Revision Test For JEE Main-2019

(FOR CLASS XIIth APPEARING/PASS STUDENTS)

Test-2 [Unit-2]
[JEE Main Pattern] Series-A
Physics, Chemistry & Mathematics
Time : 3 Hours Maximum Marks : 360
SYLLABUS
Physics : Gravitation, Simple Harmonic Motion, Properties of Matter, Fluid Mechanics, Calorimetry, Kinetic Theory of Gases,
Thermodynamics, Heat Transfer, Thermal Expansion.
Chemistry : Surface Chemistry, Chemical Kinetics, Chemical Equilibrium, Ionic Equilibrium, Chemical Energetics, Gaseous State.
Mathematics : Indefinite Integration, Definite Integration, Area Under the Curve, Differential Equation, Point, Straight Line, Circle.

IMPORTANT INSTRUCTIONS
GENERAL :

1. This paper contains 90 Qs. in all. All questions are compulsory.

SEAL
2. There is Negative Marking. Guessing of answer is harmful.

3. The question paper contains blank space for your rough work. No additional sheet will be provided for rough work.

4. The answer sheet, machine readable Optical Mark Recognition (OMR) is provided separately.

5. Do not break the seals of the question paper booklet before being instructed to do so by the invigilator.

6. Blank papers, Clipboards, Log tables, Slide Rule, Calculators, Cellular Phones, Pagers & Electronic Gadgets in any form are not
allowed to be carried inside the examination hall.

MARKING SCHEME:

1. Each Question has four options, only one option is correct. For each incorrect response, one-fourth of the weightage marks
allotted to the question would be deducted.

2. In Physics : Q. 1 - 30 carry 4 marks each,

In Chemistry : Q. 31 - 60 carry 4 marks each,

In Mathematics : Q. 61 - 90 carry 4 marks each,

RTS/Main-Adv.(FR & TR/19/Test-2(A)/PCM

CAREER POINT: CP Tower, Road No. 1, IPIA, Kota (Raj.), Ph: 0744-6630500 | www.careerpoint.ac.in
 PHYSICS
Q.1 A uniform solid sphere (A) is surrounded Q.1 ,d le:Ik Bksl ls xksyk (A) ,d le:Ik irys
symmetrically by a uniform thin spherical shell xksyh; dks'k (B) ls lefer iwoZd ifjc} gSA nksuka
(B) of equal mass but twice its radius (i.e. rB = xksyks dk nzO;eku leku gS ysfdu dks'k dh f=kT;k
2rA). The gravitational field g is plotted as a
Bksl xksys ls nqxquh gS (vFkkZr rB = 2rA). xw:Roh; {ks=k
function of the distance from the center of the
g dks Bksl xksys ds dsanz ls nwjh (r). ds Qyu ds :Ik
solid sphere (r). Which of the following shows
esa vkjsf[kr fd;k x;k gS rks fuEu esa ls dkSulk lgh
the correct plot?
gS ?

g
g
(1)
(1)
O rA rB r
O rA rB r

g
g
(2)
(2)
O rA rB r
O rA rB r

g
g
(3)
(3)
O rA rB r
O rA rB r

g
g
(4)
(4)
O rA rB r
O rA rB r

CAREER POINT 22
SPACE FOR ROUGH WORK / jQ dk;Z ds fy, txg
Q.2 Two stars of masses m1 and m2 distance r apart , Q.2 nks rkjksa ds nzO;eku Øe'k% m1 o m2 gS ;g r nwjh ls
revolve about their centre of mass. The period of i`Fkd gS ;g buds nzO;eku dsanz ds ifjr% ifjØe.k
revolution is dj jgs gSA ifjØe.k dk vkorZdky gS –
r3 r 3 (m1 + m 2 ) r3 r 3 (m1 + m 2 )
(1) 2π (2) 2π (1) 2π (2) 2π
2G (m1 + m 2 ) 2Gm1m 2 2G ( m 1 + m 2 ) 2Gm1m 2
2r 3 r3 2r 3 r3
(3) 2π (4) 2π (3) 2π (4) 2π
G (m1 + m 2 ) G (m1 + m 2 ) G (m1 + m 2 ) G (m1 + m 2 )

Q.3 A planet of mass m is moving in an elliptical Q.3 ,d xzg dk nzO;eku m gS ;g lw;Z ds ikfjr% (nzO;eku
orbit round the sun (mass M) as shown in the
M) ,d nh?kZo`rh; d{kk esa xfr dj jgk gS n'kkZ;s
figure. Then the angular momentum of the planet
may be written as vuqlkj] rks xzg dk dksf.k; laosx gS &

r1 M r2
A B r1 M r2
Sun A B
Sun

m Planet
m Planet
GMm 2GM(r1 .r2 )
(1) L = (2) L = m
(r1 + r2 )1 / 2 r1 + r2 (1) L =
GMm
(2) L = m
2GM(r1 .r2 )
(r1 + r2 )1/ 2
r1 + r2

(r1 + r2 ) (r1 + r2 )
(3) L = (4) L = 0 (3) L = (4) L = 0
GMr1r2 GMr1r2

Q.4 A small ball of density 4ρ0 is released from rest Q.4 ,d y?kq xasn dk ?kuRo 4ρ0 gS bls ,d nzo lrg ds
just below the surface of a liquid. The density of Bhd uhps fojke ls NksMk x;k gSA nzo dk ?kuRo
liquid increases with depth as ρ = ρ0 (1 + ay) xgjkbZ ds lkFk ρ = ρ0 (1 + ay) ds vuqlkj c<rk gS
where a = 2m–1 is a constant. Find the time tgk¡ a = 2m–1 ,d fu;rkad gS blds nksyuksa dk
period of its oscillation - (Neglect the viscosity vkorZdky Kkr dhft;s - (';kurk izHkko dks ux.;
effects) ekusa)
2π π 2π π
(1) sec (2) sec (1) sec (2) sec
5 5 5 5
π 3π π 3π
(3) sec (4) sec (3) sec (4) sec
2 5 2 5 2 5 2 5
CAREER POINT 33
SPACE FOR ROUGH WORK / jQ dk;Z ds fy, txg
Q.5 A rod of mass 'm' and length l is connected by Q.5 ,d NM+ dk nzO;eku 'm' o yEckbZ l gS bls k1 o k2
two springs of spring constant k1 and k2, so that it fLiazx fu;rkad dh nks fLizaxksa }kjk la;ksftr fd;k x;k
is horizontal at equilibrium. What is the natural gS] rkfd ;g {kSfrt fLFkfr esa larqyukoLFkk esa jgs
frequency of the system ?
fudk; dh ewy vko`fr D;k gS\

k1
k1

b
b
l
k2 l
k2

1 k1b 2 + k 2l 2 1 2k1b 2 + k 2l 2
(1) (2) 1 k1b 2 + k 2l 2 1 2k1b 2 + k 2l 2
2π ml 2π ml (1) (2)
2π ml 2π ml
1 k1b 2 + k 2l 2 1 3(k1b 2 + k 2l 2 )
(3) (4) 1 k1b 2 + k 2l 2 1 3(k1b 2 + k 2l 2 )
2π 2ml 2π ml (3) (4)
2π 2ml 2π ml

Q.6 Figure shows a system consisting of two Q.6 uhps n'kkZ;k fp=k ,d fudk; tks nks nzO;ekughu iqyh
massless pulley, two springs of force constant k j[krk gS dks n'kkZrk gS nksuksa fLizaxks ds fLizax fu;rkad
and a block of mass m. Frequency of small k gS o CykWd dk nzO;eku m gSA CykWd ds y?kq nksyuksa
oscillation of the block is
dh vko`fr gS
5k
(1) 2π 5k
m (1) 2π
m
1 5k
(2) 1 5k
2π m (2)
2π m
1 k
(3) 1 k
2π 5m (3)
2π 5m
1 k
(4) m 1 k
2 π 2m (4) m
2 π 2m

CAREER POINT 44
SPACE FOR ROUGH WORK / jQ dk;Z ds fy, txg
Q.7 A particle A is attached to a spring and the time Q.7 ,d d.k A dks ,d fLizax ls layXu fd;k x;k gS o
period for small oscillations is observed to be T;
y?kq nksyuks ds fy;s iszf{kr vkrZdky T gksxk tc dm
when an additional mass dm is added on, the
time period becomes T + dT. The mass of vfrfjDr nzO;eku dks blls la;ksftr fd;k tkrk gS
particle A is vorZdky T + dT gks tkrk gSA d.k A dk nzO;eku gS
–1
⎧⎪ dT ⎛ dT ⎞ 2 ⎫⎪
–1
⎧⎪ dT ⎛ dT ⎞ 2 ⎫⎪
(1) dm ⎨2 +⎜ ⎟ ⎬ (1) dm ⎨2 +⎜ ⎟ ⎬
⎪⎩ T ⎝ T ⎠ ⎪⎭ ⎪⎩ T ⎝ T ⎠ ⎪⎭
–1
⎧⎪ dT ⎛ dT ⎞ ⎫⎪
2
⎧⎪ dT ⎛ dT ⎞ ⎫⎪
2
–1

