2g
u 2 sin 2
R
g
 R 
2

2 H 2    
S S 25  2 
Average velocity      
t T /2 T T
6.

In instance 20, we have found a2  a2  2a1  0

Similarly, we can find v2  v3  2v1  0
Taking, upward direction as positive we are given:
v1  v2  1 m / s
 v3  3 m / s
i.e., velocity of block 3 is 3 m/s (downwards).
7. f max   mg  0.3  4 10  32N
At t  2s F  kt 2

F  2  2  8 N
2

f  f max
f  8N
8. Conceptual
9. a sin   g cos 
a  g cot 
 a
 cos   a  g cot 
b
10. Acceleration of block with respect to lift

m  g  a  sin 
ar    g  a  sin 
m
1 2
S ar t
2

2S 2L
 t 
ar  g  a  sin 

11.
 A max  0.5 g  4.9m / s 2
For moving together

Fmax  mT  A  12  4.9  58.8 N

12.
a    g  0.5  9.8  4.9m / s 2
v 2 19.6 19.6
d   39.2 m
2a 2  4.9 
13.
mg sin   mg cos  tan    1
2

5
1

2
The height h from the bottom, h  R  R cos 
 2  R
h  R  R    1 0.105   0.11m
 5 5

14.
N  mg  ma
mg
According to question N 
4
mg
 mg  ma
3
1 
mg   1  ma
3 

a2g
3
dm 10 g  cm 
15. F v  2.5   5dyne
dt 5s  s 
16. Velocity at maximum height of vertically projected body is 0
17. Let projection speed is u
u 2 sin  300  u 2 sin  600  R1 1/ 2 1
R1  ; R2    
g g R2 3/2 3
18. Conceptual
1
19. Using, s  ut  at 2
2
1
4.9   9.8  t 2  t  1 sec
2
In 1 sec the ball will reach the surface of water now using, v 2  u 2  2as
 v 2  0  2  9.8  4.9   v  9.8 m / s
Then in water journey = 5-1 = 4 sec
h  vt  9.8  4  39.2 m metres
20. Force equation for the rocket
Fthurst   dm .vret 
 dt 
 dm   dm 
 vret  mg   ma   3 3
  500  10  10  10  20
 dt   dt 
dm
Rate of fuel burning   60kg / s 
dt
21. Given: the time of ascent is half of its time of descent.
1
ta  td
2

2s 1 2s
 ............ 1
aa 2 ad

g 3
aa  g sin    g cos    g
2 2

g 3
ad  g sin    g cos   g
2 2
Using the above values of aa and ad and putting in Eq. (i), we
3
Will gate  
5
22. Mass per unit length = 
N=mg=  (L-x)g
f s ,max   s N

f s ,max   0.25    L  x  g

And also f s ,max  ms g

0.25  L  x  g   xg

L  x  4x
 L  5x
L 15
x   3m
5 5
23. For reaching just opposite end,

12sin   vr
1
sin      300
2
   1200
 
24.    
A  2i  3 j  k m and B  i  2 j  2k m
 
    A.B 26 2 10
Component of A along B  A.B    2 2 2   3.33
B 1 2 2 3

25. Impulse = change in momentum  m v   v    2mv  2  0.5 16  16 Ns

26. Since, all the blocks will move with same acceleration (say a) in horizontal direction.
Let us take all the blocks as a system.

Net external force on the system is 12 N in horizontal direction.

Using  Fx  mxx ,
12
We get, 12   3  2  1 a  6a Or a   2 m / s2
6
Now, let F be the net force on 2 kg block in x-direction, the using  Fx  max for 2kg block,
We get F   2  2   4 N
27. At 450 , range is maximum. At highest point, it has only horizontal component of velocity
or 20cos 450  14m / s
28. In the figure, N 2 is always equal to w or 250 N
  Maximum value of friction available at B is  N 2 =(0.3) (250) = 75 N.
1
29. Using s  ut  at 2 in vertical direction
2
1
 70   50sin 300  t   10  t 2
2
On solving this equation, we get
t  7s
9 3
30.  tan 37 0 
a 4
 a  12 m / s 2
Let N = normal reaction between rod and wedge. Then N sin 370 will provide the
necessary ma force to the wedge
g m/s

N sin 
a
0
37

37 0 N cos 

 N sin 37 0  ma  10 12   120

120 120
 N 0
  200 N
sin 37 0.6
 CHEMISTRY
31. Species Hybridisation
ICl2 sp 3d
ICl4 sp 3d 2
BrF2 sp 3d
IF6 sp 3d 3

32.

