PRODUCT NAME: ABRO Spray Lubricant

PRODUCT NUMBER/SIZE: AB-80 Revision Date: 10/28/2014

SECTION 1
Identification of the Substance and of the Company/Undertaking
MANUFACTURER’S NAME: ABRO INDUSTRIES, INC.

ADDRESS: 3580 Blackthorn Court

South Bend, IN 46628
USA

PRODUCT DESCRIPTION: Spray Lubricant

COMPANY PHONE: 574-232-8289

EMERGENCY 24-HR TELEPHONE: Chemtrec: US/Canada 1-800-424-9300

International +1-703-527-3887

SECTION 2
Hazards Identification

HMIS: Health 1 Flamm 3 React. 0 NFPA: Tox. 1 Flamm. 3 React. 0

Classification:

Extremely Flammable Aerosol Category 1

Skin irritation Category 2
Carcinogenicity – Category 1B
Mutagenicity – Category 1B
Specific Target Organ Toxicity (Single Exposure) – Category 3
Aspiration hazard Category 1

Label Pictogram(s):

Signal Word: DANGER

Hazard Phrases: Extremely flammable aerosol. Pressurized container: may burst if heated
May be fatal if swallowed and enters airways. Causes skin irritation
May cause respiratory irritation. May cause drowsiness or dizziness
May cause genetic defects . May cause cancer

Precautionary Obtain special instructions before use. Do not handle until all safety precautions
Phrases: have been read and understood. Keep away from heat/sparks/open flames/hot
surfaces. No smoking. Do not spray on an open flame or other ignition source.

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 Keep container tightly closed. Do not pierce or burn, even after use. Do not
breathe dust/fume/gas/mist/vapours/spray. Wash skin thoroughly after handling.
Do not eat, drink or smoke when using this product. Use only outdoors or in a
well-ventilated area. Wear protective gloves/protective clothing/eye
protection/face protection.

Response: IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. IF ON SKIN: Wash

with plenty of water and take off contaminated clothing. IF INHALED: Remove
victim to fresh air and keep at rest in a position comfortable for breathing.
IF IN EYES: Rinse cautiously with water for several minutes. Remove contact
lenses, if present and easy to do. Continue rinsing. Call a POISON CENTER or
doctor/physician if exposed or you feel unwell.

Storage / Store in a well-ventilated place. Keep container tightly closed. Store locked up.
Disposal: Protect from sunlight. Do not expose to temperatures exceeding 50 °C/122 °F.
Dispose of contents/ container in compliance with local and federal regulations.

Other: Keep out of reach of children. If medical advice is needed, have product
container or label at hand. Read label before use.

SECTION 3
Composition/Information on Ingredients

COMPONENTS CAS Number OSHA PEL ACGIH TLV Percent by

weight
Aliphatic Petroleum 64742-47-8 ------------ ----------- 60 %
Distillates

Liquefied Petroleum 68476-86-8 Unknown 1000 ppm 15 - 40 %

Gas

**Toluene 108-88-3 200 ppm 200 ppm 4%

**n-Heptane 142-82-5 500 ppm 400 ppm 2%

** Indicates ingredients that are subject to the reporting requirements of Section 313 of EPCRA and 40
CFR 372. Components of a blended material regulated under section 313 of SARA.

SECTION 4
First Aid Measures

First Aid Measures

Immediate Medical Provide general supportive measures and treat symptomatically. Keep victim
Attention: under observation.

Eyes Immediately flush eyes with water for at least 15 minutes. Get medical
attention if irritation persists.

Skin Remove contaminated clothing and wash skin with soap and water. Get
medical attention if irritation persists.

Ingestion DO NO induce vomiting unless directed by a physician or poison control

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 center. Get medical attention immediately.

Inhalation Remove victim to fresh air. Apply artificial respiration if needed. Get medical
attention.

Signs & Symptoms High concentrations of vapors may irritate nose and throat and cause
Of Over Exposure: symptoms of intoxication such as dizziness, nausea, headache or
indigestion. Direct spray or vapors will irritate and may harm eyes;
Product may cause irritation to the skin. Ingestion causes irritation (nausea,
vomiting, and diarrhea).