(2) dm ⎨2 + 2 +⎜ ⎟ ⎬ (2) dm ⎨2 + 2 +⎜ ⎟ ⎬
⎪⎩ T ⎝ T ⎠ ⎪⎭ ⎪⎩ T ⎝ T ⎠ ⎪⎭
–1
⎧ dT ⎫ ⎧ dT ⎫
–1
(3) dm ⎨2 ⋅ ⎬ (3) dm ⎨2 ⋅ ⎬
⎩ T⎭ ⎩ T⎭
(4) none of these (4) buesa ls dksbZ ugha
πt π
Q.8 A 2.0 kg particle undergoes SHM according to Q.8 ,d 2.0 kg d.k] x = 1.5 sin ⎛⎜ + ⎞⎟ ds vuqlkj
⎛ πt π ⎞ ⎝4 6⎠
x = 1.5 sin ⎜ + ⎟ (in SI units). What is the
⎝ 4 6⎠ SI ek=kd eas] SHM dj jgk gS. d.k dks x = 0.75 m
shortest time required for the particle to move ls x = – 0.75 m rd xfr djus esa yxk U;wUkre le;
from x = 0.75 m to x = – 0.75 m? D;k gS ?
6 4 9
(1) s (2) s (3) s (4) None 6 4 9
5 3 3 (1) s (2) s (3) s (4) dksbZ ugha
5 3 3
Q.9 An assembly of identical spring mass system is Q.9 ,d ,dleku fLizax nzO;eku fudk; dk ,d la;kstu
placed on a smooth horizontal surface as shown. ,d fpduh {kSfrt lrg ij fLFkr gS n'kkZ;svuqlkj
Initially the springs are relaxed. The left mass is vkjfEHkd :Ik ls fLizax eqDr FkhA ck;s nzO;eku dks
displaced to the left while the right mass is ck;h vksj foLFkfir fd;k tkrk gS tcfd nk;s nzO;aeku
displaced to right by two times more than the left dks nk;h vksj] ck;h fLizax dh rqyuk esa nks xquk vf/kd
spring and both are released. The resulting foLFkkfir fd;k tkrk gS o nksuksa dks NksMk tkrk gS
collision is elastic. The time period of the ifj.kkeh VDdj nzO;kLFk gSA fudk; ds nksyuks dk
oscillation of the system is
vkorZdky gSA
k k
m m k k
m m
2M M 2M M
(1) 2π (2) 2π (1) 2π (2) 2π
k 2k k 2k
M M M M
(3) 2π (4) π (3) 2π (4) π
k k k k
CAREER POINT 55
SPACE FOR ROUGH WORK / jQ dk;Z ds fy, txg
Q.10 A block P of mass m is placed on a frictionless Q.10 m nzO;eku dk ,d xqVdk P ?k"kZ.k jfgr {kSfrt lrg
horizontal surface. Another block Q of same ij j[kk gSA leku nzO;eku okyk ,d vU; xqVdk Q,
mass is kept on P and connected to the wall the P ij j[kk gS vkSj fp=kkuqlkj fLiazx fu;rkad k okyh
help of a spring of spring constant k as shown in fLizax dh lgk;rk ls nhokj ls tqM+k gSA P vkSj Q ds
the figure. μs is the coefficient of friction chp ?k"kZ.k xq.kkad μs gSA xqVds ,d lkFk pyrs gq,
between P and Q. The blocks move together
vk;ke A dh ljy vkorZ xfr djrs gSaA P vkSj Q ds
performing SHM of amplitude A. The maximum
chp ?k"kZ.k cy dk vf/kdre eku gS :
value of the friction force between P and Q is -
k
μs
Q
fpduh
k μs
Q P
P smooth
kA
(1) kA (2)
kA
(3) zero (4) μ2mg (1) kA (2) (3) 'kwU; (4) μsmg
2 2

Q.11 What is the velocity v of a metallic ball of radius Q.11 ,d /kkfRod xsan ftldh f=kT;k r gS ;g ,d nzo ds
r falling in a tank of liquid at the instant when its VSad esa fxj jgh gS] bldk osx v, ml {k.k ij D;k gS
acceleration is one half that of a freely falling body ?
(The densities of metal and of liquid are ρ and
tc bldk Roj.k eqDr :Ik ls fxjrh oLrq ds Roj.k
σ respectively and the coefficient of viscosity of the dk vk/kk gS ? (/kkrq dk ?kuRo ρ o nzo dk ?kuRo σ gS
liquid is η) - rFkk nzo dk ';kurk xq.kkad η) gS –
r2g r2g r2g r2g
(1) (ρ – 2σ) (2) (2ρ – σ) (1) (ρ – 2σ) (2) (2ρ – σ)
9η 9η 9η 9η
r2g 2r 2 g
(3) (ρ – σ) (4) (ρ – σ) r2g 2r 2 g
9η 9η (3) (ρ – σ) (4) (ρ – σ)
9η 9η
Q.12 A solid cylinder of mass m, length l and area of Q.12 ,d Bksl csyu dk nzO;eku m o yEckbZ l o vuqizLFk
cross section A is placed as shown in the figure. dkV {ks=kQy A gS ;g fp=k esa n'kh;a vuqlkj fLFkr
If Young's modulus is Y then strain energy stored
gSA ;fn ;ax xq.kkad Y gS rks csyu esa laxzfgr fod`fr
in the cylinder is-
ÅtkZ gS-
l
l

m 2g 2l m 2g 2l m 2 g 2l m 2g 2l
(1) (2) (3) (4) m 2g 2l m 2 g 2l m 2g 2l m 2 g 2l
3AY 6AY 2AY AY (1) (2) (3) (4)
3AY 6AY 2AY AY
CAREER POINT 66
SPACE FOR ROUGH WORK / jQ dk;Z ds fy, txg
Q.13 A wire of cross-sectional area A. Young's Q.13 ,d rkj dk vuqizLFk dkV {ks=kQy A gSA ;gk¡ xq.kkad
modulus Y and certain length is suspended from Y o rkj dh ,d fuf'pr yEckbZ dks blds fljks ij
two horizontal rigid supports at the end. A mass nks {kSfrt n`< vk/kkjksas ls fuyafcr fd;k tkrk gSA ,d
m is suspended at midpoint of wire. Find angle θ
m nzO;eku dks rkj ds e/; fcanq ls fuyafcr fd;k
(assumed to be very small) in radian made by the
tkrk gSA rkj ds var fljs }kjk larqyukoLFkk fLFkfr esa
end of wire with horizontal at equilibrium
{ksfrt lls cuk;k dks.k (ekuk fd cgqr y?kq gS)
position.
jsfM;u esa Kkr djsa

θ θ

m m
1 1
⎛ 2mg ⎞ 2 ⎛ mg ⎞ ⎛ 2mg ⎞ 2 ⎛ mg ⎞
(1) ⎜ ⎟ (2) ⎜ ⎟ (1) ⎜ ⎟ (2) ⎜ ⎟
⎝ AY ⎠ ⎝ 2AY ⎠ ⎝ AY ⎠ ⎝ 2AY ⎠
1 1
⎛ mg ⎞ 3 ⎛ mg ⎞ 3
(3) ⎜ ⎟ (4) none of these (3) ⎜ ⎟ (4) buesa ls dksbZ ugha
⎝ AY ⎠ ⎝ AY ⎠

Q.14 An air bubble of radius r rises steadily through a Q.14 ,d ok;q cqycqys dh f=kT;k r gS ;g ρ ?kuRo ds nzo ls
liquid of density ρ at the rate of v. Neglecting
fu;r :Ik v pky ls mij mBrk gSA ok;q ds ?kuRo dks
density of air, the coefficient of viscosity of
liquid is ux.; ekus rks nzo dh ';kurk dk xq.kkad gS –

ρ ρ
v v

1 r 2 ρg 1 r 2 ρg 1 r 2 ρg 1 r 2 ρg
(1) (2) (1) (2)
9 v 3 v 9 v 3 v
1 r 2 ρg 2 r 2 ρg 1 r 2 ρg 2 r 2 ρg
(3) (4) (3) (4)
9 v 9 v 9 v 9 v

CAREER POINT 77
SPACE FOR ROUGH WORK / jQ dk;Z ds fy, txg
Q.15 For the system shown in the figure, the cylinder Q.15 uhps fp=k esa n'kkZ;s fudk; ds fy;s cka;h vksj ds csyu
on left has a mass (M) of 25 kg and cross– dk nzO;eku (M), 25 kg o vuqizLFk dkV {ks=kQy 20
sectional area 20 cm2 and is connected to a cm2 gS ;g 1400 N/m fLizax fu;arkd dh ,d fLizax ls
spring of spring constant 1400 N/m. The piston
tqMk gSA nka;h vksj ds fiLVu dk nzO;eku m (= 5 kg)
on the right has mass m (= 5 kg) and cross-
o vuqizLFk dkV {ks=kQy 4 cm2 gSA m ij U;wure
sectional area 4 cm2. The minimum mass m′ to
fdruk nzO;eku m′ j[kk tkuk pkfg;s rkfd cka;h vksj
be kept on m so that water spills out from the left
is (g = 10 m/s2) (initially water level in both
ls ty ckgj vk tk;sA (g = 10 m/s2) (vkjfEHkd :i
limbs is same). ls nksuksa Hkqtkvksa esa ty leku Lrj ij gS).

K K
m′ m′

m 5 cm M m
5 cm M

(1) 1 kg (2) 1.4 kg (3) 0.7 kg (4) 2.5 kg (1) 1 kg (2) 1.4 kg (3) 0.7 kg (4) 2.5 kg

Q.16 In the adjoining figure the cross sectional area of Q.16 uhps n'kkZ;s fp=k esa NksVh ufydk dk vuqizLFk dkV
smaller tube is a and the target tube is 2a. A {ks=kQy a rFkk cM+h ufydk dk vuqizLFk dkV 2a gS
block of mass 2 m is kept in the smaller tube 2 m nzO;eku dk ,d CykWd] ftldk vuqizLFk dkV Hkh
have same base area a as that of the tube. The leku a gS NksVh ufydk esa j[kk x;k gS nksuksa
difference between water levels of the two tubes ufydkvksa esa ty Lrj esa varj gS
are (Where ρ is density of water and ρ0 (tgk¡ ρ ty dk ?kuRo o ρ0 ok;qe.Myh; nkc gS)
atmospheric pressure.)
2a 2a

a a
2m 2m

ρ0 m ρ0 m ρ0 m ρ0 m
(1) + (2) + (1) + (2) +
ρg aρ ρg 2aρ ρg aρ ρg 2aρ
m m m m
(3) (4) (3) (4)
aρ 2aρ aρ 2aρ

CAREER POINT 88
SPACE FOR ROUGH WORK / jQ dk;Z ds fy, txg
Q.17 A tube 1 cm2 in cross-section is attached to the Q.17 ,d ufydk dk vuqizLFk dkV {ks=kQy 1 cm2 gS ;g
top of a vessel 1 cm high and cross-section 100 ,d 1 cm Å¡ph o 100 cm2 vuqizLFk dkV ds ,d ik=k
cm2. Water fills the system upto a height of 100 ds mij layXu gSA ik=k ds isnsa ls 100 cm dh ÅapkbZ
cm from the bottom of the vessel. The force rd fudk; esa ty Hkjk x;k gSA nzo }kjk ik=k ds isnsa
exerted by the liquid at the bottom of the vessel
ij vkjksfir cy gS (g = 10 m/s2)
is : (g = 10 m/s2)
1 cm2
1 cm2

99 cm
99 cm

1 cm
1 cm
2
100 cm
100 cm2
(1) 1000 N (2) 990 N (1) 1000 N (2) 990 N
(3) 900 N (4) 100 N (3) 900 N (4) 100 N

