SIR M.

V EDUCATION TRUST(R)

SIR M.V GROUP OF INSTITUTIONS

Near Government ITI College, Hadadi Road, Davangere

2nd PU 2nd PU Grand Test-1 Date: 2024-10-02 18:28:00

Time: 50m:00s Marks: 180

Sub: Chemistry - 1 PUC Full Syllabus

Instructions:
(i) There are two sections in each subject, i.e. Section-A & Section-B. You have to attempt all 35 questions from
Section-A & only 10 questions from Section-B out of 15.
(ii) Each question carries 4 marks. For every wrong response 1 mark shall be deducted from the total score.
Unanswered/unattempted questions will be given no marks.
(iii) Use blue/black ballpoint pen only to darken the appropriate circle.
(iv) Mark should be dark and completely fill the circle.
(v) Dark only one circle for each entry.
(vi) Dark the circle in the space provided only.
(vii) Rough work must not be done on the Answer sheet and do not use white-fluid or any other rubbing material on the
Answer sheet.

NEET Section A (35 MCQ) (Chemistry)

51. The de-Broglie wavelength of a ball of mass 10 g moving with a velocity of

10 ms
−1
is [h = 6.626 × 10 J s] −34

(1) 6.626 × 10 −33

m (2) 6.626 × 10 m
−29
(3) 6.626 × 10 m
−31
(4) 6.626 × 10
−36
m

52. The number of oxygen atoms present in 14.6 g of magnesium bicarbonate is:
NA
(1) 6N A
(2) 0.6N A
(3) N A
(4) 2

53. The behaviour of lithium and magnesium is similar to each other. This suggests that both Li and M g
(1) have diagonal relationship (2) belong to same group (3) belong to groups at extreme ends
(4) Both (a) and (b)

54. In which of the following pairs, the two species are not isostructural?
(1) C O 3 and, N O
2− −

3
(2) P C l and S iC l
+

4
4 (3) P F and BrF 5 5 (4) AlF
3−

6
and S F 6

55. According to MOT, the species O possesses

+

(1) bond order of 2.5 (2) three unpaired electrons (3) diamagnetic character (4) stability lower than O 2

56. At what temperature liquid water will be in equilibrium with water vapour?
ΔH vap− 40.73 kJ mol , ΔS = 0.109 kJ K mol
−1
vap
−1 −1

(1) 282.4 K (2) 373.6 K (3) 100 K (4) 400 K

57. The difference between ΔH and ΔU at constant volume is equal to

(1) R (2) P ΔV (3) V ΔP (4) 3

2
R
58. A plot of log 10
K and 1

T
is linear with a slope, −6720 K and intercept +9.72 for H 2 O(l) ⇌ H
+
+ OH
−

Thus, at 300 K , log10 K is

(1) 12.08 (2) 2.96 (3) -2.96 (4) -12.68

59. In the following reaction

− 3− 2− 2−
H C2 O + PO ⇌ HP O + C2 O
4 4 4 4

which pair can act as Bronsted bases only?

(1) H C O and P O 2 4 (2) H P O
−
and C 4
3−
4
2−
2 O4
2−
(3) H C2 O 4
−
and H P O 4
2−
(4) P O4
3−
and C 2 O4
2−

60. K a1 , Ka2 and K a3 are the respective ionisation constants for the following reactions:
+ −
H2 S ⇌ H + HS

+ 2−
H2 S ⇌ H + S

+ 2−
H 2 S ⇌ 2H + S

The correct relationship between K a1 , Ka2 and K a3 is

(1) K = K × K a3 (2) K
a1 a2 a3 = Ka1 + Ka2 (3) Ka3 = Ka1 − Ka2 (4) Ka3 = Ka1 /Ka2

61. Thiosulphate reacts differently with iodine and bromine in the reactions given below:
2− 2− −
2S2 O + I2 → S4 O + 2I
3 6

2− 2− − +
S2 O + 2Br2 + 5H 2 O → 2S O + 2Br + 10H
3 4

Which of the following statements justifies the above dual behaviour of thiosulphate?
(1) Bromine is a stronger oxidant than iodine. (2) Bromine is a weaker oxidant than iodine.
(3) Thiosulphate undergoes oxidation by bromine and reduction by iodine in these reactions.
(4) Bromine undergoes oxidation and iodine undergoes reduction in these reactions.