Special Treatment: Pre-existing disorders of the lung can be aggravated by exposure.

SECTION 5
Fire Fighting Measures

Extinguishing media Dry Chemical (B-C), Foam, CO2

Hazardous Combustion: Unknown

Protective Equipment and Keep containers cool using water spray. Use proper equipment to
Precautions for firefighters: protect personnel from bursting containers.

Contents under pressure. Do not use near fire, sparks, or flame.

Do not puncture or incinerate container. Exposure to temperatures
above 120°F may cause container to burst.

Flammability per Flame EXTREMELY FLAMMABLE

Projection Test

SECTION 6
Accidental Release Measures
Personal precautions, protective Keep unnecessary personnel away. Keep people away from and
equipment and emergency upwind of spill/leak. Wear appropriate protective equipment and
procedures: clothing during clean-up. Avoid breathing mist or vapor. Avoid
breathing gas. Do not touch damaged containers or spilled
material unless wearing appropriate protective clothing. Ensure
adequate ventilation.

Methods/materials for Absorb spill with inert material then place in a chemical waste
containment and cleanup: container. Dispose of in accordance with local, state, and federal
regulations.

Environmental precautions: None.

SECTION 7
Handling and Storage
Precautions for DANGER: EXTREMELY FLAMMABLE. HARMFUL OR FATAL IF
Safe Handling SWALLOWED. Contents under pressure. Keep away from heat, sparks and
open flames. Do not smoke while using. Avoid contact with eyes. Avoid

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 prolonged or repeated contact with skin. Use only in a well-ventilated area.

Conditions for Safe Do not store at temperatures above 120°F. Intentional misuse by
Storage deliberately concentrating and inhaling the vapors (contents) may be
harmful or fatal. Do not puncture or incinerate containers. Keep out of reach
of children. Store in accordance with NFPA 30B for Level 3 Aerosols.

SECTION 8
Exposure Controls/Personal Protection

COMPONENTS CAS Number OSHA PEL ACGIH TLV

Aliphatic Petroleum 64742-47-8 ------------ ------------- ------

Distillates

Liquefied Petroleum 68476-86-8 Unknown 1000 ppm 1000

Gas

**Toluene 108-88-3 200 ppm 200 ppm 200

**n-Heptane 142-82-5 500 ppm 400 ppm 400

Engineering Controls: None required for normal use. Maintain

adequate ventilation
Personal Protective Equipment:
Skin Impervious clothing and boots. Wash hands
after each use. Wear CHEMICAL RESISTANT
GLOVES if repeated skin contact occurs or
causes irritation

Eyes Wear SAFETY GLASSES to prevent eye contact

Respiratory Use respirator when TLV is exceeded

SECTION 9
Physical and Chemical Properties
Appearance and Physical State: Amber, thin, oily liquid mixture packaged in
pressurized aerosol spray can.
Odor: Mild vanilla
Odor Threshold: Not Available.
pH: Not Applicable.
Melting Point/Freezing Point: Not Available.
Initial boiling point & boiling range: Greater than 200 °F
Flash Point: Not Available.
Evaporation rate: Greater than 1.0 (BuAc=1)
Flammability (solid, gas) Not Available.
Upper/lower flammability or explosive limits Not Available
Vapor pressure Not Available.
Vapor density Not Available.
Relative density / Specific gravity 0.850 – 0.950g/mL

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Solubility Insoluble in water
Partition Coefficient n-Octanol/Water 2.7 (Toluene)
Auto-ignition Temperature: Not Available.
Decomposition Temperature: Not Available.
Viscosity: Not Available.
%-VOC Content: 44.01 %
CARB VOC Category/Standard(%) EXPORT
OTC Model Rule Category/Standard(%) EXPORT
US EPA Cons Prod Category/Standard(%) EXPORT

SECTION 10
Stability and Reactivity
Reactivity Product is non-reactive under normal conditions of use.

Chemical Stability: Product is stable

Possibility of hazardous reactions: None known.

