Sec: JR.

IIT_*CO SC(MODEL-A) WAT-39 Date: 27-01-25

Time: 3 Hrs 2020_P1 Max. Marks: 198
KEY SHEET
MATHEMATICS
1 A 2 B 3 A 4 B 5 C

6 B 7 ABD 8 ABCD 9 ABD 10 BC

11 AC 12 AB 13 8 14 7 15 4

16 6 17 3.20 18 6

PHYSICS

19 B 20 D 21 C 22 A 23 B

24 D 25 AC 26 ABC 27 ABCD 28 ABCD

29 ACD 30 CD 31 01.60 32 01.50 33 60.00

34 20.00 35 80.00 36 02.00

CHEMISTRY

37 D 38 A 39 D 40 A 41 C

42 B 43 ACD 44 BCD 45 BC 46 ABC

47 ABCD 48 BCD 49 9.88 50 25.00 51 8.00

52 3.00 53 5.00 54 245.11

Narayana IIT Academy 27-01-25_ JR*CO-SC_JEE-ADV_(MODEL-A)_WAT-39_KEY& SOL
SOLUTIONS
MATHEMATICS
(a) Given parabola y  4 x .....(i )
2
1.
So, equation of tangent to parabola (i) at point (1,2) is 2 y  2( x  1)
[ equation of the tangent to the parabola y 2  4ax at a point ( x, y1 ) is given by
yy1  2a ( x  x1 ) ]
 y  x  1 ….. (ii)
Now, equation of circle, touch the parabola at point (1,2) is
( x  1) 2  ( y  2) 2   ( x  y  1)  0
 x 2  y 2  (  2) x  (4   ) y  (5   )  0 (iii )
Also, circle (iii) Touches the X-axis, So g  c
2

2
 2
  5
 2 
  2  8  16  0
8  64  64
 
2
2
  4 44 2
32
Now, radius of circle is
r  g2  f 2  c
 r f
 g 2  c 
  4 84 2 84 2
  or
2 2 2
84 2
For least area r 
2
 4  2 2 units

So, area   r   16  8  16 2
2

 
 8 3  2 2 sq units
Tangent to the parabola y  4 x
2
2.
1
y  mx 
m

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Narayana IIT Academy 27-01-25_ JR*CO-SC_JEE-ADV_(MODEL-A)_WAT-39_KEY& SOL

Which is also tangent to the point

 pr
1
2m 
m 1
1  m2

 1  2m 2  m 1  m 2
 4m2  4m2  1  m2  m2  1
 3m2  5m2  1  0
5  25  12 5  13
 m2  
6 6
4
5 10
Required Sum   mi  4  
2

i 1 6 3
 3p  4 4  3p 
3. Let circumcentre is  .
 2 p 2q 
Let circumcentre be  h, k 
3p  4 4
h  p
2p 2h  3
4  3p 4h  12
k q
2q k  2h  3

Now, p  4q
2

2
 9 1 9
h    k  
 4 2 8
2
 9 1 9
Locus  x     y  
 4 2 8
4. The shortest distance is along the common normal.

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5. A  (a,0), H  (0, 2at  at ), G  (2at  at 2 ,0), Q  (h, k )
3

(h, k )  (2a  at 2 ,2at  at 3 )

Eliminating ' t ', x  2ax  ay
3 2 2

6. Any point on the line x  y  1 is P(t ,1  t )

Equation of the chord whose mid point is P is T  S1 and it passes through ( a, 2a )
Normal is x  yt  2at  at cuts parabola at (0,0)(1,1) & (1,1)
2
7.
8. y  mx  2m  m3
  m  m3

f ( m)  m  m3

 
f '  1  3m 1  3m 
Now check options.
2 2
9. Let P(2t1 , 4t1 ) and Q (2t 2 ,4t2 )
if chord joining P(t1 ) and Q (t2 ) passes through
 Normals at P and Q intersect on parabola at R(18, 12)
which is on the parabola
 t1t2  2, t1  t2  t3  0
 t3 or R is 3
 t1  t2  3
2
1
10. a  8b  a  8.   a 2  2
2 2 2

