1

04.02.2025
 Useful Data

PHYSICS

Acceleration due to gravity g = 10m/s2

Planck constant h = 6.6  1034 J-s

Charge of electron e = 1.6  1019 C

Mass of electron me = 9.1  1031 kg

Permittivity of free space o = 8.85  1012 C2/N-m2

Density of water water = 103 kg/m 3

Atmospheric pressure Pa = 105 N.m2

Gas constant R = 8.314 J K1 mol1

CHEMISTRY

Gas constant R = 8.314 J K1 mol1

= 0.0821 Lit atm K1 mol1
= 1.987  2 Cal K1 mol1
Avogadro’s Number Na = 6.023  1023
Planck’s constant h = 6.625  1034 J.s
= 6.625  1027 erg.s
1 Faraday = 96500 coulomb
1 Calorie = 4.2 joule
1 amu = 1.66  1027 kg
1 eV = 1.6  1019 J

Atomic No. H = 1, He = 2, Li = 3, Be = 4, B = 5, C = 6, N = 7, O = 8, N = 9
Na = 11, Mg = 12, Si = 14, Al = 13, P = 15, S = 16, Cl = 17, Ar = 18,
K = 19, Ca = 20, Cr = 24, Mn = 25, Fe = 26, Co = 27, Ni = 28, Cu = 29,
Zn = 30, As = 33, Br = 35, Ag = 47, Sn = 50, I = 53, Xe = 54, Ba = 56,
Pb = 82, U = 92.
Atomic masses : H = 1, He = 4, Li = 7, Be = 9, B = 11, C = 12, N = 14, O = 16, F = 29,
Na = 23, Mg = 24, Al = 27, Si = 28, P = 31, S = 32, Cl = 35.5, K = 39,
Ca = 40, Cr = 52, Mn = 55, Fe = 56, Co = 59,Ni = 58.7, Cu = 63.5,
Zn = 65.4, As = 75, Br = 80, Ag = 108, Sn = 118.7, I = 127, Xe = 131,
Ba = 137, Pb = 2.7, U = 238.
 PART-1-PHYSICS
SECTION-A
Single Correct Choice Type

This section contains 20 multiple choice questions. Each question has 4 choices (A), (B), (C)
and (D), out of which ONLY ONE is correct.
Q1. The Wheatstone bridge shown in Fig. here, gets balanced when the carbon
resistor used as R1 has the colour code (Orange, Red, Brown). The resistors
R2 and R4 are 80  and 40 , respectively.
Assuming that the colour code for the carbon resistors gives their accurate
values, the colour code for the carbon resistor, used as R3 would be:
(A) Brown, Blue, Brown (B) Brown, Blue, Black
(C) Red, Green, Brown (D) Grey, Black, Brown

Q2. Consider the nuclear fission Ne 20  2He 4  C12 .Given that the binding energy / nucleon of Ne20,
He4 and C12 are, respectively, 8.03 MeV, 7.07 MeV, and 7.86 MeV, identify the correct statement:
(A) energy of 12.4 MeV will be supplied (B) 8.3 MeV energy will be released
(C) energy of 3.6 MeV will be released (D) None

Q3. A hoop and a solid cylinder of same mass and radius are made of a permanent magnetic material
with their magnetic moment parallel to their respective axes. But the magnetic moment of hoop is
twice of solid cylinder. They are placed in a uniform magnetic field in such a manner that their
magnetic moments make a small angle with the field. If the oscillation periods of hoop and
cylinder are Th and TC respectively, then :
(A) Th  TC (B) Th  2TC
(C) Th  1.5TC (D) Th  0.5C

Q4. An unknown metal of mass 192 g heated to a temperature of 100°C was immersed into a brass
calorimeter of mass 128 g containing 240 g of water at a temperature of 8.4°C. Calculate the
specific heat of the unknown metal if water temperature stabilizes at 21.5°C. (Specific heat of
brass is 394 J kg–1 K–1)
(A) 458 J kg–1 K–1 (B) 1232 J kg–1 K–1
–1 –1
(C) 916 J kg K (D) 654 J kg–1 K–1

Q5. Two identical spherical balls of mass M and radius R each are stuck
on two ends of a rod of length 2R and mass M (see figure). The
moment of inertia of the system about the axis passing
perpendicularly through the centre of the rod is :
137 17
(A) MR2 (B) MR2
15 15
209 152
(C) MR2 (D) MR2
15 15

