Indian School of Chemistry (INSC)

Lecture 4 JEE ADVANCED (Chemical Bonding)

L CA O

Modelplane

plodel
plane

WEE E It
IT
25 2p becomes very close
 S
p intermixing
x̅ for a
spy rap 2

132 rist artist 0250 25 Alph a spy

2 Unpaired e Paramagnetic
6
B 0 21 1 a band

02 rist is rest_ 2520402 apntarpytatapiatap.gl

2 Unpaired e Paramagnetic

HOMO Highest occupied M O

Lowest M O
LUMO unoccupied
Colours of FL Uc Pm 12 etc

A 2pm
By HOMO Apy
LUMO 572
HO MO At 2pm At spy
02
LUMO 72

Mixing of S 4
p orbitals is for B2 N2

A p g n t B q n sit
c pig D Pains
 MSP
CH Pseudo halide

Ei's
i

Selficizan
2 BrFs Bnfz7 RFT

IE EIE sp3d2
squareplenar

14
2420 I not on kw 10

2MHz NUT NNP

D
n a nothin a a

sp3 sps sp3

3 tip Grt artzep

Bond angle 027 It Is

 Paz Ho OH NO P OH
5 on hydrolysis gives
OH

E HzPO tautomeric
exists in two forms
Ho P 04 no Pff 0H
on

a
a
Fmo a E
u
on

n n no 5 on

no
Ploy
 Q How many the
following have
of no
hybridization
Has these H2 Te PHz Ask Sbhz Billy Pa
92 90 94 90 60
Bond
angle
Drago's Rule
Bond angle i hybridization index

sp I Ine
1 1 Coso 1 D 180
sp
0 120
2 2 cord
sp
s
p
p p
00

pÉIp P p PEEP PEEP

White P Red P linear polymer
Q

TECH ce sp3d TBP

b
0 0 o
115 o o 0

a
U
Teo Nhs snoa

0 0
Cha CO2 9
tsp sp
Q of different type of bond angles in ASF 42
9f no

se Find a

guAs Fact As is d
sp hybridized so its

triangular bipyramidal
F
spa 5C 10 bond angle
possible

IFF
r I T.me

Fa amal
Fa As Fe
Fe equitorial
Fa As Ce

Fa As Fa
a As Ce
U As Fe

5
 Q How many of the following is are
planar
4202 13246 Alz 46 In 46 5102 2D silicate

Bean I me c on

ay
Yo 1,0 o Tautomers
n

open Book structure

both have
4h wolf
3C ze Bond
H
f
Sps non
planar

U U Al have no
lp but a hanelp
JAE TAE e 3C 4 Bond

non
planar

I U both have lp

If FI mneeGa6 ae

Plenant
zep
yo
4r o

sp3d square planar

5102 3D silicate si sps 01 0

11
o
j o
 2D silicate 51057 non
planar

Be Be Ce 3C 4e Band
a
at tsp
Ip planar

E3 se neE7E
sp non
plane
F

d F sp'd
If Ephal
C C C non planar
Spr tsp tsp
x̅ bond formed pure orbitals

by

a intumanans

sp sp

Iii
C
a a
Q find the hybridization of Xe in reactant products
on
hydrolysis of Xef6 Also consider partial hydrolysis
products

Xe Fo 420 XeoF4 2HF

spas sped
XeoFg Hw Xe 02 Fz 2nF

sp3d
e 02 Fz Hw Xe0zt 2nF
sp

ftp.F lp present in

inert orbital
stereochemically

EFF 5s sp
5,9dam da dry
Distorted Octahedral
theation
Thigh difference in energy
Caped

F
E I o.FI
EE o

Squarepyramidal
Seesaw Triangular
sped pyramidal
sp3d
sp
 Predict hybridization
Q of carbon in the following
consider
only C C bond cleavage
ch Homolysis
9 Chz

b Homolysis
CFz CF

c Heterolysis
Chz Chz

a Chg chg
Homolyns och
1cg
Unpaired e is highly energetic sps
Triangularplanar
b Homolysis CF
Cfg Cfg

F
EF
Sps
Triangularpyramidal

Heterolysis
c
cuz chg cut Cng

E
it p
spa
n
n
t 4

Triangularplanar
sps
Triangularpyramidal
Q the
Based on
hydrolysis products of the following
deduce the structures of following

9 Ca z 2H20 Glok Cattz

H CEC H
Cat P

b
Mgc 4420 2mg 10412 Cska
C EC H
ᵗ
C P H
2Mg

Nhs
C
Mg3N2 6420 3mg104 2 2

342 2143

d Alac 420 Allon Cha

4 Aest 324

e Be c no Be 10h22 Cha
t 4
2Be
 Chs

FEE
chz

Eii if x̅ nie

lp occupies orbital of mores character

more electro negative element occupies on bital
less s charester
of
N F s character to
N N s character

N n s charter
N N s character

Bond energy N N Bond

Nz Fz Mr Ma

Bond length Tadstrength

Bond length
FL UC the Iz
Bond strength
42 the Fz Iz
 0 bond in the
Q Compare 0 length following
02 Koz Ba 021 02 As

2 at 022 of Asfa
1 0
33 0
Epao
2 5
Pa
1.5
ie.io
E
Paramagnetic
Ba 027 K 02 7 02 02 ASF

Q C 0 bond length in the

Compare following
cot CO CO2 cost CH É o
b
13.0 3 5 1 0 373 0 2
E
o o
B 0 4
6
1 43 3
cm 8 13.0 1 112 1 5

cot co con chg 0 cost