2
Locus is x  2 y  12  0
2
11.
12. Conceptual
13. Clearly ABCD is a rectangle co-ordinate of B (t1t2 ,(t1  t 2 ))

AB  (t2  t1 ) 1  t12
BC  (t2  t1 ) 1  t22
Area = AB  BC  (t2  t1 ) (1  t12 )(1  t22 )
2

14. Length of tangent =   7

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Narayana IIT Academy 27-01-25_ JR*CO-SC_JEE-ADV_(MODEL-A)_WAT-39_KEY& SOL
The point P( x0 , y0 ) lies on the parabola y  x , so y0  x0 . Equation of the tangent at
2 2
15.
A( x0 , y0 ) is therefore
y  y0
 xx0  y  x02  2 xx0
2

Which meets the y  axis at B(0,  x0 ) and the line y  x0 at A itself. Let AC be the perpendicular
2 2

from A to y  axis. Then the coordinate of C are (0, x0 )

2

 Required area of triangle ABC is

1 1
  ( BC )( AC )  (2 x02 )( x0 )  x03
2 2
 is an increasing function of x0 and x0  [1, 4]
Thus the area has the greatest value when x0  4
a
16. y  mx 
m
y  mx  2am  am3
a
   2am  am  
3 2
m 2
 1
d  
m
a
1  m2 m 1  m2

a
1  m  2
1  m2
; put m  tan 
m

sec2  .sec
a  a (sec2  .cos ec )
tan 
Put a  2 and   300
4 16
d  2. .2 
3 3
17. K1  16 & K 2  16
18. y 2  a ( x  4a )

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PHYSICS

2
19. q  C  q   C0V0
3

1 2  2
 q1    C0V0   C0V0
3 3  9
2
 U 3  C0V02
81
20.

 0ldy  0ldy
dC1  k1 , dC2  k1
y tan  d  y tan 
 k1 k2 
 0ldy   
 dC 
dC1  dC2
  y tan  d  y tan  
dC1  dC2 k1 k2

y tan  d  y tan 
 dy 
 dC  k1k2 0l  
 k1d  y tan  k2  k1 
k1k2 0l
l
dy
ln k1d  y tan   k2  k1 0
l
 C  k1k2 0l  
k d  y tan   k2  k1   k2  k1  tan 
0 1

k1k2 0l 2 k 
 ln  2 
 k2  k1  d  k1 
 A
21. Let C0  0 
d
Initial:

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Narayana IIT Academy 27-01-25_ JR*CO-SC_JEE-ADV_(MODEL-A)_WAT-39_KEY& SOL

3C0 2
 Vi  V
4
Final:

1
 U f  C0V 2
2
1
 Wbattery  Wagent  U   C0V 2
4
1  CV 1
 Wagent   C0V 2  V  0   C0V 2
4  2  4
22.

Applying loop rule twice:

yx x
V  0
C C
y yx
& 2V   0
C C
 2x  y  CV … (1)
& 2 y  x  2CV … (2)
4CV 5CV
x &y
3 3
2
4CV
 WV 
3
10CV 2
&W2V 
3
23. Let the distance between centre of cloud and  q be d

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Narayana IIT Academy 27-01-25_ JR*CO-SC_JEE-ADV_(MODEL-A)_WAT-39_KEY& SOL
1 qd
E
4 0 a03
 p  qd  4 0 a03 E
   4 0 a03
 0lV 2  0lV 2 (k  1)
24. F  k  1  a 
2d 2md
2
l 1 T 
  .a. 
3 2 4
2l 4lmd
T  4 4
3a 3 0lV 2 (k  1)
md
T 8
3 0 (k  1)V 2
25.