Conditions to avoid (e.g. static Fire, sparks, open flames, temperatures above 120°F
discharge, shock or vibration):

Incompatibilities: Strong oxidizers

Hazardous decomposition CO, CO2, Hydrocarbons

products:

Hazardous polymerization: Will not occur

SECTION 11
Toxicological Information
Likely Routes of Exposure: Skin or eye contact and inhalation

Symptoms: High concentrations of vapors may irritate nose and throat and
cause symptoms of intoxication such as dizziness, nausea,
headache or indigestion. Direct spray or vapors will irritate and
may harm eyes; Product may cause irritation to the skin.
Ingestion causes irritation (nausea, vomiting, and diarrhea).

Delayed and Immediate Effects: Deliberate inhalation of toluene at high concentrations (e.g., glue
(TOLUENE) sniffing and solvent abuse) has been associated with
adverse effects on the liver, kidney and nervous system and can
cause CNS depression, cardiac arrhythmias and death. Case
studies of persons abusing toluene suggest isolated incidences
of adverse effects on the fetus including birth defects.

Chronic Effects: Studies of workers indicate long-term exposure may be related

(TOLUENE) to impaired color vision and hearing. Some studies of workers
suggest long-term exposure may be related to neurobehavioral
and cognitive changes. Some of these effects have been
observed in laboratory animals following repeated exposure to
high levels of toluene. Several studies of workers suggest long-

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 term exposure may be related to small increases in spontaneous
abortions and changes in some gonadotropic hormones.
However, the weight of evidence does not indicate toluene is a
reproductive hazard to humans. Studies in laboratory animals
indicate some changes in reproductive organs following high
levels of exposure, but no significant effects on mating
performance or reproduction were observed. Case studies of
persons abusing toluene suggest isolated incidences of adverse
effects on the fetus including birth defects. Findings in laboratory
animals were largely negative. Positive findings include small
increases in minor skeletal and visceral malformations and
developmental delays following very high levels of maternal
exposure. Studies of workers indicate
long-term exposure may be related to effects on the liver, kidney
and blood, but these appear to be limited to changes
in serum enzymes and decreased leukocyte counts. Studies in
laboratory animals indicate some evidence of adverse effects on
the liver, kidney, thyroid, and pituitary gland following very high
levels of exposure. The relevance of these findings to humans is
not clear at this time.

Toxicity Measures: HEPTANE – Branched, Cyclic and Linear

ORAL LD50: >5g/kg (similar materials)
DERMAL LD50: >2g.kg(similar material)
INHALATION LC50: 65-103g/m³/4hr. rat (similar material)

n-HEPTANE
ORAL LD50: 17.0g/kg (Rat)
DERMAL LD50: 3400mg/kg, rabbit
INHALATION LC50: 65-103g/m³ (4-hr., Rat)

NTP Carcinogen: No.

IARC Carcinogen: Toluene Group 3
OSHA Carcinogen: No.

SECTION 12
Ecological Information

Ecotoxicity: Toluene is toxic to aquatic organisms and may cause long-term adverse
effects in the aquatic environment. If Heptane is applied to leaves, this
product may kill grasses and small plants by interfering with transpiration
and respiration. This product is not toxic to fish but my coat gill structures
resulting in suffocation if spilled in shallow, running water. Product may
be moderately toxic to amphibians by preventing dermal respiration. This
product may cause gastrointestinal distress to birds and mammals
through ingestion during pelage grooming.

Persistence and Toluene is rapidly biodegradable in aerobic conditions.

Degradability:

Bioaccumulation Potential: Not Available.

Mobility in Soil: Based on similar materials, this product will have a significant tendency
to partition to air. Hydrocarbons from this product which do partition to
air are expected to rapidly photodegrade.

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Other Adverse Effects: Degradation of this product in water occurs primarily by microbial action.
Distribution: Principally to air.
.