62. Which of the following compounds does not contain all the carbon atoms in the same hybridisation state?
(1) H − C ≡ C − C ≡ C − H (2) H C ≡ C H (3) C H = C = C H (4) C H = C H − C H = C H 2 2 2 2

63. Acetone and Propanal are

(1) Functional isomers (2) Position isomers (3) Geometrical isomers (4) Optical isomers

64. The optically active molecule is

(1) (2) (3) (4)

65. Which of the following is the correct I U P AC name?

(1) 3-Ethyl-4, 4-dimethylheptane (2) 4, 4-Dimethyl-3-ethylheptane (3) 5-Ethyl-4, 4-dimethylheptane
(4) 4, 4-Bis(methyl)-3-ethylheptane
66. What is the correct order of decreasing stability of the following cations?

(1) II > I > III (2) II > III > I (3) III > I > II (4) I > II > III

67. Arrange the following carbanions in order of their decreasing stability.

−
(I ) H 3 C − C ≡ C

−
(I I ) H − C ≡ C

−
(I I I ) H 3 C − C H
2

(1) I > II > III (2) II > I > III (3) III > II > I (4) III > I > II

68. When C H − C
3 ≡ CH reacts with one mole of H Br then product obtained is
(1) bromoethene (2) dibromopropane (3) 2-bromopropene (4) 1-bromopropane

69. For alkali metals, which one of the following trends is INCORRECT?
(1) Ionization energy : Li > N a > K > Rb (2) Hydration energy : Li > N a > K > Rb

(3) Atomic size : Li < N a < K < Rb (4) Density : Li < N a < K < Rb

70. The carbonate of which of the following is insoluble in water

(1) Sodium (2) Potassium (3) Lithium (4) Caesium

71. Which of the graphs shown below does not represent the relationship between incident light and the electron
ejected form metal surface ?

(1) (2) (3) (4)

72. The number of significant figures for the three numbers161 cm, 0.161 cm, 0.0161 cm
(1) 3,4 and 5 respectively (2) 3,4 and 4 respectively (3) 3,3 and 4 respectively (4) 3,3 and 3 respectively

73. Which of the following arrangments is possible?

(1) n = 5, l = 2, m = 2, s = + 1

2
(2) n = 2, l = 2, m = 0, s = −
1

(3) n = 3, l = −2, m = 1, s = +
1

2
(4) n = 0, l = 0, m = 1, s = +
1

74. A gas expands from a volume of 1 m to a volume of 2 m against an external pressure of 10

3 3 5
Nm
−2
. The
workdone by the gas will be
(1) 10 K J
5
(2) 10 K J 2
(3) 10 J 2
(4) 10 J 3
75. Match the following based on the effect of temperature on spontaneity of reaction
Description ΔH
0
ΔS
0
ΔG
0

1 Reaction spontaneous at all “T” p + + - (At high

‘T’)
2 reaction non spontaneous at all “T” q - - + (At high
‘T’)
3 Reaction spontaneous at high “T” r - + -
4 Reaction non spontaneous at high s + - + (At high
“T” ‘T’)
(1) 1-s; 2-r; 3-p; 4-q (2) 1-s; 2-r; 3-q; 4-p
(3) 1-r; 2-s; 3-p; 4-q (4) 1-r; 2-s; 3-q; 4-p

76. In tribromooctaoxide ( Br O ) oxidation states of bromine respectively.

3 8

(1) 0, +6, −6 (2) −6, 0, +6 (3) +6, +4, +6 (4) +2, +4, +6

77. In oxidation reduction reaction? M nO −

4
+ C2 O
2−

4
+ H
+
→ Mn
+2
+ C O 2 + H2 O the balance equation
coefficients for M nO , C O , H are−