Upper branch:
Q
 E0
k0C0 d
Q E
 0
2k0C0 d 2
 Q0  k0C0 E0.d … (1)
Lower branch:
2Q0 2Q0
 E0 &  2 E0
2k0C0 d 4k0C0 d
 Q0  k0C0 E0 d … (2)
 Q0  k0C0 E0 d  Q  3Q0  3k0C0 E0 d

1
26. Step ' a ' : Heat = CV 2  72 J
2
Step ' b ' :

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1
 8  4  2   J  24 J
2
 Final energy =
2
 Loss = 72  24  J  48  J
 Total loss = 120  J
Step ' c '

 charge supplied by battery = CV  initial

= k2C2V  8C
= 88C
 Wbattery  88  6  J  528 J
 Heat = 528  U final  U initial 
1 1 
= 528    16  36   4  4   J
2 2 
= 528  280  J  248 J

27. E points along x axis  z axis is equipotential.
Also if k1  k2  E is uniform throughout  y axis is equipotential.
 V
For lower half, E is uniform  V  0 between the two given points.
2
Let C0 : capacity without di-electrics
C
 C1  k1C0 , C2  k2C0 , C3  k3 0
2
kk C k
 Ceff  1 2 0  3 C0
k1  k2 2
28. By symmetry, C13  C24 & C12  C34
C12 : By symmetry, 15 & 52 would be in series.
Similarly, 45 & 53 would be in series.

C 3C
3C 2  2
 C12  
2 2C

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3C 3C
= 
2 8
15C

8
C15 :V2  V4 by symmetry
 54 & 52 are in parallel. Also, 14 & 12 are in parallel.

8C
2C 
 C15  3  C  15C
14C 7
3
29. Since potential difference is same, whether we see upper half or lower half
 expression of E will be same.
1
Also, since dielectric reduces E to times
k
k1
 qupper half  q
k1  k2
30. Let Cab  C0

C0
2C.
 2  C  C  2CC0  C  C
C 0
4C  C0 2
0
2C  0 2
2
 4CC0   4C  C0  2C0  C   8CC0  4C 2  2C02  C0C
 2C02  3CC0  4C 2  0
3C  9C 2  32C 2 41  3
 C0   C
4 4
2C 2C 41  3
 Q(1)  .C0V  . CV
C0 41  3 4
2C  2C  C
2 8


4  
41  3 CV

 41  15 
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   CV & Q  
2
 2 41  3
41  3 2 41  3 C
 Q(2)  (3)  . V.
 41  15  4 41  15 2
 


 41  3  .CV
4 41  15 
31.

0 A
2 0 A 
C1  
d d
 d 

4 4   CNet  C1C2  1.6  0 A
 A 8 A  C1  C2 d
C2  2  0  0 
d d

4 
32. Ans: 01.50
E0 b
Sol: E  E0 ln    V0
r a
( a b )/2
E0 1 b 
Also, Vrequired  a
r
dr  E0 ln   
 2 2a 
V0 1 b 
 .ln   
ln(b / a )  2 2a 
V0 3
 .ln  
ln 2  2 
33. Let E2  E0  E1  2 E0
d d
Also, E1.  E2 .  18 volts
2 2
3
 E0 d  18
2
 E0  6000 v / m
By Gauss’s law:    E2  E1 
   0 E0
  6000  0
34. Initial:

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1
 2 F 10V   100 J
2
Ui 
2
Final:

1
 6 F 10V   300 J
2
Uf 
2
Also, work done by battery
    .VBattery
  40 C  .10V   400  J
 Heat  WBattery  U
 400   300  100   J
 200  J
 0 .4 r 2
35. dc  k .
dr
1 1 dr 1 dr
  
4 0 kr 2 4 0  kr 2

C dC
1
 ln  b / a 
4 0 k0
1
 ln 1.05 
4 0 k0
1

80 0 k0
36.

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1  
     charge
Electric force on top layer of the liquid =
2 0  k
1  1  1
 A.h.  .g =  1   1   . A
2 0  k   k 
 2  k 2  1
h 
2 0  k 2
CHEMISTRY
1
37. K a  C 2   2  K a 
c
38. Number of moles of H 2 SO4 present in the battery initially = 8 moles
1.93  20  60  60
Charge drawn from the battery   1.44 F
96500
Pb  PbO2  2 H 2 SO4  2 PbSO4  2 H 2O
For consumption of 2 moles of H 2 SO4 , the charge drawn is 2 Faradays
Number of moles of H 2 SO4 consumed =1.44
Number of moles of H 2 SO4 left  8  1.44  6.56
6.56
Concentration of H 2 SO4 left in the battery   3.28 M
2

