Sec: ISR_*CO-SC Date: 06-06-21

Time: 3 Hrs Max. Marks: 180

06-06-21_INC.SR.IIT STAR CO-SC_Jee-ADV_WAT-45_SYLLABUS

PHYSICS: PRESENT WEEK
EEK (80%): Magnetism:Magnetic
Magnetism:Ma force on moving point

torque, magnetic dipoles, Torque, P.E and

an interaction regarding
magnetic dipole,Cyclotron
PREV
PREVIOUS WEEKEEK (20%): Potentiometer, Applications, Experiments:

s er-

resistance of a cell, RC-circuits

-circuits

CHEMISTRY: PRESENT WEEK (80%): Group-17: General characteristics, Chlorine

– preparation, properties, uses, Preparation & properties of hydrides &
oxides, Inter halogens & pseudo halogens
PREVIOUS WEEK (20%): GROUP 16 : General characteristics,
allotropes of sulphur, O2 – Preparation, Properties, uses , Different
types of oxides – classification, Ozone - Preparation, Properties, Uses,
Oxides & halides of Sulphur, Oxyacids of sulphur, Sodium
thiosulphate

MATHEMATICS: PRESENT WEEK (80%): Rotation - Coni's Theorem,

T , Rotation form,
Geometrical interpretation,, Cube roots of unity
PREV
PREVIOUS WEEK EEK (20%): Complex numbers: Algebra of complex
numbers, Addition , Multiplication, Conjugation, Polar representation
of complex numbers,, Properties of modulus, Triangular
T inequalities,
alities,
Principle arguments
Narayana IIT Academy 06-06-21_INC.SR.IIT_*CO-SC_JEE-ADV_WAT-45_Q’P
CHEMISTRY Max Marks: 60
SECTION-I
(ONE OR MORE OPTIONS CORRECT TYPE)
This section contains 10 multiple choice equations. Each question has four choices (A) (B),(C) and (D) out of
which ONE or MORE THAN ONE are correct.
Marking scheme: +3 for correct answer, 0 if not attempted and 0 in all other cases.
21. Which of the following statement(s) is/are incorrect?
A) Chlorine dioxide  ClO2  is powerful oxidising agent but bleaching action is lower
than Cl2
B) ClO2 in alkaline solution undergoes disproportionation
C) ClO2 is diamagnetic in nature
D) ClO2 is a yellow gas
22. Which of the following statement(s) is/are true about NO2 and ClO2 ?
A) Both are paramagnetic
B) Both have a bent structure
C) On cooling, both undergoes dimerization easily
D) In both oxides, the central atom has an oxidation state +4
23. The correct statement(s) about the oxoacids, HClO4 and HClO, is (are)
A) HClO4 is more acidic than HClO because of the resonance stabilization of its anion
B) HClO4 is formed in the reaction between Cl2 and H 2O
C) The central atom in both HClO4 and HClO is sp3 hybridized
D) The conjugate base of HClO4 is weaker base than H 2O
24. BrF3 can act both as Lewis acid as well as Lewis base. Then which of the following

statement(s) is(are) correct?

A) BrF3 acts as Lewis base when it reacts with SbF5

B) BrF3 acts as Lewis acid when it reacts with CsF

C) BrF3 neither act as Lewis acid nor Lewis base when treated with SF6.

D) BrF3 act as both Lewis acid and Lewis base when treated with SF6

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Narayana IIT Academy 06-06-21_INC.SR.IIT_*CO-SC_JEE-ADV_WAT-45_Q’P
25. Which of the following order given below is/are incorrect for the property indicated
against it?
A) OCl  ClO2  ClO3  ClO4 (Cl – O bond distance)
B) HClO4  HBrO4  HIO4  acidic strength 

C) Cl  F  Br  I (Electron gain enthalpy)

D) H  F  H  Cl  H  Br  H  I (Bond energy)
26.

AgClO3 
0  AgCl  O 2  x
Cl2
90 C

x 
 y  O2
excess of
O3

Which of the following is/are correct statements related to x and y?