Q6. The self produced emf of a coil is 25 volts. When the current in it is changed at uniform rate from
10 A to 25 A in 1 s, the change in the energy of the inductance is :
(A) 740 J (B) 437.5 J
(C) 540 J (D) 637.5 J
Q7. The actual value of resistance R, shown in the figure is 30 . This is
measured in an experiment as shown using the standard formula
V
R , where V and I are the readings of the voltmeter and ammeter,
I
respectively. If the measured value of R is 5% less, then the internal
resistance of the voltmeter is :
(A) 600  (B) 570 
(C) 35  (D) 350 
–6
Q8. At some location on earth the horizontal component of earth’s magnetic field is 18  10 T. At
this location, magnetic needle of length 0.12 m and pole strength 1.8 A m is suspended from its
mid-point using a thread, it makes 45° angle with horizontal in equilibrium. To keep this needle
horizontal, the vertical force that should be applied at one of its ends is :
(A) 3.6  105 N (B) 1.8  105 N
(C) 1.3  105 N (D) 6.5  10 5 N

   
Q9. Two vectors A and B have equal magnitudes. The magnitude of  A  B  is ‘n’ times the
   
 
magnitude of A  B . The angle between A and B is:

 n2  1  n  1
(A) cos1  2  (B) cos1  
 n  1  n  1
 n2  1  n  1
(C) sin1  2  (D) sin1  
 n  1  n  1

Q10. A metal plate of area 1  10–4 m 2 is illuminated by a radiation of intensity 16 mW/m2. The work
function of the metal is 5eV. The energy of the incident photons is 10 eV and only 10% of it
produces photo electrons. The number of emitted photo electrons per second and their maximum
energy, respectively, will be : [1 eV = 1.6  10–19 J]
(A) 1014 and 10 eV (B) 1012 and 5 eV
11
(C) 10 and 5 eV (D) 1010 and 5 eV
  
Q11. A particle which is experiencing a force, given by F  3 i  12 j, undergoes a displacement of
 
d  4 i . If the particle had a kinetic energy of 3 J at the beginning of the displacement, what is its
kinetic energy at the end of the displacement?
(A) 9 J (B) 12 K
(C) 10 J (D) 15 J

Q12. Consider a Young’s double slit experiment as shown in figure. What

should be the slit separation d in terms of wavelength  such that the
first minima occurs directly in front of the slit (S1)?
 
(A) (B)
2( 5  2) ( 5  2)
 
(C) (D)
2(5  2) (5  2)

Q13. The eye can be regarded as a single refracting surface. The radius of curvature of this surface is
equal to that of cornea (7.8 mm). This surface separates two media of refractive indices 1 and
1.34. Calculate the distance from the refracting surface at which a parallel beam of light will come
to focus.
 (A) 1 cm (B) 2 cm
(C) 4.0 cm (D) 3.1 cm

Q14. A current of 2 mA was passed through an unknown resistor which dissipated a power of 4.4 W.
Dissipated power when an ideal power supply of 11 V is connected across it is :
(A) 11 105 W (B) 11 103 W
(C) 11 104 W (D) 11 105 W

Q15. The diameter and height of a cylinder are measured by a meter scale to be 12.60.1 cm and 34.2
 0.1 cm, respectively. What will be the value of its volume in appropriate significant figures?
(A) 426481 cm 3 (B) 426481.0 cm3
3
(C) 426080 cm (D) 430080 cm 3
Q16. For equal point charges Q each are placed in the xy plane at (0, 2), (4, 2), (4, –2) and
(0, –2). The work required to put a fifth change Q at the origin of the coordinate system will be :
Q2  1  Q2  1 
(A) 1   (B) 1  
4  0  3 4  0  3
Q2 Q2
(C) (D)
2 2 0 4 0

Q17. The modulation frequency of an AM radio station is 250 kHz, which is 10% of the carrier wave. If
another AM station approaches you for license what broadcast frequency will you allot?
(A) 2750 kHz (B) 2900 kHz
(C) 2250 kHz (D) 2000 kHz

Q18. A closed organ pipe has a fundamental frequency of 1.5 kHz. The number of overtones that can
be distinctly heard by a person with this organ pipe will be : (Assume that the highest frequency a
person can hear is 20,000 Hz)
(A) 6 (B) 4
(C) 7 (D) 5

Q19. For the circuit shown below, the current through the Zener diode is :

(A) 9 mA (B) 5 mA
(C) Zero (D) 14 mA

Q20. The electric field of a plane polarized electromagnetic wave in free space at time t = 0 is given by
an expression

E(x, y)  10 ˆj cos[(6x  8z)]

The magnetic field B (x,z, t) is given by : (c is the velocity of light)
1 ˆ 1 ˆ
(A)
c
 
6k  8iˆ cos [(6x  8z  10 ct)] (B) 
c

6k  8iˆ cos[(6x  8z  10 ct)]

