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Chemistry

1. van’t Hoff factor i for acetic acid in water and 6. If the mole fraction of acetone in ethyl
benzene is respectively alcohol is 0.2 then the molality of acetone in
(A) Greater than unity and greater than the solution is
unity (A) 5.9 m
(B) Less than unity and greater than unity (B) 5.4 m
(C) Greater than unity and less than unity (C) 7.8 m
(D) Less than unity and less than unity (D) 2.7 m

2. Highest freezing point is shown by 7. What is the correct sequence of osmotic

(A) 0.1 M urea pressure of decinormal aq. solution of
following? (assume all electrolyte dissociate
(B) 0.2 M glucose
completely)
(C) 0.1 M KCl (I) BaCl2 , (π1 )
(D) 0.05 M BaCl2 (II) Al2 (SO4 )3 , (π2 )
(III) NaCl, (π3 )
3. If 0.2 molal aqueous solution of weak (IV) AlCl3 , (π4 )
monobasic acid is 40% ionised then the (A) π2 > π4 > π1 > π3
freezing point of the solution will be (Kf for
(B) π3 > π1 > π4 > π2
water is 1.86 K kg mol–1 ) (C) π1 > π2 > π3 > π4
(A) – 0.18°C (D) π3 > π4 > π1 > π2
(B) – 0.65°C
(C) – 0.52°C
8. A : Azeotropic mixture cannot be separated
(D) – 0.37°C by fractional distillation.
R : Mole fraction of each component in
vapour and solution phase are equal for
4. The temperature independent concentration
term is azeotropic mixture.
(A) Molarity (A) If both Assertion & Reason are true and
the reason is the correct explanation of
(B) Mole fraction the assertion.
(C) Normality (B) If both Assertion & Reason are true but
(D) %(w/v) the reason is not the correct
explanation of the assertion.
5. The gas used in tanks by scuba divers for (C) If Assertion is true statement but
breathing contains Reason is false.
(A) 78% N2 , 21% O2 and 1% He (D) If both Assertion and Reason are false
statements.
(B) 11.7% He, 58% N2 and 30.3% O2
(C) 32.1% O2 and 67.1% He
(D) 11.7% He, 56.2% N2 and 32.1% O2
9. A : ΔVmixing < 0 for negative deviation 14. The osmotic pressure of a solution of a non-
solution. electrolyte containing 20 g L–1 of y
R : ΔSmix > 0 for negative deviation. (molecular mass = 60 g mol–1 ) is equal to
(A) If both Assertion & Reason are true and that of a 10% solution (w/v) of a non-volatile,
the reason is the correct explanation of non-electrolyte solute at 30°C. The molar
the assertion. mass of the solute is
(B) If both Assertion & Reason are true but (A) 60 g mol–1
the reason is not the correct (B) 600 g mol–1
explanation of the assertion.
(C) If Assertion is true statement but (C) 400 g mol–1
Reason is false. (D) 300 g mol–1
(D) If both Assertion and Reason are false
statements.
15. One molal solution of a carboxylic acid in
benzene shows the elevation of boiling point
10. A : Nitric acid and water form maximum of 1.518 K. The degree of association for
boiling azeotrope. dimerisation of the acid in benzene is (Kb for
R : The solutions that show negative benzene is 2.53 K kg mol–1 )
deviation from Raoult’s law form maximum
boiling azeotrope. (A) 60%
(A) If both Assertion & Reason are true and (B) 70%
the reason is the correct explanation of (C) 75%
the assertion. (D) 80%
(B) If both Assertion & Reason are true but
the reason is not the correct
16. 1 g of NaOH is present in 500 ml of aqueous
explanation of the assertion.
solution at 27°C. If NaOH is 100%
(C) If Assertion is true statement but dissociated then the osmotic pressure of the
Reason is false. solution will be
(D) If both Assertion and Reason are false (A) 4.92 atm
statements.
(B) 2.46 atm
(C) 3.25 atm
11. Mole fraction of ethanol in water is 0.1. The
(D) 7.50 atm
molality of ethanol in the solution is
(A) 3.25 m
17. 0.1 molal aqueous solution of aluminium
(B) 6.17 m
sulphate is 50% dissociated. The van’t Hoff
(C) 5.24 m factor of aluminium sulphate will be
(D) 9.21 m (A) 4.5
(B) 5
12. For an ideal solution which thermodynamic (C) 3
relation is incorrect? (D) 2.5
(A) ΔmixH = 0
(B) ΔmixV = 0
18. If a solute dimerizes to 40% then its van’t
(C) ΔmixS = 0 Hoff factor (i) will be
(D) ΔmixG < 0 (A) 0.2
(B) 0.6
13. 50 mL of 0.6 M HCl is mixed with 150 mL of (C) 0.8
0.4 M H2 SO4 , the molarity of H+ ion in the (D) 0.5
resultant solution is
(A) 0.90 M 19. 1.5 mole of n-hexane is mixed with 0.5 mole
(B) 1.25 M of n-pentane to form an ideal solution at
25°C. If the vapour pressure of n-hexane
(C) 0.25 M and n-pentane at 25°C are 150 mm Hg and
(D) 0.75 M 200 mm of Hg respectively then the vapour
pressure of the resulting solution in mm of
Hg will be
(A) 215.5
(B) 250
(C) 162.5
(D) 175
20. If the Henry's law constant for the solubility of 26. What mass of urea be dissolved in 162 g of
O2 gas in water at 25°C is 5.0 × 106 atm. water so as to decrease the vapour pressure
The mole fraction of O2 in air is 0.2. The of water by 10%?
number of moles of O2 from air dissolved in (A) 30 g
10 moles of water at 25°C and 4 atm (B) 90 g
pressure is (C) 60 g
(A) 1.6 × 10–6 (D) 45 g
(B) 2.4 × 10–5
(C) 5.2 × 10–3 27. The elevation of boiling point of 0.1 molal aq
CaCl2 solution is
(D) 3.2 × 10–4
(A) Kb
(B) 0.1 Kb
21. If elevation in boiling point for aqueous
Na2 SO4 having α = 40% is ΔTb then its (C) 0.3 Kb
depression in freezing point would be (D) 10 Kb
(A) K b