Q.18 Two spherical balls of radius r1 and r2 (< r1) and Q.18 nks xksyh; xsanks dh f=kT;k r1 o r2 (< r1) o ?kuRo σ gS
of density σ are tied up with a long string and ;g ,d yach Mksjh }kjk ca/ks gS o bUgas ,d de ?kuRo
released in a viscous liquid column of lesser ρ ds ';ku nzo LrEHk esa fojke ls NksMk tkrk gSA bl
density ρ with the string just taut as shown. Find fLFkfr esa Mksjh <hd rU; gS n'kh;Z vuqlkjA Mksjh esa
the tension in the string when terminal velocity is ruko D;k gS tc vafre osx xzg.k dj fy;k tkrk gS -
attained -
r1
r1

r2
r2
3 ⎛⎜ r24 − r14 ⎞⎟
(1) π (σ – ρ) g
3 ⎛⎜ − ⎞⎟
r24 r14 4 ⎜⎝ r2 − r1 ⎟⎠
(1) π (σ – ρ) g
4 ⎜⎝ r2 − r1 ⎟⎠
2
2 (2) π(r24 – r14) (σ – ρ) g
(2) π(r24 – r14) (σ – ρ) g 3
3
4 4
(3) π (r24 – r13) (σ – ρ) g (3) π (r24 – r13) (σ – ρ) g
3 3
4 ⎛ r24 − r14 ⎞ 4 ⎛⎜ r24 − r14 ⎞⎟
(4) π⎜ ⎟ (σ – ρ) g
π (σ – ρ) g
3 ⎜⎝ r2 + r1 ⎟⎠ (4)
3 ⎜⎝ r2 + r1 ⎟⎠
CAREER POINT 99
SPACE FOR ROUGH WORK / jQ dk;Z ds fy, txg
Q.19 Heat is supplied to 2kg of solid (initially at Q.19 2kg Bksl dks fu;r nj 5kJ/min ls Å"ek lIykbZ dh tk
–20ºC) at the constant rate of 5kJ/min.
jgh gS (vkjfEHkd rki –20ºC) rki dks le; ds Qyu ds
Temperature is plotted as a function of time as
shown in the figure. Latent heat of fusion for :Ik uhps fp=k esa vkjsf[kr fd;k x;k gSA
solid is - Bksl ds xyu dh xqIr Å"ek gS &
θ(ºC)
θ(ºC)
50ºC
50ºC
40ºC
40ºC
30ºC
30ºC
20ºC
20ºC
10ºC
10ºC
2 4 5 t(min)
–10ºC t(min)
2 4 5
–10ºC
–20ºC
–20ºC
(1) 10 kJ/kg (2) 2.5 kJ/kg (1) 10 kJ/kg (2) 2.5 kJ/kg
(3) 5 kJ/kg (4) 7.5 kJ/kg
(3) 5 kJ/kg (4) 7.5 kJ/kg

Q.20 An experiment is performed to measure the Q.20 rkcsa dh fof'k"V m"ek ds ekiu ds fy;s ,d iz;ksx
specific heat of copper. A lump of copper is fd;k tkrk gSA rkcs ds ,d <sj dks ,d vkWou esa ghV
heated in an oven, then dropped into a beaker of
fd;k tkrk gS rc bls ty chdj esa NksMk tkrk gSA
water. To calculate the specific heat of copper,
the experimenter must know or measure the rkacs dh fof'k"V m"ek dh x.kuk ds fy;s iz;ksx drkZ
value of all of the quantities below EXCEPT the dks fdl ,d jkf'k dks NksMdj ckdh lHkh dks tkuuk
(1) heat capacity of water and beaker vko';d gksxk
(2) original temperature of the copper and the
(1) ty o chdj dh fof'k"V m"ek /kkfjrk
water
(2) rkacs o ty dk ewy rki
(2) final (equilibrium) temperature of the copper
and the water (2) rkacs o ty dk vafre (lkE;koLFkk) rki
(4) time taken to achieve equilibrium after the (4) rkacs dks ty esa NksMus ds Ik'pkr lkE;koLFkk
copper is dropped into the water
izkIr djus esa yxk le;
CAREER POINT 10
10
SPACE FOR ROUGH WORK / jQ dk;Z ds fy, txg
Q.21 A cubical vessel of edge 1 m and total thermal Q.21 ,d ?kukdkj ik=k dk fdukjk 1 m gSD o dqy rkih;
1 1
resistances (of its walls) is (where, R is izfrjks/k (bldh nhokjks dk) (tgka, R lkoZf=kd xSl
R R
universal gas constant) has a small hole in one of fu;rkad gS) ik=k ,d nhokj esa ,d y?kq fNnz j[krk
its walls. It is kept in a very big closed chamber
gSA bls ,d cgqr cMs psEcj esa j[kk x;k gS ftldk
whose temperature T0 remains constant. In the
chamber and vessel, a monoatomic gas is filled at rki T0 fu;r gSA psEcj o ik=k esa ,d ,dy ijek.kqd
a same constant pressure P0. At time t = 0, xSl fu;r nkc P0. ij Hkjh tkrh gS t = 0, le; ij
temperature of the gas in the vessel is ik=k esa xSl dk rki T1 (< 2T0/3). gS tc ik=k esa xSl
T1 (< 2T0/3). When temperature of the gas in the dk rki 0.8 T0, gks tkrk gS blesa eksyksa dh la[;k esa
vessel becomes 0.8 T0, rate of change of moles in
ifjorZu dh nj gksxh
it will be -
1 1 1 1
1 1 1 1 (1) (2) (3) – (4) –
(1) (2) (3) – (4) – 10 6 10 6
10 6 10 6
Q.22 Variation of internal energy with density of one Q.22 ,d eksy ,dy ijek.kq xSl dh vkarfjd ÅtkZ esa
mole of monoatomic gas is depicted in the ?kuRo ds lkFk ifjorZu dks uhps fp=k esa n'kkZ;k x;k
adjoining figure, corresponding variation of gSA lEcaf/kr nkc ds vk;ru ds lkFk ifjorZu dks
pressure with volume can be depicted as fdl fodYi }kjk lgh izdkj n'kkZ;k x;k gS (ekukfd
(Assuming the curve is rectangular hyperbola) oØ vk;rh; vfrijoy; gS)
U U

ρ ρ
P P
P P

(1) (2)
(1) (2)

v v
v v
P P P P

(3) (4) (3) (4)

v v v v
CAREER POINT 11
11
SPACE FOR ROUGH WORK / jQ dk;Z ds fy, txg
Q.23 Figure show the variation of internal energy U Q.23 uhps n'kkZ;k fp=k ,d Å"ekxfrdh; pØ ABCA ds
with the density of one mole of monoatomic gas fy, ,d eksy ,dy ijek.kqd xsl dh vkarfjd ÅtkZ
for a thermodynamic cycle ABCA. AB process is
U dks ?kuRo ds lkFk ifjorZu dks n'kkZrk gSA AB izØe
a rectangular hyperbola. The amount of work
,d vk;rh; vfrijoy; gSA izØe A → B esa fd;k
done in the process A → B is -
U
x;k dk;Z gS &
A C U
4U
4U A C

2U0 B
ρ 2U0 B
O 2ρ0 ρ
O 2ρ0
2U 0 2U 0
(1) (2) −
3 3 2U 0 2U 0
(1) (2) −
4U 0 4U 0 3 3
(3) (4) − 4U 0 4U 0
3 3 (3) (4) −
3 3

Q.24 1 mole of He and 2 moles of O2 are contained in Q.24 1 eksy] He o O2 ds 2 eksy ,d :)ks"eh; ik=k esa
an adiabatic cylinder at pressures and
fLFkr gS o blds nkc o rki uhps fp=k esa iznf'kZr gSA
temperatures as shown in figure. If the adiabatic
partition wall is removed then the final pressure ;fn :)ks"eh; foHkktd dks gVk fn;k tkrk gS rks
will be vafre nkc gksxk
Adiabatic
partition wall Adiabatic
partition wall

1 mole He 2 mole O2
P0′ Τ0 P0, Τ0/2 1 mole He 2 mole O2
P0′ Τ0 P0, Τ0/2

12 13
(1) P0 (2) P0 12 13
13 16 (1) P0 (2) P0
13 16
(3) P0 (4) None of these
(3) P0 (4) buesa ls dksbZ ugh

CAREER POINT 12
12
SPACE FOR ROUGH WORK / jQ dk;Z ds fy, txg
Q.25 He work done by the one mole gas in the cyclic Q.25 uhps n'kkZ;s pØh; izØe esa ,d eksy xSl }kjk fd;k
process shown in graph is W. Then x;k dk;Z W gS rks
V V

B C B C

A A D
D
T1 T0 T2 T1 T 0 T2
T1 + T2 W T1 + T2 T1 + T2 W T1 + T2
(1) T0 = (2) To = + (1) T0 = (2) To = +
2 2R 2 2 2R 2
W W T1 − T2 W T1 − T2
(3) To = (4) To = + (3) To =
W
(4) To = +
2R 2R 2 2R 2R 2

Q.26 The graph shown gives the temperature along an Q.26 uhps n'kkZ;k fp=k x v{k ds vuqfn'k foLrkfjr rki ds
x-axis that extends directly through a wall xzkQ dks n'kkZrk gS ;g rki ,d nhokj ls gksdj
consisting of three layers A, B and C. The air foLrkfjr gS bl nhokj dh rhu ijrsa A, B, C gS
temperature on one side of the wall is 150ºC and nhokj ds ,d vksj ok;q dk rki 150ºC o vU; vksj
on the other side is 80ºC. Thermal conduction 80ºC. gS nhokj ds vuqfn'k rki pkyu fu;r gS rhu
through the wall is steady. Out of the three layers
ijrks A, B, C esa ls fdl ds fljks ij rkih; pkydrk
A, B and C thermal conductivity is greatest of the
vf/kdre gS -
layer -
t(ºC)
t(ºC)
150
150 140
140
120
120
80
80 A B C
A B C x(cm)
x(cm) 40 60 70
40 60 70
(1)
A (1) A
(2)
B (2) B
(3)
C (3) C
(4)
Thermal conductivity of A = Thermal
(4) A dh rkih; pkydrk = B dh rkih; pkydrk
conductivity of B
CAREER POINT 13
13
SPACE FOR ROUGH WORK / jQ dk;Z ds fy, txg
Q.27 Six similar bars each of thermal resistance R are Q.27 Ng ,d leku NMsa izR;sd dk rkih; izfrjks/k R gS ;g
joined to form a regular tetrahedron as shown in ,d leprq"Qydh; vkd`fr cukus ds fy;s tksMs tkrs
the figure. Point D is maintained at a constant gS] n'kkZ; vuqlkjA fcanq D dks ,d fu;r rki TºC ij
temperature TºC and point C at 0ºC. Temperature O;ofLFkr fd;k tkrk gS o fcanq C, 0ºC. ij gSA laf/k
of junction A is A dk rki gS

D T D T

A A

B 0ºC B 0ºC
C C
T T T T T T T T
(1) (2) (3) (4) (1) (2) (3) (4)
4 3 2 5 4 3 2 5

Q.28 A rod of length L and uniform cross-sectional Q.28 ,d NM dh yEckbZ L gS o bldk vuqizLFk dkV
area have varying thermal conductivity which {kS=kQy ,d leku gS bldh rkih; pkydrk fljs A
changes linearly from 2K at end A to K at other
ls B. rd js[kh; :Ik ls 2k ls k rd ifjofrZr gksrh
end B. The ends A and B of the rod are
maintained at constant temperature 100°C and gS fljk A o B Øe'k% fu;r rki 100°C o 0°C, ij
0°C, respectively. At steady state, the graph of O;ofLFkr gSA LFkk;h voLFkk fLFkfr ij rki dk xzkQ gS
temperature : T = T(x) where x = distance from
T = T(x) tgk¡ x fljs A ls nwjh gksxh -
end A will be
T T T T