SECTION 13
Disposal Considerations

Storage and Disposal Keep out of reach of children. Do not store near heat, sparks or open
flame. Do not puncture or incinerate container. Do not store in direct
sunlight. Store in a cool, dry, well-ventilated area away from incompatible
materials. Recovered liquids may be sent to an EPA permitted re-claimer
or incineration facility. Contaminated material must be disposed of in a
permitted waste management facility. Consult Federal, state, or local
disposal authorities for approved procedures.

Waste Disposal Method: Whatever cannot be saved for recovery or recycling should be handled as
hazardous waste and sent to a RCRA approved incinerator or disposed in a
RCRA approved waste facility. Processing, use or contamination of this
product may change the waste management options. State and local
disposal regulations may differ from federal disposal regulations. Dispose of
container and unused contents in accordance with federal, state and local
requirements.

SECTION 14
Transport Information
Multi-modal shipping descriptions are provided for informational purposes and do not consider container
sizes. The presence of a shipping description for a particular mode of transport (ocean, air, etc.), does not
indicate that the product is packaged suitably for that mode of transport. All packaging must be reviewed
for suitability prior to shipment, and compliance with the applicable regulations is the sole responsibility of
the person offering the product for transport.

U.S. DOT UN/ID Number: UN1950

Proper shipping name: Aerosols
Hazard class: 2.1
Packing Group: None
Exceptions: May be shipped as a limited quantity or consumer commodity
Environmental Hazards: No
Transport in Bulk: Not Applicable.
Special Precautions: ERG#126 (no toxic subrisk for domestic shipments (MeOH))

IMO/IMDG UN/ID Number: UN1950

Proper shipping name: Aerosols
Hazard class: 2.1
Packing Group: None
Exceptions: May be shipped as a limited quantity
Environmental Hazards: No
Transport in Bulk: Not Applicable
Special Precautions: EmS F-D, S-U

ICAO/IATA UN/ID Number: UN1950

Proper shipping name: Aerosols, flammable
Hazard Class: 2.1
Packing Group: None

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 Exceptions: May be shipped as a limited quantity or reclassified as ID8000
Environmental Hazards: No
Transport in Bulk: Not Applicable
Special Precautions: None

Canada UN/ID Number: UN1950

(TDG) Proper shipping name: Aerosols, flammable
Hazard class: 2.1
Packing Group: None
Exceptions: May be shipped as a limited quantity
Environmental Hazards: No
Transport in Bulk: Not Applicable
Special Precautions: ERG#126

SECTION 15
Regulatory Information
This product is considered to be hazardous under the OSHA Hazard Communication Standard (29 CFR
1910.1200).

Section 313 Information (40 CFR 372): This product contains a chemical which is listed in Section 313 at
or above the de minimis concentrations. TOLUENE, n-HEPTANE

U. S. Toxic Substance Control Act (TSCA): All components of this product are listed on the U.S. Toxic
Substance Control Act (TSCA) Chemical Substance Inventory.

Proposition 65 – California Safe Drinking Water and Toxic Enforcement Act of 1986
This product is not known to contain any chemicals currently listed as carcinogens or reproductive toxins
under California Proposition 65 at levels which would be subject to the proposition.

SECTION 16
Other Information

We believe all information given is accurate. It is offered in good faith but without guarantee. Since
conditions of use are beyond our control, user assumes all responsibility and risk.

The supplier disclaims all expressed or implied warranties of merchantability or fitness for a specific use,
with respect to the product or the information provided herein, except for conformation to contracted
specifications. All information appearing herein is based upon data obtained from manufacturers and/or
recognized technical sources. While the information is believed to be accurate, we make no
representations as to its accuracy or sufficiency. Conditions of use are beyond our control, and therefore
users are responsible for verifying the data under their own operating conditions to determine whether the
product is suitable for their particular purposes and they assume all risks of their use, handling, and
disposal of the product. Users also assume all risks in regards to the publication or use of, or reliance
upon, information contained herein. This information relates only to the product designated herein, and
does not relate to its use in combination with any other material or process.

ABBREVIATIONS:
NG="NOT GIVEN" BT="BETWEEN"
<="LESS THAN" >="GREATER THAN"
ND = Not Determined NA = Not Applicable

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