4
2
2−

4
+

(1) 2, 5, 16 (2) 16, 5, 2 (3) 2, 16, 5 (4) 5, 2, 16

78. xI −
+ yM nO
−

4
+
z

2
H2 O →
x

2
I2 + yM nO 2 + zOH
−
. In the above reaction x , y and z are (in basic
medium)
(1) 2,4 and 8 (2) 6,2 and 8 (3) 8,2 and 6 (4) 3, 2 and 6

79. Which of the following decomposition reaction is not a redox reaction

Δ
(3)
Δ

(1) 2K C lO 3 −
→ 2K C l + 3O 2 (2) 2N aH −
→ 2N a + H 2
2H 2 O ⟶ 2H 2 + O 2

(4) C aC O 3 ⟶ C aO + C O 2

80. The correct decreasing order for acid strength is

(1) F C H C OOH > N C C H C OOH > N O C H
2 2 2 2 C OOH > C lC H 2 C OOH

(2) N C C H C OOH > O N C H C OOH > F C H

2 2 2 2 C OOH > C lC H 2 C OOH

(3) N O 2 C H 2 C OOH > N C C H 2 C OOH > F C H 2 C OOH > C lC H 2 C OOH

(4) N O 2 C H 2 C OOH > F C H 2 C OOH > N C C H 2 C OOH > C lC H 2 C OOH

81. The formula of the compound which gives violet colour in Lassaigne's test for sulphur with sodium
nitroprusside is
(1) N a [F e(C N ) S ] (2) N a [F e(C N ) N C S ] (3) N a [F e(C N ) N OS ] (4) N a [F e(C N ) N OS ]
4 6 4 5 4 5 2 5

82. Kjeldahl method for estimation of nitrogen is not applicable to

(1) Aniline (2) Acetonitrile (3) Pyridine (4) Benzamide

83. 2.18 g of an organic compound containing sulphur produces 1.02 g of BaS O 4 The percentage of sulphur in
the compound is
(1) 7.26% (2) 8.98% (3) 10% (4) 6.42%
84. Which compound amongst the following is not an aromatic compound?

(2)
(1) (3) (4)

85. Identify ‘X ’ in the following reaction

(1) (2) (3) (4)

NEET Section B (15 MCQ) (Chemistry)

86. The mass of C aO obtained by heating 100 kg of 95% pure limestone (C aC O 3) is -

(1) 56 kg (2) 28 kg (3) 53.2 kg (4) 50 kg

87. Haemoglobin contains 0.33% of iron by weight. The molecular weight of haemoglobin is approximately
67200 g . The number of iron atoms (at. weight of F e is 56 ) present in one molecule of haemoglobin are
(1) 1 (2) 6 (3) 4 (4) 2

88. For d -electron, the orbital angular momentum is

(1)
√ 6h
(2)
√ 2h
(3) h

2π
(4) 2h

π
2π 2π

89.

In the following electron-dot structure, calculate the formal charge on each nitrogen atom from left to right.
(1) -1, -1, +1 (2) -1, +1, -1 (3) +1, -1, -1 (4) +1, -1, +1

90. Consider the reactions given below. On the basis of these reactions find out which of the algebric relations
given in options (a) to (d) is correct?
(i) C + 4H
(g) (g)
→ C H 4(g) ; Δ r H = x kJ mol
−1

(ii) C (graphite, s)
+ 2H 2(g) → C H 4(g) ; Δ r H = y kJ mol
−1

(1) x = y (2) x = 2y (3) x > y (4) x < y

91. If K for H gS O is 6.4 × 10

sp 4
−5
,then solubility of its salt is:
(1) 6.4 × 10 mol litre (2)
−5 −1
6.4 × 10
−3
mol litre
−1
(3) 8 × 10 −6
mol litre
−1
(4) 8 × 10
−3 −1
mol litre

92. Arrange the following in decreasing order of their boiling points:

(I) n -Butane
(II) 2-Methylbutane
(III) n -Pentane
(IV) 2,2-Dimethylpropane
(1) I > I I > I I I > I V (2) II > III > IV > I

(3) IV > III > II > I (4) III > II > IV > I
 93. In Duma’s method 0.52 g of an organic compound on combustion gave 68.6 mL N2 at ∘
27 C and 756 mm
pressure. What is the percentage of nitrogen in the compound?
(1) 12.22% (2) 14.93% (3) 15.84% (4) 16.23%

94. The following reaction is known as

AlC l3

C6 H 6 + C H 3 C l −−−−→ C6 H 5 C H 3 + H C l
(anhy.)