31014
AgA( s)  Ag  (aq )  A (aq)
39.
( s1  s2 ) s1
 Ag  ( aq )  B  ( aq )
AgB ( s ) 
110 14

( s1  s2 ) s2
14
s1 ( s1  s2 )  3  10      (1)
s2 ( s1  s2 )  1  1014      (2)
7
Solving, we get; s1  1.5  10 M ; s2  0.5  10 7 M
  A   s1  1.5  10 7 M ;  B    s2  0.5  107 M ;  Ag    ( s1  s2 )  2  107 M
   1000    1000
 Ag    Ag   60  Ag 7
   Ag    120  1010 Scm 1
   Ag  2  10  

  1000   1000
 A   A     A   120  1010 Scm1
 
  80  A 7 
   A  1.5  10  

 Ag    A   B   375  10 10
(120  1010 )  (120  1010 )   B   375  1010   B  (375  240) 1010  135  1010
 B  1000 (135  1010 )  1000
 B  

  7
 270 Scm 2 mol 1
  B   0.5  10
40. m  HA  m  NaA  m  HCl   m  NaCl 
 83  426  126  3831cm 2 mole1

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  1000 5
3.83  10 1000
mc    38.3
m 103
mc 38.3
Degree of dissociation,     0.1
m 383
 H    c  1103 101  1104 M ; pH  4 .

41. For AgCl ,   3.4  106  2.02  106  1.38  106 ohm 1 cm 1
  1000 1.38  106  1000
m.   138   s  105 mol.lit 1  143.5  105 g lit 1
s s
127.08
42. Number of Equivalents of Cu deposited  4
31.77
Number of Equivalents of Oxygen gas liberated = 4
Mass of Oxygen gas liberated  4  8  32 grams
C3 H 8  5O2  3CO2  4 H 2O
43. Hg 22  NO3  3H   2 Hg 2  HNO2  H 2O
1
Q 3
(Assuming unit active mass for all other species)
 H 


0.06
log  H    0.02  0.03  3    log[ H  ]
3
ECell  0.02 
2
2
 0.02  0.03  3   0 V
9
Number of equivalents of Hg 2  0.6  1  0.6 F charge
2  965
46. Charge passed   0.02 F
96500
The equivalents of Chlorine or hydrogen liberated = 0.02
49. Let the mass of Na deposited = x gm
x 120
 100  12  x  gm
10  x 88
M ct 120 23  9.65  t
w    t  9.88 min
zF 88 96500
  1000 1 1000  54
50. eq.     200 S cm 2 eq 1
N 18 15
 c
200
  eq0   0.25
eq 800
The percentage of dissociation  0.25  100  25%

4  9650
51. No. of Faradays   0.4 F
96500
At anode, H  formed = 0.4 moles

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Narayana IIT Academy 27-01-25_ JR*CO-SC_JEE-ADV_(MODEL-A)_WAT-39_KEY& SOL
2  
HPO 4  H  H 2 PO 4
2 0.4 2
2  0.4 0 2  0.4
[ HPO42 ]
pH  pK a2  log
[ H 2 PO4 ]
1.6
pH  8.18  log  8.18  (0.48  0.30)  8.18  0.18  8
2.4
52. Ag   e  Ag
0.06
E  E0  log  Ag  
1
0.5  0.8  0.06log  Ag  

0.5  0.8
 Ag     5   Ag    105 M
0.06
105  350  108  100
% of Ag in the sample =    3
 3%
 1000  12.6  10
53. The cell reaction is
MnO42  5Fe 2  8H   Mn 2  5Fe3  4 H 2O
0
ECell  1.51  0.78  0.73 V
0.06
0
ECell  0.73  log[ H  ]8  0.73  0.48  0.25V
5
54. ECell  0.4  ( 0.87)  1.27 V
0

The maximum amount of electrical energy that can be obtained

  G 0  nFECell
0
 2  96500  1.27  103  245.11kJ

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