Concrete Technology
Concrete Technology
Uses of Concrete
Advantages of Concrete
Disadvantages of Concrete
i. Cement content
Mix must be designed to ensure cohesion and prevent
segregation and bleeding. If cement is reduced, then at fixed w/c
ratio the workability will be reduced leading to inadequate
compaction. However, if water is added to improve workability,
water / cement ratio increases and resulting in highly permeable
material.
ii. Compaction
The concrete as a whole contain voids can be caused by
inadequate compaction. Usually it is being governed by the
compaction equipments used, type of formworks, and density of
the steelwork
iii. Curing
It is very important to permit proper strength development aid
moisture retention and to ensure hydration process occur
completely
iv. Cover
Thickness of concrete cover must follow the limits set in codes
v. Permeability
It is considered the most important factor for durability. It can be
noticed that higher permeability is usually caused by higher
porosity. Therefore, a proper curing, sufficient cement, proper
compaction and suitable concrete cover could provide a low
permeability concrete
Types of Durability
Physical Durability
Chemical Durability
1. External Causes:
2. Internal Causes
a) Physical
b) Chemical
Corrosion of Steel
PROPERTIES OF CEMENT CONCRETE
The cement concrete possesses the following important properties:
Types of Concrete
1. Normal concrete
2. High Strength Concrete
3. High Performance Concrete
4. Air Entrained Concrete
5. Light Weight Concrete
6. Self-Compacting Concrete
7. Shotcrete
8. Pervious Concrete
9. Roller Compacted Concrete
Vacuum Concrete | Definition, Procedure and Advantages
Procedure
i. Water Content
ii. Mix Proportions
iii. Size of Aggregates
iv. Shape of Aggregates
v. Grading of Aggregates
vi. Surface Texture of Aggregates
vii. Use of Admixtures
viii. Use of Supplementary Cementitious Materials
ix. Time
x. Temperature
i. Water Content
It is the most important factor of workability. Workability increases with
the increase of water content (measured in kg or liter per cubic meter
of concrete). We can express the relation in terms of water-cement
ratio. If the water-cement ratio is small, it indicates high amount
cement which is helpful for good strength. But the small water-cement
ratio is responsible for lower workability. If proper compaction cannot
be achieved, concrete will not be enough strong as desired. On the
other hand, if the water-cement ratio is increased, workability and
compaction problem will be solved but there may occur some other
problems like bleeding and losing compressive strength. Hence an
optimum water-cement ratio has to be maintained to balance
workability and strength of concrete.
v. Grading of Aggregates
Well-graded aggregates tend to fill up voids and easily get workability.
Less amount of water can make it workable. If grading is better, there
will be fewer voids and excess paste will be available to give better
lubricating effect. Due to excess paste, the mixture gets cohesive and
prevent segregation. It also makes it get compacted easily i.e.
increases the workability.
ix. Time
Fresh concrete stiffens with time and loss workability though it is not
exactly settling or getting strength at all. After mixing concrete, some
water is absorbed by aggregate, some may be lost by evaporation and
some may be spent for initial chemical reactions. The loss in
workability by time depends on various factors like:
a. Initial workability: if initial workability is high, slump loss
will be greater
b. Property of cement: if alkali content is high and sulfate
content is low, sump loss will be greater
c. Moisture content of aggregate: dry aggregate will
absorb more water and workability will decrease
iix. Temperature
High temperature reduces workability and increases slump loss. Slump
loss is less influenced by temperature in stiff mixes because this type
of mix is less affected by a change in water content.
Concrete Slump Test - Step by Step Procedure
S1: 10-40 mm
S2: 50-90 mm
S3: 100-150 mm
S4: more than 160 mm
History of Cement
Cement, though different from the refined product found nowadays,
has been used in many forms since the advent of human civilization.