Δ Tb ×Kf
28. 92 g ethyl alcohol is dissolved in 144 g of
(B) 1.8×Kb

Δ Tb ×Kf
water. The mole fraction of water in the
solution is
(C) Δ Tb ×Kf
(A) 0.2
1.8×Kb

(B) 0.4
(D) Δ Tb ×Kf

Kb (C) 0.6
(D) 0.8
22. For an aqueous solution of K4 [Fe(CN)6 ]
(strong electrolyte) the van't Hoff factor (i) will 29. The vapour pressure of two liquids A & B are
be 123 & 168 torr respectively. The total vapour
(A) 4 pressure of solution obtained by mixing 6
(B) 1 moles of A and 3 moles of B would be
approximately
(C) 3
(A) 138 torr
(D) 5
(B) 151 torr
(C) 93 torr
23. The vapour pressure of a pure liquid ‘A’ is 40 (D) 1239 torr
mm Hg at 25°C. It forms an ideal solution
with another liquid B. The mole fraction of B
is 0.4 and total vapour pressure of the 30. If 50% of acetic acid dimerises in a solvent
solution is 70 mm Hg. So, the vapour and rest ionises, then its van’t Hoff factor is
pressure of pure liquid, B at the same (A) 1
temperature is
(B) 1.25
(A) 115 mm Hg
(C) 0.75
(B) 80 mm Hg
(D) 2
(C) 90 mm Hg
(D) 125 mm Hg
31. Concentrated aqueous sulphuric acid is
98% H2 SO4 by mass. How many grams of
24. The mass of urea to be dissolved in 100 g of concentrated sulphuric acid solution should
water (Kb = 0.52 K kg mol–1 ) to prepare a be used to prepare
solution having boiling point 101°C, is 250 ml of 2.0 M H2 SO4 ?
(A) 10.26 g (A) 98 g
(B) 4.2 g (B) 50 g
(C) 11.54 g (C) 110 g
(D) 14.66 g (D) 100 g