 Total number of lone pair of electrons is 9.

33. Isoelectronic species have same number of electrons and isostructural species have same
type of hybridization at central atom.
NO3 ; No.of e   7  8  3  1  32, hybridization of N in


NO3is sp 3
CO32 ; No, of e   6  8  3  2  32 , hybridisatio of C in
CO32 is sp 3
ClO3 ; No, of e   17  8  3  1  42 , hybridization of Cl in
ClO3 is sp 3
SO3 ; No, of e   16  8  3  40 , hybridization of S in SO3 is sp 2
 NO3 and CO32 are isostructural and isoelectonic.

1
34. H  V  M  C  A were H=No. of orbitals involved in hybridization (viz. 2,3,4,5,6) and
2
hence, nature of hybridization (viz. sp 2 , sp 3 , sp 3d , sp 3d 2 ) can be ascertained.
V=No. of electrons in valence sheel of the central atom, M=No. of monovalent atoms,
C=Change on cation, A=Charge on anion,
1
For ClO2 . we have, H   7  0  0  1
2
1
 H   7  1  4 or sp 3 hybridization as 4 orbitals are involved
2

35. According to not the electronic configuration of O2 ion is

 1s 2 *1s 2 2s 2 * 2s 2 2 pz2 2 px2   2 p y2 * 2 px2   * 2 p1 y
10  7
Bond order   1.5
2
It is also exhibit paramagnetic character due to the presence of unpaired electrons.
36. Li2   1s 2 *1s 2 2 s 2
 Bond order

37. Conceptual

38. Alc.KOH performs dehydrohalogenation

39. Na in liq.ammonia trans alkene by syn addition

40. Side chain oxidation

41. Does not follows (4n+2) electons and ring is not planar

42. Benzene and ethyne gives Glyoxal on ozonolysis.

43. Conceptual

44. Conceptual

45. Conceptual
Br
4

2
1 5
3
46.

47. Both byproducts are gases

48. RCOOAg  Br2  R  Br  CO2  AgBr

49. Conceptual

50. Conceptual

51. Conceptual

52. Conceptual

53. H 2 , Li2 , Be2 , C2 , N 2 , F2 , O22

54. Conceptual

55. Conceptual
CH 3

O
56.
 H
H

H C H

H
H H

57. H





58. 


O O O
|| || ||
F ; CH CH COH, ; S C2H5; N  O , CH CHCOH
..
59.

60. ABDEFG Highly deactivating and highly activating groups which form complex AlCl3 do
not give Fridealcrafts reactions
 MATHEMATICS
61. Give V   r 2 h.
Differentiating both sides, we get
dV  dh dr   dh dr 
   r2  2r h    r  r  2h 
dt  dt dt   dt dt 
dr 1 dh 2
 and 
dt 10 dt 10
dV   2  1  r
  r  r     2h      r  h 
dt   10   10   5
Thus, when r  2 and h  3 ,
dV   2  2
  2  3 
dt 5 5
62. f  x   x kx  x 2
 k  2x x 2  kx  x 2   kx  2 x 2 3kx  4 x 2 x  3k  4 x 
f '  x   kx  x 2
   
2 2
2 kx  x 2 kx  x 2
2 kx  x 2 kx  x 2
f  x  is increasing for x   0, 3 .
So, f '  x   0x   0,3  kx  x 2  0, x  0,3 and x  3k  4 x   0, x   0,3
 x  x  k   0, x   0,3 and x  4 x  3k   x   0,3  k  4  m  4
Maximum f  x  when k =4 is
3 4  3  32  3 3  M .
 m, M    4,3 3 
dy
63.  3 x 2  2ax  1
dx
dy
Given that  0 Or 3 x 2  2ax  1  0 for all x
dx
Or D  0 or 4a 2  12  0 Or  3  a  3
 4 x 12 x 180 x 31
 x  2x  7 
3 2