From volcanic ashes, crushed pottery, burnt gypsum and hydrated lime
to the first hydraulic cement used by the Romans in the middle ages,
the development of cement continued to the 18th century, when James
Parker patented Roman cement, which gained popularity but was
replaced by Portland cement in the 1850s.
In the 19th century, Frenchman Louis Vicat laid the foundation for the
chemical composition of Portland cement and in Russia, Egor
Cheliev published the methods of making cement, uses of cement and
advantages. Joseph Aspdinbrought Portland cement to the market in
England and his son, William Aspdin, developed the “modern” Portland
cement, which was soon in quite high demand. But the real father of
Portland cement is considered to be Isaac Charles Johnson, who
contributed immensely by publishing the process of developing meso-
Portland cement in the kiln.
In the 19th century, Rosendale cement was discovered in New York.
Though its rigidity made it quite popular at first, the market demand
soon declined because of its long curing time and Portland cement was
again the favorite. However, a new blend of Rosendale-Portland
cement, which is both highly durable and needs less curing time, was
synthesized by Catskill Aqueduct and is now often used for highway or
bridge construction.
The cement used today has undergone experimentation, testing and
significant improvements to meet the needs of the present world, such
as developing strong concretes for roads and highways, hydraulic
mortars that endure sea water and stucco for wet climates. Different
kinds of modern cement, most of them known as Portland cement or
blends, including blast furnace cement, Portland fly-ash cement,
Portland pozzolan cement, pozzolan-lime cement, slag-lime cement
etc.
Cement Chemistry
Cement is chiefly of two kinds based on the way it is set and
hardened: hydraulic cement, which hardens due to the addition of
water, and non-hydraulic cement, which is hardened by carbonation
with the carbon present in the air, so it cannot be used underwater.
Non-hydraulic cement is produced through the following steps (lime
cycle):
1. Belite (2CaO·SiO2);
2. Alite (3CaO·SiO2);
3. Tricalcium aluminate/ Celite (3CaO·Al2O3)
4. Brownmillerite (4CaO·Al2O3·Fe2O3)
Portland cement
The most commonly used cement nowadays is a hydraulic cement (i.e.
hardens when water is added) known as Portland cement or Portland
cement blends. These are usually the basic ingredient in making
concrete, which is a construction material used as a load-bearing
element. Portland cement is suitable for wet climates and can be used
underwater. Different types or blends of Portland cement include
Portland blast furnace slag cement, Portland fly-ash cement, Portland
pozzolan cement, Portland-silica fume cement, masonry cement,
expansive cement, white blended cement, colored cement and very
finely ground cement.
Ingredients of Cement
Composition of Cement
There are eight major ingredients of cement. The general percentage
of these ingredients in cement is given below:
Ingredient Percentage in
cement
Lime 60-65
Silica 17-25
Alumina 3-8
Magnesia 1-3
Iron oxide 0.5-6
Calcium 0.1-0.5
Sulfate
Sulfur 1-3
Trioxide
Alkaline 0-1
Fineness of cement
Soundness
Consistency
Strength
Setting time
Heat of hydration
Loss of ignition
Bulk density
Specific gravity (Relative density)
Fineness of Cement
The size of the particles of the cement is its fineness. The required
fineness of good cement is achieved through grinding the clinker in the
last step of cement production process. As hydration rate of cement is
directly related to the cement particle size, fineness of cement is very
important.
Soundness of Cement
Soundness refers to the ability of cement to not shrink upon hardening.
Good quality cement retains its volume after setting without delayed
expansion, which is caused by excessive free lime and magnesia.
Tests:
Unsoundness of cement may appear after several years, so tests for
ensuring soundness must be able to determine that potential.
Le Chatelier Test
This method, done by using Le Chatelier Apparatus, tests the
expansion of cement due to lime. Cement paste (normal
consistency) is taken between glass slides and submerged in
water for 24 hours at 20+1°C. It is taken out to measure the
distance between the indicators and then returned under water,
brought to boil in 25-30 mins and boiled for an hour. After cooling
the device, the distance between indicator points is measured
again. In a good quality cement, the distance should not exceed
10 mm.