25. Unit of Ebullioscopic constant is 32. Out of the following aqueous solutions,
(A) K mol kg–1 which one will exhibit the lowest freezing
point depression?
(B) K kg mol–1
(A) 0.1 m NaCI (α = 50%)
(C) kg mol–1 (B) 0.2 m K2 SO4 (α = 20%)
(D) kg mol g–1 (C) 0.1 m Urea
(D) 0.2 m Glucose
33. A solution has 2 : 3 mole ratio of hexane and 38. The van’t Hoff factor (i) for infinitely dilute
benzene. If vapour pressure of hexane and aqueous solution of Al2 (SO4 )3 is
benzene at 25°C are 360 mm and 300 mm (A) 2
of Hg respectively then the mole fraction of
hexane in the vapour phase would be (B) 3
(A) 0.44 (C) 4
(B) 0.55 (D) 5
(C) 0.35
(D) 0.72 39. Two liquids A and B have PoA and PoB in
the ratio of 1 : 4 and the ratio of the number
34. The graph between PTotal (Total vapour of moles of A and B in liquid phase are 1 : 5.
Then the mole fraction of B in vapour phase
pressure of solution) and XB (mole fraction in equilibrium with the solution is equal to
o
of solute) is given below ( PA : Vapour (A) 20
21
o
pressure of pure liquid A and PB is vapour (B) 18

19
pressure of pure liquid B) (C) 19

21

(D) 18

21

40. Which of the following is not an application

of Henry's law?
(A) Solubility of CO2 in soft drinks
(B) Tanks used by scuba divers are filled
with diluted air
(C) Symptoms of anoxia at high altitude
(D) Cooking in a pressure cooker
The slope of graph is
(A) o o
PA − PB 41. A : 1.5% (w/v) glucose is isotonic with 1.5%
(w/v) of urea solution at room temperature.
(B) o o
R : Solutions having similar % (w/v) are said
PB − PA
to be isotonic solutions.
(C) o o
(A) Both Assertion & Reason are true and
PA + PB
the reason is the correct explanation of
(D) P
o
+
o
P the assertion
A B

2
(B) Both Assertion & Reason are true but
the reason is not the correct
explanation of the assertion
35. 3.7 g of calcium hydroxide is dissolved in
(C) Assertion is true statement but Reason
100 g of water. Assuming the base to be
80% ionised, the freezing point of the is false
solution will be (Kf for water = 1.86 K mole–1 (D) Both Assertion and Reason are false
statements
kg)
(A) –2.79°C
(B) –0.9°C 42. The vapour pressure of two liquids A and B
are 90 mm of Hg and 120 mm of Hg
(C) –2.418°C respectively. The ratio of mole fractions of A
(D) –0.744°C and B in vapour phase over the liquids if
they are mixed in molar ratio of 2 : 1.
36. The van’t Hoff factor for 0.1 M Ba(NO3 )2 is (A) 1 : 3
2.74. Percentage degree of dissociation is (B) 3 : 2
(A) 91.3% (C) 1 : 2
(B) 87% (D) 2 : 1
(C) 75%
(D) 63.5% 43. At 25°C, the highest value of molal
depression constant is for which solution?
(A) 0.1 M of glucose
37. Pressure exerted by vapours above the
surface of liquid in liquid gas equilibrium (B) 0.2 M of NaCl
depends on (C) 0.3 M of CaCl2
(A) Temperature (D) All the above have same values
(B) Surface area
(C) Nature of liquid
(D) Both (1) and (3)
44. If the molality of methanol in the aqueous 49. A : Abnormal molecular mass of benzoic
solution is 10 then the mole fraction of acid is greater than its normal molecular
methanol in the solution will be mass in benzene.
(A) 0.22 R : Benzoic acid dissociate is Benzene.
(B) 0.15 (A) Both Assertion & Reason are true and
the reason is the correct explanation of
(C) 0.35 the assertion
(D) 0.10 (B) Both Assertion & Reason are true but
the reason is not the correct
45. If the molality of NaOH in D2 O is 2 m, then explanation of the assertion
mole fractions of D2 O will be (C) Assertion is true statement but Reason
is false
(A) 1