(1) Wurtz-Fittig reaction (2) Friedel-Crafts reaction (3) Rosenmund reaction (4) Sandmeyer reaction

95. How many isomers are possible for the compound having molecular formula C 3 H 5 Br3 ?

(1) 5 (2) 4 (3) 6 (4) 8

96. The most suitable method of separation of 1 : 1 mixture of ortho and para-nitrophenols is :
(1) Chromatography (2) Crystallisation (3) Steam distillation (4) Sublimation

97. The correct statement regarding electrophile is :

(1) Electrophile is a negatively charged species and can form a bond by accepting a pair of electrons from
another electrophile
(2) Electrophiles are generally neutral species and can form a bond by accepting a pair of electrons from a
nucleophile
(3) Electrophile can be either neutral or positively charged species and can form a bond by accepting a pair of
electrons from a nucleophile
(4) Electrophile is a negatively charged species and can form a bond by accepting a pair of electrons from a
nucleophile

98. Paper chromatography is an example of :

(1) Adsorption chromatography (2) Partition chromatography (3) Thin layer chromatography
(4) Column chromatography

99. During change of O to O ion, the electron adds on which one of the following orbitals ?
2
−

(1) π orbital (2) σ orbital ∗

(3) σ orbital (4) π orbital ∗

100. pH of a saturated solution of Ba(OH ) is 12 . The value of solubility product K

2 sp of Ba(OH ) is 2

(1) 3.3 × 10
−7
(2) 5.0 × 10
−7
(3) 4.0 × 10
−6
(4) 5.0 × 10
−6

Chemistry - 50Q
51) 1 52) 2 53) 1 54) 3 55) 1 56) 2 57) 3 58) 4 59) 4 60) 1
61) 1 62) 3 63) 1 64) 3 65) 1 66) 1 67) 2 68) 3 69) 4 70) 3
71) 3 72) 4 73) 1 74) 1 75) 3 76) 3 77) 1 78) 2 79) 4 80) 3
81) 3 82) 3 83) 4 84) 3 85) 1 86) 3 87) 3 88) 1 89) 2 90) 3
91) 4 92) 4 93) 2 94) 2 95) 1 96) 3 97) 3 98) 2 99) 4 100) 2
51. m = 10 g = 0.01 kg, v = 10 ms −1

According to de-Broglie equation,

h
λ =
mv
−34
6.626×10
=
0.01×10

−33
= 6.626 × 10 m

52. Magnesium bicarbonate is M g(H C O 3)

2
So, 146g of M g(H C O 3)
2
contains O atom = 0.6 NA
53. The behaviour of lithium is more similar to that of magnesium, which refers to a diagonal relationship between
the two as both belongs to adjacent groups and are diagonally placed.

54. (a) CO
2−

3
, NO
−

3
Triangular planar
(b) P Cl
+

4
, S iC l4 Tetrahedral
(c) P F 5 , BrF 5 Trigonal bipyramidal
(d) AlF
6
3−
, S F6 Square pyramidal
Octahedral

55. O (15electrons ): K K σ2s

+

2
2 ∗ 2 2 2 2 ∗ 1
σ 2s σ2pz π2px = π2py π 2px = π 2py
⋆ 0

8−3
B. O. = = 2.5
2

56. At equilibrium ΔG = 0 for ΔG = ΔH − T ΔS

or T = =
ΔH

ΔS
40.73

0.109

= 373.6 K

57. H = U + P V ⇒ ΔH

= ΔU + P ΔV + V ΔP

At constant volume, ΔV = 0

Hence ΔH = ΔU + V ΔP

i.e., ΔH − ΔU = V ΔP

∘ ∘

58. log 10
K =
ΔH

2.303 RT
+
ΔS

2.303 R

Slope = −
ΔH

2.303 R
= −6720

Intercept ΔS

2.303 R
= −9.72

6720
∴ log10 K = − + 9.72
300

log10 k = −12.68.

