Wrong Answered Questions
28
Rate of replacement of hydrogens of alkanes in halogenation process is
A You marked
✘
D
✓
29
Iodination of alkanes is always carried out in the presence of some oxidizing agents
like . This is because
A it is a very fast process
B it is a reversible reaction ✓
C bond is very weak
D all of these You marked
✘
32
Choose the correct option regarding product (A&B) of the given reaction
A
✓
D None of the above You marked
✘
44
which of the following has highest boiling point.
A butane You marked
✘
B methyl butane
C pentane ✓
D dimethyl propane
47
A compound contains .The empirical formula of this compound is . Find
YOUR ANSWER 24
CORRECT ANSWER 7
48
The number of orbitals associated with quantum number is
YOUR ANSWER 11
CORRECT ANSWER 25
53
In which of the following functions Roll’s theorem is applicable?
C You marked
✘
D
✓
63
The curve has two horizontal tangents. The distance between these two horizontal lines is:
A You marked
✘
B
D
✓
69
The tangent to at is parallel to the normal at the point on the curve Then the value of .
A 2
B 0 You marked
✘
C 3
✓
D 1
70
If be the point on the curve where normal to the curve make equal intercepts with the axis then the value of is
A 0
C
✓
D None of these You marked
✘
Skipped Questions
1
A P-V diagram is obtained by changing the temperature of the gas as shown. During this process, the gas is
A heated continuously
B cooled continuously
C heated in the beginning but cooled towards the end ✓
D cooled in the beginning but heated towards the end
3
The pressure of the gas that should be increased to decrease the volume by 10% at constant temperature is
A 10%
B 9.5%
C 11.11% ✓
D 5.11%
5
At the bottom of a lake where temperature is 70C the pressure is 2.8 atm. An air bubble of radius
1 cm at the bottom rises to the surface, where the temperature is 270C. Radius of bubble at the surface is
A 31/3 cm ✓
B 41/3 cm
C 51/3 cm
D 61/3 cm
16
Two chambers, one containing m1 gram of a gas at pressure P1 and other containing m2 gram of same gas at pressure P2 are put in
communication with each other. If temperature remains constant, the common pressure reached will be
A
✓
D
26
Which of the following method is used to synthesis alkanes having even number of carbon atoms only?
A Decarboxylation
B Kolbe’s electrolytic method ✓
C Hydrogenation
D None of the above
27
Liquid hydrocarbons can be converted to a mixture of gaseous hydrocarbons by
A hydrolysis
B oxidation
C cracking ✓
D distillation under reduced pressure
30
In presence of X, ordinary alkanes resist oxidation but alkanes having tertiary H-atom can be easily oxidized to alcohols. Identify “X”.
C
✓
33
Which of the following statements are correct regarding Kolbe’s electrolytic process?
I) Alkanes containing even number of C- atoms are prepared
II) Sodium or Potassium salts of carboxylic acids are taken as substrate.
III) Methane can be prepared by this method.
IV) gas is liberated at anode.
Choose the correct statement.
A Both I& II ✓
B Both II & III
C Both I& III
D All of these
34
The possible rotamers of ethane is/are
A 2
B 3
C 4
D
✓
35
Double bond equivalent (degree of unsaturation) of (A) is:
A 1
B 2
C 3
✓
D 4
36
Arrange the following alkanes in decreasing order of their heats of combustion.
A I>II>III
B III>I>II
C III>II>I ✓
D I>III>II
37
Product of the above reaction will be:
A racemic mixture
B Diastereomers ✓
C Meso
D Constitutional isomers
38
B
✓
39
On catalytic reduction how many alkenes will give 2-methylbutane?
A 1
B 2
C 3
✓
D 4
41
Products obtained in above Wurtz reaction is :
D
✓
42
The number of possible monobromo products is (excluding stereoisomers):
A 4
B 5
✓
C 8
D 10
43
Which of the following is the correct match regarding controlled oxidation of alkane and catalyst used in the reaction?
Column-I Column-II
a) 1.
b) 2.
c) 3.
d) 4.