26
(D) Both Assertion and Reason are false
(B) 1
statements
52

(C) 49

50 50. The order of freezing points of equimolal

(D) 25 aqueous solutions is C < A < B.
26
The correct order of their boiling point is
(A) A < C < B
46. A solution containing 2 g per 100 mL of urea (B) B < C < A
(molecular mass = 60 g mol–1 ) is isotonic (C) B < A < C
with a 5% (w/v) solution of a non-volatile
solute. The molecular mass of this non- (D) A < B < C
volatile solute is
(A) 175 g mol–1 51. A solution of aniline in phenol
(B) 200 g mol–1 (A) Behaves like an ideal solution
(B) Shows a positive deviation from
(C) 350 g mol–1
Raoult’s law
(D) 150 g mol–1 (C) Obeys Raoult’s law
(D) Shows a negative deviation from
47. Osmotic pressure of an aqueous solution of Raoult’s law
0.1M of Na2 SO4 at 27°C is (consider
complete ionisation) 52. Two volatile liquids A and B are mixed in the
(A) 1.2 atm molar ratio of 2 : 3. If vapour pressure of pure
(B) 2.4 atm liquids A and B is 300 mm Hg and 400 mm
Hg respectively then the vapour pressure of
(C) 3.6 atm the solution in mm Hg will be
(D) 7.4 atm (A) 360
(B) 380
48. Assertion : The composition of the (C) 340
components in vapour phase is same as that
(D) 390
of in the liquid phase of an azeotropic
mixture.
Reason : Azeotropic mixture strictly follows 53. Incorrect statement among the following is
Raoult's law. (A) A mixture of 68% nitric acid and 32%
(A) Both Assertion & Reason are true and water by mass forms maximum boiling
the reason is the correct explanation of azeotropes
the assertion
(B) The components of azeotropes cannot
(B) Both Assertion & Reason are true but be separated by fractional distillation
the reason is not the correct
(C) At azeotropic composition, the liquid
explanation of the assertion
and the vapour have the same
(C) Assertion is true statement but Reason composition
is false
(D) Solution which shows negative
(D) Both Assertion and Reason are false deviation from Raoult's law, form
statements minimum boiling azeotrope
54. A : Azeotropic mixture cannot be separated 60. A : 1.5% (w/v) glucose is isotonic with 1.5%
by fractional distillation. (w/v) of urea solution.
R : Acetone and aniline forms maximum R : Solutions having similar % (w/v) are said
boiling azeotropes. to be isotonic solutions.
(A) Both Assertion & Reason are true and (A) Both Assertion & Reason are true and
the reason is the correct explanation of the reason is the correct explanation of
the assertion the assertion
(B) Both Assertion & Reason are true but (B) Both Assertion & Reason are true but
the reason is not the correct the reason is not the correct
explanation of the assertion explanation of the assertion
(C) Assertion is true statement but Reason (C) Assertion is true statement but Reason
is false is false
(D) Both Assertion and Reason are false (D) Both Assertion and Reason are false
statements statements