59. P O and C O
3−

4
2
2−

4
cannot release H +
thus cannot act as bronsted acid. Instead they accept protons and act as
bronsted bases.
60. For the reaction:
+ −
H2 S ⇌ H + HS ; Ka1
+ −
[H ][H S ]
Ka1 = … (i)
[H 2 S]

For the reaction:

− + 2−
HS ⇌ H + S ; Ka2
+ 2−
[H ][S ]
Ka2 = −
… (ii)
[H S ]

For the reaction:

+ 2−
H 2 S ⇌ 2H + S ; Ka3
2
+ 2−
[H ] [S ]
Ka3 = … (iii)
[H 2 S]

By multiplying eqn. (i) and eqn. (ii), we get

+ − + 2−
[H ][H S ] [H ][S ]
Ka × Ka = ×
1 2 [H S] −
2 [H S ]

+ 2 2−
[H ] [S ]
= = Ka
3
[H 2 S]

61. Br oxidises S to a higher oxidation state

2 and I oxidises S to a lower
2

oxidation state . Thus, Br is stronger oxidising agent than I . 2 2

62. Hybridisation of carbon atoms in different compounds is shown below :

In options (a), (b) and (d), all carbon atoms are in same hybridisation state, i.e. in sp, sp and sp - 2

hybridisation respectively. Only option (c) does not contain all the carbon atom in same hybridisation.
63. In functional isomerism, molecules have same, molecular formula, but different functional groups. Aldehydes
show functional isomerism with ketones

64.

Only molecule (c) is optically active. Other moelcules are meso, due to presence of plane o f symmetry.
65. While writing the name of the substituents in alphabetical order, the prefixes such as di, tri, tetra, penta, hexa,
etc. are not considered. Therefore, as "e" of ethyl comes before "m" of dimethyl thus, lower locant 3 assigned
to ethyl group and is written first. Hence, the correct IUPAC name is 3-Ethyl-4,4-dimethylbutane.

66.

Thus, the stability of carbocations decreases in the order : I I > I > III .

67. The order of decreasing stability of carbanions is:

sp-hybridised carbon atom is more electronegative than sp -hybridised carbon atom and hence, can
3

accommodate the negative charge more effectively. — C H group has +I effect, therefore, it intensifies the
3

negative charge and hence, destabilises the carbanion

68. The complete reaction is shown below :

Thus, product is 2-bromopropene.

69. In general, density increases on moving downward in a group but density of potassium

(K) is lesser than that of the sodium (Na).

This is because of the abnormal increase in atomic size on moving from Na (86 pm) to K (227 pm).

Thus, the correct order of density is

Li < K < N a < Rb

70. Lithium carbonate is sparingly soluble in water. The carbonates of other alkali metals are soluble in water.

71. E = W +
1

2
mv
2

K . E. = hv − 4v0

K . E. = hv + (−hv0 )

y = mx + C
––
72. (d) (i) All non-zero digits are significant.
(ii) Non-zero digits to the right of the decimal point are significant.
(iii) Zeroes to the left of the first non-zero digit in a number are not significant.
So, the number of significant figures for the numbers 161 cm, 0.161 cm and 0.0161 cm are same, i.e. 3.

74. W = P ΔV 1N m = J

76.

77. 2M nO −

4
+ 5C 2 O
2−

4
+ 16H
+
→ 2M n
+2
+ 10C O 2 + 8H 2 O

78.

79. C aC O oxidation states of C a, C and O does not changes

3

80.
Order of electron withdrawing effect exerting group is
−N O 2> −C N > −F > −C l .

Hence, the acid strength order is

O 2 N C H 2 C OOH > N C C H 2 C OOH >

F C H 2 C OOH > C lC H 2 C OOH .

81. If sulphur is present in the organic compound, sodium fusion will converted into sodium sulphide. Sulphide
ions are easily identified using sodium nitroprusside
2N a + S → N a 2 S

N a 2 S + N a 2 [F e(C N )5 N O] → N a 4 [F e(C N )5 N OS ]

82. Kjeldahl method is not applicable to compounds containing nitrogen in nitro and azo groups and nitrogen
present in the ring such as pyridine.