A) Both x and y are mixed anhydride i.e., on treatment with water produces two acids

B) y is a dark red liquid at room temperature

C) x is a paramagnetic

D) y can be obtained by dehydrating perchloric acid with P4O10

27. The incorrect statement(s) regarding ClO n molecular ions is

A) On decreasing value of ‘n’, ‘Cl – O’ bond order increases

B) On increasing value of ‘n’, ‘Cl – O’ bond length increases

C) On increasing value of ‘n’, oxidation state of central atom increases

D) On increasing value of ‘n’, total number of hybrid orbitals on central atom

increases

28. Which one of the following is correctly matched?

A) ClF3  sp3d hybridised chlorine – T shape

B) BrF5  sp3d hybridised bromine – Pentagonal bipyramidal shape

C) ICl3  sp 2 hybridised iodine – Trigonal planar shape

D) I3  sp3d hybridised iodine – Linear shape

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Narayana IIT Academy 06-06-21_INC.SR.IIT_*CO-SC_JEE-ADV_WAT-45_Q’P
29. Which of the following product(s) is / are obtained when Cl2O reacts with ammonia?

A) NO2 B) N 2 C) NCl3 D) NH 4Cl

30. Which of the following statement(s) is/are correct?

A) BaO2  O2  O2  AsF6  : order of oxygen – oxygen bond length

B) Bond order in ozone is 1.5

M
C) In the roasting of iron pyrites, the Gram equivalent weight of FeS2 is
11

( M – GMW of FeS2 )  FeS2  O2  Fe2O3  SO2  (unbalanced)

D)   sulphur is stable above 369K and transforms into   sulphur below this
SECTION-II
INTEGER TYPE
This section contains 10 questions. The answer to each question is a single digit integer, ranging from 0 to 9
(both inclusive).
Marking scheme: +3 for correct answer, 0 if not attempted and 0 in all other cases.
31. In the reaction of chlorine with excess ammonia, how many millimoles of ammonia
are required to react with 0.213gm of chlorine in given products as per stoichiometric
equation?
32. Consider the following ions
S2O 22 ,S2O32 ,S2O 42 ,S2O52 ,S2O62 ,S2O72 ,S2O82

If the number of ions having S – S or S = S linkage be ‘x’, the number of ions having
S – O – S linkages be ‘y’ and the number of ions having peroxy linkage be ‘z’, find
 x 
the value of 2   ?
 yz

33. In the preparation of Cl2 by Deacon’s process, ‘x’ is used as a catalyst at 723K. The
spin – only magnetic moment of the metal ion in x is a , then ‘a’ is
34. Given that:
MnO 2  4HCl  MnCl2  Cl2  2H 2O..... 1

2KMnO 4  16 HCl  2KCl  2MnCl2  8H 2O  5Cl2 .....  2 

If x and y are the n-factors of HCl in reactions (1) and (2) respectively, then the value
x
of 5    is
y 

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Narayana IIT Academy 06-06-21_INC.SR.IIT_*CO-SC_JEE-ADV_WAT-45_Q’P
35. Total number of halogen atoms present in each molecule of the following is ‘x’, then
the value of ‘x’ is:
Phosgene, Tear gas, mustard gas
36.
Number of Number of
p  p bonds d  d bonds
SO2 a p
SO3 b q
Cyclic trimer of SO3 c r
ClO 2 d s
ClO3 e t
ClO 4 f u

 p  q  r    s  t  u  
Find the value of 2  
 a  b  c    d  e  f  

37. When 3 parts of concentrated HCl and 1 part of concentrated HNO3 are mixed, aqua
regia is formed which is used for dissolving noble metals, e.g., gold, platinum and
form two complexes x and y respectively. If the oxidation states of metals in x and y
are +p and +q respectively, then the value of ‘p+q’ is