1 ˆ 1 ˆ
(C)
c
 
6k  8iˆ cos[(6x  8z  10 ct)] (D) 
c

6k  8iˆ cos[(6x  8z  10 ct)]
 Section-B
(Numerical Answer Type)

This section contains 05 questions. Each question, when worked out will result in numerical answer

Q21. Particle of mass m is moving in a circular path of constant radius r, such that its centripetal
acceleration ac is varying with time as ac = k2rt2, where k is a constant power delivered to the
particle by the forces acting on it is, given by P = m(kr)nt. Find n

Q22.  
A force F  yiˆ  r ˆj N is acting particle of mass m. If it is displaced from (3,4) to (5,3) then work
done by the force F is n. Find n.

Q23. A point moves along a circle of radius r with constant speed v. Its angular velocity about any fixed
point on the circle is given by x rad/ s
Find x, If v= 500m/s and r = 8 cm.

Q24. A uniform rod of length  and mass 2m rests on a smooth horizontal table. A point mass m
moving at right angle to the rod with velocity V collides with one end of the rod and sticks to it,
 
then the loss in K.E of the system is x mv 2  104 .
z
 
Q25. In the relation P  e K , P is pressure Z is distance, K is Boltzmann constant and  is

 3a  4b  6c 
temperature. If dimensional formula for  is given by  M a Lb T c  , then find  
   0.003 
 PART-2-CHEMISTRY
SECTION-A
Single Correct Choice Type

This section contains 20 multiple choice questions. Each question has 4 choices (A), (B), (C)
and (D), out of which ONLY ONE is correct.
Q1. The ground state energy of hydrogen atom is –13.6 eV. The energy of second excited state of
He+ ion in eV is:
(A) –54.4 (B) –3.4
(C) –6.04 (D) –27.2

Q2. Haemoglobin and gold sold are examples of:

(A) positively and negatively charged sols, respectively
(B) positively charged sols
(C) negatively charged sols
(D) negatively and positively charged sols, respectively

Q3. The major product of the following reaction is:

(A) (B)

(C) (D)

Q4. The amount of sugar (C12H22O11) required to prepare 2 L of its 0.1 M aqueous solution is :
(A) 136.8 g (B) 17.1 g
(C) 68.4 g (D) 34.2 g

Q5. Among the following reactions of hydrogen with halogens, the one that requires a catalyst is:
(A) H2  I2  2HI (B) H2  Cl2  2HCl
(C) H2  Br2  2HBr (D) H2  F2  2HF

Q6. 5.1 g NH4SH is introduced in 3.0 L evacuated flask at 327°C. 30% of the solid NH4SH
decomposed to NH3 and H2S as gases. The Kp of the reaction at 327°C is (R = 0.082 L atm mol–1
K–1, Molar mass of S = 32 g mol–1, molar mass of N = 14 g mol–1)
(A) 0.242  10–4 atm2 (B) 1  10–4 atm 2
(C) 4.9  10–3 atm 2 (D) 0.242 atm2

Q7. The reaction that is NOT involved in the ozone layer depletion mechanism in the stratosphere is :
   
uv
(A) CF2 Cl2 (g)  Cl(g)  CF2Cl(g) (B) Cl O(g)  O(g)  Cl(g)  O2 (g)
 
hv
(C) CH4  2O3  3CH2  O  3H2O (D) HOCl(g)  OH(g)  C l(g)
Q8. In the cell Pt(s) H2 (g,1bar) HCl(aq) AgCl(s) Ag(s) Pt(s) the cell potential is 0.92 V when a 10–6
molal HCl solution is used. The standard electrode potential of (AgCl / Ag,Cl ) electrode is :
 2.303RT 
Given,  0.06V at 298K 
 F 
(A) 0.94 V (B) 0.76 V
(C) 0.40 V (D) 0.20 V

Q9. The 71st electron of an element X with an atomic number of 71 enters into the orbital:
(A) 6p (B) 4f
(C) 5d (D) 6s

Q10. The correct match between item ‘I’ and item ‘II’ is:
Item ‘I’ Item ‘II’
(compound) (reagent)
(a) Lysine (p) 1-naphtol
(b) Furfural (q) Ninhydrin
(c) Benzyl alcohol (r) KMnO4
(d) Styrene (s) Ceric ammonium nitrate
(A) (a)(q); (b) (p); (c) (s); (d) (r) (B) (a)(q); (b) (p); (c) (r); (d) (s)
(C) (a)(r); (b) (p); (c) (q); (d) (s) (D) (a)(q); (b) (r); (c) (s); (d) (p)