55. If the vapour pressure of CH3 Cl and CH2 Cl2 61. 0.25 M BaCl2 solution is isotonic with 0.5 M
are 360 mm and 480 mm of Hg respectively sucrose solution at a temperature of 298 K.
at a given temperature. If 202 g of CH3 Cl is The percentage ionisation of BaCl2 solution
mixed with 170g of CH2 Cl2 at the same is
temperature, then vapour pressure of the (A) 50%
solution will be (B) 75%
(A) 420 mm (C) 45%
(B) 400 mm (D) 85%
(C) 480 mm
(D) 360 mm
62. The value of van't Hoff factor, i for
FeSO4 ·(NH4 )2 SO4 ·6H2 O when it is
56. If 12 g urea is dissolved in 400 g of water dissolved in aqueous solution is (Assume
then freezing point of the solution will be (Kf complete dissociation)
of water = 1.86 K kg mol–1 ) (A) 4
(A) –1.93°C (B) 3
(B) –0.25°C (C) 5
(C) –0.93°C (D) 7
(D) –1.25°C
63. The freezing point of the solution containing
57. The mixture which shows negative deviation 0.25 moles of CH3 COOH in 500 g of water is
from Raoult’s law is equal to –1.15ºC. The fraction of CH3 COOH
(A) Phenol + Aniline that undergoes dissociation is (Given: Kf for
(B) Ethanol + Acetone water = 1.86 K kg mol–1 )
(C) Acetone + Carbon disulphide (A) 0.33
(D) Hexane + Pentane (B) 0.42
(C) 0.24
58. Two liquids A and B are mixed in a ratio of 2 (D) 0.71
∘
: 3. If PA = 100mmHg and
∘
PB = 300mmHg, then the mole fraction of A 64. The solution which shows negative
in vapour phase will be deviation from Raoult’s law is
(A) 2 (A) Chloroform and acetone
11
(B) Ethanol and acetone
(B) 10

11 (C) Acetone and carbon disulphide

(C) 3
(D) Acetone and benzene
5

(D) 2

5
65. The van't Hoff factor (i) for a dilute aqueous
solution of the strong electrolyte barium
59. The colligative property which is preferred hydroxide is
for determining molar masses of proteins (A) 0
and polymers is (B) 1
(A) Relative lowering of vapour pressure (C) 2
(B) Elevation in boiling point (D) 3
(C) Depression in freezing point
(D) Osmotic pressure
66. Calculate the vapour pressure of pure B If 72. Which among the following aqueous
Ptotal = 0.172 XA + 0.215 atm at 306 K solution has minimum freezing point?
(A) 0.38 atm (A) 0.1 m CaCl2
(B) 0.04 atm (B) 0.1 m Urea
(C) 0.215 atm (C) 0.1 m NaCl
(D) 0.172 atm (D) 0.1 m Glucose

67. Benzene and toluene form an ideal solution 73. The van't Hoff factor (i) for 50% dissociation
at 298 K. For this process, the incorrect of MgCl2 is
statement is (A) 2
(A) ΔSmix (system) is positive (B) 3
(B) ΔVmix = 0 (C) 2.5
(C) ΔHmix = 0 (D) 1.5
(D) ΔGmix is positive
74. At a given temperature, total vapour
68. Which has maximum osmotic pressure? pressure of a mixture of volatile components
A and B is given by
(A) 200 mL of 0.2 M NaCl solution P = 120 – 75XB.
(B) 200 mL of 0.1 M glucose solution Hence, vapour pressure of pure A and B
(C) 200 mL of 0.2 M sucrose solution respectively are
(D) 200 mL of 0.2 M urea solution (A) 120, 75
(B) 120, 195
69. Consider the following Assertion (A) and (C) 120, 45
Reason (R) and choose the correct option. (D) 75, 45
Assertion (A) : More the value of KH (Henry's
Law Constant) , lesser will be solubility of
gas in water. 75. Value of van’t Hoff factor i, for a weak binary
Reason (R) : CO2 is more soluble than H2 in electrolyte having 40% dissociation is
water (A) 0.8
(A) Both Assertion & Reason are true and (B) 0.6
the reason is the correct explanation of (C) 1.4
the assertion (D) 2
(B) Both Assertion & Reason are true but
the reason is not the correct
explanation of the assertion 76. The correct order of osmotic pressure of
given aqueous solution is (consider 100%
(C) Assertion is true statement but Reason
dissociation of electrolytes)
is false
(A) 1 M glucose > 1 M sugar > 1 M KCl > 1
(D) Both Assertion and Reason are false M CaCl2
statements
(B) 1 M glucose = 1 M sugar = 1 M KCl = 1
M CaCl2
70. The elevation in boiling point of a solution of
0.585 g of NaCl in 100 g of water will be (C) 1 M glucose = 1 M sugar < 1 M KCl < 1
(assuming 100% dissociation of NaCl, At. wt. M CaCl2
of Na = 23 ; Kb = 0.52 kmolal–1 ) (D) 1 M glucose = 1 M sugar > 1 M KCl > 1
M CaCl2
(A) 0.05°C
(B) 0.10°C
(C) 0.20°C 77. 36% (
w
) solution of glucose is
v

