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(JAM)Assignment Atom Structure & Quantum Chemistry of JAM

The document is an assignment for online classes focused on Atom Structure and Quantum Chemistry for IIT-JAM 2020. It contains multiple-choice questions covering various topics such as quantum numbers, energy levels, and wavefunctions, along with an answer key. The questions assess knowledge of physical chemistry principles related to atomic structure and quantum mechanics.

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aimiitdelhi202324
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12 views

(JAM)Assignment Atom Structure & Quantum Chemistry of JAM

The document is an assignment for online classes focused on Atom Structure and Quantum Chemistry for IIT-JAM 2020. It contains multiple-choice questions covering various topics such as quantum numbers, energy levels, and wavefunctions, along with an answer key. The questions assess knowledge of physical chemistry principles related to atomic structure and quantum mechanics.

Uploaded by

aimiitdelhi202324
Copyright
© © All Rights Reserved
Available Formats
Download as PDF, TXT or read online on Scribd
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MADCHEM CLASSES

TARGET IIT- JAM 2020 PHYSICAL CHEMISTRY


ONLINE Classes Assignment

Atom Structure & Quantum Chemistry

1) [Lx, Ly] and [Lx, L] is respectively


ℎ ħ
a) –ħLz, 2пz c) - 2п𝑖 Lz, iħz
𝑖ħ ħ
b) 2п
Lz, iħz d) 2п𝑖
Lz, iħz
2) The principal quantum number of an atom is related to the
a) Size of the orbital c) orientation of the orbital in space
b) Spin angular momentum d) orbital angular momentum
3) The orbital angular momentum of an electron in 2s orbital is
1 ℎ ℎ
a) + . c)
2 2п 2п
ℎ
b) zero d) √2.2𝜋
4) The energy of an electron in the Bohr orbital of H-atom is -13.6eV. The possible energy value (s)
of the excited state (s) for electrons on Bohr orbits of hydrogen is (are)
a) -3.4 eV c) -6.8 eV
b) -4.2 eV d) +6.8 eV
5) Which hydrogen like species will have same radius as that of Bohr orbits of hydrogen atom
a) n =2, Li2+ c) n =2, He+
3+
b) n =2, Be d) n =3, Li2
6) The energy of a hydrogen atom in a state is –hcRh/64. The degeneracy od state will be
a) 5 c) 75
b) 25 d) 125
7) A function has sin O cos O in its angular part of the function in may be
a) px c) 𝑑𝑧 2

b) d) 𝑠
8) The angular part of the wavefunction for the electron in a hydrogen atom is pproportional to
sin2Ɵ cos Ɵ e2iɸ. The values of the azimuthal quantum number l and the magnetic quantum
number (m) are respectively
a) 2 and 2 c) 3 and 2
b) 2 and -2 d) 3 and -2
9) The operator[x, [x, p2]] is identical with
a) [px,[x, p]] c) -[p,[x2, p]]
b) [xp,[x, p]] d) [x,[x2, p]]
10) The value of commutator of px with ly is
a) iħpz c) + iħpy
b) - iħpy d) 0
11) The probability of finding the particle in a one dimensional box of length L in the region between
L/4 and 3L/4 for quantum number n=1 is
1 1 1
a) c) -
2 2 п
1 1 2
b) + d)
2 п 3
3
12) The commutator [x , px] is equal to
3ℎ𝑥 2 ℎ𝑥 2
a) - 2п𝑖
c) 2п𝑖
13) When the operator –h2d2/dx2, operates on the function e-ikx, the result is
a) K2ħ2e-ikx c) iħ2e-ikx
b) iK2ħ2e-ikx d) ħ2e-ikx
14) Degeneracy of level 27h2/8ml2 for a 3-D box is
a) g =3 c) g =4
b) g =2 d) g =1
15) What is the degeneracy of the energy level with n=6(n being the principal quantum number) in a
hydrogenic atom or ion?
a) 16 c) 36
b) 9 d) 25
16) The number of radial nodes in 3s and 2p respectively are
a) 2 and 0 c) 1 and 2
b) 0 and 2 d) 2 and 1
17) The redius of which of the following orbit is same as that of the first Bohr’s orbit of hyodrogen
atom?
a) He+(n =2) c) Li2+(n =3)
b) Li2+(n =2) d) Be3+(n =2)
18) The normalisation constant ‘A’ for the wavefunction

1
a) 2𝜋
c) 2 𝜋
b) √2𝜋 d) 1/√2𝜋
19) Which of the following pairs of operators commute?
𝑑 𝑑
a) X and c) x2 and d2/dx2
𝑑𝑥 𝑑𝑥
𝑑 𝑑
b) 𝑑𝑥
𝑎𝑛𝑑 d2/dx2+2d/dx d) x3 and 𝑑𝑥
𝑑
20) The eigenvalur of the eigenfunction Ѱ=e2ax2 for an operator 𝑑𝑥 is
a) 4ax c) cannot be calculated
b) 2ax d) e2ax2
21) A 3p atomic orbital has
a) One redial node and one angular node c) one angular node
b) Two angular nodes d) one radial node
+ 2+
22) The energirs of the 1 s orbital in H, He and Li are in the ratio
a) H: He+ : Li2+ = 1:1:1 c) H: He+ : Li2+ = 1:4:9
b) H: He+ : Li2+ = 1:2:3 d) H: He+ : Li2+ = 1:1/4:1/9

Answer key
1. c 2. a 3. b 4. a 5. b 6. b 7. a 8. c 9. c 10. a 11. b 12. a 13. a

14. c 15. c 16. a 17. d 18. d 19. b 20. c 21. a 22. c

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