(1) (2) (1) (2)

x x x x
L L L L
T T T T

(3) (4) (3) (4)

x x x x
L L L L

CAREER POINT 14
14
SPACE FOR ROUGH WORK / jQ dk;Z ds fy, txg
Q.29 When the centre of earth is at a distance of Q.29 tc i`Foh dk dsanz lw;Z ds dsanz ls 1.5 × 1011 m dh
1.5 × 1011 m from the centre of sun, the intensity nwjh ij gS i`Foh lrg ij igqapus okys vkSj fofdj.kksa
of solar radiation reaching at the earth’s surface
dh rhozrk 1.26 kW/m2. gS ;gkW dkWfLed /kwy (dust)
is 1.26 kW/m2. There is a spherical cloud of
cosmic dust, containing iron particles. The
dk ,d xksyh; ckny gS] ftlesa ykSg d.k gSA ckny
melting point for iron particles in the cloud is esa ykSg d.kksa dk xyu fcanq 2000 K. gS ykSg d.kks ds
2000 K. Find the distance of iron particles from lw;Z ds dsanz ls nwjh Kkr djs ftl ij ykSg d.k
the centre of sun at which the iron particle starts xyuk vkjEHk gks tkrs gS (ekukfd lw;Z o ckny ,d
melting. (Assume sun and cloud as a black body,
d`fC.kdk oLr] dh rjg dk;Z djrs gS, σ = 5.6 × 10–8
σ = 5.6 × 10–8 W/m2 K4) -
W/m2 K4) -
(1) 2.81 × 108 m (2) 2.81 × 1010 m
(1) 2.81 × 108 m (2) 2.81 × 1010 m
(3) 2.81 × 109 m (4) 1.40 × 1010 m
(3) 2.81 × 109 m (4) 1.40 × 1010 m

Q.30 A wall of width l and cross sectional area A is Q.30 ,d nhokj dh pkSM+kbZ l o vuqizLFk dkV {ks=kQy A gS
having variable coefficient of thermal ;g ifjofrZr rkih; pkydrk xq.kkad k = k0 + αx
conductivity given by k = k0 + αx (where k0 and
j[krk gS (tgk¡ k0 o α /kukRed fu;rkad gS) o x nhokj
α are positive constant) and x is measured from
dh cká lrg ls ekih xbZ nwjh gSA ;fn ifjos'kh rki
outer surface of wall. If the temperature of
surroundings is T0 °C and the temperature of the T0 °C gS o dejs dks Tr °C rki ij O;ofLFkr fd;k
room is maintained at Tr °C(T0 > Tr). The x;k gSA (T0 > Tr) rks x = l/2 nwjh ij nhokj dk rki
temperature of the wall at x = l/2 is (given αl/K0 gS (fn;k gS αl/K0 = 1 S.I. ek=kd, T0 = 45°C rFkk
= 1 S.I. unit, T0 = 45°C, and Tr = 20°C) Tr = 20°C)
(1) 20°C (2) 25°C
(1) 20°C (2) 25°C
(3) 28°C (4) 30.37°C
(3) 28°C (4) 30.37°C

CAREER POINT 15
15
SPACE FOR ROUGH WORK / jQ dk;Z ds fy, txg
 CHEMISTRY
Q.31 Consider the following statements: Q.31 fuEu dFkuks ij fopkj dhft,
(i) increase in concentration of reactant increase (i) vfHkdkjd dh lkUnzrk esa o`f)] 'kwU; dksfV
the rate of zero order reaction vfHkfØ;k dh nj c<k nsrh gS
(ii) rate constant K is equal to collision frequency (ii) nj fLFkjkad K, VDdj vko`fÙk A ds cjkcj gS] ;fn
A if Ea = 0 Ea = 0 gS
(iii) rate constant K is equal to collision frequency (iii) nj fLFkjakd K, VDdj vko`fÙk A ds cjkcj gksrk gS]
A if Ea = ∞ ;fn Ea = ∞ gS
(iv) ln K vs. T is a straight line (iv) ln K vs. T esa oØ ljy js[kk gS
(v) ln K vs. 1/T is a straight line (v) ln K vs. 1/T esa oØ ljy js[kk gS
Correct statement are: lgh dFku gS:
(1) (i) and (iv) (2) (ii) and (v) (1) (i) rFkk (iv) (2) (ii) rFkk (v)
(3) (iii), (iv) and (v) (4) (i), (ii) and (v) (3) (iii), (iv) rFkk (v) (4) (i), (ii) rFkk (v)

Q.32 For a first order reaction 2A → Products, the rate of Q.32 izFke dksfV vfHkfØ;k 2A → mRikn ds fy,] [A] = 0.2M
reaction at [A] = 0.2M is 1.0 × 10–2 mol litre–1min–1. ij vfHkfØ;k dh nj 1.0 × 10–2 mol litre–1min–1 gSA
The half-life period for the reaction vfHkfØ;k dk v)Zvk;qdky Kkr djsa
(1) 832 sec (2) 440 sec (1) 832 sec (2) 440 sec
(3) 416 sec (4) 14 sec (3) 416 sec (4) 14 sec

Q.33 Q.33
T1 T1
T2 T2
1 T3 1 T3
Z Z

P P
For a gas 'x' the Z v/s P, plots are shown above. S 'x' ds fy, Z v/s P, xzkQ mijksDr fn;k gqvk gS]
,d xSl
if Boyle's temperature is 267°C, then which of ckW;y rkieku 267°C, gS rks dkSulk dFku lR; gSA
the following option is/are true –
(A) T1 = 300 K
(A) T1 = 300 K
(B) T2 280 K gks ldrk gS
(B) T2 may be 280 K
(C) Tc would be 160 K (C) Tc 160 K gks ldrk gS
(D) the gas can be liquefied below – 113°C (D) xSl – 113° ds uhps nzaohd`r gks ldrh gSA
(1) B,C (2) B,C,D (3) C,D (4) A,D (1) B,C (2) B,C,D (3) C,D (4) A,D

CAREER POINT 16
16
SPACE FOR ROUGH WORK / jQ dk;Z ds fy, txg
Q.34 A gasesous mixture is prepared at 900 K in Q.34 900 K ij ,d xSlh; feJ.k rS;kj djrs gS] ftldk
which initially the partial pressure are izkjEHk esa vkaf'kd nkc PSO3 = 1.50 atm, PSO2 = 1.00 atm,
PSO3 = 1.50 atm, PSO2 = 1.00 atm, PO2 = 0.500 atm PO2 = 0.500 atm gSA
2SO3(g) 2SO2(g) + O2(g); KP = 0.023 at 900K 2SO3(g) 2SO2(g) + O2(g); 900K ij KP = 0.023
The correct statement for the reaction is- vfHkfØ;k ds fy, lgh dFku gS&
(1) At equilibrium partial pressure of SO3 is less (1) lkE; ij SO3 dk vkaf'kd nkc 1.5 atm ls de
than 1.5 atm gksrk gSA
(2) The reaction goes in forward direction when (2) tc 900 K ij xSl dks xeZ djrs gS rks vfHkfØ;k
gases are heated at 900 K vxz fn'kk eas tkrh gSA
(3) The reaction goes in backward direction (3) tc 900 K ij xSl dks xeZ djrs gS] rks vfHkfØ;k
when gases are heated at 900 K i'p fn'kk esa tkrh gSA
(4) At equilibrium partial pressure of SO2 = 1.00 atm (4) lkE; ij SO2 dk vkaf'kd nkc = 1.00 atm gSA

Q.35 For the gaseous equilibrium Q.35 ,d xSlh; lkE; ds fy,

A2 (g) + B2 (g) 2 AB (g) the equilibrium A2 (g) + B2 (g) 2 AB (g) lkE; fu;rkad 49 gS
constant is 49. If an equimolar mixture of A2 and
;fn A2 o B2 dk leeksyj feJ.k dks ,d can ik=k esa
B2 is heated in a closed container to this
temperature the mole fraction of B2 in the bl rki ij xeZ fd;k tkrk gS rks B2 dh eksy fHkUu
equilibrium mixture is bl feJ.k esa gksxh-
(1) 2/9 (2) 1/9 (1) 2/9 (2) 1/9
(3) 3/8 (4) 1/8 (3) 3/8 (4) 1/8

Q.36 In the following reaction started only with A8 Q.36 fuEu vfHkfØ;k dsoy A8 'kq: gksrh gS
2A8 (g) 2A3 (g) + 3 A2 (g) + A4 (g) 2A8 (g) 2A3 (g) + 3 A2 (g) + A4 (g)
Mole fraction of A2 is found to be 0.36 at total A2 dh eksy fHkUu lkeus ij 0.36 o dqy nkc 100
pressure of 100 atm at equilibrium. The mole
atm ik;k x;k A8 (g) dh eksy fHkUu] lkE; ij gksuh –
fraction of A8 (g) at equilibrium is –
(1) 0.28 (2) 0.72 (1) 0.28 (2) 0.72
(3) 0.18 (4) 0.92 (3) 0.18 (4) 0.92

Q.37 Calculate [S2–] in 0.1 M H2S solution, in 10-4 M Q.37 0.1 M H2S foy;u esa [S2–] dh x.kuk (10-4 M HCl
HCl (Given K a1 = 10–7 and K a 2 = 10–14) dh mifLFkfr es½a dhft, (fn;k gS K a1 = 10–7 rFkk
K a 2 = 10–14)
(1) 10–7 (2) 10–14
(3) 2 × 10–14 (4) 10–21 (1) 10–7 (2) 10–14
(3) 2 × 10–14 (4) 10–21
CAREER POINT 17
17
SPACE FOR ROUGH WORK / jQ dk;Z ds fy, txg
Q.38 For a first order reaction A (g) → 2 Β (g) + C (g) at Q.38 ,d izFke dksfV vfHkfØ;k A (g) → 2 Β (g) + C (g) ds
constant volume and 300 k, the total pressure at fy, fu;r vk;ru o 300 k, rki ij izkjEHk esa
the beginning (t = 0) and at time t are P0 and Pt (t = 0 ij) o le; t ij nkc Øe'k% P0 o Pt gSA ;fn
respectively. if initial concentration of A is (A0)
and t1/3 is the time required for partial pressure of A dh izkjfHHkd lkUnzrk Ao o vkaf'kd nkc dks mlds
A to reach 1/3 rd if its initial value. The correct 1
izkjfHHkd eku ds Hkkx rd iagqpus esa yxk le; t1/3
curve is/are (if gas behaves ideally) 3
gSA lgh oØ gS (;fn xSl vkn'kZ O;ogkj n'kkZrh gS)
(A) (B) T1/3
(A) (B) T1/3
time (A)0
time (A)0