(D) 0.25°C (A) 1.25 M

(B) 2.0 M
71. van’t Hoff factor (i) for a Na2 SO4 solution (C) 2.25 M
which is 75% ionised is (D) 3.0 M
(A) 3
(B) 2.5 78. Solution having highest osmotic pressure at
(C) 2 27°C among the following is
(D) 4.5 (A) 0.2 M sucrose
(B) 0.1 M NaCl
(C) 0.15 M Al2 (SO4 )3
(D) 0.2 M Al(NO3 )3
79. Which one of the following is incorrect for a 84. A : For 0.1 molal aq. NaCl and 0.1 molal aq.
solution having negative deviation? benzoic acid solution the ebullioscopic
(A) ΔHmix< 0 constant is different.
R : Ebullioscopic constant depends on the
(B) ΔSmix< 0 nature of solute.
(C) ΔGmix< 0 (A) Both Assertion & Reason are true and
(D) ΔVmix< 0 the reason is the correct explanation of
the assertion
(B) Both Assertion & Reason are true but
80. Select the property which is not colligative? the reason is not the correct
(A) Boiling point explanation of the assertion
(B) Depression in freezing point (C) Assertion is true statement but Reason
(C) Osmotic pressure is false
(D) Relative lowering in vapour pressure (D) Both Assertion and Reason are false
statements

81. Incorrect thermodynamic relation for ideal

solution is 85. Which of the following relation holds true for
solution showing negative deviation from
(A) Δmix G < 0
Raoult's law?
(B) Δmix S < 0 (A) ΔHmix > 0
(C) Δmix H = 0 (B) ΔVmix > 0
(D) Δmix V = 0 (C) ΔS > 0
(D) PA > PAo XA
82. A : When 10 ml of benzene is mixed with 20
ml of toluene then net volume of solution is
30 ml. 86. If two liquids A (boiling point = t1 °C) and B
R : Benzene and toluene on mixing form (boiling point = t2 °C) on mixing forms
ideal solution. azeotropic solution which shows positive
(A) Both Assertion & Reason are true and deviation from Raoult's law, then boiling
the reason is the correct explanation of point of azeotropic solution will be [Given, t1
the assertion > t2 )
(B) Both Assertion & Reason are true but (A) > t1
the reason is not the correct
(B) > (t1 + t2 )
explanation of the assertion
(C) Assertion is true statement but Reason (C) = t1
is false (D) < t2
(D) Both Assertion and Reason are false
statements
87. The solution which forms minimum boiling
azeotrope is
83. A : A solution of acetone and ethanol shows (A) CHCl3 + CHBr3
a positive deviation from Raoult's law.
R : During mixing of ethanol and acetone, (B) HNO3 + H2 O
entropy of solution decreases. (C) HCl + H2 O
(A) Both Assertion & Reason are true and (D) C6 H5 OH + H2 O
the reason is the correct explanation of
the assertion
(B) Both Assertion & Reason are true but 88. 50 ml of liquid A and 50 ml of liquid B is
the reason is not the correct mixed to give a solution which obey Raoult’s
explanation of the assertion law. The volume of the solution
(C) Assertion is true statement but Reason (A) Will be 100 ml
is false (B) Can be more or less than 100 ml
(D) Both Assertion and Reason are false (C) Can be more, equal to or less than 100
statements ml
(D) Will be more than 100 ml