Autoclave Test
Cement paste (of normal consistency) is placed in an autoclave
(high-pressure steam vessel) and slowly brought to 2.03 MPa,
and then kept there for 3 hours. The change in length of the
specimen (after gradually bringing the autoclave to room
temperature and pressure) is measured and expressed in
percentage. The requirement for good quality cement is a
maximum of 0.80% autoclave expansion.
Standard autoclave test: AASHTO T 107 and ASTM C 151:
Autoclave Expansion of Portland Cement.
Consistency of Cement
The ability of cement paste to flow is consistency.
It is measured by Vicat Test.
In Vicat Test Cement paste of normal consistency is taken in the
Vicat Apparatus. The plunger of the apparatus is brought down to
touch the top surface of the cement. The plunger will penetrate the
cement up to a certain depth depending on the consistency. A
cement is said to have a normal consistency when the plunger
penetrates 10±1 mm.
Strength of Cement
Three types of strength of cement are measured – compressive, tensile
and flexural. Various factors affect the strength, such as water-cement
ratio, cement-fine aggregate ratio, curing conditions, size and shape of
a specimen, the manner of molding and mixing, loading conditions and
age. While testing the strength, the following should be considered:
Compressive Strength
It is the most common strength test. A test specimen (50mm) is taken
and subjected to a compressive load until failure. The loading
sequence must be within 20 seconds and 80 seconds.
Standard tests:
Tensile strength
Though this test used to be common during the early years of cement
production, now it does not offer any useful information about the
properties of cement.
Flexural strength
This is actually a measure of tensile strength in bending. The test is
performed in a 40 x40 x 160 mm cement mortar beam, which is loaded
at its center point until failure.
Standard test:
Heat of Hydration
When water is added to cement, the reaction that takes place is called
hydration. Hydration generates heat, which can affect the quality of
the cement and also be beneficial in maintaining curing temperature
during cold weather. On the other hand, when heat generation is high,
especially in large structures, it may cause undesired stress. The heat
of hydration is affected most by C 3S and C3A present in cement, and
also by water-cement ratio, fineness and curing temperature. The heat
of hydration of Portland cement is calculated by determining the
difference between the dry and the partially hydrated cement
(obtained by comparing these at 7th and 28th days).
Standard Test:
ASTM C 186: Heat of Hydration of Hydraulic Cement
Loss of Ignition
Heating a cement sample at 900 - 1000°C (that is, until a constant
weight is obtained) causes weight loss. This loss of weight upon
heating is calculated as loss of ignition. Improper and prolonged
storage or adulteration during transport or transfer may lead to pre-
hydration and carbonation, both of which might be indicated by
increased loss of ignition.
Standard Test:
AASHTO T 105 and ASTM C 114: Chemical Analysis of Hydraulic
Cement
Bulk density
When cement is mixed with water, the water replaces areas where
there would normally be air. Because of that, the bulk density of
cement is not very important. Cement has a varying range of density
depending on the cement composition percentage. The density of
cement may be anywhere from 62 to 78 pounds per cubic foot.
The above events can be condensed into four major stages based on
the change of temperature inside the kiln:
Toky Siddiquee
Kerosene
Ordinary Portland Cement
Le-Chatelier Flask of 250 ml or Specific Gravity Bottle /
Pycnometer of 100 ml
Weighing balance with 0.1 gm accurate
Definition:
Coarse Aggregate
Fine Aggregate
Those particles passing the 9.5 mm (3/8 in.) sieve, almost entirely
passing the 4.75 mm (No. 4) sieve, and predominantly retained on the
75 µm (No. 200) sieve are called fine aggregate. For
increased workability and for economy as reflected by use of less
cement, the fine aggregate should have a rounded shape. The purpose
of the fine aggregate is to fill the voids in the coarse aggregate and to
act as a workability agent.