(C) (D) Rate

const (C) (D) Rate
const
time (A)0
(1) A,B,C (2) B,D (3) A,C (4) A,D time (A)0
(1) A,B,C (2) B,D (3) A,C (4) A,D
Q.39 A 10 litre container at 300 K contains CO2 gas at Q.39 300 K ij 10 yhVj ds ik=k esa 0.2 atm nkc ij CO2
pressure of 0.2 atm and an excess solid CaO xSl rFkk Bksl CaO vf/kD; esa mifLFkr gS (Bksl CaO
(neglect the volume of solid CaO). The volume of
dk vk;ru ux.;)A ik=k ds vk;ru dks fQV fd;s
container is now decreased by moving the movable
piston fitted in the container. What will be the x;s xfr'khy fiLVu }kjk de fd;k tkrk gSA ik=k dk
maximum volume of container when pressure of vf/kdre vk;ru D;k gksxk tc CO2 dk nkc viuk
CO2 attains its maximum value given that vf/kdre eku xzg.k dj ysxkA fn;k x;k gSA
CaCO3(s) CaO(s) + CO2(g) Kp = 0.800 atm CaCO3(s) CaO(s) + CO2(g) Kp = 0.800 atm
(1) 5L (1) 5L
(2) 2.5 L (2) 2.5 L
(3) 1 L (3) 1 L
(4) The information is insufficient (4) lwpuk vi;kZIr gS

Q.40 The heat of atomization of methane and ethane Q.40 esFksu o ,Fksu dh ijekf.odj.k dh ÅtkZ Øe'k%
are 360kJ/mol and 620 kJ/mol respectively the 360kJ/mol o 620 kJ/mol gSA C – C ca/k dks rksMus ds
longest wavelength of light capable of breaking
the C – C bond is fy, vko';d izdk'k dh vf/kdre rajxnS/;Z gS –
(NA = 6.02 × 1023, h = 6.62 × 10–34 Js) (NA = 6.02 × 1023, h = 6.62 × 10–34 Js)
(1) 1.49 × 103 nm (2) 2.48 × 103 nm (1) 1.49 × 103 nm (2) 2.48 × 103 nm
4
4
(3) 2.48 × 10 nm (4) 1.49 × 104 nm (3) 2.48 × 10 nm (4) 1.49 × 104 nm
CAREER POINT 18
18
SPACE FOR ROUGH WORK / jQ dk;Z ds fy, txg
Q.41 For a reaction, A P, the plots of [A] and Q.41 vfHkfØ;k A P, ds fy, [A] o [P] ds xzkQ le;
[P] with time at temperatures T1 and T2 are ds lkFk rkieku T1 o T2 ij uhps fn;s gS -
given below.
10
10

[A] / (mol L–1)

[A] / (mol L–1)

5
5
T2
T2 T1
T1
Time
Time
10
10

[P] / (mol L–1)

T1
[P] / (mol L–1)

T1 T2
T2
5
5

Time
Time
If T2 > T1, the correct statements(s) is (are)
;fn T2 > T1, gks rks lgh dFku gSS
(Assume ΔHθ and ΔSθ are independent of (ekuk fd ΔHθ o ΔSθ rkieku ls Lora=k gS o T1 ij
temperature and ratio of lnK at T1 to lnK at
lnK, dk T2 ij lnk2 ls vuqiku T2 . ls vf/kd gSA
T1
T2 is greater than T2 . Here H, S, G and K
T1
;gk¡ H, S, G rFkk K (,Fksyih] ,aVªksih] fxCl eqDr
are enthalpy, entropy, Gibbs energy and
ÅtkZ o lkE; fu;rkad gS)
equilibrium constant, respectively.)
(A) ΔHθ < 0, ΔSθ < 0 (A) ΔHθ < 0, ΔSθ < 0

(B) ΔGθ < 0, ΔHθ > 0 (B) ΔGθ < 0, ΔHθ > 0
(C) ΔGθ < 0, ΔSθ < 0 (C) ΔGθ < 0, ΔSθ < 0
(D) ΔGθ < 0, ΔSθ > 0 (D) ΔGθ < 0, ΔSθ > 0
(1) A,B (2) B,C (1) A,B (2) B,C
(3) A,C (4) A,D (3) A,C (4) A,D
CAREER POINT 19
19
SPACE FOR ROUGH WORK / jQ dk;Z ds fy, txg
Q.42 A reversible cyclic process for an ideal gas is Q.42 ,d vkn'kZ xSl ds fy, pfØ; izØe uhps n'kkZ;k gqvk
shown below. Here, P. V. and T are pressure,
volume and temperature respectively. The gSA ;g P. V. o T Øe'k% nkc vk;ru o rkieku gSA
thermodynamic parameters q, w, H and U are Å"ekxfrdh; eku q, w, H o U Øe'k% Å"ek] dk;Z
heat, work, enthalpy and internal energy,
respectively. ,FkSYih o vkUrfjd ÅtkZ gS -
A(P1,V1,T1) C(P2,V1,T2) A(P1,V1,T1) C(P2,V1,T2)

Volume (V)
Volume (V)

B(P2,V2,T1) B(P2,V2,T1)

Temperature (T) Temperature (T)

if (A) qAC = ΔUBC and wAB = P2(V2 – V1)
(A) qAC = ΔUBC and wAB = P2(V2 – V1)
(B) wBC = P2(V2 – V1) and qBC = ΔHAC
(B) wBC = P2(V2 – V1) and qBC = ΔHAC
(C) ΔHCA < ΔUCA and qAC = ΔUBC
(C) ΔHCA < ΔUCA and qAC = ΔUBC
(D) qBC = ΔHAC and ΔHCA > ΔUCA (D) qBC = ΔHAC and ΔHCA > ΔUCA
Correct option is lgh fodYi gSA
(1) A,B (2) B,C (3) C,D (4) A,B,C (1) A,B (2) B,C (3) C,D (4) A,B,C

Q.43 A balloon has maximum capacity of 20 L. At one Q.43 ,d xqCckjk 20 L vf/kdre {kerk j[krk gS] xqCckjs esa
atmospheric pressure 10 L of air is filled in the 10 L ok;q ,d ok;qe.Myh; nkc ij Hkjh x;h gSA tc
balloon. It will burst when external pressure is ;g QwVrk gS rc vkUrfjd nkc gSA (lerkih; fLFkfr
(assuming isothermal condition) : ekurs gq;s)-
(1) 0.5 atm (2) 0.4 atm (1) 0.5 atm (2) 0.4 atm
(3) 0.7 atm (4) 0.8 atm (3) 0.7 atm (4) 0.8 atm

Q.44 What is the pH of 1.0 M Na3PO4 in aqueous Q.44 1.0 M Na3PO4 dh tyh; foy;u esa pH gS ?
solution. (pKa1 = 2.16, pKa2 = 7.21, pKa3 = 12.38).
(pKa1 = 2.16, pKa2 = 7.21, pKa3 = 12.38).
(1) 12.4 (2) 13.2 (3) 7.6 (4) 6.2
(1) 12.4 (2) 13.2 (3) 7.6 (4) 6.2

Q.45 Calculate pH of 10–2M BaX2 - Q.45 10–2M BaX2 dh pH gksxh-

(Given Ka, HX = 10–4) (fn;k gS Ka, HX = 10–4)
(1) 8.15 (2) 8.56 (1) 8.15 (2) 8.56
(3) 8.23 (4) 9.4 (3) 8.23 (4) 9.4

CAREER POINT 20
20
SPACE FOR ROUGH WORK / jQ dk;Z ds fy, txg
Q.46 2SO2 (g) + O2 (g) 2SO3 (g) at equilibrium Q.46 2SO2 (g) + O2 (g) 2SO3 (g) ;fn lkE;koLFkk
If the partial pressure of SO2, O2 and SO3 are ij ;fn SO2, O2 o SO3 dk vkf'kd nkc Øe'k 0.0,
0.50, 0.10 and 0.30 atm respectively What would
be the partial pressure of O2 gas, to get equal 0.10 o 0.30 atm gS SO2 o SO3 ds leku eksy dh
moles of SO2 and SO3 izkfIr ds fy, O2 xSl dk vkaf'kd nkc gS -
(1) 0.19 atm (2) 0.28 atm (1) 0.19 atm (2) 0.28 atm
(3) 0.39 atm (4) 0.49 atm (3) 0.39 atm (4) 0.49 atm
Q.47 One litre of a buffer solution containing 0.01 M Q.47 0.01 M (NH4)2SO4 rFkk 0.1 M NH4OH ;qDr 1
(NH4)2SO4 and 0.1 M NH4OH having pH if
PKb= 4.7 fyVj cQj foy;u dk pH D;k gksxk \ ;fn PKb= 4.7
(1) 9 (2) 10 (3) 4 (4) 6 (1) 9 (2) 10 (3) 4 (4) 6

Q.48 1.28 g of HI were heated to attain equilibrium Q.48 1.28 g of HI dks fuEu lkE; LFkkfir djus ds fy,
2 HI H2 + I2 The reaction reaction mixture xeZ fd;k tkrk gS 2 HI H2 + I2 vfHkfØ;k feJ.k
on titration requires 16 mL of N/20 hypo. vuqekiu esa N/20 gkbiks ds 16 ml vko';d gSA HI
Calcullate % dissociation of HI. (MM of HI = 128 ) dh % fo;kstu fd x.kuk djkssa] (MM of HI = 128 )
(1) 20% (2) 12% (3) 8% (4) 25% (1) 20% (2) 12% (3) 8% (4) 25%

Q.49 The heat of neutralisation of HCl by NaOH is Q.49 HCl dh NaOH ls mnklhuhdj.k dh m"ek
–55.9 kJ/mole. If the heat of neutralization of –55.9 kJ/mole gSA ;fn HCN dh NaOH ls
HCN by NaOH is –12.1 kJ/mole, then energy of mnklhuhdj.k dh m"ek –12.1 kJ/mole gS] rks HCN
dissociation of HCN is -
ds fo?kVu dh ÅtkZ gS -
(1) – 43.8 kJ (2) 43.8 kJ
(1) – 43.8 kJ (2) 43.8 kJ
(3) 68 kJ (4) – 68 kJ (3) 68 kJ (4) – 68 kJ