38. How many of the following statement(s) is / are correct?

(i) I2 is more reactive than ICl
(ii) ClF, ClF3 and IF7 are all colourless gases
235
(iii) ClF3 and BrF3 are used for the production of UF6 in the enrichment of U

(iv) When HCl reacts with finely powdered iron, it forms ferric chloride
(v) HCl is used in the manufacture of glucose from corn starch
(vi) Cl2O6 is best made by the action of ozone on ClO2
39. What is the percentage of SO3 by mass in 101.8 % oleum?
40. 3.55gm of bleaching powder when treated with acetic acid and excess of KI, liberated
iodine required 60mL of 0.5M sodium thiosulphate solution for the reaction. The
x
percentage of available chlorine in the sample is ‘x’, then is:
10

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Narayana IIT Academy 06-06-21_INC.SR.IIT_*CO-SC_JEE-ADV_WAT-45_KEY&SOL
CHEMISTRY
21. ClO2  paramagnetic
ClO2  bleaches 30 times more than chlorine
22. Though ClO2 is an odd electron it has the least tendency to dimerize, as the unpaired electron is less
localised on the central atom due to strong electronegativity of oxygen
24. BrF3  BrF2  BrF4
BrF3  SbF5  BrF2 SbF6
BrF3  CsF  Cs  BrF4
25. HClO 4  HBrO 4  HIO 4  acidity

26. 2AgClO3  Cl2 
0  2AgCl  2ClO 2 x   O 2
90 C
2ClO 2  2O3  Cl2O6  2O 2
 y
Cl2O6  2NaOH  NaClO3  NaClO 4  H 2O
4HClO 4  P4 O10  2Cl2O7  5HPO3
30.   sulphur is stable below 369K and transforms into   sulphur above this
31. 3Cl2  8 NH 3  N 2  6 NH 4Cl
33. CuCl2  catalyst
Cu 2  1 unpaired electrons
1 5
34. x  ,y 
2 8
1 2  4  n f
2  5  16  n f
35. Phosgene  COCl2
Tear gas  CCl3 NO 2
Mustard gas  ClCH 2 CH 2SCH 2 CH 2Cl
36. a  1, p  1
b  1, q  2
c  0, r  6
d  0,s  1
e  0, t  2
f  0, u  3
37. Au  4H   NO3  4Cl  AuCl4  NO  2H 2O
3Pt  16H   4NO3  18Cl  3PtCl62  4NO  8H 2O
40. CaOCl2  2CH 3COOH   CH 3COO 2 Ca  H 2O  Cl2
Cl2  2 KI  I 2  2 KCl
2 Na2 S 2O3  I 2  Na2 S 4O6  2 NaI

21 AC 22 ABD 23 ACD 24 ABC 25 ABD

26 ABC 27 ABD 28 AD 29 BD 30 ABC
31 8 32 5 33 3 34 4 35 7
36 3 37 7 38 4 39 8 40 3

JR.IIT_*CO SC Page 9
Narayana IIT Academy 26-03-22_JR.IIT_*CO-SC(MODEL-A)_JEE-ADV_WAT-45_Q’P
CHEMISTRY Max Marks:60
SECTION-I
(One or More options Correct Type)
This section contains 10 multiple choice equations. Each question has four choices (A) (B)(C) and (D) out of
which ONE or MORE are correct.
21. Which of the following statement(s) is /are correct?

A) Chlorine dioxide (ClO2 ) is powerful oxidizing agent but bleaching action is lower

than Cl2

B) ClO2 in alkaline solution undergoes disproportionation

C) ClO2 is diamagnetic in nature

D) ClO2 is a yellow gas but deep red liquid

22. Cl2 O6  NaOH  ?

A) NaClO4 B) NaOCl C) NaClO2 D) NaClO3

23. Predict product(s) in the following reaction,

Cl 2  OH  
hot
?