A a-2,b-3,c-4,d-1
B a-1,b-2,c-3,d-4 ✓
C a-2,b-1,c-3,d-4
D a-4,b-3,c-2,d-1
45
Among the following, which hydrocarbon is not produced by Wurtz reaction?
A methane ✓
B ethane
C butane
D octane
46
The weight of iron which will be converted into its oxide by the action of of steam on it will be (Atomic weight of Fe= 56)
SKIPPED
CORRECT ANSWER 42
49
atomic orbitals combine to give how many molecular orbital ?
SKIPPED
CORRECT ANSWER 8
50
One liter of a buffer solution containing 0.01 M having is 5 find of solution.
SKIPPED
CORRECT ANSWER 10
51
The angle at which the curve intersects the is
A
B
✓
52
The equation has at least one root in:
B
✓
54
The function
A Increasing in its domain
B Decreasing in its domains
C
Decreasing in and increasing in
D
Increasing in and Decreasing in ✓
55
Let C be the curve . The tangent at A meets the curve again at B. If the gradient at B is K times the gradient at A
then K is equal to:
A 4 ✓
B 2
C -2
D
56
, Lagrange’s Mean Value Theorem is NOT applicable to:
Where and denotes the greatest integer and fraction part function.
A f, g , h ✓
B h,k
C f,g
D g,h,k
57
If a variable tangent to the curve makes intercepts a, b on x and y-axis respectively, then the value of is:
C
✓
58
The figure shows a right triangle with its hypotenuse OB along the and its vertex A on the parabola . Let h represents the length
of the hypotenuse which depends on the of the point A. The value of equals:
A 0
B
C 1 ✓
D 2
59
A point is moving along the curve . The interval, in which the abscissa changes at slower rate than ordinate, is:
C
✓
60
Consider and then which of the following is correct?
A
Rolles theorem is applicable to both
B
LMVT is not applicable to f and Rolles theorem if applicable to g with
C LMVT is applicable to f and Rolles theorem is applicable to g with b = 1 ✓
D Rolles theorem is not applicable to both f, g for any real b.
61
If the function satisfies LMVT at on the closed interval then the value of a is equal to:
A 3
✓
B 4
C 6
D 1
62
Consider the curve represented parametrically by the equation
If H denotes the number of point on the curve where the tangent is horizontal and V the number of point where the tangent is vertical then:
B
✓
66
A function has a second order derivative If its graph passes through the point and at that point the tangent to the
graph is , then the function is
B
✓
67
A spherical iron ball 10cm radius is coated with a layer of ice of uniform thickness that melts at a rate of . When the thickness of
ice is , then the rate at which the thickness of ice decreases is
B
✓
68
A g is increasing on ✓
B
g is decreasing on
C
g is increasing on and decreasing on
D
g is decreasing on and increasing on
71
Two straight roads OA and OB intersect at an angle . A car approaches O from A, where at a uniform speed of ,
Simultaneously, a runner starts from O towards B at a uniform speed of . The time after start when the car and the runner are closest
is:
SKIPPED
CORRECT ANSWER 30
72
The tangent at a point P on the curve meets the y-axis at T; then equals to
SKIPPED
CORRECT ANSWER 4
73
If is a decreasing function for every . Find the least value of .