Q11. An aromatic compound ‘A‘ having molecular formula C7H6O2 on treating with aqueous ammonia
and heating forms compound ‘B’. The compound ‘B’ on reaction with molecular bromine and
potassium hydroxide provides compound ‘C’ having molecular formula C6H7N. The structure of ‘A’
is :
(A) (B)

(C) (D)

Q12. The process with negative entropy change is:

(A) Dissociation of CaSO4(s) to CaO(s) and SO3(g)
(B) Sublimation of dry ice
(C) Dissolution of iodine in water
(D) Synthesis of ammonia from N2 and H2

Q13. An ideal gas undergoes isothermal compression from 5 m3 to 1 m3 against a constant external
pressure of 4 NM–2. Heat released in this process is used to increase the temperature of 1 mole
of Al. If molar heat capacity of Al is 24 J mol–1K–1, the temperature of Al is increases by:
3
(A) K (B) 2 K
2
2
(C) K (D) 1 K
3

Q14. Elevation in the boiling point for 1 molal solution of glucose is 2 K. The depression in the freezing
point for 2 molal solution of glucose in the same solvent is 2 K. The relation between Kb and Kf is :
 (A) K b  1.5K f (B) K b  K f
(C) K b  0.5K f (D) K b  2K f
Q15. The major product of the following reaction is :

(A) (B)

(C) (D)

Q16. Sodium metal on dissolution in liquid ammonia gives a deep blue solution due to the formation of:
(A) sodium-ammonia complex (B) sodamide
(C) sodium ion-ammonia complex (D) ammoniated electrons

 k d[A]
Q17. For an elementary chemical reaction, A 2 1

k 1
2A, the expression for is
dt
(A) k1[A 2 ]  k 1[A]2 (B) 2k1[A 2 ]  k 1[A]2
(C) k1[A 2 ]  k 1[A]2 (D) 2k1[A 2 ]  2k 1[A]2

Q18. Which of the following tests cannot be used for identifying amino acids?
(A) Biuret test (B) Barfoed test
(C) Ninhydrin test (D) Xanthoproteic test

Q19. The difference in the number of unpaired electrons of a metal ion in its high-spin and low-spin
octahedral complexes is two. The metal ion is :
(A) Ni2 (B) Fe2
(C) Co 2 (D) Mn2

Q20. The major product obtained in the following reaction is:

(A) (B)

(C) (D)
 Section-B
(Numerical Answer Type)

This section contains 05 questions. Each question, when worked out will result in numerical answer
type


Q21. B2 H 6  NH3 
 X  y  H 2 . Find total number of sp2 hybridised atoms per Y
compound
ionic

molecule

Q22. At what atomic number would a transition from n = 2 to n= 1 energy level results in emission of
photon of   3  10 8 m .

Q23. Heat of neutralization of 1 mole H2SO4 and 1 mole NaOH will be………………… K. Cal.

Q24. Calculate approx atomic wt of element (solid) if its specific heat is 0.00065 Cal / gm

Q25. Equivalent weight of KMnO4 in acidic medium is E1 and that of K2Cr2O7 is E2 and following
1 1 1
relation exist   find ‘x’
x E1 E 2
 PART-3-MATHEMATICS
SECTION-A
Single Correct Choice Type

This section contains 20 multiple choice questions. Each question has 4 choices (A), (B), (C)
and (D), out of which ONLY ONE is correct.

Q1. The value of  such that sum of the squares of the roots of quadratic equation,
x 2  (3   )x  2   has the lest value is :
15
(A) (B) 1
8
4
(C) (D) 2
9

   
Q2. The value of cos 2
 cos 3    cos 10  sin 10 is :
2 2 2 2
1 1
(A) (B)
512 1024
1 1
(C) (D)
256 2

Q3. The curve amongst the family of curves represented by the differential equation,
(x 2  y 2 )dx  2xy dy  0 which passes through (1, 1), is :
(A) a circle with centre on the x-axis
(B) an ellipse with major axis along the y-axis
(C) a circle with centre on the y-axis
(D) a hyperbola with transverse axis along the x-axis

Q4.  
Let f : (–1, 1)R be a function defined by f(x)  max  x ,  1  x 2 . if K be the set of all
points at which f is not differentiable, then K has exactly :
(A) five elements (B) one element
(C) three elements (D) two elements

10
  
Q5. The positive value of  for which the co-efficient of x2 in the expression x 2  x  is 720, is :
 x 2 
(A) 4 (B) 2 2
(C) 5 (D) 3