A) Cl B) ClO2 C) OCl D) ClO3

24. In the isolation of fluorine a number of difficulties were encountered. Which

statements are correct:

A) Fluorine reacts with moist glass vessels

B) Fluorine has great affinity for hydrogen

C) Electrolysis of aqueous HF gives ozonized oxygen

D) The potential required for the discharge of the fluoride ions lowest

25. Which reactions are used for the preparation of the halogen acid?

A) 2KBr  H 2SO4  K 2SO4  2HBr B) CaF2  H 2SO4  CaSO4  2HF

(conc.) (conc.)

C) NaCl  H 2SO4  NaHSO4  HCl D) 2KI  H 2SO4  K 2SO4  2HI

(conc.) (conc.)

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Narayana IIT Academy 26-03-22_JR.IIT_*CO-SC(MODEL-A)_JEE-ADV_WAT-45_Q’P
26. Which of the following statement(s) is /are correct for Halogens.

A) Halogen which is liquid at room temperature is bromine

B) The most electronegative element is fluorine

C) The most reactive halogen is fruorine

D) The strongest oxidising agent is iodine

27. The possible product(s) formed in the following reaction is /are:

IF5  H 2 O  ?

A) HIO3 B) HIO C) HIO 4 D) HF

28. If adsorption of a gas a solid is limited to monolayer formation, then which of the
following statements are true?
x
A) At low pressures, varies proportionately with p
m
x
B) At moderate pressures, varies less than proportionately with p
m
x
C) At high pressures, becomes independent of p
m
x
D) At high pressures, varies more than proportionately with p
m
29. Colloidal gold can be prepared by :
A) Bredig’s are method B) reduction of AuCl3
C) hydrolysis D) peptization
30. Colloidal solution can be purified by:
A) dialysis B) electrodialysis
C) electrophoresis D) ultrafiltration

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Narayana IIT Academy 26-03-22_JR.IIT_*CO-SC(MODEL-A)_JEE-ADV_WAT-45_Q’P
SECTION-II
(Integer Value Correct Type)
This section contains 10 questions. The answer to each question is a single digit integer, ranging from 0 to 9
(both inclusive).
31. For oxyacid HClO x , if x = y = z (x, y and z are natural numbers), then calculate the

value of | x  y  z | . Where x = Number of ‘O’ atoms

y = Total number of lone pairs at central atom

z = Total number of pi () electrons in the oxyacid

32. If hydrolysis of interhalogen compound can be represented by following general

reaction:

XYn1 
water
 n1HY  HXOn 2

If given interhalogen compound is polar and non – planar, then calculate value of

n1  n 2 .

33. How many colloidal systems exist in nature?

34. How many colloidal systems exist in nature in which liquid is dispersed phase?

35. How many colloidal system exist in nature in which gas is dispersed phase?

36. What is the minimum diameter (in nm) of colloidal particles?

37. For soaps critical micelle concentration (CMC) is 10  x (min). to 10  y (max.) mol/L.

What is the value of x?

38. How many lone pair(s) is /are present in central atom I of I3 ion?

39. How many water of crystallization is (are) present in the ore carnallite?

40. How many Cl – Cl bond(s) is /are present in Cl2 O7 ?

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 Narayana IIT Academy 26-03-22_JR.IIT_*COSC(MODEL-A) _WAT-45_Key&Sol’s
26. Conceptual
27. Conceptual
28. Conceptual
29. Conceptual
30. Conceptual
31. HClO2
xyz2
xyz 6
32. Conceptual
33. Eight gas colloidal system does not exists.
34. Aerosol, Emulsion, Gels.
35. Foam, Solid foam.
36. Size 1 nm
37. CMC of soap
104 M to 103 M
x=4
38. Conceptual
39. Conceptual
40. Conceptual
MATHS
41. g ( x )  1  ln x
1
42. ( x)  x  BD
f 21 22 AD 23 AD 24 ABC 25 BC
x
50. Find I  J and I  J
26 ABC 27 AD 28 ABC 29 AB 30 ABD
54.
31 6 32 8 33 8 34 3 35 2

36 1 37 4 38 3 39 6 40 0

CHEMISTRY
21. ClO 2 is powerful oxidising agent, also strong chlorinating agent. Its bleaching power is

almost 30 times strong than Cl2 . In alkaline solution undergoes disproportionation.