89. 24 g of difluoroacetic acid in 400 g of water

has observed freezing point depression by
1.4°C. The van't Hoff factor for difluoroacetic
acid is (Kf of water = 1.86 K kg mol–1 ; Atomic
weight of F = 19)
(A) 1.20
(B) 1.05
(C) 1.45
(D) 0.85
90. If two volatile liquids A(PA° = 540 torr) and 95. A : People taking a lot of salt or salty food
° experience water retention in tissue cells
B(PB = 420 torr) are mixed in the molar ratio and intercellular space.
of 2 : 1 then total vapour pressure of solution R : There is phenomena of osmosis in tissue
is cells and intercellular space.
(A) 100 torr (A) Both Assertion & Reason are true and
(B) 200 torr the reason is the correct explanation of
(C) 600 torr the assertion
(D) 500 torr (B) Both Assertion & Reason are true but
the reason is not the correct
explanation of the assertion
91. Among the following parameters of an ideal (C) Assertion is true statement but Reason
solution, identify the incorrect one. is false
(A) ΔVmix = 0 (D) Both Assertion and Reason are false
(B) ΔHmix = 0 statements
(C) ΔSmix = 0
(D) ΔG = –ve 96. A : For 0.1 M aq. NaOH and for 0.1 M aq.
CH3 COOH solution, the ebullioscopic
constant is different.
92. A : Mass percentage of 2 m glucose solution R : Ebullioscopic constant depends on the
is 28.5%. nature of solute.
R : Molality is the mole of the solute present
(A) Both Assertion & Reason are true and
in 1 kg of the solution.
the reason is the correct explanation of
(A) Both Assertion & Reason are true and the assertion
the reason is the correct explanation of
(B) Both Assertion & Reason are true but
the assertion
the reason is not the correct
(B) Both Assertion & Reason are true but explanation of the assertion
the reason is not the correct
explanation of the assertion (C) Assertion is true statement but Reason
is false
(C) Assertion is true statement but Reason
is false (D) Both Assertion and Reason are false
statements
(D) Both Assertion and Reason are false
statements
97. Concentrated HNO3 solution is 63% HNO3
by mass and has a density of 1.4 g/ml. The
93. A : Pressure does not have any significant molarity of this solution in terms of HNO3 as
effect on solubility of solids in liquids.
R : Solids and liquids are highly solute is
incompressible. (A) 1.4 M
(A) Both Assertion & Reason are true and (B) 6.3 M
the reason is the correct explanation of (C) 12.6 M
the assertion (D) 14 M
(B) Both Assertion & Reason are true but
the reason is not the correct
explanation of the assertion 98. A : Molecules of ethanoic acid demerise in
benzene.
(C) Assertion is true statement but Reason
R : There is intermolecular hydrogen
is false
bonding between ethanoic acid molecules.
(D) Both Assertion and Reason are false (A) Both Assertion & Reason are true and
statements the reason is the correct explanation of
the assertion
94. A : A mixture of chloroform and acetone (B) Both Assertion & Reason are true but
forms a solution with negative deviation from the reason is not the correct
Raoult's law. explanation of the assertion
R : Chloroform molecule is able to form (C) Assertion is true statement but Reason
hydrogen bond with acetone molecule. is false
(A) Both Assertion & Reason are true and (D) Both Assertion and Reason are false
the reason is the correct explanation of statements
the assertion
(B) Both Assertion & Reason are true but
the reason is not the correct
explanation of the assertion
(C) Assertion is true statement but Reason
is false
(D) Both Assertion and Reason are false
statements
99. A : The freezing point of 0.1 m glucose 103. A : Heat is evolved when anhydrous form of
solution is higher than that of 0.1 m NaCl salt gets hydrated.
solution. R : Hydration involves bond formation
R: Depression in freezing point is directly between water and ions of salt.
proportional to the number of moles of non- (A) Both Assertion & Reason are true and
volatile solute particles present in the the reason is the correct explanation of
solution. the assertion
(A) Both Assertion & Reason are true and (B) Both Assertion & Reason are true but
the reason is the correct explanation of the reason is not the correct
the assertion explanation of the assertion
(B) Both Assertion & Reason are true but (C) Assertion is true statement but Reason
the reason is not the correct is false
explanation of the assertion
(D) Both Assertion and Reason are false
(C) Assertion is true statement but Reason statements
is false
(D) Both Assertion and Reason are false
statements 104. A : Ethylene glycol is used as coolant in car
radiators under the name of coolant
Prestone.
100. Two liquids A and B have Po and Po in R : Lower the vapour pressure of a given
A B