64. f ' x   e 2

 12 x 2
 24 x  180   2  x  1 
 4 x 12 x 18031
 
3 2

f ' x   e 12  x  1  6)
2

 x  5  x  3  2  x  1)
Clearly, for x   3,0 , f  x   0.
So, f  x  is decreasing function on [-3, 0].
Therefore, the absolute maximum value of the function f  x  is at
x  3 .
   3
65. Since f  x  is a polynomial function, it is continuous and differentiable in [0,1].
Now, f  0   11, f 1  1  4  8  11  16
f '0 x  3 x 2  8 x  8
 f 1  f  0  16  11 8  2 7 1 7
 f ' c     3c 2  8c  8  5  3c 2  8c  3  0  c  
1 0 1 6 3
4 7
 c   0,1
3
x2
2
66. f  x    , x  0
 x
 log e f  x   x 2  log e 2  log e x   f '  x   0
   x   log e , 2  log e x  2 x   0  log e  x / 2   1/ 2  x / 2  e 1/2
2
x , point of maxima.
e
4
2
 2 e
So, local maximum value =    e e
 2/ e 
67. Surface area of the balloon is
S  4 r 2 , where r is the radius.
dS dr
  8 r   k (constant)  8 r dr  kdt
dt dt
Integrating, we get
4 r 2  kt  C ............. 1
For t  0, r  3  36  C
So, (1) reduces to
4 r 2  kt  36
For t  5, r  7 .............  2 
 196  5k  36  k  32
So, (2) reduces to
4 r 2  32 t  36  r 2  8t  9
At t  9 seconds, r 2  81 .
So, r  9
68. Given that
f  2   8, f '  2   5, f '  x   1, f " x   4, x  1,6 
f  5  f  2
f ' x   1  f  5   11 ............ 1
52
f '  5  f '  2 
f " x    4  f '  5   17 ............  2 
52
 f  5   f '  5   28
69. Let at any time t, the length of each edge of the cube be x cm. Let S denote the surface
area and V be the volume of the cube.
Then
dS dx dV dx
S  6 x 2 and V  x 3  12 x and  3x 2
dt dt dt dt
dx dV 2 dx
 2  12  90 and  3  90 
dt dt dt
  dS 
 x  90 cm and dt  2 
dx 1 dV  dx 
 90   and  3  90   90  
dt 6 dt  dt 
dV 1
  3  90  cm3 / sec  45cm 2 / sec.
dt 6
70. Let g  x   4 x3  12 x 2  11x  3
 g '  x   12 x 2  24 x  11  12  x  1  1
2

 0 for x   2,3
Thus, g  x  is increasing in [2,3]
f  x max  f  3  log10  4.27  12.9  11.3  3   log10  30   1  log10 3
1 1
71. m1  , m2
2 2
m1  m2
tan  
1  m1m2
3  1  3
72. Slope of 3x  2 y  1 is  f '  
2 2 2
x  x  1 2x 1 1 1
 lim  lim  
x 0 2
e  x 2 x 2
 e  x  0 2 x .  e  2 x
x 2 x
2  1 1 3
f  f   e f ' e f '  f '   f ' 
 2   2   2   2  2  2
dy
73. m1   270 x 4  50 x 3  210 x 2  360 x  210
dx
1
m2  
90
1
m1m2  1  m1  
m2
270 x 4  50 x3  210 x 2  360 x  210  90

9 x 4  18 x 3  7 x 2  12 x  4  0

By observation, two roots are 1 and 2

2 1
By using Horner’s method other two are ,
3 3

So there will be four normals

74. We must have f 1  f  2   1  a  b  4  8  4a  2b  4  3a  b  7 ........1

4
Also f '    0 (given)   3 x 2  2ax  b  4  0
3 x
3
16 8a
   b  0  8a  3b  16  0
3 3
Solving (1) and (2), we get …………...(2)
 a  5, b  8
75. For Rolle’s theorem and LMVT, f  x  must be continuous in  a, b  and differentiable in
(a,b). Hence, Statement-I is true.
 
Since f  x  | sin | x || in   ,  is non-differentiable at x  0 . Hence Statement-II is also
 4 4
true.
76. a  2 R sin A
da dA
 2 R cos A
dt dt
dA dA
3R  2 R cos A
dt dt
3
cos A 
2

A
6
dx dy
77. x 2  y 2  20  2 x  2y  0
dt dt
dy
 1.5 ; y  4, x  2
dt
4 x3  3x 2
78. f  x   2sin x   2 x  1 cos x
6
f '  x    2 x 2  x   2 cos x  2 cos x   2 x  1 sin x   2 x  1 x  sin x 
For x  0, x  sin x  0
For x  0, x  sin x  0

For x   ,0   ,   , f '  x   0

1 
2 
 1
For x   0,  , f ' x  0
2  
1 
Thus, f  x  increases in  ,  
2 
 1 
79. f ( x)   tan 1 x  f '  x    2
 0 for all x . So the greatest value is f (0)  and least
4 1 x 4
value is f (1)  0 .
80. f  x    x  8   x  9  ,0  x  10
4 5

 f '  x   4  x  8   x  9   5  x  9   x  8    x  8   x  9   4  x  9   5  x  8  
3 5 4 4 3 4