Q.50 For an equilibrium H2O (s) H2O (l) which Q.50 lkE; H2O (s) H2O (l) lkE; ds fy, dkSulk
of the following statement is true- dFku lR; gS-
(1) The pressure changes do not affect the
(1) nkc ijhorZu lkE; dks izHkkfor uagh djrk gSSA
equilibrium
(2) As we take this equilibrium system to high (2) tSls ge lkE; dks vf/kd ÅapkbZ ij ys tkrs gS
altitude (at const. temp.) more ice get formed (fu;r rki ij) vf/kd cQZ cusxhA
(3) More of liquid freezes if pressure on the
(3) vf/kd nzo tesxk ;fn fudk; ij nkc c<+k;k
system is increase
(4) The pressure increase may increase or tk,A
decrease the degree of advancement of the (4) nkc esa o`f) ls vfHkfØ;k dh izxfr c<+ vFkok
reaction. ?kV ldrh gS
CAREER POINT 21
21
SPACE FOR ROUGH WORK / jQ dk;Z ds fy, txg
Q.51 Which of the following expression is not Q.51 fuEu esa ls dkSulk O;atd CN– ds ty vi?kVu ds
applicable on the equilibrium for hydrolysis of
CN– lkE; ij ekU; ugha gS –
CN– + H2O HCN + OH– CN– + H2O HCN + OH–
K K
(1) Kh = w (1) Kh = w
Ka Ka
KH KH
(2) h = (2) h =
C C
1 1
(3) pH = (pKa – logC) (3) pH = (pKa – logC)
2 2
KwKa K wKa
(4) [H+] = (4) [H+] =
C C

Q.52 What is the maximum volume of water required to Q.52 25C ij 1 g dsfY'k;e lYQsV dks ?kksyus ds fy, ty
dissolve 1 g of calcium sulphate at 25°C For calcium dk vf/kdre fdruk vk;ru vko';d gSA dsfY'h;e
sulphate, Ksp = 9.0×10–6 (mol mass of CaSO4 = lYQsV dk Ksp = 90×10–6 (mol mass of CaSO4 =
136g/mol) 136g/mol)
(1) 1.5 (2) 2.45L (1) 1.5 (2) 2.45L
(3) 3.8L (4) 8.2 L (3) 3.8L (4) 8.2 L

Q.53 Which of the following statement is not correct Q.53 ty Lusgh lksy ds fy, fuEu esa ls dkSulk dFku lgh
in respect of hydrophilic sol.– ugha gS -
(1) The particles are hydrated (1) blesa d.k ty;ksftr gksrs gSa
(2) They are coagulated by addition of (2) ;g oS|r q vi?kV; o foyk;d izfrLFkkiu ds }kjk
electrolyte and solvent displacement LdafUnr gksrh gSA
(3) They shows tyndall effect (3) ;g fVaMy izHkko n'kkZrs gS
(4) There are considerable interactions between
(4) buesa ijh{ksi.k ek/;e o ifjf{kIr voLFkk esa
the dispersed phase and dispersion medium
vkd"kZ.k gksrh gS
Q.54 1 : 2 moles of He and CH4 gases are placed in a Q.54 He rFkk CH4 ds 1 : 2 eksy ,d ik=k esa j[ks gS
container with a pin-hole through which both can ftles ls ,d NksVs ls Nsn ls ;s ckgj tk ldrs gSA
escape. What fraction of the CH4 escapes in the time vk/ks He dks fudyus esa yxs le; esa CH4 dk fdruk
required for one-half of the He to escape ? Hkkx fudysxkA
(1) 1/4 (2) 3/8 (1) 1/4 (2) 3/8
(3) 1/2 (4) 1/8 (3) 1/2 (4) 1/8
CAREER POINT 22
22
SPACE FOR ROUGH WORK / jQ dk;Z ds fy, txg
Q.55 MY and NY3, two nearly insoluble salts, have the Q.55 MY vkSj NY3 nks yxHkx v?kqy'khy yo.k gS tks
same KSP values of 6.2 × 10–13 at room temperature.
leku Ksp eku 6.2 ×10–13 dejs ds rki ij j[krs
Which statement would be true in regard to MY and
NY3 ? gSA MY o NY3 ds lEcU/k esa dkSulk dFku lR; gS ?
(1) The molar solubility of MY in water is less (1) MY dh ty esa eksyj foys;rk NY3 ls de gSSA
than that of NY3 (2) MY vkSj NY3 yo.k 0.5 M KY esa 'kq) ty dh
(2) The salts MY and NY3 are more soluble in
rqyuk esa vf/kd ?kqyu'khy gSA
0.5 M KY than in pure water
(3) The addition of the salt of KY to solution of (3) KY yo.k dk MY o NY3 eas ;ksx ls mudh
MY and NY3 will have no effect on their foys;rk ij dksbZ izHkko uagh iM+rk gSA
solubilities
(4) MY vkSj NY3 dh eksyj foys;rk ty easa leku
(4) The molar solubilities of MY and NY3 in
water are identical
gSA

Q.56 Consider the following liquid-vapour equilibrium Q.56 nzo-ok"i lkE; ij fopkj djks -
Liquid Vapour nzo ok"i
Which of the following relations is correct ? fuEu esa ls dkSulk lEcU/k lgha gS ?
d ln P −ΔH v d ln P −ΔH v d ln P −ΔH v d ln P −ΔH v
(1) = (2) = (1) = (2) =
dT RT dT 2 T2 dT RT dT 2 T2
d ln P ΔH v d ln G ΔH v d ln P ΔH v d ln G ΔH v
(3) = (4) = (3) = (4) =
dT RT 2 dT 2 RT 2 dT RT 2 dT 2 RT 2

Q.57 Which of the following expression is not true ? Q.57 fuEu esa ls dkSulk O;atd lgh ugha gS ?
+ –
(1) [H ] = [OH ] = K w for a neutral solution (1) lHkh rki ij mnklhu foy;u ds fy,
at all temperatures [H+] = [OH–] = Kw
+ –
(2) [H ] > K w & [OH ] < K w for an acidic (2) vEyh; foy;u ds fy,
solution [H+] > K w o [OH–] < Kw
(3) [H+] < K w & [OH–] > K w for an (3) {kkjh; foy;u ds fy,
alkaline solution [H+] < K w o [OH–] > Kw
(4) [H+] = [OH–] = 10–7 M for a neutral (4) lHkh rki ij mnklhu foy;u ds fy,
solution at all temperatures [H+] = [OH–] = 10–7 M
CAREER POINT 23
23
SPACE FOR ROUGH WORK / jQ dk;Z ds fy, txg
Q.58 The decomposition of phosphine [PH3] on Q.58 QkWLQhu [PH3] dk VxLVu ij fuEu nkc ij vi?kVu
tungsten at low pressure is a first-order reaction.
izFke dksfV vfHkfØ;k gSA D;ksafd
It is because the
(1) rate is proportional to the surface coverage (1) nj vkPNkfnr {ks=k ds lekuqikrh gSA
(2) rate is inversely proportional to the surface (2) nj vkPNkfnr {ks=k ds O;qRØekuqikrh gSA
coverage
(3) nj vkPNkfnr {ks=k ls LorU=k gSA
(3) rate is independent of the surface coverage
(4) rate of decomposition is very slow (4) vi?kVu /kheh nj ls gksrk gSA

Q.59 The percentage of pyridine (C5H5N) that forms Q.59 0.10 M tyh; fijhfMu foy;u
pyridinium ion (C5H5N+H) in a 0.10 M aqueous (Kb for C5H5N = 1.7 × 10–9) fijhMhu (C5H5N) dh
pyridine solution (Kb for C5H5N = 1.7 × 10–9) is izfr'kr D;k gksxh tks fijhfMfu;e vk;u (C5H5N+H)
(1) 0.0060% (2) 0.013% cukrs gSA
(3) 0.77% (4) 1.6% (1) 0.0060% (2) 0.013%
(3) 0.77% (4) 1.6%

Q.60 Which of the following gas molecules have Q.60 fuEu esa ls fdl xSlh; v.kq dh HkkSfrd vf/k'kks"k.k dh
maximum value of enthalpy of physisorption Å"ek vf/kdre gksxh –
(1) C2H6 (2) SO2 (1) C2H6 (2) SO2
(3) N2 (4) Ne (3) N2 (4) Ne

CAREER POINT 24
24
SPACE FOR ROUGH WORK / jQ dk;Z ds fy, txg
 MATHEMATICS
d θ dx d θ dx
Q.61 The function f(θ) = ∫
dθ 0 1 – cos θ cos x
satisfies Q.61 Qyu f(θ) =
dθ ∫ 1 – cos θ cos x fuEu vody lehdj.k
0
the differential equation dks larq"V djrk gS &
df (θ) df (θ)
(1) + 2f(θ) cotθ = 0 (1) + 2f(θ) cotθ = 0
dθ dθ
df (θ) df (θ)
(2) – 2f(θ) cotθ = 0 (2) – 2f(θ) cotθ = 0
dθ dθ
df (θ) df (θ)
(3) + 2f(θ) = 0 (3) + 2f(θ) = 0
dθ dθ
df (θ) df (θ)
(4) – 2f(θ) = 0 (4) – 2f(θ) = 0
dθ dθ

Q.62 The general solution of differential equation Q.62 vody lehdj.k (2 xy – x)dy + ydx = 0 dk
(2 xy – x)dy + ydx = 0 is O;kid gy gS
y x y x
(1) lnx + =c (2) lny – =c (1) lnx + =c (2) lny – =c
x y x y

x x x x
(3) lny + =c (4) lnx + =c (3) lny + =c (4) lnx + =c
y y y y

Q.63 If n is a positive integer, then the line x + y = n cuts x Q.63 ;fn n /kukRed iw.kkZad gS] rks js[kk x + y = n; x-v{k dks A
axis at A and y axis at B. The number of points with ij rFkk y-v{k dks B ij dkVrh gS] rks ΔOAB ds vUnj
integral co-ordinates lying within the ΔOAB must be fLFkr iw.kkZad funsZ'kkadksa okys fcUnqvksa dh la[;k gksxh
n2 + n + 2 n 2 − 3n + 2 n2 + n + 2 n 2 − 3n + 2
(1) (2) (1) (2)
2 2 2 2
n (n + 1) n (n − 1) n (n + 1) n (n − 1)
(3) (4) (3) (4)
2 2 2 2