2
Q6. The tangent to the curve, y  xe x passing, through the point (1, e) also passes through the point
:
4 
(A) (2, 3e) (B)  ,2e 
3 
5 
(C)  ,2e  (D) (3, 6e)
3 
Q7. Let N be the set of natural numbers and two functions f and g be defined as f, g : NN such that
n  1
 2 if n is odd
f(n)  
 n if n is even
 2
and g(n)  n  ( 1)n . Then fog is :
(A) onto but not one-one. (B) one-one but not onto.
(C) both one-one and onto. (D) neither one-one nor onto.
Q8. The number of values of   (0,) for which the system of linear equations
x  3y  7z  0
x  4y  7z  0
(sin3)x  (cos 2)y  2z  0 has a non-trivial solution, is :
(A) three (B) two
(C) four (D) one
       
Q9. Let   (  2) a  b and   (4  2) a  3b be two given vectors where a and b are non
 
collinear. The value of  for which vectors  and  are collinear, is :
(A) –4 (B) –3
(C) 4 (D) 3

Q10. Two sides of a parallelogram are along the lines, x + y = 3 and x – y + 3 = 0. If its diagonals
intersect at (2, 4), then one of its vertex is :
(A) (3, 5) (B) (2, 1)
(C) (2, 6) (D) (3, 6)

x 1
Q11. If  f(t)dt  x   t f(t)dt, then f 1
0
2

x
2 '
 2 is :
24 18
(A) (B)
25 25
4 6
(C) (D)
5 25

5 5
 3 i  3 i
Q12. Let z        . If R(z) and I(z) respectively denote the real and imaginary
 2 2   2 2 

parts of z, then :
(A) I(z) = 0 (B) R(z) > 0 and I(z) > 0
(C) R(z) < 0 an I(z) > 0 (D) R(z) = –3

1
Q13. If the probability of hitting a target by a shooter, in any shot, is , then the minimum number of
3
independent shots at the target required by him so that the probability of hitting the target at least
5
once is greater than , is :
6
(A) 3 (B) 6
(C) 5 (D) 4
 5 4 x3 1 4x3
Q14. If x e dx 
48
e f(x)  C, where C is a constant of integration, then f(x) is equal to :

(A) 2x3  1 (B) 4x 3  1

(C) 2x3  1 (D) 4x 3  1

Q15. If the area of an equilateral triangle inscribed in the circle, x 2  y 2  10x  12y  c  0 is 27 3
sq. units then c is equal to :
(A) 13 (B) 20
(C) –25 (D) 25

Q16. Consider the following three statements :

P : 5 is a prime number.
Q : 7 is a factor of 192.
R : L.C.M. of 5 and 7 is 35.
Then the truth value of which one of the following statements is true?
(A) (~ P)  (Q  R) (B) (P  Q)  (~ R)
(C) (~ P)  (~ Q  R) (D) P  (~ Q  R)

Q17. The length of the chord of the parabola x2 = 4y having equation x  2y  4 2  0 is :

(A) 3 2 (B) 2 11
(C) 8 2 (D) 6 3

2 b 1
Q18. Let A  b b 2  1 b  where b > 0. Then the minimum value of
det(A)
  is :
b
 1 b 2 
(A) 2 3 (B) 2 3
(C)  3 (D) 3

 y2 x2 
Q19. Let S  (x, y)  R2 :   1 , where r   1. Then S represents :
 1 r 1 r 
2
(A) a hyperbola whose eccentricity is , when 0  r  1.
1 r
2
(B) an ellipse whose eccentricity is , when r  1.
r 1
2
(C) a hyperbola whose eccentricity is , when 0  r  1.
r 1
1
(D) an ellipse whose eccentricity is , when r  1.
r 1

25
Q20. if 
r 0
50

Cr  50r C25r  K  50

C25 , then K is equal to :
(A) (25)2 (B) 225 – 1
(C) 224 (D) 225
 Section-B
(Numerical Answer Type)

This section contains 05 questions. Each question, when worked out will result in numerical answer
type

Q21. A man starts from point P(3,4) and reaches point Q (0,1) touching x axis at point R such that
PR + RQ is minimum at point R is (,0) then value of 5 is ?

Q22. If angle between pair of tangent from p to circle x2 + y2 = 25 is /3, than locus of point P is circle
of radius R then value of R/10 is?
x 2 y2
Q23. Eccentricity of hyperbola conjugate to hyperbola   1 is e then value of e2 is?
4 12
a 2  b 2  c2
Q24. In a triangle the maximum value of is K then K/10 equal to ?
R2

Q25. In triangle ABC the centroied (2,3) ortho centre is (5,1) then circumcentre is (a, b) then value of
(a + b).
ANSWER
SOLUTION
PHYSICS
Sol1. R1 = 32 × 10 = 320 
Ry 40  320
R3 =  R1  = 160 
R2 80
 Colour code of R3 be Brown, Blue, Brown.