4 76 
 9  x  8  x  9   x  
3

 9 
Sign scheme of f '  x  is as follow:
_
+ + +

8 76/9 9

 76   76 
f '  x   0 if x   8,  , i.e., f  x  decreases if x   8,  .
 9   9 
 dy 2 1  sin t   cos t
81. 
dx 1  cos 2 t  sin 2 t
dy 2 1  sin t  cos t 1  sin t 
  2
 3  given    3  t   y0  27 .
dx 2 cos t cos t 6
82. Given curves S1; x  y and S 2 : xy  k
4

dy 1
For S1,  3  m1
dx 4 y
dy  y 2
For S2 ,   m2
dx k
Curves intersect orthogonally.
 1  y2  1
 m1m2  1   3      1  y 
 4 y  k  4k
1
Putting this value in S1, we get x 
 4k 
4

Putting the values of x and y in S2 , we get

1 1
 k or  4k   4  2   4k   6
6 6
.
 4k 
4
4k
83. y  5 x 2  2 x  25
 y '  10 x  2  y '  x  2   22
So, the equation of tangent at P  2, 1 is
y  22 x  45 ............1
Now, y  x 3  x 2  x
y '  3x2  2 x  1
y ' xa  3a 2  2a  1  22.............  2 
 
For common tangent
Also  a, b  lies on the curve
y  x3  x2  x
 b  a 3  a 2  a..........  3
 2   a  3,  3  b  21
3a  9b   198

84.

In DBE , tan 600 

2b
b
3 2 2 l  
2 2 l 2
3
Area of rectangle, A  l 
2

2 2 l 
 dA 3
dl

2

2 2  2l  0 
l 2
3
 Amax  2 
2

2 2 2  3 
dy 2
85. For parabola y 2  4 x, 
dx y
 dy 
   1
 dx 1,2
So, equation of normal to parabola y 2  4 x at point (1, 2) is
y  2  1 x  1 Or x  y  3  0
It meets x-axis is at A  3,0  .
Now, tangent to the curve y  e x at point p  c, ec  passes through the point A(3, 0)
c
 dy  e
    ec  c4
 dx  p c3
dx dy
86. We have   1   1
dy dx
dy x
From curve,   1  x  4 y
dx 4 y
1 4
16 y 2  4 y 2  4 Or y   x  
3 3
dx 1
 sub  tangent  y. 
dy 3
 k 3
87. Tangent
t 3  3th  2k  0...........(1) .
Product of the roots  2k
t1t2t3  2k
Put t1t2  1 then t3  2k
(1)   2k   3  2k  h  2k  0
3

4k 2  3h  1  0
Locus of  h, k  4 y 2  3x  1
a 2  b 2  42  32  25
 P  x 
88. lim  3  2   4
x 0
 x 
P  x
lim 3
 6  P  x   ax5  bx 4  6 x 3
x 0 x
P '  1  0  5a  4b  18  0..........(1)
P ' 1  0  5a  4b  18  0..........(2)
18
1 &  2  a ,b  0
5
 18 5
P  x  x  6 x3
5
 P  2    67 .
 

89.
Let A be the vertex and AO axis of the cone. Let O’A=h be the depth of water in the
cone.
In AO ' C ,
O 'C h
tan 300  or O ' C   radius
h 3
1 1  h2 
V=Volume of water in the cone    O ' C   AO '      h
2

3 3  3
 dV  2 dh
V h3 Or  h 1
9 dt 3 dt
But given that depth of water increases at the rate of 1 cm/s. So,
dh
 1 cm / s  2
dt
dV  h 2
From (1) and (2), 
dt 3
When h  24 cm, the rate of increases of volume is
dV   24 
2

  192cm3 / s
dt 3

90.
Let H be the height of the cone and  be its semi vertical angle. Suppose that x is the
radius of the inscribed cylinder and h be its height h  QL  OL  OQ  H  x cot 
V  volume of the cylinder
  x 2  H  x cot  
1
Also p    H tan   H ...............(1)
2

3
dV
   2 Hx  3x 2 cot  
dx
dV
So,  0  x  0,
dx
 2 d 2V
x H tan  , 2  2 H  0.
3 dx 2
x  H tan 
3

2 4
V is maximum when x  H tan  and q  Vmax   H 2
3 9
1 4
tan 2  H  p. [using (i)]
3 9
Hence p : q  9 : 4 .