SKIPPED
CORRECT ANSWER 1
74
Let where a is a positive constant. The interval in which is increasing is . Then is equal to
SKIPPED
CORRECT ANSWER 1
Not Visited Questions
2
A vessel of volume 4 litres contains a mixture of 8g of O2, 14g of N2 and 22g of CO2 at 270C. The pressure exerted by the mixture is
A 10 atmosphere
B
C
✓
4
Two closed vessels of equal volume contain air at 105kPa at 300K and are connected through a narrow tube. If one of the vessels is now
maintained at 300K and the other at 400K, then the pressure becomes
A 120 kPa ✓
B 105 kPa
C 150 kPa
D 300 kPa
6
The graph drawn between pressure and volume in Boyle’s law experiment is shown in figure for different masses of same gas at same
temperature, then
A m2 > m1
✓
B m1 < m2
C m1 = m2
7
For an ideal gas, V-T curves at constant pressures P1 and P2 are shown in figure. From the figure
A P1 > P2
B P1 < P2
✓
C P1 = P2
D
8
The total kinetic energy of 8 litres of helium molecules at 5 atmosphere pressure is
(1 atm = 1.013 x 105 pascal)
A 607 J
B 6078 J ✓
C 607 erg
D 6078 erg
9
The average energy for molecules in one degree of freedom is
B
✓
10
A vessel contains a mixture of 1 mole of oxygen and two moles of nitrogen at 300K. The ratio of the rotational kinetic energy per O2 molecule
to that of per N2 molecule is
A 1:1 ✓
B 1:2
C 2:1
D 4:1
11
The temperature at which the mean kinetic energy of hydrogen molecules increases to such that they will escape out of the gravitational
field of earth forever is (take escape velocity ve = 11.2 km/sec)
A 12075 K
B 10000 K ✓
C 20000 K
D 30075 K
12
The respective speeds of five molecules are 2, 1.5, 1.6, 1.6 and 1.2 km/sec. The most probable speed in km/sec will be
A 2
B 1.58
C 1.6 ✓
D 1.31
13
At a certain temperature, the ‘rms’ velocity for O2 is 400 m/sec. At the same temperature, the ‘rms’ velocity for H2 molecules is
A 100 m/s
B 25 m/s
C 1600 m/s ✓
D 6400 m/s
14
At a pressure of 24 x 105 dyne/cm2, the volume of O2 is 10litre and mass is 20 gm. The ‘rms’ velocity is (in m/sec)
A 800
B 400
C 600 ✓
D 200
15
In a cubical vessel (1m x 1m x 1m) the gas molecules of diameter are at a temperature of 300 K and a pressure of mm of
mercury. The mean free path of the gas molecule is
A 1m
B 4m
C 2.42 m ✓
D 1 cm
17
‘N’ molecules each of mass ‘m’ of gas ‘A’ and ‘2N’ molecules each of mass ‘2m’ of gas ‘B’ are contained in the same vessel, which are
maintained at a temperature T. The mean square velocity of molecules of B type is denoted by ‘v2’and the mean square of the ‘X’ component
of the velocity of A type is denoted by , then is
A 2
B 1
D
✓
18
The upper and lower fixed points of a faulty mercury thermometer are 2100F and 340F respectively. The correct temperature read by this
thermometer is
A 220F
B 800F
C 1000F
D 1220F ✓
19
A rail track made of steel having length 10m is clamped on a railway line at its two ends (figure). On a summer day due to rise in
temperature by 200C, it is deformed as shown in figure. Then x (displacement of the centre) is
A 5 cm
B 20 cm
C 15 cm
D 11 cm ✓
20
A wooden block of density 860 kg/m3 at 00C is floating on benzene liquid of density 900 kg/m3 at 00C. The temperature at which the block just
submerge in benzene is
A 240C
B 420C ✓
C 160C
D 320C
21
The rms velocity of hydrogen molecules at a certain temperature is 300 ms–1. If the temperature is doubled and hydrogen gas dissociates into
atomic hydrogen. Find the rms speed of the gas molecules now.
SKIPPED
CORRECT ANSWER 600
22
The mean kinetic energy of 32gm of oxygen at –730C is (in Joule)
SKIPPED
CORRECT ANSWER 2490
23
A vertical cylinder of height 100cm contains air at a constant temperature and its top is closed by frictionless piston at atmospheric pressure
as shown in Fig. If mercury is slowly poured on the piston, due to its weight air is compressed. If the maximum height of the mercury
column which can be put on the piston is x cm. Then x is
SKIPPED
CORRECT ANSWER 24
24 Three steel rods of equal length from an equilateral triangle ABC. Taking midpoint of BC as origin, the increase in y-coordinate of centre of
mass per unit change in temperature is .
(Assuming the length of each rod is 2m and ). Then n is
SKIPPED
CORRECT ANSWER 4
25
An ideal gas is found to obey the additional law VP2 = constant. The gas is initially at a temperature T and volume V, when it expands to
volume 2V, its temperature becomes . Then the value of x is
SKIPPED
CORRECT ANSWER 2