∫ sec x cosec10/9 x dx cjkcj gS &

8/ 9
∫
Q.64 sec8 / 9 x cosec10/9 x dx equals Q.64

(1) – (cot x)1/9 + c (2) 9(tan x)1/9 + c (1) – (cot x)1/9 + c (2) 9(tan x)1/9 + c
1 1
(3) – 9 (cot x)1/9 + c (4) – (cot x)9 + c (3) – 9 (cot x)1/9 + c (4) – (cot x)9 + c
9 9
CAREER POINT 25
25
SPACE FOR ROUGH WORK / jQ dk;Z ds fy, txg
Q.65 If the origin is shifted to the point (ab/(a – b), 0) Q.65 ;fn funsZ'kkad v{kksa dks ifjofrZr fd;s fcuk ewyfcUnq
without rotation, then the equation dks fcUnq (ab/(a – b), 0) ij LFkkukUrfjr fd;k tkrk
2 2
(a – b) (x + y ) – 2abx = 0 becomes gS] rc lehdj.k (a – b) (x2 + y2) – 2abx = 0 dk
(1) (a – b) (x2 + y2) – (a + b)xy + abx = a2 ifjofrZr :i gksxk
(2) (a + b) (x2 + y2) = 2ab (1) (a – b) (x2 + y2) – (a + b)xy + abx = a2
(3) (x2 + y2) = (a2 + b2) (2) (a + b) (x2 + y2) = 2ab
(3) (x2 + y2) = (a2 + b2)
(4) (a – b)2 (x2 + y2) = a2b2
(4) (a – b)2 (x2 + y2) = a2b2

Q.66 If the sum of the distances of a point from two Q.66 ;fn ,d lery esa ,d fcUnq dh nks yEcor~
perpendicular lines in a plane is 1, then its locus js[kkvkas ls nwfj;ksa dk ;ksx 1 gSa] rc bldk fcUnqiFk
is gksxk &
(1) a square (2) a circle (1) oxZ (2) o`Ùk
(3) a straight line (4) two intersecting lines (3) ljy js[kk (4) nks izfrPNsfnr js[kk,sa

Q.67 The area bounded by loop of |y| = sin x for Q.67 0 ≤ x ≤ π ds fy, |y| = sin x ds ywi ls ifjc)
0 ≤ x ≤ π, is {ks=kQy gS-
(1) 2 (2) 4 (3) 1/2 (4) None (1) 2 (2) 4 (3) 1/2 (4) dksbZ ugha

⎛ x+3 ⎞ ⎛ x+3 ⎞
Q.68 ∫ x.d ⎜ ⎟ =
⎜ x −3 ⎟
Q.68 ∫ x.d ⎜ ⎟ =
⎜ x −3 ⎟
⎝ ⎠
⎝ ⎠

x+3 x +3 − x −3 x+3 x +3 − x −3
(1) 3 + 3 ln +c (1) 3 + 3 ln +c
x −3 x +3 + x −3 x −3 x +3 + x −3

x −3 x +3 + x −3 x −3 x +3 + x −3
(2) 2 – 3 ln +c (2) 2 – 3 ln +c
x+3 x +3 − x −3 x+3 x +3 − x −3

x −3 x +3 − x −3 x −3 x +3 − x −3
(3) 3 + 3 ln +c (3) 3 + 3 ln +c
x+3 x −3 − x +3 x+3 x −3 − x +3

x+3 x +3 − x −3 x+3 x +3 − x −3
(4) 3 + ln +c (4) 3 + ln +c
x–3 x +3 + x –3 x–3 x +3 + x –3

CAREER POINT 26
26
SPACE FOR ROUGH WORK / jQ dk;Z ds fy, txg
Q.69 If A1 and A2 respectively represents the area Q.69 ;fn A1 ,oa A2 Øe'k% oØ f(x, y) : 4x2 ≤ y ≤ 3x rFkk
bounded by the curves f(x, y) : 4x2 ≤ y ≤ 3x and g(x, y) : 4x2 ≤ y ≤ |3x| ls ifjc) {ks=kQy dks
g(x, y) : 4x2 ≤ y ≤ |3x| then A1 : A2 equals iznf'kZr djrs gS] rc A1 : A2 cjkcj gS &
(1) 2 : 1 (2) 3 : 1 (3) 1 : 2 (4) 1 : 3 (1) 2 : 1 (2) 3 : 1 (3) 1 : 2 (4) 1 : 3

Q.70 Consider a family of circles, which are passing Q.70 ,d o`Ùk fudk; ij fopkj dhft, tks fcUnq (–1, 1) ls
through the point (–1, 1) and are tangent to
x-axis. If (h, k) are the coordinates of the centre
xqtjrk gS rFkk x-v{k dks Li'kZ djrk gSA ;fn (h, k)
of the circles, then the set of values of k is given o`Ùkksa ds dsUnzksa ds funsZ'kkad gS] rc k ds ekuksa dk
by the interval leqPp; fuEu vUrjky ds }kjk fn;k tkrk gS
1 1
(1) 0 < k < (2) k ≥ 1 1
2 2 (1) 0 < k < (2) k ≥
2 2
1 1 1
(3) – ≤k≤ (4) k ≤ 1 1 1
2 2 2 (3) – ≤k≤ (4) k ≤
2 2 2

Q.71 The equations of the sides of a triangle are Q.71 ,d f=kHkqt dh Hkqtkvksa ds lehdj.k x + y – 5 = 0,
x + y – 5 = 0, x – y + 1 = 0, and y – 1 = 0. Then x – y + 1 = 0 rFkk y – 1 = 0 gS] rc ifjdsUnz ds
the coordinates of the circumcenter are
funsZ'kkad gksaxs &
(1) (2, 1) (2) (1, 2)
(1) (2, 1) (2) (1, 2)
(3) (2, –2) (4) (1, – 2)
(3) (2, –2) (4) (1, – 2)

Q.72 The solution of the differential equation Q.72 vody lehdj.k

dy dy
(x + 2y3) = y is (x + 2y3) = y dk gy gS &
dx dx
x x x x
(1) =y+c (2) = y2 + c (1) =y+c (2) = y2 + c
y2 y y2 y

x2 y x2 y
(3) = y2 + c (4) = x2 + c (3) = y2 + c (4) = x2 + c
y x y x

CAREER POINT 27
27
SPACE FOR ROUGH WORK / jQ dk;Z ds fy, txg
Q.73 If parameter a, c, b are in H.P. and 'p' be the Q.73 ;fn izkpy a, c, b g- Js- esa gS rFkk 'p' ewyfcUnq ls js[kk
length of perpendicular from origin to any
fudk; xc (a + b – 2ab) –2ab(y – 5c) – 3abc = 0
member of family of lines
dh fdlh js[kk ij Mkys x;s yEc dh yEckbZ gS] rc
xc (a + b – 2ab) –2ab(y – 5c) – 3abc = 0, then
maximum value of | 2 p | is - | 2 p | dk vf/kdre eku gksxk -

(1) 7 (2) 3 (3) 5 (4) 1 (1) 7 (2) 3 (3) 5 (4) 1

Q.74 The point of contact of two circles Q.74 nks o`Ùkksa x2 + y2 – 2x – 4y = 0 rFkk x2 + y2 –8y – 4 = 0
x2 + y2 – 2x – 4y = 0 and x2 + y2 –8y – 4 = 0 is dk Li'kZ fcUnq gS
(1) (0, 2) (2) (0, 1) (1) (0, 2) (2) (0, 1)
(3) (2, 0) (4) (1, 0) (3) (2, 0) (4) (1, 0)

∫ (x ∫ (x + 2 x 4 + 3x 6 ) (1 + x2 + x4)1/2 dx
2
Q.75 If 2
+ 2 x 4 + 3x 6 ) (1 + x2 + x4)1/2 dx Q.75 ;fn

= k(Ax2 + Bx4 + Cx6)p + D then = k(Ax2 + Bx4 + Cx6)p + D, rc &

1 1
(1) k = , A = B = C = p (1) k = ,A=B=C =p
3 3
1 1
(2) k = , A = B = C, p = 3/2 (2) k = , A = B = C, p = 3/2
3 3
(3) k = 3, p = 1/3, A = B = C (3) k = 3, p = 1/3, A = B = C
(4) k = 3, A = B = C = p = 1/3 (4) k = 3, A = B = C = p = 1/3

Q.76 If (a cos θi, a sin θi) i = 1, 2, 3 represent the Q.76 ;fn o`Ùk ds vUrxZr leckgq f=kHkqt ds 'kh"kZ
vertices of an equilateral triangle inscribed in a (a cos θi, a sin θi) i = 1, 2, 3 ls iznf'kZr gS] rc -
circle, then -
(1) cos θ1 + cos θ2 + cos θ3 = 0
(1) cos θ1 + cos θ2 + cos θ3 = 0
(2) sec θ1 + sec θ2 + sec θ3 = 0 (2) sec θ1 + sec θ2 + sec θ3 = 0

(3) tan θ1 + tan θ2 + tan θ3 = 0 (3) tan θ1 + tan θ2 + tan θ3 = 0

(4) cot θ1 + cot θ2 + cot θ3 = 0 (4) cot θ1 + cot θ2 + cot θ3 = 0

CAREER POINT 28
28
SPACE FOR ROUGH WORK / jQ dk;Z ds fy, txg
Q.77 If f(x) = lim (2x + 4x3 +……..+ 2nx2n–1) Q.77 ;fn f(x) = lim (2x + 4x3 +……..+ 2nx2n–1)
n→∞ n →∞

(0 < x < 1) then ∫ f ( x) dx is equal to (0 < x < 1) gS] rks ∫ f ( x) dx dk eku gS

⎛ 1 ⎞ ⎛ 1 ⎞
(1) log ⎜ ⎟ +c (1) log ⎜ ⎟ +c
⎜ ⎟ ⎜ ⎟
⎝ 1− x
2
⎠ ⎝ 1− x
2
⎠
(2) log 1 − 2 x 2 + c (2) log 1 − 2 x 2 + c
⎛ 1 ⎞ ⎛ ⎞
(3) log ⎜ ⎟ +c (3) log ⎜
1 ⎟ +c
⎜ ⎟ ⎜ ⎟
⎝ 1 − 2x
2
⎠ ⎝ 1 − 2x
2
⎠
(4) log ( 1 – x 2 ) + C (4) log ( 1 – x 2 ) + C

Q.78 C is the centre of the circle with centre (0, 1) and Q.78 C ml o`Ùk dk dsUnz gS] ftldk dsUnz (0, 1) rFkk
radius unity. P is the parabola y = ax2. The set of f=kT;k bdkbZ gSA P ijoy; y = ax2 gSA 'a' ds ekuksa
values of 'a' for which they meet at a point other dk leqPp; ftlds fy;s os ewyfcUnq ds vfrfjDr
than the origin, is fcUnq ij feyrs gS] gksxk &
⎛ 1⎞ ⎛ 1⎞
(1) a > 0 (2) a ∈ ⎜ 0, ⎟ (1) a > 0 (2) a ∈ ⎜ 0, ⎟
⎝ 2⎠ ⎝ 2⎠
⎛1 1⎞ ⎛1 ⎞ ⎛1 1⎞ ⎛1 ⎞
(3) a ∈ ⎜ , ⎟ (4) a ∈ ⎜ , ∞ ⎟ (3) a ∈ ⎜ , ⎟ (4) a ∈ ⎜ , ∞ ⎟
⎝4 2⎠ ⎝2 ⎠ ⎝4 2⎠ ⎝ 2 ⎠