the ratio of 1 : 4 and the ratio of the number substance, smaller will be its boiling point.
of moles of A and B in liquid phase are 1 : 5. (A) Both Assertion & Reason are true and
Then the mole fraction of B in vapour phase the reason is the correct explanation of
in equilibrium with the solution is equal to the assertion
(A) 20 (B) Both Assertion & Reason are true but
21 the reason is not the correct
(B) 18
explanation of the assertion
19
(C) Assertion is true statement but Reason
(C) 19
is false
21

(D) 18 (D) Both Assertion and Reason are false

21 statements

101. A : When red blood cells are placed in 105. 5 g of a non-volatile, non-electrolyte solute is
distilled water, water flows into the cells. dissolved in 250 g of water. If molar mass of
R : Direction of osmosis is from hypertonic solute is 80 g mol–1 then the freezing point
solution to hypotonic solution. of the solution will be
(A) Both Assertion & Reason are true and (Kf of water = 1.86 K kg mol–1 )
the reason is the correct explanation of
the assertion (A) –1.52°C
(B) Both Assertion & Reason are true but (B) –0.46°C
the reason is not the correct (C) –0.12°C
explanation of the assertion (D) –2.5°C
(C) Assertion is true statement but Reason
is false
106. At 2 atm pressure, mole of O2 (g) dissolved in
(D) Both Assertion and Reason are false
10 moles water at 293 K is (Henry’s constant
statements
for O2 (g) in water is 0.3 × 105 atm)
(A) 6.67 × 10–3
102. A : Osmosis involves movement of solvent
molecules from higher concentration of (B) 6.67 × 10–5
solution to its lower concentration. (C) 6.67 × 10–4
R : Solutions having different osmotic
pressures are called isotonic solutions. (D) 6.67 × 10–6
(A) Both Assertion & Reason are true and
the reason is the correct explanation of
the assertion 107. If the mass ratio of methanol and water in a
solution is 4 : 9, then the mole fraction of
(B) Both Assertion & Reason are true but methanol in the solution will be
the reason is not the correct
(A) 0.4
explanation of the assertion
(B) 0.1
(C) Assertion is true statement but Reason
is false (C) 0.6
(D) Both Assertion and Reason are false (D) 0.2
statements
108. What will be the value of PoB if total pressure
of the solution is given by PTotal = 75 +
150XB mm Hg?
(A) 225 mm Hg
(B) 200 mm Hg
(C) 75 mm Hg
(D) 150 mm Hg

109. In the following question, a statement of

assertion (A) is followed by a statement of
reason (R).
A : If 0.1 m NaCl solution boils at 101°C then
0.1 m BaCl2 solution will boil at
approximately 101.5°C
R : i ≃ 2 for 0.1 m NaCl solution and i ≃ 3 for
0.1 m BaCl2 solution.
(A) Both Assertion & Reason are true and
the reason is the correct explanation of
the assertion
(B) Both Assertion & Reason are true but
the reason is not the correct
explanation of the assertion
(C) Assertion is true statement but Reason
is false
(D) Both Assertion and Reason are false
statements