2ClO2  2NaOH  NaClO  NaClO3  H2O

Unpaired electron that’s why paramagnetic.

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Narayana IIT Academy 26-03-22_JR.IIT_*CO-SC(MODEL-B)_JEE-ADV_WAT-45_Q’P
CHEMISTRY Max Marks:60
SECTION-I
(One or More options Correct Type)
This section contains 10 multiple choice equations. Each question has four choices (A) (B)(C) and (D) out of
which ONE or MORE are correct.
21. The correct statement(s) about inter halogen compounds is/are

A) All are covalent molecules B) All are diamagnetic

C) All are more reactive than all halogens D) All these can under go hydrolysis

22. Which of the following reaction(s) is/are feasible?

1
A) Cl2  2 Br   2Cl   Br2 B) I 2  H 2O  2 H   2 I   O2
2
C) Br2  2 F 1  2 Br   F2 D) I 2  2 Br   Br2  2 I 

23. Among the property of halogen acids, that indicated correct statement(s) is/are

A) HF  HCl  HBr  HI : acidic strength B) HI  HBr  HCl  HF : reducing strength

C) HI  HBr  HCl  HF : bond length D) HI  HBr  HCl  HF : thermal stability

24. Which one of the following can give halogen when heated with acidified KMnO4
solution?

A) HF B) HCl C) HBr D) HI

25. HI can be prepared by which of the following methods

A) Pl3  H 2O  B) KI  ConcH 2 SO4  C) H 2  I 2 

Pt
 D) I 2  H 2 S 

26. Which of the following statement(s), is/are correct?

A) All oxoacids of chlorine undergo disproportionation on heating

B) CIO2 does not dimerise

C) Six Cl  O bonds in Cl2O7 are the same

D) Rb  ICI 2  on heating produces RbI  CI 2

27. The possible product(s) formed in the following reaction is/are: IF5  H 2O 

A) HIO3 B) HIO C) HIO4 D) HF

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Narayana IIT Academy 26-03-22_JR.IIT_*CO-SC(MODEL-B)_JEE-ADV_WAT-45_Q’P
28. Among the following, the surfactant that will form micelles in aqueous solution at the
lowest molar concentration at ambient conditions is

A) CH3(CH2)15N+(CH3)3Br− B) CH3(CH2)11OSO3−Na+

C) CH3(CH2)6COO−Na+ D) CH3(CH2)11N+(CH3)3Br−

29. Select the adsorption isobar for chemical adsorption

A) B)

C) D)

30. Choose the correct reason(s) for the stability of the lyophobic colloids

A) Preferential adsorption of ions on their surface from the solution

B) Preferential adsorption of solvent on their surface from the solution.

C) Attraction between different particles having opposite charges on their surface.

D) Potential difference between the fixed layer and the diffused layer of opposite
charges around the colloidal particles.

SECTION-II
(Integer Value Correct Type)
This section contains 10 questions. The answer to each question is a single digit integer, ranging from 0 to 9
(both inclusive).
31. When Cl2 reacts with cold, dilute NaOH solution, the salt of oxyacid X and another salt
Z are formed along with colourless liquid, which give blue colour with anhydrous
CuSO4 .

Z gives a white precipitate with AgNO3 . The oxidation state of chlorine in Y is

________.

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Narayana IIT Academy 26-03-22_JR.IIT_*CO-SC(MODEL-B)_JEE-ADV_WAT-45_Q’P
32. How many of different oxidation state can be shown by fluorine when it combines
with other elements? (neglect free state)

33. The number of lone pairs of electrons present on chlorine in CIF3 is:

34. How many compounds from the following list undergo dimerisation as mentioned:
NO2 (in solid state)

ClO2 , BeCl2 (in solid state)

BeCl2 (in vapour state)

BeH 2 (in solid state)

AlCl3 (in vapour state)

CH 3COOH (in solvent water)

CH 3COOH (in solvent benzene)

AlCl3 (in inert organic solvent)

35. How many halogens can form a compound of type KHX 2 ?( X  halogen)

36. 3.55g of bleaching powder when treated with CH 3COOH and excess of potassium
iodide liberated I 2 which required 60mL of 0.5N hypo solution. If the percentage of
available chlorine in the sample is 6 x %, then the value of x is.