Q.79 The straight line ax + by + c = 0 where abc ≠ 0 will Q.79 ljy js[kk ax + by + c = 0 (tgk¡ abc ≠ 0) izFke
intersect in positive direction of coordinate axis if prqFkk±'k esa funsZ'khZ v{kksa dks izfrPNsfnr djrh gS]
(1) ac > 0, bc > 0 ;fn -
(2) c > 0 and bc < 0 (1) ac > 0, bc > 0
(2) c > 0 rFkk bc < 0
(3) bc > 0 and / or ac < 0
(3) bc > 0 rFkk / ;k ac < 0
(4) ac < 0 and/or bc < 0
(4) ac < 0 rFkk/ ;k bc < 0

Q.80 The angle at which the circles (x – 1)2 + y2 = 10 Q.80 og dks.k ftl ij o`Ùk (x – 1)2 + y2 = 10 rFkk
and x2 + (y – 2)2 = 5 intersect is x2 + (y – 2)2 = 5 izfrPNsnu djrs gS] gksxk &
(1) π/6 (2) π/4 (1) π/6 (2) π/4
(3) π/3 (4) π/2 (3) π/3 (4) π/2

CAREER POINT 29
29
SPACE FOR ROUGH WORK / jQ dk;Z ds fy, txg
 dx dx
Q.81 If ∫ (x + 2)(x 2
+ 1)
Q.81 ;fn ∫ (x + 2)(x 2
+ 1)
1 1
= a ln (l + x2) + b tan–1 x + ln |x + 2| + C, then = a ln (l + x2) + b tan–1 x + ln |x + 2| + C, rc
5 5
1 2 1 2 1 2 1 2
(1) a = – ,b=– (2) a = ,b=– (1) a = – ,b=– (2) a = ,b=–
10 5 10 5 10 5 10 5
1 2 1 2 1 2 1 2
(3) a = – ,b= (4) a = ,b= (3) a = – ,b= (4) a = ,b=
10 5 10 5 10 5 10 5

Q.82 One of the diameter of the circle circumscribing Q.82 vk;r ABCD ds ifjxr o`Ùk dk ,d O;kl 4y = x + 7 gSA
the rectangle ABCD is 4y = x + 7. If A and B ;fn fcUnq A rFkk B Øe'k% (–3, 4) rFkk (5, 4) gS]a rc
are the points (–3, 4) and (5, 4) respectively,
vk;r dk {ks=kQy gS-
then the area of the rectangle is -
(1) 16 sq unit (2) 24 sq unit (1) 16 oxZ bdkbZ (2) 24 oxZ bdkbZ
(3) 32 sq unit (4) 64 sq. unit (3) 32 oxZ bdkbZ (4) 64 oxZ bdkbZ

1 1 1 1

Q.83 If A = ∫ x 50 (2 − x ) 50 dx ; B = ∫ x 50 (1 − x ) 50 dx, Q.83 ;fn A = ∫ x 50 (2 − x ) 50 dx ; B = ∫ x 50 (1 − x ) 50 dx,

0 0 0 0

then which of the following is true? rc fuEUk esa ls dkSUklk lR; gS ?

(1) A = 250 B (2) A = 2–50 B (1) A = 250 B (2) A = 2–50 B
(3) A = 2100 B (4) A = 2–100 B (3) A = 2100 B (4) A = 2–100 B

Q.84 If f(x) is monotonic & differentiable function on Q.84 ;fn f(x) vUrjky [a, b] esa ,dfn"V rFkk vodyuh;
f (b) f (b)
[a, b], then 2 ∫ x (b – f –1 ( x )) dx equals
f (a )
Qyu gS] rc 2 ∫ x (b – f –1 ( x )) dx cjkcj gS &
f (a )
b b

∫ (f (1) f2(x) – f2(a) ∫ (f

2 2 2
(1) f (x) – f (a) (2) 2 2
( x ) – f (a )) dx (2) ( x ) – f 2 (a )) dx
a a
b b b b

∫ (f (x) – f (a )) dx ∫ (f ( x ) + f (a )) dx ∫ ∫ (f ( x ) + f 3 (a )) dx
2 3 2
(3) (4) (3) (f ( x ) – f (a )) dx (4)
a a a a

CAREER POINT 30
30
SPACE FOR ROUGH WORK / jQ dk;Z ds fy, txg
Q.85 If one side of a rhombus has end points (4, 5) Q.85 ;fn leprqHkqZt dh ,d Hkqtk ds fljs (4, 5) rFkk
and (1, 1) then the maximum area of the (1, 1) gSa] rks leprqHkqZt dk vf/kdre {ks=kQy
rhombus is- gksxk -
(1) 50 sq. units (2) 25 sq. units
(1) 50 oxZ bdkbZ (2) 25 oxZ bdkbZ
(3) 30 sq. units (4) 20 sq. units
(3) 30 oxZ bdkbZ (4) 20 oxZ bdkbZ
1 1
Q.86 The area bounded by the curve y = Q.86 oØ y = rFkk x-v{k ds }kjk dksfV;ksa
1 + tan x 1 + tan x
& x-axis between the ordinates x = π/6 & x = π/3
x = π/6 ,oa x = π/3 ds e/; ifjc) {ks=kQy gS &
is
π π π π π π π π
(1) (2) (3) (4) (1) (2) (3) (4)
4 2 5 12 4 2 5 12

Q.87 The radius of any circle touching the lines Q.87 js[kkvksa 3x – 4y + 5 = 0 rFkk 6x – 8y – 9 = 0 dks
3x – 4y + 5 = 0 and 6x – 8y – 9 = 0 is – Li'kZ djus okys o`Ùk dh f=kT;k gS –
(1) 1.9 (2) 0.95 (3) 2.9 (4) 1.45 (1) 1.9 (2) 0.95 (3) 2.9 (4) 1.45

Q.88 If φ (x) = φ' (x) and φ(1) = 2, then φ(3) equals- Q.88 ;fn φ (x) = φ' (x) rFkk φ(1) = 2 gS] rc φ(3) cjkcj gS-
(1) e2 (2) 2e2 (3) 3e2 (4) 2e3 (1) e2 (2) 2e2 (3) 3e2 (4) 2e3

Q.89 The locus of the point of intersection of the Q.89 o`Ùk x2 + y2 = a2 ds mu fcUnqvksa ij Li'kZ js[kkvksa ds
tangents to the circle x2 + y2 = a2 at points whose izfrPNsnu fcUnq dk fcUnqiFk] ftuds izkpfyd dks.kksa
parametric angles differ by π/3, is- dk vUrj π/3 gS] gksxk &
(1) 3 (x2 – y2) = 4a2 (2) 3 (x2 + y2) = 4a2 (1) 3 (x2 – y2) = 4a2 (2) 3 (x2 + y2) = 4a2
2 2 2
(3) (x + y ) = a (4) 4(x2 – y2) = 3a2 (3) (x2 + y2) = a2 (4) 4(x2 – y2) = 3a2

Q.90 The value of k > 0 such that Q.90 k > 0 dk eku rkfd
k k k k

∫
0
[tan –1 x ] dx = ∫
0
[cot –1 x ] dx, where [.]
∫ [tan
–1
∫
x ] dx = [cot –1 x ] dx, tgk¡ [.] egÙke
0 0

denote the greatest integer function, is iw.kkZad Qyu dks iznf'kZr djrk gS] gksxk &
3 – 4 cos 4 ⎛ 3 + cos 4 ⎞ 3 – 4 cos 4 ⎛ 3 + cos 4 ⎞
(1) (2) 2 ⎜ ⎟ (1) (2) 2 ⎜ ⎟
1 – cos 4 ⎝ 1 – cos 4 ⎠ 1 – cos 4 ⎝ 1 – cos 4 ⎠
1 – cos 4 2(1 – cos 4) 1 – cos 4 2(1 – cos 4)
(3) (4) (3) (4)
3 + cos 4 3 + cos 4 3 + cos 4 3 + cos 4
CAREER POINT 31
31
SPACE FOR ROUGH WORK / jQ dk;Z ds fy, txg
 Time : 3 Hours Maximum Marks : 360
SYLLABUS
HkkSfrd foKku : xq:Rokd"kZ.k] ljy vkorZ xfr] inkFkZ ds xq.k/keZ] nzO; ;kaf=kdh] dSyksjhferh] xSlksa dk vkf.od xfr fl)kar] Å"ekxfrdh]
Å"ek LFkkukUrj.k] rkih; izlkj
jlk;u foKku : i`"Bh; jlk;u] jklk;fud xfrdh] jklk;fud lkE;] vk;fud lkE;] jlk;fud ÅftZdh] xSlh; voLFkk
xf.kr : vfuf'pr lekdyu] fuf'pr lekdyu] oØ ls ifjc) {ks=kQy] vody lehdj.k] fcUnq] ljy js[kk] o`Ùk

IMPORTANT INSTRUCTIONS

lkekU; %

1. bl iz'u i=k esa dqy 90 iz'u gSaA lHkh iz'u gy djus vfuok;Z gSaA

2. blesa _.kkRed vadu gS vr% mÙkj vuqekfur djuk gkfudkjd gks ldrk gSA

3. bl iz'u i=k esa gh jQ odZ ds fy, [kkyh LFkku fn;k x;k gSA jQ odZ ds fy, dksbZ vfrfjDr 'khV ugha nh tk,sxhA

4. mÙkj O.M.R.(Optical Marks Recognisation) 'khV esa vafdr djus gSaA ;g vyx ls nh xbZ gSA

5. iz'u i=k dh lhy rc rd u [kksysa tc rd ,slk djus ds fy, ifjoh{kd }kjk dgk u tk,sA
SEAL

6. [kkyh dkx+t] fDyi cksMZ] ykWx lkj.kh] LykbM :y] dsYdqysVj] lsY;qyj Qksu] istj ;k fdlh Hkh izdkj dk vU; bysDVªkWfud midj.k
fdlh Hkh :i esa ijh{kk gkWy ds vUnj ys tk;s tkus dh vuqefr ugha gSA

vadu i)fr :

1. izR;sd iz'u esa pkj fodYi fn;s x;s gSa] dsoy ,d fodYi lgh gSA izR;sd xyr mÙkj ds fy, ml iz'u ds fy, fu/kkZfjr vadksa esa
ls ,d&pkSFkkbZ vad dkV fy, tk,saxsA

2. HkkSfrd foKku esa : Q. 1 - 30 izR;sd ds fy, 4 vad,

jlk;u foKku esa : Q. 31 - 60 izR;sd ds fy, 4 vad,

Xkf.kr esa : Q. 61 - 90 izR;sd ds fy, 4 vad,

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