Sol2. Q = (B.E.)R – (B.E.)P

= 20 × 8.03 – (8 × 7.07 + 12 × 7.86)
= 160.6 – (56.56 + 94.32)
 Q = +9.72 meV
9.72 MeV released.

I
Sol3.  T  2
B
Th I 
 R c
Tc Ic h
1
= 2 1
2
T h = Tc

Sol4. Heat loss = Heat gain

192 × S(100 – 21.5) = (128 × 0.394 + 240 × 4.2) (21.5 – 8.4)
192 × 78.5 × S = 1058.432 × 13.1
S = 0.91995 J/g K–1
S = 919.95 J/kg K–1

2  4R2
Sol5. I  2  MR 2  M4R 2   M
5  12
1 4  137
= MR 2    8  = MR2
 3 5  15

LT
Sol6.  25
t
25  1 5
 L 
15 3
1 1 5
 
U  L I2f  I12    (252  102 )
2 2 3
5
=  525  4.7.5 J
6

30 R
Sol7.  30  00.95
R  30
 R = 570 
Sol8.  = F × 0.06 = 1.8 × 0.012 × 18 × 10–6
F = 6.48 × 10–5
   
Sol9. A B n A B
 A2 + B2 + 2AB cos 
= n2(A2 + B2 – 2AB cos )
2a2 (n2  1)
 cos (1  n2 ) 
2a2
A  B  a
n2  1
cos  
n2  1

16  10 3  10 4
Sol10. n   1.6  1011
10  10  10 19
(K.E.)max = (10 – 5) eV = 5eV
 
Sol11. K.E. – 3 = F  d
K.E. = 3 + (3iˆ  12ˆj)  (4iˆ )
K.E. = 3 + 12 = 15 J


Sol12. (2d)2  (d)2  2d 
2

 ( 5  2)d 
2

 d
2( 5  2)

2 1 2  1
Sol13.  
v u R
1.34 1 0.34
  
v  7.8
1.34  7.8
 v nm = 3.074 cm
0.34

P 4.4
Sol14. R  2
 
I 4  106
V 2 11 11  4  10 6
P   W
R 4.4
= 11 × 10–5 W

 2
Sol15. v  R 2h  Dh
4
= 4260 cm2
v D h
 2 
v D h
  0.1 0.1 
= 2  v
 12.6 34.2 
2x426 426
= 
12.6 34.2
= 67.61 + 12.459 = 80.075
 v = 4260  80 cm3

Sol16. Y
1 1 1 2 
W  VQ  Q2    
40 2 2 2 5 
Q Q (4, 2)
(0, 2) Q2  1 
 1 
4 0  5
x
0 Q 0

Q Q
(0, –2) (4, –2)

Sol17. The interval between two carrier frequencies should be at least two times of AM frequency.

250 kHz
Sol18.  13.33
1.5 kHz
 Possible hormones
1, 3, 5, 7, 9, 11, 13
i.e 6.

50
Sol19. i10 k   5 mA
10k
120  50
i5 k  = 14 mA
5k
i2  (14  5) mA = 9 mA

Sol20. E  10ˆj cos(6x  8z  10ct)
Eo 10
Bo  
C C
W = 10 C
 ˆ
Eˆ  Bˆ  C
ˆi ˆj kˆ
6iˆ  8 ˆj
0 1 0 
10
Bx By Bz
3 4
 Bz ˆi  0ˆj  B xkˆ  ˆi  ˆj
5 5
3 4  1
Bz  , B y  0, Bz   B  ( 8iˆ  6k)
ˆ cos (6x  8z  10 ct)
5 5 C
  
Sol21. Power F.V  (Ftangential)V
v2
  k 2 rt 2  v  krt
r
 a tan gential  kr
 Ftan gential   m.kr 

 Power   mkr  .krt  mk 2 r 2 t

CONCEPT Involved:- Power = tangential force  velocity
TOPIC:- WEP and Circular motion

5,3
  5,3

Sol22. Work done = F.ds  ydx  xdy 
   d  xy    xy3,4  3
3,4
  ds  smalldisplacement
CONCEPT : - Work =
 F.ds, 
F  force applied
TOPIC: - WEP
Sol23.
Clearly
1 1v 500 v
p  0  
2 2 r 2  8  102
5
  104  3125rad / s P 
2r
16 O

Concept: - Circular motion

TOPIC:- Kinematics
Sol24.
2 2
1  1 2ML2  
MV    3M     2M    
 3    3 12  6  
MV  3MVcm  2m