83. % of S =
32

233
×
1.02

2.18
× 100 = 6.42%

84.

85. C 6 C l6
86. C aC O 3 ( s ) → C aO ( s ) + C O 2 ( g )

mass = 10 ×95

100×100
× 56 gm

= 53.2 kg

87. ∵ of iron by weight means 100 g of haemoglobin has 0.33 g of iron

0.33%

100 g of haemoglobin contains iron = 0.33 g

∴ 67200 g of haemoglobin contains iron

0.33×67200
= g = 221.76g of F e
100

Number of Fe-atoms = 221.76

56

= 3.96 ≈ 4

−− −−−−
88. The orbital angular momentum (L) = √l(l + 1)
h

2π
–
= √6
h

2π
(l = 2 for d - orbital )

89. Formal charge on an atom

= total no. of valence electrons in the free atom - total no. of non-bonding electrons − 1

2
× total no. of bonding
electrons
1 1
N = 5 − 4 − × 4 = 5 − 6 = −1
2

2 1
N = 5 − 0 − × 8 = 5 − 4 = +1
2

3 1
N = 5 − 4 − × 4 = −1
2

90. In eqn (i) , no bond is being broken while in eqn (ii), 2 H − H bonds are broken. So, in eqn (ii) some of the
energy is used up to break the bonds. Thus, x > y.
−−−
91. Given that, K sp for H gS O 4 = 6.4 × 10
−5
H gS O 4 is a binary salt, hence, for it, K sp = S
2
∴ S = √Ksp
−−−−−−− −
−5 −3
= √6.4 × 10 = 8 × 10 mol/litre

92. Boiling point of alkanes increases with increase in molecular mass and for the same alkane the boiling point
decreases with branching.
Thus, the decreasing order of their boiling points is :
n − Pentane > 2 − Methylbutane > 2, 2 − Dimethylpropane > n − Butane
(I I I ) (I I ) (I V ) (I )

93. V 1 = 68.6 mL P 1 = 756 mm , ,T 1 = 300 K

V 2 =? ,p 2 = 760 mm ,T 2 = 273 K
P1 V 1 P2 V 2
=
T1 T2
P1 V 1 T2
At N T P , vol. of N 2, V2 =
T1
⋅
P2
=
756×68.6

300
×
273

760

= 62.09 mL

Percentage of nitrogen in organic compound

28 V2
= × × 100
22400 w

28 62.09
= × × 100
22400 0.52

= 14.93%

94. Alkylation and acylation of benzene in the presence of anhydrous aluminium chloride are known as Friedel-
Crafts reaction.
 95. C 3 H 5 Br3

96. Steam distillation is the most suitable method of separation of 1 : 1 mixture of ortho and para nitrophenols as
there is intramolecular H-bonds in ortho nitrophenol.

97. Electrophiles are either neutral (electron-deficient) or positively charged species.

These are electron deficient or electron loving species and can form a bond by accepting a pair of electrons
from a nucleophile.
For example, N O , Br , R C , S O , F eC l etc.
+

2
+
3
+
3 3

98. Paper Chromatography is a type of partition chormatography. Chormatography paper contains water trapped in
it, which acts as the stationary phase. The paper selectively retains different components according to their
differing partition in two phases.

99. configuration of O is −

2 ∗ 2 2 2 2 ∗ 2 ∗ 1
K K σ(2s) σ (2s) σ(2pz) π(2px) π(2py) π (2px) π (2py)

100. Ba(OH ) 2 ⇄ Ba
2+
+ 2OH
−

pH = 12 ⇒ p(OH ) = 14 − pH

→ p(OH ) = 14 − 12 = 2

[OH
−
] = 10
−P OH
= 10
−2
or 1 × 10 −2

as conc. of Ba 2+
is half of OH −

2+ −2
→ Ba = 0.5 × 10
2
−2 −2
Ksp = (0.5 × 10 ) (1 × 10 )

−6
Ksp = 0.5 × 10

−7
= 5 × 10