37. If F2 is passed through cold dilute NaOH , a pale yellow gas is obtained. Then the
oxidation state of less electronegative element in that pale yellow gas is:

38. Addition of 4.0 mL of 0.005 M BaCl2 solution to 16.0 mL of arseneous sulphide sol

just causes the complete coagulation. Find out the flocculating value of the effective
ion.

39. 10% sites of catalyst bed have absorbed by H2 . On heating H2 gas is evolved from
sites and collected at 0.03 atm and 300 K in a small vessel of 2.46 cc. Number of sites
available is 5.4  1017 per cm2 and surface area is 100 cm2. Find out the number of
surface sites occupied per molecule of H2 . (Given N A  6  1023 )
40. Number of Hybrid orbitals on the central atom in I 3 is

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Sec: JR.IIT_*CO SC(MODEL-B) WAT-45 Date: 26.03.22
Time: 3 HRS 2014_P1 Max. Marks: 180
KEY SHEET

CHEMISTRY
21 ABD 22 A 23 BCD 24 BCD 25 ACD

26 BC 27 AD 28 A 29 C 30 AD

31 1 32 1 33 2 34 5 35 1

36 5 37 2 38 1 39 3 40 5

CHEMISTRY
21. less reactive than F
22. Oxidizing power: F2  Cl2  Br2  I 2
23. F2 is the strong oxidising agent among halogens due to

a) high heat of hydration

b) low bond dissociation energy
24. HF cannot be oxidised
25. 3KCIO3  3H 2 SO4  2CIO2  3KHSO4  H 2O

26. HCIO2 , HCIO3 : undergoes disproportionation Rb  ICI 2  

 RbCl  ICI

27. Hydrolysis of interhalogen compounds gives halide and oxohalide ions. Note that the
oxohalide ion is always formed from the larger halogen present. IF5  H 2O  HF  HIO3
28. Larger the hydrophobic part lower is CMC
29. Conceptual
30. Conceptual
31. Cl2  2NaOH  NaCl  NaOCL  H 2O

32. ‘F’ shows only -1 oxidation state

33. sp 3 d hybridised chlorine, 2 lone pairs near central atom
Narayana IIT Academy 26-03-22_JR.IIT_*COSC(MODEL-B) _WAT-45_Key&Sol’s
34. NO2 (in solid state), BeCl2 (in solid state), BeH 2 (in solid state), CH 3COOH (in solvent

benzene), AlCl3 (in inert organic solvent)

35. Only KHF2 exists.
60  0.5  35.5
36. % of available chlorine   30
1000  3.55
37. F2  NaOH  OF2  NaF  H 2O

4  5  103  103
38.
20
39. Conceptual
40. SP3d hybridization
MATHS
41. g(x)  ln(1  x)
1
42. f ( x)  x 
x
50. Find I  J and I  J
54.

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Narayana IIT Academy 31-05-20_Incoming.Sr.IIT_*CO SC_JEE-Adv_WAT-46_Q’P
CHEMISTRY Max.Marks:62
SECTION – I
(MULTIPLE CORRECT CHOICE TYPE)
This section contains 8 multiple choice questions. Each question has 4 choices (A), (B), (C) and (D) for its
answer, out of which ONE OR MORE is/ are correct.
Marking scheme +4 for correct answer , 0 if not attempted and -1 in all other cases.
19. Among the inerhalide/halogen species IF2 ,IF3 ,IF4 ,IF5 and IF7 ; incorrect statement(s)
is/are:

A) None of the given species contain at least one lone pair on the central atom

B) One of the anionic species is isoelectronic and isostructural to XeF2 and the other
anionic species is isoelectronic and isostructural to XeF4

C) One of the given species contain angular separation between fluorine atoms is 600

D) In the given species all iodine centres are either sp3d or sp3d 2

20. Which of the following reaction(s) is/are feasible?

A) Br2  2KI  I 2  2KBr B) Cl2  2NaBr  Br2  2NaCl

C) I 2  2KCl  Cl2  2KI D) I 2  2KF  F2  2KI

21. Which of the following changes will occur when NO 2 is passed into a dark red liquid
of Cl2O6 ?
A) NO 2 undergoes disproportionation
B) Cl2O 6 undergoes disproportionation
C) It form nitronium perchlorate salt
D) ClO 2 is liberated
22. Which of the following is/are correct order(s) regarding the hydrogen halides?
A) HF > HI > HBr > HCl – Melting point
B) HI > HF > HBr > HCl – Boiling point
C) HF < HCl < HBr < HI - pK a values
D) HF > HCl > HBr > HI – Dipole moment
23. Hydrolysis of ClF3 gives

A) HOCl B) HCl C) HF D) HClO 2

Narayana IIT Academy 31-05-20_Incoming.Sr.IIT_*CO SC_JEE-Adv_WAT-46_Q’P
24. Which of the following statement(s) is/are correct?

A) When HCl reacts with finely powdered iron, it forms ferric chloride and H 2

B) Both OF2 and O 2 F2 acts as fluorinating agents

C) ClO 2 is used as a bleaching agent for paper pulp and textiles

D) I 2O5 is a good oxidizing agent and is used in the estimation of CO

25. Which of the following is/are correct regarding the anomalous behaviour of fluorine?

A) its small size

B) highest electronegativity

C) availability of d – orbitals in valence shell

D) high F – F bond dissociation enthalpy

26. The correct statement(s) about the oxoacids HClO 4 and HClO, is(are)

A) The central atom in both HClO 4 and HClO is sp3 hybridized

B) HClO 4 is formed in the reaction between Cl 2 and H 2O

C) The conjugate base of HClO 4 is weaker base than H 2O

D) HClO 4 is more acidic than HClO, because of the resonanace stabilization of its anion

SECTION – II
(Numerical Value Answer Type )
This section contains 6 questions. The answer to each question is a Numerical values comprising of
positive or negative decimal numbers (place value ranging from Thousands Place to Hundredths
place).
Eg: 1234.56, 123.45, -123.45, -1234.56, -0.12, 0.12 etc.
Marking scheme : +3 for correct answer, 0 in all other cases.
27. Cl 2 is prepared by the action of HCl on KMnO 4

2KMnO 4  16HCl  2KCl  2MnCl 2  8H 2O  5Cl 2

If ‘M is the gram molecular weight of HCl, then its gram equivalent weight is 'x  M ' .

The value of ‘x’ is:

Narayana IIT Academy 31-05-20_Incoming.Sr.IIT_*CO SC_JEE-Adv_WAT-46_Q’P
28. Reaction of Br2 with Na 2CO3 in aqueous solution gives sodium bromide and sodium
bromated with evolution of CO 2 . The number of sodium bromide molecules involved in
the balanced chemical equation is:

29. A sample copper(II) ore weighing 2gm is dissolved in acid and copper is completely
electrolysed for 9.65 minutes by using a constant current of 2 amp. The % of Cu in the
sample is:

30. ‘X’ is the catalyst used in the manufacture of chlorine by Deacon’s process. The spin
only magnetic moment of the cation in ‘X’ is:

31.
Oxoanion Bond
order
ClO2 P

ClO4 Q

Then  P  Q  is:

32. The molar conductance of NH 4Cl solution at infinite dilution is 150cm 2 mol1 and the
ionic conductance of OH and Cl at infinite dilution are 200 and 80 S.cm2 .mol1
respectively. If the molar conductance of a 0.01M solution of NH 4OH is 13.5 Scm 2 mol1
, what will be degree of dissociation of NH 4OH ?
SECTION-III
(MATCHING LIST TYPE)
This section contains 4 questions, each having two matching lists (List-1 & List-II). The options for the correct
match are provided as (A), (B),(C) and (D) out of which ONLY ONE is correct.
Marking scheme: +3 for correct answer, 0 if not attempted and -1 in all other cases.
Answer Q.33 and Q.34 by appropriately matching the lists based on the information
given in the paragraph.
List – I(Reaction) List –
II(products)
(I) 2AgClO3  Cl2  (P) Cl2O 6
(II) 2ClO 2  2O3  (Q) ClO 2
(III) 2HClO 4  P4O10  (R) O2
(IV) 2HgO  2Cl2  (S) Cl2O
(T) Cl2O 7
(U) Cl 2
Narayana IIT Academy 31-05-20_Incoming.Sr.IIT_*CO SC_JEE-Adv_WAT-46_Q’P
33. Which of the following options has the correct combination considering List – I and
List – II?
A) (I),(Q) B) (I),(S) C) (III),(T) D) (III),(R)
34. Which of the following options has the correct combination considering List – I and
List – II?
A) (II),(P) B) (II),(U) C) (IV),(S) D) (IV),(R)

Answer Q.35 and Q.36 by appropriately matching the lists based on the information
given in the paragraph

List – I List – II
(I) Conductivity(k) (P) Depends on cell constant as well as on
concentration of electrolyte
(II) Molar conductance (Q) Depends on electrodes used
 M 
(III) Conductance(G) (R) Increase with dilution and independent on cell
constant
(IV) E 0cell of galvanic cell (S) Decrease with dilution and independent on cell
constant
(T) Intensive property
(U) Extensive property

35. Which of the following options has the incorrect combination considering List – I and

List – II?

A) (IV),(Q,T) B) (IV),(Q,U) C) (II),(R) D) (I),(S)

36. Which of the following options has the correct combination considering List – I and

List – II?

A) (I),(R) B) (II),(S) C) (III),(Q) D) (III),(P)

Narayana IIT Academy 31-05-20_Incoming.Sr.IIT_*CO SC_JEE-Adv_WAT-46_Key & Sol’s

CHEMISTRY
 
19. IF  3LP;IF3  2LP;IF : 2LP;IF5 :1LP;IF7 : zero LP
2 4
20. Fluorine > Chlorine > Bromine > Iodine – oxidizing power
21. NO 2  Cl2O6  ClO 2  NO 2 ClO4  
22. HI > HF > HBr > HCl – melting point
HF  HI  HBr  HCl - boiling point
23. ClF3  H 2O  HF  HClO 2
24. HCl  Fe  FeCl 2  H 2
25. i) its small size ii) highest electronegativity
iii) absence of d – orbitals in the valence shell
iv) low F – F bond dissociation enthalpy
26. Cl 2  H 2O  HCl  HClO
27. 2  5  16  n  factor
28. 3Br2  3Na 2CO3  5NaBr  NaBrO3  3CO 2
M
29. w   ct
nF
63.5  2  9.65  60
  0.381
2  96500
0.381
% of copper =   100  19.05
2
30. Catalyst is CuCl 2
31. P=1.5 and Q=1.75
m
32.  
 0m
33 & 34.
2AgClO3  Cl2  2AgCl  2ClO 2  O 2
2ClO 2  2O3  Cl2O6  2O 2
4HClO 4  P4O10  2Cl2O 7  4HPO3
2HgO  2Cl2  HgO.HgCl2  Cl2O

19 ACD 20 AB 21 BCD 22 CD 23 CD

24 BCD 25 AB 26 ACD 27 1.6 28 5

29 19.05 30 1.73 31 3.25 32 0.05 33 B

34 A 35 B 36 D