V
 Vcm  P
3 3M

1

 K.E i  MV 2 M V
3

2

1  ML2  2 1 V 2 MV 2  V MV 2
 K.E f       3M     K.E   0.16666MV 2
2  3  2 9 3  t  6
CONCEPT: Conservation of angular momentum and Rotational K.E
TOPIC :- RM
 z
Sol25. is dimensionless
k
  k is dimensionally equivalent to (Force displacement)
  z  is dimensionally equivalent to (Force displacement)
 F
 must be dimensionally equivalent to  
 A
2
     L 
 
3a  4b  6c 8
   2666.66
0.003 0.003
CHEMISTRY
n2
Sol1. E  13.6 eV
z2
 4
EHe  13.6
9

Sol2. Fact based

Sol3.
O O

HO - C - C - OH
HO OH

OH
O
O O C

O
n

HO
nC12H22O11
Sol4. 0.1 
2
nC12H22O11  0.2
Wt C12H22O11  0.2  342  68.4

Sol5. First reaction will be requiring a catalyst among halogens oxidizing power decrease down the
group.

Sol6. 

NH4HS  s  
 NH3  g  H2S  g
5.1 g
0.1 g mol – 0.03 0.03 mol 0.03 mol
0.98 0.98
V = 3L, T = 327oC
2 2
KP  PNH3 PH2S PV = nRT

0.98 0.98
KP   P  3 = 0.06  0.0821  600
2 2
0.06  0.0821 200
P
3
KP = 0.243 P = 0.98
Sol7. CH4 is not present in stratosphere.

o
H  Cl 
Sol8. E  E  0.06 log 1/2
H2 
106.10 6
0.92  Eo  0.06log
11/2
0.92 = Eo - 0.06 log10–12
Eo + 0.06  12
Eo = 0.92 - 0.06  12
Eo = 0.92 – 0.72
EoAg / AgCl  0.20

14 1 2
Sol9. The electron configuration is [Xe]4f 5d 6s

Sol10. Lysine is an amino acid nindydrin test is used for amino acids.
Furfural reacts with 1-napthol to give violet colouration.
Benzyl alcohol undergoes reaction with ceric ammonium nitrate to give red colouration.
CH = CH 2

Styrene , discharges color of KMnO4

Sol11. CH3 CONH2 NH2

NH3 , Br2 , KOH

   

[A] [B]

Sol12. CaSO 4  s  
 CaO  s   SO3  g 
CO2  s  
 CO2  g
 I2  aq
I2 
N2  g   3H2  g  
 2NH3  g 


N2  g   3H2 
 2NH3  g 
S  2SNH3   SN2  3SH2 
There is decrease in number of moles of NH3 entropy is decreasing.

Sol13. q = PV
q = 16
CP = 24
qP
CP 
T
16 2
T  K K
24 3
Sol14. Tb = Kbm
Tb = Kb  1  2 = Kb
Tf = Kfm
2 = 2Kf = Kf
Kf 1

Kb 2

Sol15. NaBH4 reduces both carbonyl group and imine.

Sol16. Na  s    x  y  NH3  Na  NH3 x  e  NH3 y

Blue colour
ammoniated electrons

1 dA  2
Sol17.  K 1  A 2  K 1  A 
2 dt
dA  2
 2K 1  A 2   2K 1  A 
dt

Sol18. Barfoed test is used to detect monosaccirides.

Sol19. Co2+ high spin t 52g e2g ‘3’ unpaired electrons

Co2+ low spin t 62ge1g ‘1’ unpaired electron

Difference is 3 – 1 = 2

Sol20. O O
O O
1. NaOEt
2. 

O OC2 H5 O OC 2H5

O O O
NaOEt H2O

 HO
 

HO O
COOEt COOEt COOEt

Sol21. y is B3N3H6
CONCEPT: Borazinie
TOPIC: Boron family

12400  1 1 
Sol22.  13.6  Z 2  2  2   z 2  4 or z  2
300 1 2 
CONCEPT: Hydrogen spectrum
TOPIC: Atomic structure

Sol23. Heat of neutralization is given on the basis of per gm-eq and is fixed to 13.7 K. Cal
 CONCEPT: involved
TOPIC: Heat of Neutralization

Sol24. Use Dulong petits law

Specific heat (Cal/ gm)  At. Wt = 6.4 (approx)
6.4
At. Wt =  9846.15
CONCEPT: Involved
0.00065
TOPIC:- Atomic Wt.
M 156
Sol25. Eq wt of KMnO4 is acidic medium  E1    31.6
5 M 5 294
Eq. Wt of K2Cr2O7 in acidic medium  E 2   4
1 1 1 1 1 6 6
     0.052054
x I1 1E 2 31.6 49
x  19.21
CONCEPT: Involved
0.052054
TOPIC:- eq Wt.
MATHEMATICS
2
Sol1.  2  2        2
2
 3     2  2   
  2  9  6  4  2
 2  4  5
 For least value   2

sin 2n A
Sol2. Using formula n
 cos A cos 2 A cos 22 A...........cos 2n1 A
2 sin A

Sol3. x 2dx  2xydy  y 2dx  0

x 2dx  y 2dx  2xy dy
x 2

 y 2 dx  2xy dy  0
 x.2y dy  y 2dx 
dx    
 x2 
Integrals
y2
x c
x
x 2  y2  cx
y
Sol4. A, B, C are sharp edges

–1 1
x

A C

10
2  
Sol5. x  x 2
 x 
Consider constant term
r
10 r   
10
Cr  x  2
x 
10  r
 2r  0
2
10  5r  0
r 2
 10 C2  2  720    4
 2
Sol6. y  xe x
(1, e) lies on this
dy 2 2
Now  xex .2x  ex .1
dx
Put x = 1
m  2e  e  3e
Equation of tangent at (1, e)
y  e  3e  x  1
y  e  3ex  3e
y  3ex  2e
4 
 3 , 2e  satisfies it
 
f  g 1   1
Sol7.  Many one
f  g  2    1
f  g  2k    k
f  g  2k  1   k  1
 Onto

7 sin 3  14 cos 2  14  0
1
sin3  2 cos 2  2  0, sin  
2
 
Sol9.     2 a  b
  
   4  2  a  3b
 
 and  are collinear
2 1
0
4  2 3
3  6  4  2  0
  4  0
  4

D (3, 6) C
Sol10. Intersection point is A (0, 3)
M   4, 6 
B  1, 2  , D   3, 6 

A (0, 3) x+y=3 B (1, 2)

Sol11. Differentiability we get f  x   2x  x 2 f  x 

f x 
2x
 f " x  2
1 x2  
1  x2 1 x2
2
 
 1  24
f '  
 2  25

5 5
 3 i   i b 
Sol12.    e  ei5 /6
 2 2   
   
5  3
 z  2 cos  2     3
6 
 2 

n
2 5
Sol13. 1    
3 6
n
2 1
  
3 6
n5
3 3
5
Sol14. x .e 4 x dx   x 2 . x3 e 4x dx
4x 3  t
12x 2 dx  dt
1 t
   et dt
12 4
1
 t et dt
48 
1 t
 te  1.et  c
48
1 4 x3 3

48

e . 4x 3  e4x  c 
Sol15. r  25  36  c  36
c  25

Sol16. P is True
Q is False
R is True
~Q is True
~ Q  R is True
 P   ~ Q  R  is True.
Sol17. x  2y  4 2
2
x  4y
Solving we get point of intersection

A 2 2, 2 , B 4 2,8   
2
 AB  6 2   6  6 2
3

Sol18. Det A  b2  3
det A 3
b
b b
 Least value  2 3

y2 x2
Sol19.  1
1 r 1 r
r  1  ellipse
 r  1 2
e  1   
 r  1 r 1

25
50 50  r
Sol20.  r 50  r 
r 1 25  r 25
25
50

r 1 r 25  r 25
50 25 1
 
25 r 1 r 25  r
50 25
 
25 25 r 1
25

Cr  50 C25 225  1 
Sol21.
PR + RQ is minimum than APR & BQR must be P(3,4)
similar

Q (0,11)
AR PA  A 3
    
RB QB 0 1 5

 
3  3 x
 R  ,0    ,0   5  5y  3 A R(,0) B
5  5
CONCEPT Involved: Reflection of point straight line.
Sol22.
25
Required locus   2  2   100 (,)
2
sin  / 6 P M3 (0,0)
2 2
 x  y  100  Radius of circle = 10

 R / 10  1
CONCEPT : Pair of tangent to Circle.
Sol23. We have
4
e2  1 
12
1 4
 e2  1  
3 3
2
e
13

a 2  b 2  c2
Sol24.
R2

 4 sin 2 A  sin 2 B  sin 2 C 
 8 1  cos A  cos Bcos C 
 1
 8 1    9
 8
CONCEPT: Properties of triangle.

Sol25.
We no orthocenter (H) circum centre Q and centoried G is 2 1
collinear and G divide in 2:1
2a  5 1 H G O
 2a 
3 2 (5,1) (2,3) (a,b)

2b  1
and 3 p  4
3
9
a  b   4.5
2
CONCEPT: Centre of triangle